VIN K THUT HA HC

B MN CNG NGH HU C-HA

DU

TM HIU XC TC CCR
GVHD:PGS.TS.Phm Thanh Huyn
Nhm sinh vin thc hin: Nhm 2
H v tn
1. Bi Vn Thanh
2. Trn Th Phng
3. Phm Thi Loan
4. Nguyn Cng Sn
5. L Mnh Linh
 NI DUNG CHNH
TIU LUN XC TC CCR
1 LCH S HNH THNH XC TC CCR

2 THNH PHN & CHC NNG XC TC CCR

3 PHNG PHP IU CH XC TC

4 NGHIN CU CC C TRNG XC TC CCR

5 NGUYN NHN GIM HOT TNH XC TC &

6 CCH KHC PHC
66 QUI TRNH CNG NGH TI SINH XC TC CCR
3
77 THU HI V X L XC TC THI
GII THIU V QU TRNH
REFOMING XC TC ( CCR)

Reforming xc tc :
Naphten, parafin hydrocacbon thm c tr s octan cao
Nguyn liu:
Phn on xng chng ct trc tip
t du th
Nh qt lm sch bng hydro => s
dng xng ca cc qu trnh lc du
khc (nh xng ca qu trnh cc ha,
xng cracking nhit...).
Sn phm:
Xng c tr s octan cao
Cc hydrocacbon thm
Kh hydro k thut
GII THIU V QU TRNH REFOMING
XC TC ( CCR)

V tr phn xng CCR trong nh my lc du

I. LCH S HNH THNH XC TC CCR

MoO2/Al2O3 R tin, bn vi S
1940 Hot tnh thp =>T cao, P thp
Lp xt c nh
Pt /Al2O3 Hot tnh xt ci thin, P=70 bar
1949 S dng vi thng
c clo ho
Xt 1 chc KL Hot tnh tng, P=30 bar
1950 Pt/silice alumine Gi thnh gim
2003
Xt 2 chc KL bn cao, P=10 bar.
1960 Thm Sn, Re Chng li s to cc
Ti sinh lin tc Xc tc t b cc ho, P gim
1970
xc tc Hiu sut tng
Platforming 2 Hao ht xc tc t (0,02 %m)
1988
ti sinh lin tc P gim => hiu sut tng
New Reforming Tnh chn lc cao.
1997 S dng Zeolit => Tng Ar mt vng
II. THNH PHN & CHC NNG XT CCR

1. Thnh phn xc tc CCR

Xc tc ca phn xng CCR trong nh my lc du Dung Qut:

STT Tn thng mi Hng cung cp

1 R-134 (hoc R-234) UOP-M

2 Diethyl sulphide (DES) ELF Atofina-Singapore

Thnh phn xc tc:

Tm hat ng kim lai: 0,2-0,6 % Pt.

Cht mang v tm hat ng acid: - Al O c clo ha lin tc vi

2 3
HCl, C2H4Cl2, CH3Cl, . . .
Cc kim loi ph gia nh: Re, Sn, Ir, Ge (cc cht xc tin)
II. THNH PHN & CHC NNG XT CCR

1. Thnh phn xc tc CCR

ng knh : 1.6 mm
KLR: 560 kg/m3
Khi lng Pt: 0,29% m
Clo s dng ti sinh xc
tc : 1.1-1.3% m
Tui th ca xc tc : 6
nm

Hnh dng xc tc
II. THNH PHN & CHC NNG XT CCR

2. Chc nng ca xc tc lng chc

Chc oxy ho - kh (chc kim

loi ): kim loi dng phn tn
nhm tng cng cc phn ng
hydro ho, dehydro ho
Chc acid: oxyt nhm c b mt
ring ln v c clo ha iu
chnh lc axit thch hp nhm tng
cng cc phn ng alkyl ho,
isomer ho, cracking
II. THNH PHN & CHC NNG XT CCR

2. Chc nng ca xc tc lng chc

a. Chc kim loi:
Kim loi Pt c a vo xc tc l dng dung
dch H2(PtCl6). Platin c chc nng:
Oxy ho-kh xc tin cho phn ng oxy ha,
dehydro ha to hydrocarbon vng no v vng thm.
Thc y qu trnh no ho cc hp cht trung gian, lm gim tc to

thnh cc bm trn xc tc.

