A k1

I k2
P
dA
1. k1 A A Ao e k1t
dt
dI
2. k1 A k2 I
dt
dP
3. k2 I
dt
dI
k1 Ao e k1t k2 I
dt
dI
k2 I k1 Ao e k1t
dt
dI
k2 I k1 Ao e k1t
dt
dy
+yf (x) = g(x) ye f x dx
e f x dx
g(x)dx C
dx
Ie e k A e k1t dt C

k2 dt k2 dt
1 o

Ie k2t e k2t k1 Ao e k1t dt C

Ie k2t k1 Ao e k2t k1t dt C
1 1
Ie k2t
k1 Ao e ( k2 k1 ) t
e C I k1 Ao
k2t
e ( k2 k1 )t Ce k2t
k2 k1 k2 k1
1
I k1 Ao e k1t Ce k2t t 0 I 0
k2 k1
1 1
0 k1 Ao C C k1 Ao
k2 k1 k2 k1
1 1
I k1 Ao e k1 Ao
k1t
e k2t
k2 k1 k2 k1

I Ao
k1
k2 k1
e k1t e k2t
Pada setiap waktu berlaku:
A I P Ao

P Ao A I Ao Aoe k1t Ao
k1
k2 k1
e k1t e k2t

k2 e k1t k1e k1t k2t k2 e k1t k1e k2t

P 1
k2 k1

k1
k2 k1
e e Ao 1
k1t

k2 k1
Ao

k1e k2t k2 e k1t
P 1 Ao
k2 k1
(b) The steady-state approximation
One feature of the calculation so far has probably not
gone unnoticed: there is a considerable increase in
mathematical complexity as soon as the reaction
mechanism has more than a couple of steps. A

d I
0
dt
d I
k1 A k2 I 0
dt
k1
I A
k2
d P k1
k2 I k2 A k1 A k1 Ao e k1t
dt k2
t

d P A o 1
k e k1t
dt A o 1 e k1t

0
Reaksi Paralel

M
k1 d A
k1 A k2 A
A dt
k2 N
 Example
Devise the rate law for the decomposition of N2O5,

2 N2O5(g)4 NO2(g) + O2(g)

on the basis of the following mechanism:

N2O5NO2 + NO3 ka
NO2 + NO3N2O5 ka
NO2 + NO3NO2 + O2 + NO kb
NO + N2O5NO2 + NO2 + NO2 kc
(c) The rate-determining step