IKA FARIDA YULIANA (093194007) LUTHFI FAZA AFINA RIZA WALIDA (093194016) Alcohol is often used to refer to ethanol, also called grain alcohol, and sometimes for beverages containing alcohol. This is because of ethanol was used as a basic ingredient in the drink instead of methanol, or other alcohol groups (or alkanol) is a general term for any organic compounds that have hydroxyl (-OH) is bound to carbon atoms, which he himself attached to hydrogen atoms and / or other carbon atom. Alcohol functional group is attached to the hydroxyl group on carbon sp3 hybridization. There are three main types of alcohol - 'primary', secondary, and 'tertiary'. These names refer to the amount of carbon that is bound to carbon C-OH. General chemical formula alcohol is CnH2n +1 OH ' - Preservatives Alcohol can also be used as preservative for animal collection (small size) alcohol; - Automotive Alcohol can be used as an automotive fuel. Ethanol and methanol can be made to burn cleaner compared to gasoline or diesel. Alcohol can be used as an antifreeze in the radiator. To increase the performance of internal combustion engines, methanol can be injected into the engine Turbocharger and supercharger. This will cool the entry of air into the pipe entrance, providing a more solid entry of air. There are two ways to name the alcohol: the common name and IUPAC name. The common name is usually made by taking the name of alkyl group, then add the word "alcohol". For example, "methyl alcohol" or "ethyl alcohol". IUPAC names are formed by taking the name of the alkane chain, remove the last "e", and adds "ol". For example, "methanol", and "ethanol". • isopropyl alcohol (sec-propyl alcohol, propane-2-ol, 2-propanol) H3C-CH (OH)-CH3, or rubbing alcohol • ethylene glycol (ethane-1 ,2-diol) HO-CH2-CH2-OH, which is a major component in antifreeze • glycerin (or glycerol, propane-1 ,2,3-triplet) of HO- CH2-CH (OH)-CH2-OH bound in natural fats and oils, ie triglycerides (triacylglycerol) • Phenol is an alcohol hydroxyl group attached to the benzene ring Alcohol is widely used in industry and science as reagents, solvents, and fuel Ether is a compound containing a group R-O-R ', where R = alkyl. One typical example is a solvent and anesthetic diethyl ether (etoksietana, CH3-CH2-O- CH2-CH3). Ether should not be equated with the following type of classes that have a similar structure - ROR. * A kind of aromatics such as furans in which oxygen is a party rather than an aromatic system. * Like where one rather than the carbon atoms adjacent to oxygen is bound with oxygen, nitrogen, or sulfur: - esters R-C (= O)-O-R - Asetals R-CH (-O-R)-O-R - Aminals R-CH (-NH-R)-O-R - Anhidridas R-C (= O)-O-C (= O)-R Ether can be separated completely from a mixture via distillation whereby the boiling point of ether is 34.5 degrees Celsius, and when evaporated without distillation, ether was difficult to separate completely. Form of the word "primary ether", "secondary ether", and "ether tertiar (ranked third)" is the use of in season and refers to the carbon atom adjacent to the ether oxygen. In a primary ether this carbon-carbon linked to the other just like in diethyl ether CH3-O- CH2-CH3-CH2. One example of a secondary one is diisopropil ether ether (CH3) 2CH-O-CH (CH3) 2 and examples are in the ether tertiar-tert-butyl ether (CH3) 3C-OC (CH3) 3. 1. Combustion
Ether flammable gases to form carbon dioxide and water vapor.
Example: 2. Reaction with Active Metals Unlike alcohol, ether does not react with sodium metal (active metal). 3. Reaction with PCl5 Ether reacts with PCl5, but does not liberate HCl.
4. Reaction with Hydrogen Halides (HX)
Ether decomposed by acid halides, especially by HI. If
the acid halide is limited:
If excessive acid halides:
Alcohol and ether can be differentiated based on ITS REACTION with sodium metal and phosphorus pentachloride.
* Alcohol reacts with sodium metal to free
hydrogen, while the ether does not react. * PCl5 produce alcohol reacts with HCl gas, while the ether is reacted but did not produce HCl.