ANALYTICAL

CHEMISTRY-I
CH-301
ELECTROANALYTICAL TECHNIQUES
BASIC ELECTROCHEMISTRY
CONDUCTOMETRY
• Electrolytic Conductance
Resistance
• Specific resistance/ Resistivity
• Conductance
• Specific Conductance/
Conductivity
• Cell Constant Electrolytic Conductance
Specific Conductance/ Conductivity
Equivalence and
Molar
Conductance/
Conductivity
Measurement of Conductance
Wheat Stone Bridge
Cell Constant
Numericals
Conductometric Titrations
It is a titration used to measure the amount of an analyte present in the given
solution by measuring the change in conductance as a function of volume of
titrant.
Equivalence point is determined graphically.
Few Facts:
Molar Conductivity of various ions: (Scm2/mol)
Advantages and Disadvantages:
Conductometric Titrations
Effect of Concentration on Conductance
Variation of Conductance with
Temperature