Hm lng Pt vo khong 0,2-0,6%m.

Yu cu Pt phi phn tn u trn b mt cc acid rn.

II. THNH PHN & CHC NNG XT CCR

Cc qu
trnh
chuyn
ha
ch yu
ca cc
paraffine
xy ra
trn b
mt cht
xc tc
II. THNH PHN & CHC NNG XT CCR

2. Chc nng ca xc tc lng chc

b. Chc acid:
Al O l cht mang c tnh acid, c chc nng acid- base:
2 3

Thc y phn ng isomer ha, hydrocracking.

S dng - Al O b mt ring khong 150-250 m2/g.
2 3

tng acid cho xc tc, ngi ta tin hnh clo ha thng qua s
dng cc hp cht halogen nh HCl, C2H4Cl2, CH3Cl, . . .
II. THNH PHN & CHC NNG XT CCR

Cc phn ng xy ra trn xc tc tm axit

II. THNH PHN & CHC NNG XT CCR

2. Chc nng ca xc tc lng chc

c. Vai tr ca kim loi ph gia

Cc kim loi ph gia nh

Re, Sn, Ir, Ge (cn gi l
cc cht xc tin) lm
tng tc phn ng
dehydro ha v dehydro
vng ha (c bit vng
p sut thp) ca h xt
lng kim so vi xc tc
ch cha Pt.
nh hng ca kim loi th 2 n qu trnh
dehydro ha Cyclohexan
II. THNH PHN & CHC NNG XT CCR

2. Chc nng ca xc tc lng chc

c. Vai tr ca kim loi ph gia

vng p sut thp, cc

kim loi ph gia cng
ng vai tr quan trng
trong vic gim tc
cracking v hydro phn
(hydrogenolysis) t
lm gim kh nng to
cc v tng hiu sut sn
phm chnh.
II. THNH PHN & CHC NNG XT CCR

2. Chc nng ca xc tc lng chc

c. Vai tr ca kim loi ph gia
Hai h xc tc Pt-Sn v Pt-Re t
ra u vit hn c, cho php lm
vic P thp (<10 atm) m vn
bo m hot tnh dehydro ha v
dehydro ng vng ha cao.
Ring h xc tc Pt-Sn hi c
bit, ch th hin hot tnh cao
vng p sut thp. Ln hn 5 atm,
h xc tc ny khng pht huy
c tc dng tch cc so vi Pt
v cc h lng kim khc
II. THNH PHN & CHC NNG XT CCR

2. Chc nng ca xc tc lng chc

c. Vai tr ca kim loi ph gia
Chc nng Re: thay i c ch to cc v c tc dng bo v kim loi

chnh Pt v lm tng bn v tui th xc tc, t lm tng chu k

hot ng ca xc tc.
Chc nng Sn : lin kt vi Pt lm thay i c ch phn ng theo

hng c li. Cho hiu sut v la chn theo reformat cao iu kin
p sut thp (< 5 atm). Nhc im: loi xc tc ny km bn hn so vi
xc tc cha Re.
Vi cc c im trn, ngi ta thng s dng Re trong cng ngh

bn ti sinh v Sn trong cng ngh ti sinh lin tc (CCR).

II. THNH PHN & CHC NNG XT CCR

2. Chc nng ca xc tc lng chc

c. Vai tr ca kim loi ph gia

Mt s xc tc lng kim mi ca cc hng xc tc ln trn th gii

III. PHNG PHP IU CH
XC TC CCR

m bo cho cht mang, -Al2O3 cn c cc tnh cht sau:

Cu to: Tnh cht c hc:

+ T trng ht: 1.1 g/cm3 T trng nhi: 0.6-0.7 g/cm3
+ B mt ring: 180-220 m2/g Kch thc ht: 1-2 mm
+ Tng th tch l xp:0.60 Lc nghin nt > 1 MPa
cm3/g

Hm lng tp cht cho php:

