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Nuclear Physics
Atomic structure
Atomic Structure
John Dalton said that atoms were tiny
indivisible spheres, but in 1897 J. J.
Thomson discovered that all matter contains
tiny negativelycharged particles.
He showed that these particles are smaller
than an atom.
He had found the first subatomic particle
the electron.
Thomsons Crossed-Field
Experiment
In 1895 Thomson measured the deflection of
cathode-ray particles by both a magnetic and
electric field.
Parallel-plate electrodes and the poles of a magnet
were placed so that the electric and magnetic fields
were perpendicular to each other, thus creating
what came to be known as a crossed-field
experiment.
Thomson was the first to measure the charge-to-
mass ratio q/m of cathode rays (electrons).
q/m = 1.76 1011 C/kg
Scientists then set out to find the structure of
the atom.
Thomson thought that the atom was a
positive sphere of matter and the negative
electrons were embedded in it as shown here
This `model' was called the `plumpudding'
model of the atom.
Rutherford and the Discovery of the
Nucleus
In 1896 Rutherfords
experiment was set up
to see if any alpha
particles were
deflected from gold
foil at large angles.
Not only were alpha
particles deflected at
large angles, but a very
few were reflected
almost straight
backward toward the
source!
Most of the particles passed straight
through the foil, but to his surprise a few
were scattered back towards the source.
Rutherford said that this was rather like
firing a gun at tissue paper and finding that
some bullets bounce back towards you!
The nuclear model of the atom
Rutherford soon realized that the positive
charge in the atom must be highly
concentrated to repel the positive aparticles
in this way.
The diagram shows a simple analogy:
The ball is rolled towards the hill and
represents the aparticle.
The steeper the `hill' the more highly
concentrated the charge.
The closer the approach of the steel ball to
the hill, the greater its angle of deflection.
In 1911 Rutherford described his
nuclear model of the atom. He said
that:
All of an atom's positive charge and most of
its mass is concentrated in a tiny core.
Rutherford called this the nucleus.
The electrons surround the nucleus, but they
are at relatively large distances from it.
The atom is mainly empty space!
The Nuclear Model of the atom
Can we use this model to explain the particle
scattering?
The concentrated positive charge produces an
electric field which is very strong close to the
nucleus.
The closer the path of the particle to the
nucleus, the greater the electrostatic repulsion
and the greater the deflection.
Most particles are hardly deflected
because they are far away from the
nucleus and the field is too weak to repel
them by much.
The electrons do not deflect the particles
because the effect of their negative charge
is spread thinly throughout the atom.
Using this model Rutherford calculated that the
diameter of the gold nucleus could not be larger
than 10-14 m.
This diagram is not to scale. With a 1 mm diameter
nucleus the diameter of the atom would have to be
10 000 mm or 10 m!
The nucleus is like a pea at the centre of a football
pitch.
Millikan and the Fundamental Unit of
Charge
Millikan observed oil droplets in an electric field.
He found that some of his droplets were positively
charged and some negatively charged, but all had
charges that were integer multiples of a certain
minimum charge value.
That value, the fundamental unit of charge that we now
call e, is measured to be
Absorption Spectra
For example, the emission spectrum of
sodium shows a pair of characteristic bright
lines in the yellow region of the visible
spectrum.
An absorption spectrum will show 2 dark lines
Li Na K
Absorption Spectrum
To study the behaviour of individual atoms, low-pressure gases are
used in which the atoms are relatively far apart.
A source of radiation that contains all wavelengths is passed
through the sample of gas and the resultant spectrum is examined .
The gas absorbs some of the wavelengths of the light
source. The observed spectrum, therefore, has lines
missing which correspond to the absorbed wavelengths.
Emission Spectrum
Emission spectra can be observed by
supplying a sufficiently large potential
difference across the gas within a tube.
Individual wavelengths emitted by the gas
can be observed.
Absorption and emission spectra for the same gas
Emission spectrum of hydrogen
H H H H
H = 656.3 nm H = 486.1 nm
H = 434.1 nm H = 410.2 nm
Balmer Series
By trial and error a Swiss
school teacher, Johann Balmer,
found a formula which correctly
predicted the wavelengths of
Angstroms four visible lines.
Balmer gave his formula in the form:
n
2
(cm) C2 2 2 n = 3, 4, 5, ...
n 2
Where C2 = 3645.6 x 108 cm and is known as the
convergence limit.
Only four lines were known to Balmer when he
started his investigation of the spectral series.
By the time he finished, ten more lines in the
violet and ultraviolet range had been measured.
These newly measured lines agreed to the
empirical formula to within 0.1%!
Encouraged by his success, Balmer
speculated that other hydrogen series
might exist of the form:
n 2
(cm) C2 2 2
n 3
n 2
(cm) C2 2 2
n 4
Rydberg Formula
Balmer was correct.
The Rydberg formula combines all of
these series into the single formula:
1 1 1
R 2
n 2
n
f i
Ei E f hf
Bohr Postulate 4
The size of the stable orbits are determined
by imposing a further quantum constraint
on the angular momentum of the electrons.
L me vr nh
h
where h
2
Allowed energy orbits
The total energy of the
orbit it a combination
of the electrons
kinetic energy and
electric potential
energy.
E EK EP
2
ke
me v
1
2
2 (1)
r
Also the centripetal force is due to the
electrostatic force:
2 2
mv ke
2
r r
2
1 ke
2 mv 2
1 2
(2)
r
Substituting (2) into (1):
2
ke
E
2r
Radius of electron orbit
Take postulate 4, solve for v, and square.
nh
v
me r
2 2
nh
v 2 2
2
(3)
me r
2 2
nh
rn 2
n = 1, 2, 3, ...
me ke
The smallest radius, when n = 1, is known
as the Bohr radius (a0).
2
h
a0 2
0.0529 nm
me ke
Quantisation of orbital radii leads to
quantisation of energy levels.
This can be seen by substituting rn=n2a0
into the previously obtained energy
equation to give the energy levels for
hydrogen:
ke 2 1
En 2
2a0 n
Substituting in numerical values gives:
13.6
En 2 eV
n