Assignment 1

AS/JUN 2018/CHM456
2b) The pKa value of anilium ion C6H5NH3+ and
ammonium ion NH4+ are 4.63 and 9.2
respectively. On the basis of this fact, explain
whether aniline, C6H5NH2 is a stronger or
weaker base than ammonia, NH3.
AS/JAN 2018/CHM456
3b) Arrange the following molecules by increasing reactivity
as a nucleophile. Justify your answer.

AS/JUN 2016/CHM456
4a) Ethyl chloride and propyl chloride have different melting
point. Determine which one shows higher melting point.
Justify your answer.