Na < 50 ppm
Fe < 200 ppm
III. PHNG PHP IU CH
XC TC CCR

Cc bc iu ch xc tc reforming trong cng nghip

To hnh n si
cho cht mang To ht
Ht ri trong du
a kim loi Tin cht, dung mi
ln cht mang Tng tc KL-Cht mang

Loi b dung mi
X l nhit Phn hy tin cht
a hp phn cha clo

Hot ha Kh
III. PHNG PHP IU CH
XC TC CCR

Oxyt nhm c
th c ch to
bng cc
phng php to
ht bng thit b
to ht dng a
(Pangranulation)
phng php p
n (Extrusion)
v phng php
to git trong
du (Oil drop).
Cc phng php to ht oxyt nhm
III. PHNG PHP IU CH
XC TC CCR

Pha kim loi (Pt v cc kim

loi ph gia) c mang ln
cht mang bng phng
php tm: dng dd mui
[PtCl6]2- rt y ln cht
mang, quay u, dung mi
c tch ra khi cht mang
bng phng php bay hi
=> trn b mt cht mang
to cc vi tinh th mui
platin, sau khi kh trong M hnh thit b tm trong cng
dng H2 s to c cc ht nghip a kim loi ln cht mang
III. PHNG PHP IU CH
XC TC CCR

Cc phn ng xy ra trong qu trnh tm

IV. NGHIN CU CC C TRNG CA
XC TC CCR

Nghin cu c trng ca xc tc l nghin cu nhng g?

Bn cht thnh phn ha hc ca b mt cht rn v ca ton khi xc tc.
Cu trc ca xc tc: cu trc b mt, cu trc ton khi xc tc, kch thc tinh th v s phn b kch

thc tinh th , hnh thi tinh th, xp v din tch b mt.

Tnh cht ha hc ca b mt: trng thi ha tr, axit, nng lng b mt, trng thi in t b mt

Tnh cht xc tc: hot tnh ca xc tc, chn lc, n nh ca hot tnh.
IV. NGHIN CU CC C TRNG CA
XC TC CCR

Mc ch:
1. Nghin cu mi quan h gia cu trc ha hc,vt l & tnh cht xt
a ra mqh gia cu trc xc tc v chc nng ca n.
2. Tm ra nguyn nhn gy mt hot tnh
cch khc phc.
3. Xc nh c tnh cht vt l: t/c mao qun, din tch b mt, kch
thc ht bn, v tr tm hot tnh ca xc tc
thit k thit b ph hp ti u ha c qu trnh
4. Gim st c s thay i hot tnh ca xc tc trong qu trnh phn
ng, qu trnh iu ch
iu khin c cht lng sn phm..
IV. NGHIN CU CC C TRNG CA
XC TC CCR

Cc phng php nghin cu c trng xc tc

1. Xc nh b mt xc tc bng phng php hp th vt l
2. Xc nh phn tn ca phn t kim loi bng phng php hp ph
ha hc
3. o phn b kch thc ht bng phng php nhiu x tia X
4. Xc nh trng thi ha tr ca kim loi bng phng php rn ghen.
IV. NGHIN CU CC C TRNG CA
XC TC CCR

Vy hp ph vt l v hp ph ha hc l g?

Hp ph: s tp trung cht

trn b mt phn chia pha.
IV. NGHIN CU CC C TRNG CA
XC TC CCR
IV. NGHIN CU CC C TRNG CA
XC TC CCR

1. Xc nh b mt xc tc bng phng php hp th vt l

Nguyn tc: o hp ph vt l cc
phn t kh hoc lng ln b mt
xc tc.
Theo Emmet v Brunauer, nu
hp ph kh bi lc Van Der
Waals ti nhit si ca kh
(hp ph vt l) ta s c, p sut
tng i cao, hp ph a phn t
v ngng t mao qun.
c xy dng trn c s hp
ph a phn t.
IV. NGHIN CU CC C TRNG CA
XC TC CCR

1. Xc nh b mt xc tc bng phng php hp th vt l

Gi thit:

Hp th a phn t

Hp ph ch yu bi lc Van Der Waals

Cc cht b hp ph ch tng tc vi cc phn t trc v sau n,

khng tng tc vi cc phn t bn cnh.

