CEMENTS BASED ON ORGANOMETALLIC

CHELATE COMPOUND

□ Bbrp semen kg memp. karakteristik in rx setting 

divalent metallic ions ( Zn ion) + orthodisubstituted

aromatic compound  chelate compound

□ Tipe aromatic compound adalah :

1. ZnO / Eugenol cements
2. Ortho-ethoxybenzoic acid (EBA ) cements
3. Calcium hydroxide cements , in which the
aromatic
□ Dasar rx : Asam + Basa  garam gel

□ KOMPONNEN UTAMA :
SERBUK MASA SOLID
CAIRAN PASTA KENTAL
+ / PADAT

Amfoter Asam
/ basa

Proton Proton

Aceptor Donor
 REAKSI UMUM

□ MO + H2 A MA + H2 O
proton proton gel-salt
acceptor donor

MxSiO + H 2A MA + xSiO 2 + H 2 O

Setting tda :
1. Inti (sisa serbuk)
2. Matrik (gel-salt)
1. Cavitiy lining
2. Cementing agent
3. Temporary restoration
4. Restorastion : Decidui, anterior, posterior
5. Pit : Fissure salent
6. Pulp capping
7. Root canal filling materials
8. Periodntal dressing
Diagram cavity lining protects the dental pulp

CHEMICAL THERMAL GALVANIC

ATTACK SHOCK EFFECT

CAVITY LINING

VITAL PULP
FUNGSI
Final cementation of completed
restoration
Temporary cementation of
completed restoration or cemen-
tation of temporary restoration
High strength bases
Temporary fillings
Low strength bases
Liners
Varnish
SEMEN
ZnPO 4 , ZnSilikoPO 4 , rein-forced
ZnOE, Znpolikar-boksilat, SIK
ZnOE, Non-Eugenol ZnO
ZnPO 4 , reinforced ZnOE,
Zn polikarboksilat
ZnOE, reinforced ZnOE,
Zn polikarboksilat
ZnOE, CaOH
CaOH in a suspension
Resin in a solvent
SPECIAL APPLICATION

FUNGSI SEMEN

Root canal sealer ZnOE, Zn Polikarboksilat

Gingival tissue pack ZnOE

Surgical dressing ZnOE, ZnOPreparation

Cementation of ZnPO 4 , Zn Polikarboksilat

orthodontic bands

Orthodontic Resin akrilik, Resin

komposit
1. Non toksik, non iritan
2. Melindungi pulpa dari material restorasi
- thermal insulation  eq. Dibawah amalgam
- proteksi kimiawi  dr m. restorasi
- electrical insulation
3.Tidak larut in saliva & cairan in mulut.
4. Sifat adesif thd gigi & material restorasi
5. Sifat mekanis ttn
6. Sifat optik  menyerupai s. optis jar gigi
7. Sifat reologi  adonan viskositas rendah  lap
semen tipis & wkt kerja cukup
Sifat karakteristik semen kg
Tebal Set time Compressive
(µm) (Mnt) Str (MPa)
Zn Ph (luting) 25 2,5 - 8 70
Zn Polikarboksil (lt) 25 2,5 - 8 70
Zn Ph (base/liner) 25 2,5 – 6 70

Zn Poli (base/liner) 25 2,5 - 6 70

SIK (Lt ) - 2,5 - 8 70
SIK Base/liner) - 2,5 – 6 70
SIK restorative - 2,5 – 8 130
 Dental cements classified
by ingredient and application
I. Water-Bases Cements
1. Glass and resin-modified glass ionmer cements
2. Zinc polyacrylate
3. Zinc phosphate
II. Resin – Bases Cements
1. Composites and adhesive resins
2. Compomers
III. Oil – Based Cements
1. Zinc oxide Eugenol
–
2. Non eugenol zinc oxide
Glass and resin–modified glass ionomer cements

□Class 5 restoration
□ Retention of convensional alloy based
restorations
□ Retention of alumina or zirconia-bases all-
ceramic restorations
 Retention of orthodontic bands
□ High strength bases
□ Long-term profesional restoration
Zinc polyacrylate = polikarboksilat

□ Retention of alloy restoration, orthodontic bands and

pediatric stainless steel crowns
□ High strength bases
□ Long term provesional restorations
 - CH 2 – CH – CH2 – CH –

