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Matriculation Chemistry ( Reaction Kinetics ) part 2

# Matriculation Chemistry ( Reaction Kinetics ) part 2

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rate law and write the rate equation, order of reaction and the rate constant, determine the overall order of a reaction from experimental data 5. calculate the value and determine the units of rate constants
rate law and write the rate equation, order of reaction and the rate constant, determine the overall order of a reaction from experimental data 5. calculate the value and determine the units of rate constants

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01/09/2013

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RATE LAW
11.1

Objectives:
5. calculate the value and determine the units of rate constantsAt the end of the lessonthe students should be ableto:1. define rate law and write the rate equation2. define the order of reaction and the rate constant3. calculate the order with respect to a certain reactantfrom experimental data4. determine the overall order of a reaction fromexperimental data

The Rate Law
The
rate law
expresses the relationship of the rate of areaction to the rate constant and the concentrations of the reactants raised to some powers.
a
A +
b
B
C +
D
Rate =
[A]
x
[B]
y
reaction
order is x with respect to
Areaction
order
is y
with respect
to BOverall reaction order is
(x + y)
The exponents x, y, The exponents x, y,
can be integers,can be integers,fractions or decimal or negative values.fractions or decimal or negative values.
is calledis called
rate constant rate constant
Rate
α
[reactant]

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