Phng trnh:

B mt ring xc nh theo phng trnh BET :

Sbet = 4,3.Vm
p dng xc nh b mt ring ca tt c cc cht rn, vi iu kin
p sut tng i (P/Po) t 0,05 n 0,3 v hng s C >1.
IV. NGHIN CU CC C TRNG CA
XC TC CCR

2. Xc nh phn tn ca nguyn t kim loi bng phng php

hp ph ha hc
Tng hm lng kim loi hot ng a ln cht mang c xc nh

trong qu trnh iu ch xc tc.

Trong qu trnh nung, x l xc tc hoc qu trnh phn ng thng

xy ra nhit cao lm cho mt s tm kim loi hot ng tr nn

khng thun li hoc mt hot tnh i vi phn t cht phn ng.
phn tn -T l cc tm kim loi hot ng
IV. NGHIN CU CC C TRNG CA
XC TC CCR

2. Xc nh phn tn ca nguyn t kim loi bng phng php

hp ph ha hc
Phng trnh Langmuir

Gi thit:
Hp ph l n lp

Nhit hp ph l nh nhau ti mi im

Cc cht hp ph khng tng tc vi nhau

IV. NGHIN CU CC C TRNG CA
XC TC CCR

Kt lun:
Ty thuc vo phng php ch to v x l xc tc m s phn b ca

cc kim loi trn cht mang l tinh th rt nh hay nhng cu trc tin
tinh th.
phn tn cao lm tng hot tnh ca xc tc.
V. NGUYN NHN LM GIM HOT
TNH XC TC V CCH KHC PHC

S HNH THNH CC
1 LNG NG

2 NG C XC TC

3 DO THIU KT
V. NGUYN NHN LM GIM HOT
TNH XC TC V CCH KHC PHC
1. S hnh thnh cc lng ng
Cc c hnh thnh t cc hp cht dng olefin v diolefin sinh ra

trong qu trnh phn ng v hm lng cc hydrocabon a vng v cc

phn t mch di trong nguyn liu.
Cc bm trn b mt xc tc lm bt cc trung tm hot ngn cch tip

xc tc nhn phn ng vi xc tc lm gim dn hot tnh xc tc.

c th loi b cc bng qu trnh ti sinh t chy cc t t nhit

di 500 oC. Hm lng cc sau ti sinh ti da l 0,2 % kl.
V. NGUYN NHN LM GIM HOT
TNH XC TC V CCH KHC PHC
2. Ng c xc tc
Hin tng ng c xc tc xy ra do s c mt c t trong thnh phn
nguyn liu. c th xy ra di 2 dng :
Ng c c th hon nguyn

Ng c vnh vin
V. NGUYN NHN LM GIM HOT
TNH XC TC V CCH KHC PHC
2. Ng c xc tc
a. Ng c c th hon nguyn
Cc hp cht cha lu hunh

Cc hp cht cha S => H2S ,u c chc nng kim loi do hnh thnh

sunfua platin: Pt + H2S = PtS + H2.

H2S c tnh acid nn gy n mn tht b

Lm bin i Al2O3 thnh kt ta sunfat nhm Al2(SO4)3 ,

Mc ng c ca mi hp cht S khc nhau s khc nhau. Kh nng

lm gim hot tnh xc tc:

mercaptan > sunfit > thiofen > H2S > S nguyn t
Cn phi lm sch lu hunh ngay t khi a nguyn liu vo. Hm
lng cho php 3 => 5 ppm.
V. NGUYN NHN LM GIM HOT
TNH XC TC V CCH KHC PHC

2. Ng c xc tc
a. Ng c c th hon nguyn
Cc hp cht cha nit

Hp cht cha nito =>amoniac sau

NH3 + Cl2 => NH4Cl => gim chc
nng acid =>lm gim hot tnh xt lm
tng s hnh thnh hydro .
NH4Cl d bay hi trong vng phn
ng nn lm tng nhit thit b v
d kt tinh phn lnh gy h hng
thit b .
Hm lng nit cho php < 1 ppm.
V. NGUYN NHN LM GIM HOT
TNH XC TC V CCH KHC PHC

2. Ng c xc tc
a. Ng c c th hon nguyn
nh hng ca nc

Nc pha long cc trung tm axit lm gim axit cht mang.