 C=O C=O

 O O

 H H

□ Asam poliakrilat = polikarboksilat

Zinc phosphate semen

□ Retention of conventional restorations,

orthodontic bands

High strengh bases
□ Long-term provesional restorations
Komposisi Z n P O 4 semen

POWDER Weight (%)

□ ZnO 90,2
□ MgO 8,2
□ SiO 2 1,4
□ Bi 2 O 3 0,1
□ Misc. BaO, Ba 2 SO 4 , CaO 0,1
LIQUID Weight (%)
H PO (free acid) 38,2
2 4
H 3 PO 4 (combined with Al & Zn) 16,2
Al 2,5
Zn 7,1
H2 O 36
Serbuk
□ MgO + ZnO sampai 10 %  (-) suhu pemanasan in
proses kalsinasi.
□ Serbuk dibakar in suhu 1000°C---1300 °C4-8
jam
(-) reaktivitasnya
 memberikan working/ setting time sesuai dgn semen.
□ Tanpa proses pembakaran semen setting terlalu cpt

Cairan
□ Al + Zn  larutan asam ortoposporik.
□ As. Posporik-----------  larutan buffe
□ (85 %)
Manipulasi

□ P/L ratio : 1,4 g m / 0,5 ml

□ Diaduk diatas glass slab dgn stainless spatula, gerakan
memutar

Lama pencampuran : 15 – 20 dt
□ Ketika serbuk ZnPO 4 semen kontak dgn cairan-nya 
percampuran.
□ Pada tahap inisiasi terjadilah pembasahan & rx
kimia.
Permukaan serbuk alkalin terurai oleh cairan asam
menghasilkan reaksi eksotermis.

□ 3 Z n O + 2 H 3 P O 4 + H 2O Zn 3 (PO 4 ) 2 . 4 H 2 O
□ Hidrat amorphous Zn phospat
□ Isolator termis & me(-) efek galvanik
Composite and adhesive resins

□ Bonded conventional alloy-based restoration

□ Bonded ceramic crowns, bridges, veneers, inlays, and
onlays
 Bonded laboratory composite crown, bridges, veneers,
inlays , and onlays
□ Bonded posts and cores

□ Retention of provisional restoratui

□ Retention of orthodontic brackets
Compomer

□ Bonded conventional alloy-based

restoration
 –
Rcertaemnticonreosftoarlautmioin a based all-
or zinkonia
Zinc oxide-Eugenol

□ High strength bases


Provesional restorations
□ Root canal sealers
□ Gingival tissue packs

□Surgical dressings
Komposisi Z nO /E ugenol semen

Komponen Fungsi

Powder ZnO Primary reactive ingredient

Zn Acetat Accelerator
(1-5%)

Liquid Eugenol Primary reactive ingredient

Olive oil To control viscosity

(5-15 %)
Komposisi E B A semen

Component Function

Powder ZnO (60%) Primary reactive

ingredient
Quartz (35%) Reinforcing -

Hydrogenated rosin agent

(5%)
Liquid O-Ethoxybenzoic Reactive ingridient
acid
Eugenol
Ortho-ethoxybenzoic acid

(EBA) cement

CO 2 H
OC2 H 5
□ Ratio asam orthoetoksibensoik : eugenol : 2 : 1
□ Cavity lining u/amalgam
□ Luting semen
□ Compressive strength 85 MPa
Non eugenol- zinc oxide
□ Provesional restorations
□ Root canal sealers
□ Gingival tissue packs
□ Surgical dressings
Calsium hidroxide cements

□ Tda 2 pasta
□ Setting time : 2,5 – 5,5 menit
□ Reaksi setting :
□ CaOH + ester salisilat Chelate viz.
Amorphous calsium disalicylate
Etilen glikol salisilat
CH 3
CH 2 CH 2 CH

CO 2 CO 2
OH OH
 Komposisi C a O H semen

Component Function
Paste 1 CaOH 50 % Primary reactive ingridient
ZnO 10 % - ,, -
Zn stearat 0,5 % Accelerator
Ethyl toluene sulphon- Oil compound, acts as carrier
amide 39,5 %

Paste 2 Glycl salicylate 40 % Primer reactive ingridient

Titanium dioxide Inert, fillers, pigments, radiopa-
cifers
Calsium sulphate - ,, -
Callsium tungstate