TD-4100XD Operator Training

Training Topics

• Monitoring Applications
• Principles of Operation
• Application Sites
• TD-4100XD
Components
• User Interface
• Calibration
• Maintenance
 Monitoring Application
• Storm water Run-off
• Bilge Water
• Leaks from Heat Exchangers
• Oil in Cooling Water
• Hydrocarbons in Raw Drinking Water
and Wastewater
• Oil in Produced Water
Principles of Operation
Fluorescence
E2
1. Molecules are M

excited by the
absorption of light.
M E1
2. Relaxation to lower
energy state.

Energy
Emission
3. Molecules return to νEm = (E1-E0)/h
ground state by
emitting
fluorescent light.
Excitation
M M E0
νEx = (E2-E0)/h
10-8 sec
Fluorescence
E2
1. Molecules are M

Cexcited
∞ IF by the
absorption of light.
M E1
2. Relaxation to lower
energy state.

Energy
Emission
3. Molecules return to νEm = (E1-E0)/h
ground state by
emitting
fluorescent light.
Excitation
M M E0
νEx = (E2-E0)/h
10-8 sec
The TD-4100XD
Lamp
Fluorometer
UV & Visible
Light

Excitation
Filter

Excitation Light
specific to sample
Emission
Filter

Light Sample
D
Detector Cell
Fluorescent Fluorescent
Light Light +
specific to sample Stray Light
The TD-4100XD
Lamp
Fluorometer
UV & Visible
Light

Closed Loop Excitation

Drift Compensation Filter
TD-4100, TD-4100XD Light Pipe
Excitation Light
Chopper specific to sample
Emission
Filter

Light Sample
D
Detector Cell
Fluorescent Fluorescent
Light Light +
specific to sample Stray Light
The TD-4100XD
Lamp
Fluorometer
UV & Visible
Light

Closed Loop Excitation

Drift Compensation Filter
TD-4100, TD-4100XD Light Pipe
Excitation Light
Chopper specific to sample
Emission
Filter

Light Sample
D
Detector Cell
Fluorescent Fluorescent
Light Light +
specific to sample Stray Light
 TD-4100XD Sample Cell
Non-fouling Falling
Stream Design
– Water falls through air
to drain.
– Water never touches
an optical surface.
Air Curtain
– Prevents condensation
on optical windows.
– Water temperature
can be up to 212ºF.
TD-4100XD
On-Line
Hydrocarbon
Monitor
On-Site, On-Line
TD-4100XD
Components
 TD-4100XD Components
• Air System
– Air Curtain
– Air Purge
• Water Sampling System
– Bubble Trap
– Auto-valve
– Falling Stream Flow Cell
• Electronics & Optics
– Lamp, Filters & Windows
– Signal Processing
– User Interface
– Analog & Digital Outputs
 TD-4100XD Components
Bubble Trap

Auto-valve
Air Purge Indicator Flow Cell
Auto-valve Control Electronics
& Optics

Air Purge Control

Air Curtain Control

Air System
Water Sampling System
Electronics & Optics
 Air System

Air Purge Indicator

- “Cyclops”
* Green light “purge on”
* Remote pressure
indicator “dry contact
Air Purge Control
switch”

Air Curtain Control

 Air Curtain Control
Air Pressure Gauge

Air Flow Meter

Air Pressure Adjust

Air Flow Adjust

Settings
Pressure: 10-20 psi
Flow Rate: 15 scfh
Air Purge (ATEX Zone II, C1D2)

Settings Cyclops Air

Pressure: 5 psig max. Purge
Indicator
Air Pressure Gauge Air Pressure Adjust

Wait 1 hour after

light turns green
before turning
instrument on!
 Water Sampling System
Bubble Trap
Auto-valve
Flow Cell

Auto-valve Control
 Bubble Trap
Gas Vent

Inlet Valve

Drain Valve

Overflow Observation Port

Pneumatic Auto-Valve Switch
System (P-AVS)
Auto-valve indicator

Auto-valve actuator

Auto-valve Control
-Open
-Off
-Auto
 Falling Stream Flow Cell
Water Inlet

Desiccant Plug

View Port

Drain
Electronics & Optics

Electronics
& Optics
 Electronics & Optics

LCD Display

Keypad
Lamp Housing

Lamp ON
Indicator
TD-4100XD (Cabinet Open)
 TD-4100XD Alarms
Sample Level Alarms
– Zero alarm
– Early Warning alarm
– High Alarm
System Alarm
– Lamp
– Chopper RPM
– High Voltage
Cause audible BEEP and flashing “ALM” to
appear on the HOME screen.
Change the state of Relay A or Relay B.
 Sample Level Alarms
Warn operators of significant changes in
sample concentration.
Can be monitored or not monitored.
Can be set to user-defined concentrations.
Can be configured with a user-defined delay.
– Setting: 0.1 to 999.9 min.

Alarm Settings Relay Affected

Zero Alarm -999.999 to 999.999 Relay A

Early Warning Alarm 0.000 to 999.999 Relay B
High Alarm 0.000 to 999.999 Relay A
 System Alarms
• Notify operators of instrument malfunctions.
• Change the state of Relay A.
• System alarms are not affected by the user-
defined alarm delay.
• System alarms are always monitored.