Gy n mn thit b.

Loi b nc bng cch cho qua cc ct hp ph cha ry phn t

(zeolit 5A). H2O <= 4ppm

V. NGUYN NHN LM GIM HOT
TNH XC TC V CCH KHC PHC
2. Ng c xc tc
b. Ng c vnh vin
Cc kim loi kim v kim th lm trung ha tm axit ca cht mang

to thnh alumilat kh bn.

Cc kim loi As, Cu, Pb, Hg, kt hp vi Pt to mi lin kt bn, u

c vnh vin tm kim loi khng phc hi li c.T lm mt chc

nng chnh l hydo-dehydro ho ca xc tc .
Hm lng cho php ca chng trong dng vo thit b :

As< 0.001ppm , Pb, Cu, Hg < 0,05ppm.

V. NGUYN NHN LM GIM HOT
TNH XC TC V CCH KHC PHC
3. Do thiu kt
Khi nhit phn ng cao (>5000C) lm cho b mt xt kim loi

gim do cc tinh th xt tp hp li thnh tinh th ln, or do b mt

cht mang b ph v cu trc t cc mao qun.
V. NGUYN NHN LM GIM HOT
TNH XC TC V CCH KHC PHC

Kt lun:
C rt nhiu yu t nh hng n hot tnh ca xc tc tuy nhin ch

yu l vn ca nguyn liu u vo. V vy bo v hu hiu cc

cht xc tc reforming bin php bt buc v hiu qu trong cng ngh
l phi c phn on x l s b nguyn liu bng hydro (hydrotreating)
nhm loi b cc cht c gy gim hot tnh xc tc.
Xc tc sau thi gian s dng cho php cn c ti sinh ti sinh li

hot tnh ca n.
VI. QUI TRNH CNG NGH TI SINH
XC TC CCR

1. Cc phng php ti sinh xc tc

Phng php Oxy ha

1

2 Phng php kh

3 Phng php Clo ha

VI. QUI TRNH CNG NGH TI SINH
XC TC CCR

1. Cc phng php ti sinh xc tc

Phng php oxy ha ( t cc ):

CxHy + O2 CO2 +H2O + Q

Mc ch : loi b cc khi b mt xc tc.
S dng khng kh pha long vi N2 (0.5 2% O2).
Nhit 300 500oC.
Cht xc tc sau khi ti sinh cha t hn 0,2% cc.
VI. QUI TRNH CNG NGH TI SINH
XC TC CCR

1. Cc phng php ti sinh xc tc

Phng php kh

Mc ch: Loi b cc hp cht lu hunh khi xc tc. Kh Pt

dng oxyt v Pt kim loi.
S dng: dng kh cha khong 10% H2 , p sut 2 atm.

Xc tc sau ti sinh cha 0.03-0.05% cc

Phng php Clo ha

Mc ch: B sung lng Cl mt, tng tnh axit, tng hot tnh
xc tc. Loi b cc kim loi nh Pb, Fe, Bi. Phn b li Pt.
S dng: cc hp cht hu c cha Cl.

Lng Cl gi mc ~0.1%
VI. QUI TRNH CNG NGH TI SINH
XC TC CCR

2. Quy trnh ti sinh xc tc

Trng ra h thng

t cc

Oxy-clo ha

Nung xc tc

Kh xc tc
VI. QUI TRNH CNG NGH TI SINH
XC TC CCR

2. Quy trnh ti sinh xc tc

Trng ra h thng:

Dng N2 thi sch nguyn liu ra khi TBP

t cc:
Nhit : 300 500oC.

Oxy: 0.5-2% th tch.

Oxy-clo ha:

Nhit : 510oC.

Oxy : 5% th tch

Cl trong xc tc gi ~1% khi lng.

Thi gian 6h
VI. QUI TRNH CNG NGH TI SINH
XC TC CCR

2. Quy trnh ti sinh xc tc

Nung xc tc:

Nhit : 510 oC.

Oxy: 8% th tch

Thi gian : 4h

Kh xc tc:

Nhit : 480 oC.

p sut: 2 atm.

