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AIEEE 2010 Solution

AIEEE 2010 Solution

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Published by Resonance Kota
AIEEE 2010 Solution (English) by Resonance, Kota
AIEEE 2010 Solution (English) by Resonance, Kota

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Categories:Types, Research
Published by: Resonance Kota on Apr 25, 2010
Copyright:Attribution Non-commercial

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04/14/2011

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Date : 25-04-2010 Duration : 3 Hours Max. Marks : 432
QUESTIONS & SOLUTIONS OF AIEEE 2010
IMPORTANT INSTRUCTIONS
1.
Immediately fill the particulars on this page of the Test Booklet with Blue / Black Ball Point Pen.Use of pencil is strictly prohibited.
2.
The Answer Sheet is kept inside this Test Booklet. When you are directed to open the Test Booklet, take out the Answer Sheet andfill in the particulars carefully.
3.
The test is of 3 hours duration.
4.
The Test Booklet consists of 
90
questions. The maximum marks are
432.5.
There are three parts in the question paper. The distribution of marks subjectwise in each part is as under for each correct response.
Part A
CHEMISTRY (144 marks)
Question No.
4 to 9
and 13 to 30 consist of 
FOUR (4)
marks each and Question No.
1 to 3
and
10 to 12
consist of 
EIGHT (8)
markseach for each correct response.
Part B
PHYSICS (144 marks)
Question No.
33 to 49
and
54 to 60
consist of 
FOUR (4)
marks each and Question No.
31 to 32
and
50 to 53
consist of 
EIGHT (8)
marks each for each correct response.
Part C
MATHEMATICS (144 marks)
Question No.
61 to 69, 73 to 81
and
85 to 90
consist
FOUR (4)
marks each and Question No.
70 to 72
and
82 to 84
consist of 
EIGHT(8)
marks each for each correct response.
6.
Candidates will be awarded marks as stated above in Instructions No. 5 for correct response of each question.
¼ (one fourth)
markswill be deducted for indicating incorrect response of each question. No deduction from the total score will be made if no response isindicated for an item in the Answer sheet.
7.
Use Blue/Black Ball Point Pen only for writing particulars/marking responses on Side-1 and Side-2 of the Answer Sheet. Use of pencilis strictly prohibited.
8.
No candidate is allowed to carry any textual material, printed or written, bits of papers, paper, mobile phone, any electronic device, etc.,except the Admit Card inside the examination hall/room.
9.
Rough work is to be done on the space provided for this purpose in the Test Booklet only. This space is given at the bottom of eachpage.
10.
On completion of the test, the candiate must hand over the Answer Sheet to the Invigilator on duty in the Room/Hall. However, thecandidates are allowed to take away this Test Booklet with them.
11.
Make sure that the CODE printed on Side-2 of the Answer Sheet is the same as that on this booklet. In case of discrepancy, the condidateshould immediately report the matter to the Invigilator fo replacement of both the Test Booklet and the Answer Sheet.
12.
Do not fold or make any stray marks on the Answer Sheet.
Name of the Candiate (in Capital letters) : ____________________________________________________________ Roll Number : in figures : in words : _______________________________________________ Examination Centre Number :Name of Examination Centre (in Capital letters) : ________________________________________ Candidate's Signature : ______________________________ Invigilator's Signature : ___________________________________ 
 
Page # 2
PART - A (CHEMISTRY)
1.
The standard enthalpy of formation of NH
3
is
 –
46.0 kJ mol
 –
1
. If the enthalpy of formation of H
2
from its atomsis
 –
436 kJ mol
 –
1
and that of N
2
is
 –
712 kJ mol
 –
1
, the average bond enthalpy of N
 –
H bond in NH
3
is(1)
 –
964 kJ mol
 –
1
(2) + 352 kJ mol
 –
1
(3) + 1056 kJ mol
 –
1
(4)
 –
1102 kJ mol
 –
1
Ans.(2)Sol.
N
2
(g) +23H
2
(g)
   
NH
3
(g) ;
H
f
º =
 –
46.0 kJ mol
 –
1
2H(g)
   
