IKE DAYI FEBRIANA, S.Si., M.T.

To quantify the heat flow into or out of a system in a constant

pressure process, chemists use a property called enthalpy (H).

The enthalpy of reaction, H, is the difference between the

enthalpies of the products and the enthalpies of the
reactants:
1. Bila persamaan dikalikan suatu konstanta k
maka nilai ∆H = k∆Ho.
2. Bila suatu reaksi dibalik maka ∆H berubah tanda
 Calculate ∆H for the complete combustion of 1.00 mole of propane, a
major component of lighter fluid!

∆Hreaksi = ∑∆Hproduk - ∑∆Hreaktan

∆Hreaksi = [(3∆H CO2 + 4 ∆H H2O)] – [(∆H C3H8 + ∆H O2)
∆Hreaksi = {[3mol (-393.5 kJ/mol) + 4 mol(-285.9 kJ/mol)] –
[1 mol(-105 kJ/mol)+ 0]}
∆Hreaksi = - 2324.1 – (- 105)
∆Hreaksi = - 2429.1 kJ

Senyawa kimia yang merupakan unsur tunggal atau

diatomik memiliki ∆H = 0
1. By using data of ∆Ho, Calculation ∆H reaction for
combustion of ammonia with excess oxygen!
4NH3(g) + 7O2(g)  4NO2(g) + 6H2O(g)
2. Calculate the enthalpy change for the combustion
of 1.00 mol of butane (C4H10), to give CO2 and H2O!
3. Calculate the value of 1.00 mol of ethyl alcohol
(C2H5OH), if we know that entalphy of combustion is –
1371 kJ/mole !
4. Tentukan ΔHreaksi :
C(s) + H2O(g)  H2(g) + CO(g)