Professional Documents
Culture Documents
There are two general categories of zinc rich primers: organic and inorganic.
Both types of primers incorporate zinc powder as a pigment in order to provide
galvanic protection to steel surfaces.
Organic zinc rich primers use an organic resin, most often epoxy, as a binder to
hold the zinc particles in the primer film.
Inorganic zinc rich primers, including ethyl silicates, rely on a more complex
chemical reaction to cure that involves zinc, oxygen, and silicon.
Inorganic Zinc Binder Curing Mechanism
There are several types of inorganic zinc rich primer resins, all of them based on
silicate chemistry.
Inorganic zinc rich primers are typically classified as alkali silicates or alkyl
silicates.
Alkali silicates include post cured or high-temperature cured resins based on sodium
silicate, and self-cured resins usually based on potassium or lithium silicate.
Waterborne inorganic zinc is based on water soluble alkali silicates. These binders
initially form a film simply by water evaporation. The film then hydrolyzes by reaction
with metallic pigment and the steel substrate to form an insoluble film.
Waterborne Inorganic Zinc Challenges
Waterborne inorganic zinc primers have been used successfully for years but have
presented their own unique challenges.
Since the alkali silicate binder is initially water-soluble, the initial film is water-
soluble. In some cases, it has been found that the hydrolysis reaction that renders
the binder insoluble was not 100% complete after a few weeks.
As a result, exposure to condensing humidity dissolved a small amount of the
resin. When the condensing humidity evaporated, the resin became concentrated
in small craters and on the top of bottom flanges of I-beams.
The concentration of resin in these areas encapsulated the zinc particles and
prevented them from providing cathodic protection, resulting in rust spots.
Inorganic Zinc Binder Curing Mechanism
C 2H 5
O OH
H 5C 2 O Si O C2H5 + 2 H 2O HO Si O C2H5 + 2 C 2H 5O H + Zn + H 2O
O O
C 2H 5 C 2H 5
Curing Mechanism – Cross-linking
+ +
Zn Zn
O O OH
+
Zn O Si O Si O Si O C 2H5
O O O
Zn Zn Zn + 2 C 2H 5O H
O O O
HO Si O Si O Si OH
O O O
+ + +
Zn Zn Zn
Inorganic Zinc-Rich Primer
Inorganic zinc rich primers protect the steel surface primarily by providing
galvanic protection.
The coating film is comprised of spherical metallic zinc particles bound together
by an inorganic resin.
In order for the coating to provide effective galvanic protection, the zinc particles
must be tightly packed in the film so that they are in electrical contact with each
other throughout most of the film.
Because of the chemistry of the inorganic resin, the resin actually reacts with the
zinc particles to provide a chemical bond. As a result, not as much resin is
required to hold the film together as with conventional coatings.
With traditional coatings, there has to be at least enough resin to completely fill
the void space between the pigment particles. The pigment must be totally
encapsulated by the resin.
If not mostly encapsulated by the resin, the pigment particles would be held
weakly in place and the coating would have poor physical properties and be
somewhat crumbly. Additionally, water would transfer through the coating freely.
Use of Ethyl Silicate Inorganic Zinc-rich
Primer
Ethyl silicate zinc rich primers have been widely used to protect steel surfaces for
decades.
Because the high zinc loading of ethyl silicate zinc rich primers leads to excellent
galvanic protective properties and the chemistry of the silicate binder creates a
hard tough film, it is considered one of the most effective primers in most exterior
exposures.
The composition and chemistry of the primer creates various conditions that make
successful application somewhat challenging.
As a result, ethyl silicate zinc rich primers are often applied to new steel in a shop
environment where application conditions can be more closely controlled.
Application Challenges
Many of the challenges with applying ethyl silicate zinc rich primer are the result
of either the extremely high pigment to resin ratio in the film or the need for
atmospheric water during the curing process. Some of the more common
application problems include:
Pinhole formation in the topcoat due to outgassing
Dry spray
Mud cracking of the applied film
Primer cohesive failure after top coating
Mixing anomalies
Mixing
The active pigment in zinc rich primer is a zinc dust, which is very dense.
For comparison, the density of zinc is compared to other common pigments:
Talc 2.75 gm/cc
Titanium Dioxide 4.23 gm/cc
Zinc 7.13 gm/cc
Because zinc is so much denser than typical pigments it can settle out from the wet
coating quickly.
Most manufacturers of ethyl silicate zinc rich primer recommend that the coating be
agitated continuously during the application process to prevent settling
Mud Cracking
Mud cracking of the applied ethyl silicate zinc rich primer is a common problem
when the primer is applied above the recommended dry film thickness.