H
2
(g);
H
f
º =
 –
436 kJ mol
 –
1
2N(g)
   
N
2
(g);
H
f
º =
 –
712 kJ mol
 –
1
NH
3
(g)
   
21N
2
(g) +23H
2
(g);
H
 
= + 4623H
2
 
   
3 H;
H
 
= + 436
×
2321N
2
 
   
N;
H
 
= + 712
×
21
 ––––––––––––––––––––––––––––––––––––––––––––––––
NH
3
(g)
   
N
 
(g) + 3H (g);
H
 
= + 1056 kJ mol
 –
1
Average bond energy of N
 –
H bond =
31056
= + 352 kJ mol
 –
1
2.
The time for half life period of a certain reaction A
   
Products is 1 hour. When the initial concentrationof the reactant
A
, is 2.0 mol L
 –
1
, how much time does it take for its concentration to come from 0.50 to 0.25mol L
 –
1
. If it is a zero order reaction?(1) 4 h(2) 0.5 h(3) 0.25 h(4) 1 h
Ans.(3)Sol.
A
   
productFor zero order reactiont
1/2
 
1n
a1
a = initial concentration of reactantt
1/2
a
2122 / 1 12 / 1
aa)t()t(
50.02)t(1
22 / 1
t
1/2
=25.0= 0.25 h.
 
Page # 33.
A solution containing 2.675 g of CoCl
3
. 6 NH
3
(molar mass = 267.5 g mol
 –
1
) is passed through a cationexchanger. The chloride ions obtained in solution were treated with excess of AgNO
3
to give 4.78 g of AgCl(molar mass = 143.5 g mol
 –
1
). The formula of the complex is (At. mass of Ag = 108 u)(1) [Co(NH
3
)
6
] Cl
3
(2) [CoCl
2
(NH
3
)
4
] Cl(3) [CoCl
3
(NH
3
)
3
](4) [CoCl(NH
3
)
5
] Cl
2
Ans.(1)Sol.
Mole of CoCl
3
. 6NH
3
=
5.267675.2
= 0.01AgNO
3
(aq) + Cl
 –
(aq)
   
AgCl

(white)Mole of AgCl =
5.14378.4
= 0.030.01 mole of CoCl
3
. 6NH
3
gives 0.03 mole of AgCl
1 mole of CoCl
3
.
 
6NH
3
ionises to give 3 moles of Cl
 –
.Hence the formula of compound is [Co(NH
3
)
6
] Cl
3
4.
Consider the reactionCl
2
(aq) + H
2
S(aq)
   
S(s) + 2H
+
(aq) + 2Cl
 –
(aq)The rate equation for this reaction israte = k [Cl
2
][H
2
S]Which of these mechanisms is/are consistent with this rate equation?A.Cl
2
+ H
2
S
   
H
+
+ Cl
 –
+ Cl
+
+ HS
 –
(slow)Cl
+
+ HS
 –
 
   
H
+
+ Cl
 –
+ S (fast)B.H
2
S
H
+
+ HS
 –
(fast equilibrium)Cl
2
+ HS
 –
 
   
2Cl
 –
+ H
+
+ S (slow)(1) B only(2) Both A and B(3) Neither A nor B(4) A only
Ans.(4)Sol.
Mechanism (1)rate = K [Cl
2
] [H
2
S]Mechanism (2)rate = K
1
[Cl
2
] [HS
 –
]K
eq
=]SH[ ]HS][H[
2
[HS
 –
] =
]H[]SH[K
2eq
= K
1
K
eq
 
]H[]SH][Cl[
22
Mechanism (1) is consistent with this rate equation.
5.
If 10
 –
4
dm
3
of water is introduced into a 1.0 dm
3
flask at 300 K, how many moles of water are in the vapourphase when equilibrium is established ?(Given : Vapour pressure of H
2
O at 300 K is 3170 Pa ; R= 8.314 J K
 –
1
mol
 –
1
)(1) 5.56
× 10
 –
3
mol(2) 1.53
× 10
 –
2
mol(3) 4.46
× 10
 –
2
mol(4) 1.27
× 10
 –
3
mol
Ans.(4)

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