You are on page 1of 17

Batteries

Eng.Mohamed Bayoumi
What is a battery?
• It is something that converts chemical energy
into electrical energy.
• They produce current via redox reactions:
– Red=reduction (gaining electrons) ›››› “Cathode"
– Ox=oxidation (losing electrons) ›››› “Anode"
• Batteries are essentially Voltaic Cells
connected in series.
What is a voltaic cell?
Major components:
ZINC
• Metals

COPPER
What is a voltaic cell?
Major components:
ZINC
• Metals
• Electrolytes ZnSO4(aq)

CuSO4(aq)

COPPER
What is a voltaic cell?
Major components:
ZINC
• Metals
• Electrolytes ZnSO4(aq)
1.0 Molar
• “Salt Bridge”
• Wire
AGAR

Battery lifetime depends


on the mass of metal in CuSO4(aq) WIRE
the electrodes. 1.0 Molar

COPPER
What is a voltaic cell?
ZINC

ZnSO4(aq)

ANODE

AGAR

CATHODE WIRE
CuSO4(aq)

COPPER
How does it make energy?

• The solid zinc anode


oxidizes and becomes Zn2+
• Electrons travel through
the wire toward the cathode
• The aqueous Cu2+ is reduced
and adds to the solid copper
cathode
The standard hydrogen electrode
(SHE)
How much energy can it make?
• You can predict the voltage (direct current) between
any two materials based on reduction potentials.
• A reduction potential, Eocell, is the difference between
the standard reduction potential of the cathode
(Eored(cathode)) and the anode (Eored(anode)).

Eocell= Eored(cathode)-Eored(anode)
How can you get more
energy?
1. Connect several cells in series
(1.044V+1.044V+1.044V…)
2. Work outside of standard
conditions (concentration, temp,
etc.)
3. Use different compounds for the
electrodes.
The greatest voltages are from
a combination of the compound with
the most negative potential
(anode) and the most positive
(cathode). These happen to be Li
and F, respectively.
Rechagable li ions
nppa
Environmental Impacts
• Some electrodes are made of
hazardous materials
– Cadmium in Ni-Cd batteries
– Lead in lead-acid batteries (like
a car battery)
– Mercury-electrode batteries
(banned in 1996)
– Arsenic and Antimony in
lead-acid batteries
Environmental Impacts
• When batteries are not
recycled, they ultimately end
up contaminating soil, air,
water, and finally end up in
the food chain.
• Using secondary (rechargeable)
batteries helps to prevent
pollution.
THANK YOU!

You might also like