Cause Delay Alarm Normal

Lamp 1 min. OFF ON

Chopper RPM 2 min. <500 RPM 588 - 612 RPM

High Voltage 3 min. <25 or >1000 25 - 1000

 LCD Display

User
Interface
Keypad
 TD-4100XD Keypad
Back up Go to
one screen HOME screen

ESC 7 8 9 HOME
Adjust LCD
contrast,
* 4 5 6
Fine tune
sensitivity,
? 1 2 3 Enter negative
numbers
# 0 . ENT

Clear numeric Enter values,

entries Toggle values,
Advance to next screen
 User ID
Please input ID:
█

Please input ID:

8 5 2 0 8520

ENT
Default User ID: 8520

ESC 7 8 9 HOME

* 4 5 6

? 1 2 3

# 0 . ENT
 HOME Screen
Over >999

10 PPM
HOME During Normal Operation CAL 28 DAYS AGO

ALM 15 PPM
During Alarm Condition CAL 28 DAYS AGO

HiAlm
ESC Current Alarm
HiAlm No alarm
Alarm History ErlyWrn or since last reset

* * * * *
Calibration Standard Values 0

12 PPM
HOME CAL 28 DAYS AGO

<1> Hi Std Conc

0 <2> Low Std Conc

Hi Std Conc:
1 15.000 PPM (Same procedure for <2>)

15.000
ENT New:

15.000
Type new value New: 30.000

30.000
ENT New:
Concentration Units 1

12 PPM
HOME CAL 28 DAYS AGO

Conc Units
1 Display Option

Unit Display:
ENT PPM

Unit Display:
ENT PPB

Unit Display:
ENT NO UNIT
 Relays A and B 2

12 PPM
HOME CAL 28 DAYS AGO

1. Relay A: NO
2 2. Relay B: NC

Relay A Ctrl: Relay A Ctrl:

1 NO ENT NC ENT

Relay B Ctrl: Relay B Ctrl:

2 NC ENT NO ENT
 Zero Alarm 3

12 PPM
HOME CAL 28 DAYS AGO

Zero alarm:
3 YES -1.000 PPM

1. Monitor: YES
ENT 2. Level: -1.000

Monitor Alarm: Monitor Alarm:

1 YES ENT NO ENT

-1.000 -1.000
2 New:
Type new value New: 2.000

2.000
ENT New:

-1.000 -1.000
Type new value New: 2.000 New: -2.000
 Early Warning Alarm 4

12 PPM
HOME CAL 28 DAYS AGO

Early Warning:
4 YES 50.000 PPM

1. Monitor: YES
ENT 2. Level: 50.000

Monitor Alarm: Monitor Alarm:

1 YES ENT NO ENT

50.000 50.000
2 New:
Type new value New: 25.000

25.000
ENT New:
 High Alarm 5

12 PPM
HOME CAL 28 DAYS AGO

High alarm:
5 YES 100.000 PPM

1. Monitor: YES
ENT 2. Level: 100.000

Monitor Alarm: Monitor Alarm:

1 YES ENT NO ENT

100.000 100.000
2 New:
Type new value New: 75.000

75.000
ENT New:
 Alarm Delay 6

12 PPM
HOME CAL 28 DAYS AGO

Alarm delay:
6 1.0 min

1.0 1.0
ENT New: Type new value New: 5.0

5.0
ENT New:
 4 mA Output 7

12 PPM
HOME CAL 28 DAYS AGO

4 mA output:
7 0.000 PPM

0.000 0.000
ENT New: Type new value New: 5.000

5.000
ENT New:
 20 mA Output 8

12 PPM
HOME CAL 28 DAYS AGO

20 mA output:
8 100.000 PPM

100.000 100.000
ENT New: Type new value New: 50.000

50.000
ENT New:
Relay A / Relay B Status 9

12 PPM
HOME CAL 28 DAYS AGO

Relay A: Open
9 Relay B: Closed
 Diagnostic Screens *

Lamp ON 598 RPM

* HV 325 Din: ON

Raw: 60.92
ENT FS%: 60

Test: 1: Relay A
ENT 2: Relay B ON / OFF

Relay A: Relay A: ON
1 <ENT> to toggle ENT <ENT> to toggle ENT

Relay B:
2 <ENT> to toggle (Same as for Relay A)

Oper: 986 Hrs

ENT

High Std: 102.8

ENT Low Std: 8.9
 Misc. Screens
Firmware Version Serial Data Output Rate (NA)

12 PPM 12 PPM
HOME CAL 28 DAYS AGO HOME CAL 28 DAYS AGO

TURNER DESIGNS Serial data out:

? Ver P0-1F 1197 . every 10 sec

Change User ID Calibration

12 PPM 12 PPM
HOME HOME CAL 28 DAYS AGO
CAL 28 DAYS AGO

Input MASTER ID: 1. Calibration

# ENT 2. Cal data

User ID:
ENT 8520
Calibration
 Calibration
1. Prepare a High
Concentration Standard
2. Prepare a Low
Concentration Standard.
3. Read fluorescence of
both standards while
flowing them through the
instrument.
4. Enter the concentrations
of both standards.
Calibration Bottles & Valves
 Prepare Isopropyl Alcohol (IPA)
Standard
1. Pipette 100 μL of oil into a 100 mL
volumetric flask.
2. Fill the flask to the mark with IPA.
3. Tightly cap the flask and shake it
vigorously to dissolve the oil.
a. Ultrasonic bath may be required for viscous oils.
b. Viscous oils may not completely dissolve.

