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Dr David Law
Room 12.13.31
Service Life Modelling
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Service Life Modelling
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Service Life Modelling
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Model Types – Initiation Phase
• Deterministic
– Uses measured values
– Cover
– Chloride profiles (diffusion coefficients)
– Cementitious material
– Age
– Threshold value
– Surface chloride level
– Well established models
– LIFE365, Duracrete
– All give very similar values
– Single output value
– Time to corrosion
– Cover required to provide required service life
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Model Types - Initiation Phase
– Probabilistic
– Uses distribution curves, mean and standard deviation
– Cover
– Diffusion coefficient
– Threshold
– Surface chloride level
– Models still in development stage
– Probability/Reliability as output
– Confidence limits
– y% chance corrosion will/will not be initiated after x years
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Initiation Phase
• Deterministic
– Measured values
– Site measurements
– Specified design
– Provides time to initiation of corrosion or chloride concentration at bar
after a set time (service life)
– Structure specific
• Probabilistic
– Distribution function for each variable (based on experience)
– Monte Carlo, risk simulations
– Provides probability that service life is reached
– Reliability Index
– Confidence Limit
– Applicable to network of structures
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Chloride Models
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Typical Chloride Profile – Core
Sample
Sample 1C1
Best Fit Data
0.25
% Chloride by weight of
0.2
concrete
0.15
0.1
0.05
0
0 10 20 30 40 50 60 70
Depth (mm)
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Chloride Ponding Test
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Initiation Phase
Chloride Diffusion Model (Fick’s 2nd Law)
Cx,t = CS [1 - erf ( x )]
2(DappT)½
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Chloride Diffusion Model
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Chloride Diffusion Model
• Surface Chloride
– Builds up with time
– Marine structures immediate
– Roads annual de-icing salts
– Build up over winter, washed out over rest of year
– Coastal gradual continuous build up by aerosol action
– Reaches a maximum value
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Chloride Diffusion Model
Surface chloride
Cs = C0(1 –et) where Cs < 0.06 (or any other pre-set value)
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Apparent Chloride Diffusion Coefficients
(Eurocrete)
N factor
OPC -0.264
PFA -0.699
GGBS -0.621
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Chloride Diffusion Coefficients – Silica Fume
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Chloride Diffusion Model
Chloride Diffusion Coefficient
Dapp = Dtm(t/tm)n
where
Dtm = chloride diffusion coefficient at time tm and n is the material coefficient
This allows for the change in diffusion coefficient with time. Thus a diffusion
coefficient determined when structure is built would have a t m value of 1, (0 can
not be used) while a diffusion coefficient measured from a core taken at an age
of 20 years would have a tm value of 21.
Chloride concentrations at the bar for every subsequent year can then be
calculated until the threshold value is determined.
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Surface Chloride Concentrations
(%wt of concrete, Bamforth 1997)
Mean Values
OP cement 0.36%
Blended cements 0.51%
95% Confidence Limits
OP cement 0.75%
Blended cements 0.90%
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Chloride Diffusion Model
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Chloride Diffusion Model
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Cover Required
Cl- concentration
(% g Cl-/g cement)
0.4%
10 20 30 40 Cover (mm)
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Carbonation Modelling
Where:
Q = Instantaneous Carbonation
C = Carbonation Coefficient for Concrete
(Assumptions for C are made for differing grades of concrete)
t = time
k1 = factor - effect of CO2 concentration in the air
k2 = factor - effect of Exposure
k3 = factor - effect of orientation (N,S,E,W)
k4 = factor - effect of Curing
k5 = factor - effect of supplementary cementitious materials
(e.g. - flyash, BFS)
• Simplified to
xc(t) = Kt0.5
t – time
xc(t) – carbonation depth at time t
K – constant
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Initiation - Carbonation
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Initiation - Carbonation
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Probabalistic Models
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Probabalistic Models
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Probabalistic Models
39 20 10 – 29
40 40 30 – 69
41 20 70 – 89
42 10 90 - 99
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Probabalistic Models
62 40 120
81 41 125
13 39 115
48 40 120
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Distribution Curve
90
80
70
60
Frequency
50
40
30
20
10
0
0 50 100 150 200
Predicted Time to Corrosion (years)
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