Hydro : 50% th tch.

Thi gian : 4h
VI. QUI TRNH CNG NGH TI SINH
XC TC CCR

3. Cng ngh ti sinh xc tc

c im :

Lp xc tc c chuyn dng nh nhng, lin tc trong h thng thit

b phn ng vi vn tc va phi (trong khong 3- 10 ngy).

Ton b h thng c vn hnh lin tc.

Lp xc tc sau khi ra khi h thng phn ng c a ra ngoi ti

sinh trong mt h thng ti sinh ring. Sau c quay tr li h thng

phn ng.
VI. QUI TRNH CNG NGH TI SINH
XC TC CCR

3. Cng ngh ti sinh xc tc

Cu to mt l phn ng
dng ng thng vi lp xc tc
chuyn ng dng trong cng
ngh CCR c m t trn hnh
bn:
ng knh 1,5 3,5m,
Chiu cao 4 12m
Th tch lp xc tc 6 80 m3

Mt ct dc l phn ng
reforming xc tc
VI. QUI TRNH CNG NGH TI SINH
XC TC CCR

3. Cng ngh ti sinh xc tc

H thng cu to t nhiu l phn ng gip cho dng hn hp nguyn

liu v kh giu hidro (kh tun hon) t c nhit phn ng v b

tr nhit nng t cc phn ng ha hc
Nhit gim nhanh trong l th nht do s xut hin ca cc phn

ng thu nhit quan trng (ch yu l phn ng dehydro ha naphten),

lng xc tc tiu th cho giai on ny chim 10-15% trng lng.
l phn ng th 2 nhit gim t hn, lng xc tc tiu th chim

20-30%.
Ti l phn ng cui cng, nhit gn nh n nh do c s b tr

nhit gia cc phn ng thu nhit nh vi cc phn ng ta nhit nh

hydrocracking
VI. QUI TRNH CNG NGH TI SINH
XC TC CCR

3. Cng ngh ti sinh xc tc

VI. QUI TRNH CNG NGH TI SINH
XC TC CCR

3. Cc cng ngh ti sinh xc tc

Cng ngh ti sinh lin tc(CN Platforming ca UOP-M)-Dung Qut

VII. THU HI & X L XC TC THI

Sau qu trnh s dng, xt b lo ha,

gim tui th, mt hot tnh

loi b, thay th

Gy lng ph v kinh t, nh
hng ti mi trng

Thu hi kim loi qu v x l xc

tc thi.
VII. THU HI & X L XC TC THI

CC BC THU HI V X L XC TC THI

t cc

Ngm chit
Cn rn Dung dch
bng kim/axit

Pt, Pd hoc Ir Re
VII. THU HI & X L XC TC THI

1. t cc
Cc lng ng trn b mt cht xc tc c loi b bng cch t chy

trong dng khng kh nhit 500 - 700 oC trong 4h,

Trong qu trnh nung, cn ch n tc gia nhit trnh hin

tng qu nhit cc b lm gim din tch b mt, gim bn c hc

ca cht mang hoc lm tng qu trnh thiu kt dn n gim phn
tn kim loi.
VII. THU HI & X L XC TC THI

2. Qu trnh ngm chit (leach) bng kim hoc axt

Cht mang Al2O3 c ha tan trong NaOH hoc H 2SO4
Al2O3 + 2NaOH + H2O 2NaAl(OH)4
Al2O3 + 3H2SO4 Al 2(SO4)3 + 3H2O
Leach chemical H2SO4 NaOH

Temperature < 1000C 180 2200C

Pressure 1 bar 8 24 bar

Sau khi qu trnh lc , Rhenium trong dung dch; Platinum, Palladium,

hoc Iridium trong cn rn
Nhm sulfat v Natri aluminat c s dng trong x l nc thi
VII. THU HI & X L XC TC THI

