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Clausius-Mossotti relation – This relates the relative permittivity of to the polarizability of the atoms of
a material.
Let’s consider a dielectric medium of number density = no. of molecules / unit volume.
An external electric field is applied to the dielectric. Due to charge separation an internal field is generated.
Total Electric field , This total electric field induces a dipole in each particle.
Hence, .
The polarization vector is sum of all induced moments in unit volume ;
Therefore,
Avogadro's number
Mass density
Molecular weight
2
𝑛 −1
2
= 𝑘 𝜌𝑚
𝑛 +2