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UTILIZING COAL FLY ASH TO REDUCE CO2

THROUGH MINERAL CARBONATION PROCESS

S U LTA N FAT I H Z A A B D I L L A H
1016040043

PROPOSED SUPERVISOR:
1. D r. M i r n a A p r i a n i S . T. , M . T. ,
2. A d h i S e t i a w a n S . T. , M . T. ,
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INTRODUCTION

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BACKGROUND
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Coal-Fired Excessive Global CO2 CO2

Power Plant CO2 Warming, Sequestration Sequestration
Combustion Emissions Actions Potential through
Process Needed using Coal Mineral
Fly Ash Carbonation

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RESEARCH PROBLEMS
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• Efficiency of CO2 Sequestration of Coal Fly Ash through Direct Mineral

Carbonation Process.

• Effect of Liquid-to-Solid Ratio (L/S Ratio) Parameter from Coal Fly Ash Slurry on
CO2 Sequestration Efficiency.

• Effect of Initial CO2 gas Pressure Parameter from Coal Fly Ash Slurry on CO2
Sequestration Efficiency.

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AIMS/OBJECTIVE

• To analyze the efficiency of CO2 Sequestration of Coal Fly Ash through Direct
Mineral Carbonation Process.

• To analyze the effect of Liquid-to-Solid Ratio (L/S Ratio) Parameter from Coal
Fly Ash Slurry on CO2 Sequestration Efficiency.

• To analyze Effect of Initial CO2 gas Pressure Parameter from Coal Fly Ash

Slurry on CO2 Sequestration Efficiency.

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RESEARCH Master title style
DELIMITATIONS

• Coal Fly Ash used in this research already collected from Fly Ash Silo unit in PLTU
Jawa Barat on 27 October 2019.

• The research does not analyze the impact of CO 2 diffusion stage which present in
the reactor towards sequestration efficiency.

• Air proof stainless steel reactor with maximum pressure capacity of 2,5 bar and 1
liter of volume will be used in this research.

• XRD and XRF Analysis will be conducted to one of the best sample which will be
determined after all of the runnings are done.
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RESEARCH METHOD

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STAGES

Preliminary
Stages

Research

Reactor Sample
Manufacturing Preparation

Analysis

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PRELIMINARY STAGEStitle style
1. XRF
2. XRD
3. Free
Ca2+

Primary
Identifying
Preliminary Literature
Problems and Collecting Data
Stages Studies
Objectives
Secondary

Coal Fly
Ash
Characteri
stics 9
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REACTOR Master title style
MANUFACTURING

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SAMPLE PREPARATIONS
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CFA from Sieve Dried in Stabilized in Prepared CFA

Coal-Fired Filtering Drying Oven Desicator Samples
Power Plant (<1 mm) (105 oC; 24 (1 hours)
Combustion hours)
Process

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ANALYSIS

Variety of
Initial CO2
Pressure
P

Room
Pure CO2
Temperature

Magnetic
Stirrer 500
rpm

Variety of 1 hour batch

L/S Ratio reaction
CFA Slurry

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ANALYSIS
RUNNING SCHEME
Trial Initial CO2 pressure L/S Ratio
Trial 1 10 v/w
Trial 2 15 v/w
1 bar
Trial 3 20 v/w
Trial 4 25 v/w
Trial 5 10 v/w
Trial 6 15 v/w
2 bar
Trial 7 20 v/w
Trial 8 25 v/w
Trial 9 10 v/w
Trial 10 15 v/w
3 bar
Trial 11 20 v/w
Trial 12 25 v/w
Trial 13 10 v/w
Trial 14 15 v/w
4 bar
Trial 15 20 v/w
Trial 16 25 v/w
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ANALYSIS

Analysis Method Time

Free Ca2+ ion AAS (SNI 06-6989-56-2005) Before and After Each Trial
to each sample.
Chemical Composition XRF Before and After Research
using best sample.
CFA Characteristics XRD Befor and After Research
using best sample.

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Thank You

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