Oil Concentration = 1000 ppm

 Standard Solutions
1. Choose a Standard Solution concentration.
Example: 5 ppm
2. Using a graduated cylinder, add IPA
Standard to the 1 gallon Cal Solution bottle.
Add 3.79 mL IPA Standard for each 1 ppm.
Example: Add 18.95 mL IPA Standard to
make a 5 ppm Cal Solution.
3. Fill the Cal Solution bottle to the 1 gallon
mark with Blank water.
4. Tightly cap the bottle and shake it
vigorously.
 Calibration Reset
12 PPM
HOME CAL 28 DAYS AGO

1. Calibration
ENT 2. Cal data

<1> High <2> Low

1 <3> Reset Cal

Reset CAL deflts

3 Press <*> 5 times

CALIBRATION
* * * * * reset to default

ESC
 Calibration – High Standard
12 PPM
HOME CAL 28 DAYS AGO

1. Calibration
ENT 2. Cal data

<1> High <2> Low

1 <3> Reset Cal ENT

High Standard
Close inlet valve. Drain bubble trap.
1 Highest conc! Mount High Std calibration bottle.
Close drain valve. Open Auto-valve.

High Standard:
Open PVC valve.
ENT XXX.X Wait for readings to stabilize.
Must be <142.

High Standard: High Standard: FINISHED!

YYY.Y
* XXX.X WAIT Press <ENT>
Calibration Timing Hint

Press * when water

level is near bottom of
label.

High Standard:
Open PVC valve.
ENT XXX.X Wait for readings to stabilize.
Readings must be <142

High Standard: FINISHED!

* XXX.X WAIT Press <ENT>
 Calibration – Low Standard
12 PPM
HOME CAL 28 DAYS AGO

1. Calibration
ENT 2. Cal data

<1> High <2> Low

1 <3> Reset Cal ENT

Close inlet valve. Drain bubble trap.

Low Standard
2 Mount Low Std calibration bottle.
Lower conc!
Close drain valve. Open Auto-valve.

Low Standard:
Open PVC valve.
ENT XXX.X Wait for readings to stabilize.
Must be <142 & <High Standard

Low Standard: Low Standard: FINISHED!

YYY.Y
* XXX.X WAIT Press <ENT>
 Calibration Abort

High Standard Low Standard

FROM Highest conc! OR Lower conc! OR Beyond…

<1> - Abort Cal

ESC <ESC> - Continue

<1> High <2> Low

1 <3> Reset Cal
Viewing Calibration Data

12 PPM
HOME CAL 28 DAYS AGO

1. Calibration
ENT 2. Cal data

High Std: 106.5

2 Low Std: 3.2 Raw Fluorescence

Slope: 0.0484
ENT Inter: -0.1531 Slope & Intercept
Calibration Standard Values 0

12 PPM
HOME CAL 28 DAYS AGO

<1> Hi Std Conc Same procedure for

0 <2> Low Std Conc <1> and <2>

Hi Std Conc:
1 15.000 PPM

15.000
ENT New:

15.000
Type new value New: 30.000

30.000
ENT New:
Concentration Units 1

12 PPM
HOME CAL 28 DAYS AGO

Conc Units
1 Display Option

Unit Display:
ENT PPM

Unit Display:
ENT PPB

Unit Display:
ENT NO UNIT
 CheckPoint
Solid Standard
 CheckPoint Solid Standard

CheckPoint Solid Standard Case

CheckPoint & adjustment tools

Inserting the CheckPoint
Remove the screw hole plugs

Adjust and inserting the

CheckPoint
Maintenance
 Maintenance
Daily or Weekly
1. Inspect bubble trap overflow
2. Inspect falling stream and optical
windows (as viewed through view
port window).
3. Check air pressure and flow rate
4. Record CheckPoint fluorescence

As Required
1. Clean sample flow cell
2. Clean flex hoses
3. Clean bubble trap assembly
4. Clean drain assembly
5. Adjust air pressure and flow rate
 Maintenance
Every 6 Months
1. Change lamp & recalibrate
2. Change desiccant plug
3. Change activated carbon filter

Every 5 Years
1. Change Battery Backup (NVRAM)
I. Record instrument settings
II. Replace NVRAM chip
III. Re-enter settings and
recalibrate Instrument
2023 North Gateway, Suite 101
Fresno, CA 93727 USA
Phone: +1 559 253-1414
FAX: +1 559 253-1090
Service@oilinwatermonitors.com
www.oilinwatermonitors.com