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Chapter 7
ENTROPY
Mehmet Kanoglu
University of Gaziantep
Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.
Objectives
• Apply the second law of thermodynamics to processes.
• Define a new property called entropy to quantify the second-
law effects.
• Establish the increase of entropy principle.
• Calculate the entropy changes that take place during
processes for pure substances, incompressible substances,
and ideal gases.
• Examine a special class of idealized processes, called
isentropic processes, and develop the property relations for
these processes.
• Derive the reversible steady-flow work relations.
• Develop the isentropic efficiencies for various steady-flow
devices.
• Introduce and apply the entropy balance to various systems.
2
ENTROPY
Clasius
inequality
Formal
definition
of entropy
A cycle composed of a
reversible and an
irreversible process.
7
ENTROPY CHANGE OF PURE SUBSTANCES
Entropy is a property, and thus the
value of entropy of a system is fixed
once the state of the system is fixed.
During an internally
reversible, adiabatic
(isentropic) process, the The isentropic process appears as a
entropy remains constant. vertical line segment on a T-s diagram.
9
PROPERTY DIAGRAMS INVOLVING ENTROPY
On a T-S
diagram, the
area under the
process curve
represents the
heat transfer for
internally
reversible
processes.
Boltzmann
relation
15
THE ENTROPY CHANGE OF IDEAL GASES
From the first T ds relation From the second T ds relation
A broadcast
from channel IG.
16
Constant Specific Heats (Approximate Analysis)
On a unit–mass basis
18
19
Isentropic Processes of Ideal Gases
Constant Specific Heats (Approximate Analysis)
20
Isentropic Processes of Ideal Gases
Variable Specific Heats (Exact Analysis)
Isentropic
Efficiency
of
Turbines
A substance leaves
actual nozzles at a
higher temperature
(thus a lower velocity)
as a result of friction.
28
ENTROPY BALANCE
Entropy Change of a
System, ∆Ssystem
31
Entropy Generation, Sgen Entropy generation
outside system
boundaries can be
accounted for by
writing an entropy
balance on an
extended system that
includes the system
and its immediate
surroundings.
33
Control Volumes
The entropy of a
substance always
increases (or
remains constant in
the case of a The entropy of a control
reversible process) volume changes as a result
as it flows through a of mass flow as well as heat
single-stream, transfer.
adiabatic, steady-
flow device. 34
EXAMPLES
Entropy balance for heat
transfer through a wall
35
Entropy Generated when a Hot
Block Is Dropped in a Lake
or
36
Entropy
generation
associated with
a heat transfer
process