It is not uncommon for inorganic zinc rich primers to have a maximum
recommended dry film thickness of around 3 mils. With some primers application
above 5 or 6 mils leads to the formation of a series of cracks in the surface of the
primer.
Mud Cracking
Dry spray is a condition where the surface of an applied coating has a rough
grainy appearance.
Almost all liquid applied coatings can be applied in a manner that could lead to
dry spray but some coatings are more prone to the condition.
Dry spray is created when the small globules of coating that travel from a spray
gun to the painted surface do not flow into the body of the coating but instead
loosely attach to the surface.
Dry Spray Causes
Ethyl silicate zinc rich primers are extremely prone to dry spray.
When solvent evaporates too quickly from the film the low resin-to-pigment ratio
causes the globules of coating to become too viscous to flow into the film.
The causes are the same as any coating with solvent in the formulation but are
intensified by the composition.
Application on exterior surfaces can be challenging when wind is present because
dry particles of the primer deposits dry spray on adjacent surfaces.
Dry Spray Avoidance
Dry spray can be prevented when applying ethyl silicate zinc-rich primers by
avoiding the application parameters that lead to the condition.
The spray gun should be held perpendicular to the surface that is being coated and
at a distance no further than recommended. Good spraying technique is critical.
Avoid spraying inorganic zinc-rich primer when there is wind or high air
movement past the surface to be coated.
If dry spray occurs, it can often be removed to some degree by rubbing a screen
over the surface to remove the loose particles, or by sanding.
Top Coating Problems
Ethyl silicate zinc rich primer is capable of protecting a steel surface for years
with a single coat. Regardless, for various reasons, it is usually top coated.
Top coating of ethyl silicate zinc rich primer has its own challenges. These top
coating challenges are the result of the porous nature of the film and the need for
moisture to cure the film.
Common top coating problems include:
Pinholing (outgassing)
Cohesive splitting of the film
Pinhole formation
The cohesive break in the primer occurs when the primer is over coated before it
has sufficiently cured.
Generally, the failure does not occur immediately. As the intermediate and/or
topcoat dry and cure, they developed shrinkage and contractive curing stresses.
Once the stresses become greater than the cohesive strength of the zinc rich
primer, the primer splits and the coating system delaminates.
The problem occurs most often when the entire coating system is applied in a
shop, especially during winter months in colder environments, when the relative
humidity is low.
Zinc Splitting
In order for an ethyl silicate zinc rich primer to adequately cure, it needs 3 things.
Moisture
Adequate temperature
Time
When steel is primed in a shop and top coated in the field, there is generally no
problem.
When an ethyl silicate zinc rich primer and the appropriate topcoat is applied in a
shop environment, the temperature is generally not a problem, but time and
moisture may be in short supply.
Zinc Splitting - Time
To avoid zinc splitting, care must be taken to assure that the primer has adequately
cured before application of the 2nd coat. Three methods to determine the cure are:
Solvent rub
Pencil hardness
Coin Rub
Solvent Rub
ASTM D 4752 – Measuring Resistance of Ethyl Silicate (Inorganic) Zinc-Rich
Primers by Solvent Rub
Ethyl silicate zinc rich primers develop excellent resistance to methyl ethyl ketone
(MEK) when they cure.
The surfaces are first cleaned with tap water or a dry cloth to remove loose
material.
A cloth saturated with MEK is rubbed over the surface until the metal substrate is
exposed or until 50 double rubs have been completed.
No residue or only a trace of residue should be transferred to the cloth from a
well-cured ethyl silicate zinc rich primer.
Pencil Hardness
ASTM D3363 – Standard Test Method for Film Hardness by Pencil Test
The silicate resin develops considerable hardness when it is substantially cured.
Pencils of varying hardness are held against the film had a 45° angle and pushed
away from the operator.
The gouge hardness is the hardest pencil that will not gouge the primer.
Consult the coating manufacturer for the minimum acceptable hardness.
The hardness scale: 6B-5B-4B-3B-2B-B-HB-F-H-2H-3H-4H-5H-6H
Softer Harder
Coin Rub
The coin rub can be used on some but not all the zinc rich primers.
A edge of a nickel (since it is non-serrated) is rubbed repeatedly across the surface
of the zinc rich primer.
If the coin causes the zinc rich primer to crumble or powder, or the primer is
otherwise removed by the edge of the coin, the primer is considered to be in
sufficiently cured.
A sufficiently cured ethyl silicate zinc rich primer should burnish when rubbed
with the edge of the coin creating a somewhat shiny surface.
The manufacturer of the primer should be consulted to determine whether the coin
rub test is an indicator of cure.
Summary