related phenomena observed since the late 1970s: a steady decline of about 4% per decade in the total volume of ozone in Earth's stratosphere (the ozone layer), and a much larger springtime decrease in stratospheric ozone over Earth's polar regions. In1974,Molina and Rowland (1974) revealed a potential air pollution threat to this protective ozone shield. They hypothesized that chlorofluorocarbons (CF2CI2 and CFCI3 – often abbreviated as CFC), which are used as propellants and refrigerants, react with ozone. The frightening aspects of this series of reactions are that the chlorine atom removes ozone from system, and that the chlorine atom is continually recycled to convert more ozone to oxygen. It has been estimated that a 5 percent reduction in ozone could result in nearly a 10 percent increase in skin cancer (ICAS, 1975). CFCs and other contributory substances are referred to as ozone-depleting substances (ODS). Since the ozone layer prevents most harmful UVB wavelengths (280–315 nm) of ultraviolet light (UV light) from passing through the Earth's atmosphere, observed and projected decreases in ozone have generated worldwide concern leading to adoption of the Montreal Protocol that bans the production of CFCs, halons, and other ozone-depleting chemicals such as carbon tetrachloride and trichloroethane.. GLOBAL WARMING Global warming refers to the current rise in the average temperature of Earth's atmosphere and oceans and its projected continuation. In the last 100 years, Earth's average surface temperature increased by about 0.8 °C (1.4 °F) with about two thirds of the increase occurring over just the last three decades. Warming of the climate system is unequivocal, and scientists are more than 90% certain most of it is caused by increasing concentrations of greenhouse gases produced by human activities such as deforestation and burning fossil fuels. An increase in global temperature will cause sea levels to rise and will change the amount and pattern of precipitation, and a probable expansion of subtropical deserts. Warming is expected to be strongest in the Arctic and would be associated with continuing retreat of glaciers, permafrost and sea ice. Other likely effects of the warming include more frequent occurrence of extreme weather events including heat waves, droughts and heavy rainfall events, species due to shifting temperature regimes, and changes in crop yields. Warming and related changes will vary from region to region around the globe, with projections being more robust in some areas than others KYOTO PROTOCOL Kyoto Protocol was an agreement or international treaty to bring all countries together to reduce global warming and for dealing the effects of unavoidable increase in temperature after 150 years of industrialization. Kyoto Protocol was developed with the collaboration of many countries in December 1997 but come into power in 16 February 2005. The reason for this duration was the terms of agreement settled upon Kyoto Protocol. The countries involved in this agreed to reduce emission of greenhouse gases that contribute to global warming. Industrialized countries support Kyoto Protocol except U.S state which release more and more greenhouse gas and responsible for those more than 25 percent of generated by humans worldwide. There were two conditions for the Kyoto Protocol to enter into force. The first condition was that no fewer than 55 participants in the convention needed to ratify the protocol. The second condition was that countries who participated in producing a leased 55% of the total carbon dioxide emissions for 1990 needed to ratify the protocol as well. AIR POLLUTION METEOROLOGY THE ATMOSPHERIC ENGINE
The atmosphere is somewhat like an engine.
It is continually expanding and compressing gases, exchange heat, and generally raising chaos. The driving energy for this unwieldy machine comes from the sun. The difference in the heat input between the equator and the poles provides the initial overall circulation of the earth’s atmosphere. The rotation of the earth coupled with the different heat conductivities of the oceans and land produce weather. HIGHS AND LOWS Because air has mass, it also exerts pressure on things under it. Like water, which we intuitively understand to exert greater pressures at greater depths, the atmosphere exerts more pressure at the surface than it does at higher elevations. The highs and lows depicted on weather maps are simply areas of greater and lesser pressure. The elliptical lines shown on more detailed weather maps are lines of constant pressure, or isobars. The wind flows from the higher pressure areas to the lower pressure areas. On a nonrotating planet, the wind direction would be perpendicular to the isobars. The resultant wind direction in the northern hemisphere. The technical names given to these systems are anticyclones for highs and cyclones for lows. Anticyclones are associated with good weather. Cyclones are associated with foul weather. Tornadoes and hurricanes are the foulest of the cyclones. TURBULENCE MECHANICAL TURBULENCE
In its simplest terms, we may consider
turbulence to be the addition of random fluctuations of wind velocity (that is, speed and direction) to the overall average wind velocity. These fluctuations are caused, in part, by the fact that the atmosphere is being sheared THERMAL TURBULENCE
Heating of the ground surface causes
turbulence in the same fashion that heating the bottom of a beaker full of water causes turbulence. Likewise, if the earth’s surface is heated strongly and in turn heats the air above it, thermal turbulence will be generated. The converse situation can arise during clear nights, when the ground radiates is heat away to the cold night sky. The cold ground, in turn, cools the air above It, causing a sinking density current. STABILITY The tendency of the atmosphere to resist or enhance vertical motion is termed stability. It is related to both wind speed and the change of air temperature with height. There are three stability categories. When the atmosphere is classified as unstable, mechanical turbulence is enhanced by the thermal structure. A neutral atmosphere is one in which the thermal structure inhibits mechanical turbulence. The atmosphere is said to be stable. Cyclones are associated with unstable air. Anticyclones are associated with stable air.
NEUTRAL STABILITY In a neutral atmosphere, the two lapse rates are equal. If a parcel of air is lifted through a neutral layer, the temperature and pressure of the parcel will be identical to the temperature and pressure of the surrounding air at every height and is always in equilibrium with the environment. Thus, the parcel is not buoyant. If the force producing the motion ceases, the parcel will neither continue to rise nor begin to sink, rather, the motion of a parcel will also cease. UNSTABLE ATMOSPHERE
If a parcel of air is lifted and continues to
rise after the lifting force disappears, the atmosphere is unstable. In an unstable layer, the lapse rate of a rising parcel is less than the lapse rate of the environment. Though the parcel cools as it rises, its temperature remains warmer than the surrounding air during its ascent through an unstable layer. Because the parcel is warmer than the environment, the parcel has positive buoyancy and continues to rise on its own. STABLE ATMOSPHERE In a stable atmosphere, if you lift a parcel of air, the temperature of the rising air will decrease fast enough that its temperature will always be colder than the temperature of the environment. Colder air sinks. If the force pushing the air up suddenly disappeared, the parcel would sink back down to its original position where its temperature and pressure would be in equilibrium with the environment. Another way of stating that the atmosphere or a layer in the atmosphere is stable is to say that the lapse rate of the rising air is greater than the lapse rate of the environment. PLUME TYPES
The smoke trail or plume from a tall stack
located on the flat terrain has been found to exhibit a characteristic shape that is dependent on the stability of the atmosphere. HEAT ISLANDS
A heat island results from a mass of
material, either natural or anthropogenic, that absorbs and reradiates heat at a greater rate than the surrounding area. Large industrial complexes and small to large cities are examples of places that would have a heat island. The effect is superimposed on the prevailing meteorological conditions. It is nullified by strong winds. LAND/SEA BREEZES
During the night, the land cools more
rapidly than the water. The relatively cooler air over the land flows toward the water. During the morning the land heats faster than water. The air over the land becomes relatively warm and begins to rise. The rising air is replaced by the air from over the water body. VALLEYS Under stagnating anticyclone, the valley will set up its own circulation. Warming of the valley walls will cause the valley air to be warmed. It will become more buoyant and flow up the valley. At night the cooling process will cause the wind to flow down the valley. Valleys oriented in the north-south direction are more susceptible to inversions than level terrain. The valley walls protect the floor from radiative heating by the sun. Yet, the walls and the floor are free to radiate heat away to the cold night sky.