2. Qu trnh ngm chit (leach) bng kim hoc axt

Schematic diagramalkaline and sulfuric leach process

VII. THU HI & X L XC TC THI

3. Thu hi v lm sch kim loi qu

a. Thu hi Platinum
Phn cn ca dd sau kh chit ha tan trong nc cng toan hoc axit

hydrochloric v clo.
Pt + 2HCl + 2Cl2 H2PtCl6
Sau chuyn cc mui platinum thnh Platinum kim loi c th c
thc hin bng cc cch sau:
Kh t (wet chemical reduction) (s dng dung dch Aliquat 336:

R3RN+Cl-)
2R3RN+Cl- + H2PtCl6 (R3RN+)2PtCl62 -+ 2HCl,
(R3RN+)2PtCl62- + Na2S2O3 Pt2+
Pt2+ + Mg Pto + Mg2+
VII. THU HI & X L XC TC THI

3. Thu hi v lm sch kim loi qu

a. Thu hi Platinum
Phn hy nhit phn

(NH4)2PtCl6 Pt0 + 2NH4Cl + Cl2

Hoc bng qu trnh in phn
H2PtCl6 + 4e- Pt0 + 2HCl + 4Cl-
Qu trnh in phn c thc hin lin tc trong 22 h
Sn lng 80 kg/ngy

tinh khit 99.95% - 99.99%.

in phn l qu trnh quan trng v ph bin nht trong qu trnh thu

hi Pt t xc tc thi CCR,
VII. THU HI & X L XC TC THI

3. Thu hi v lm sch kim loi qu

a. Thu hi Platinum

Platinum electrowinning process.

VII. THU HI & X L XC TC THI

3. Thu hi v lm sch kim loi qu

b. Thu hi Palladium v Iridium

TH1: xc tc cha
Palladium=> thu hi ging
platinum => to mui
hexachloropalladium (mu
vng) => Palladium;
Sn phm c sy kh v x
l nhit cao hn thu c
palladium xp

Palladium Catalyst
VII. THU HI & X L XC TC THI

3. Thu hi v lm sch kim loi qu

b. Thu hi Palladium v Iridium
TH2: xc tc cha Platinum v
Iridium=>phn cn c x l qua
nhiu bc:
Chit qung HCl/chlorine
Phn cn li tip tc c lc qua
mt ln na vi HCl/chlorine, ha
tan cc alumina cn li.
Dng pp chit dung mi tch
Platinum & Iridium
Lm sch Iridium bng pp thy luyn
bao gm chit xut dung mi , trao 99.95 Iridium powder
(www.alibaba.com)
VII. THU HI & X L XC TC THI

3. Thu hi v lm sch kim loi qu

b. Thu hi Rhenium

Rhenium thu c t phn dd

sau khi chit bng axit hoc
kim
Tch Rhenium t nhm sunfat
hoc natri aluminat thng s
dng 2 phng php chit xut
dung mi hoc trao i ion.

Ammonium Perrhenat (APR )

 TM HIU XC TC CCR

KT LUN
Bi tiu lun gm cc phn chnh sau:
Tm hiu c bn v qu trnh refoming xc tc

Mt s nt v lch s hnh thnh xc tc cho qu trnh qua cc giai on

Tm hiu v xc tc trong qu trnh refoming xc tc: thnh phn, chc

nng, phng php iu ch c bit l nh my lc du Dung Qut.

Tm hiu v cng ngh ti sinh xc tc v thu hi kim loi qu trong

cng ngh CCR

Rt mong s nhn xt, nh gi, gii thch ca c v cc bn
v bi tiu lun.
 TI LIU THAM KHO

1. ng Hc Xc Tc, o Vn Tng, Nh Xut Bn KHKT, H Ni

2005
2. Ha hc du m v kh, inh th Ng, Nh xut bn KHKT, H ni,
2011
3. Catalytic Naphtha Reforming, Author: George J Antos- Abdullah M
Aitani, Publisher: New York : Marcel Dekker, 2004.
4. http://www.alfalaval.com/industries/oil-refinery/catalytic-
reforming/pages/catalytic-reforming.aspx
5.http:// www.hoahocngaynay.com/vi/hoa-hoc-va-doi-song/hoa-hoc-dau-
khi/1127-cong-nghe-reforming-va-xuc-tac-su-dung.html
6.http://www.vinachem.com.vn/XBP%5CVien_hoa%5CVC_PB
%5Cbai7.htm