about them Preparation: Before you go any further, it would be helpful to download: ◦ Data sheet (click here) – to view the data sheet you will need to be in slide show, press F5 ◦ This product, used as an example, is a commercial cleaning product containing some hazardous chemicals What do MSDSs contain? Identification of the product
Teepol Aluminium Cleaner
◦ - sales unit and stock code ◦ - address and contact details for the supplier What do MSDSs contain?
Composition/ information on ingredients. (Exact
formulations & details of non-hazardous components not required – protects from rival manufacturers)
CAS & EINECS are identifications codes
Risk phrases (from CHIP data- see later)
Alcohol Ethoxylate <1%
Phosphoric acid 15 – 30% Benzotriazole <1% Formaldehyde <1% What do MSDSs contain? Hazards identified (i.e. those known about when the product is used in the way the manufacturer intends)
Irritating to eye and skin
Large amounts could be hazardous to aquatic environment What do MSDSs contain? First aid measures ◦ Eyes - irrigate with water 10-15 minutes ◦ Skin – remove gloves and wash ◦ Ingestions – plenty of water to drink (This is incorrect - should be small sips!!) ◦ Inhalation- remove to fresh air
Always check out first aid information with
your Departmental First Aider or Safety Services What do MSDSs contain? Fire fighting measures
The material is non-flammable
If involved in a fire anyway, it may produce hydrogen chloride (an acid gas)
Breathing apparatus is relevant
to the Fire Service – not us! What do MSDSs contain? Measures for spillage or accidental release Spillage ◦ contain with sand or earth ◦ Beware of slipping hazard ◦ Do not allow to go down the drains (report any significant leakage down the drains to the water authorities – take advice)
You will need to ensure that your
department stocks appropriate materials to deal with these incidents. What do MSDSs contain? Handling and storage
Store away from food
Tightly closed containers Away from children At temperatures between 5oC & 30oC Shelf life 1 year
In this case, largely “common sense”
information but for some products it could be more critical What do MSDSs contain? Exposure controls &/or personal protective equipment (PPE)
◦ These are standard safety signs denoting the need to
wear gloves, face shield and protective clothing.
◦ NB It does not tell you what sort of gloves are
appropriate. You would need to find this out by consulting a gloves manufacturer regarding the hazardous materials in the product – see the “Guidance” section of Safety Services website What do MSDSs contain? Physical & Chemical Properties ◦ Appearance – what it looks like ◦ pH – acidity/alkalinity of the product – a pH of <1 denotes significant acidity ◦ Flash point – it is not flammable ◦ Density (>1 means it is more dense than water) In terms of hazard, both high pHs (strong alkali) and low pHs (strong acid) are nasty. For substances with pHs around 7 acidity & alkalinity are not generally a problem. What do MSDSs contain? Stability & reactivity No stability concerns – it won’t “go off” Avoid contact with strong oxidisers, chlorine & chlorine products – nasty gases possible Contact with some alloys may produce hydrogen – explosion potential because of low pH! (but not in normal use) What do MSDSs contain? Toxicological information (what nasty things will it do to you?)
Irritating to organic tissue (skin & eyes)
Inhalation of aerosol may cause irritation Ingestion – irritation to mouth & digestive tract (it’s a strong acid) Eye contact – may cause severe irritation (acid again!) Skin contact – irritation!
Connected with first aid information here, but in
some circumstances, may give details of longer term medical problems, where appropriate What do MSDSs contain? Ecological information How environmentally friendly is it? ◦ Biodegrades – does not remain in soil etc ◦ Don’t release into surface waters eg detergents can cause unsightly rivers and may affect waterproofing of water birds What do MSDSs contain? Disposal considerations ◦ Use suitable PPE (see previous information) ◦ Rinse out containers ◦ Don’t allow to enter drains ◦ Dispose of according to local regulations ◦ Do not mix with other waste
This is not as formidable as it
sounds – a bit of advice from Safety Services or Estates will help What do MSDSs contain? Transport information ◦ None
◦ Where substances need special consideration
for transport, it will be detailed here – usually only applicable to larger quantities What do MSDSs contain? Regulatory information ◦ Irritant to eyes and skin ◦ Keep away from children ◦ First aid information
◦ These are “risk phrases” associated with the
CHIP regulations – simple advice phrases ◦ There may also be symbols – as here , indicating “irritant”. Risk phrases - examples R1: Explosive when dry R20: Harmful by inhalation R2: Risk of explosion by shock, friction, fire or R21: Harmful in contact with skin other sources of ignition R22: Harmful if swallowed R3: Extreme risk of explosion by shock, R23: Toxic by inhalation friction, fire or other sources of ignition R24: Toxic in contact with skin R4: Forms very sensitive explosive metallic R25: Toxic if swallowed compounds R26: Very toxic by inhalation R5: Heating may cause an explosion R27: Very toxic in contact with skin R6: Explosive with or without contact with air R28: Very toxic if swallowed R7: May cause fire R29: Contact with water liberates toxic gas. R8: Contact with combustible material may cause fire R30: Can become highly flammable in use R9: Explosive when mixed with combustible R31: Contact with acids liberates toxic gas material R32: Contact with acids liberates very toxic R10: Flammable gas R11: Highly flammable Up to: - R12: Extremely flammable R66: Repeated exposure may cause skin dryness or cracking R14: Reacts violently with water R67: Vapours may cause drowsiness and R15: Contact with water liberates extremely dizziness flammable gases R68: Possible risk of irreversible effects What do MSDSs contain? Other information (variable)
In this case it tells you its immediate
application and how to use it REMEMBER MSDS’s are NOT Risk Assessments! They make no distinction between a gram and a tonne of a substance. When using substances you must carry out a risk assessment but use the information in MDSD’s to help you. Controls should be proportional to risk! Not all MSDS’s contain comprehensive. information, although they should have! If in doubt, always consult an expert.