ABC CLASSES FOR IIT-JEE

ALKANES, ALKENES, ALKYNES Home Assignment-1

1. Me CH = CH2 on reaction with BrCl gives (A) and with NOCl gives (B). (A) and (B) are :
(a) MeCH Cl CH2 Br, MeCH (Cl) CH2NO (b) Me CHCl CH2Br, Me CH (NO) CH2Cl
(c) Me CHBr CH2 Cl, MeCH Cl CH2 NO (d) MeCH Br CH2 Cl, Me CH (NO) CH2 Cl.
2. An alkene (A) is less stable (thermodynamically) than its diastereomer (B). Either of (A) or (B) on ozonolysis gives
only one aldehyde. Which of the following is correct :
(a) (A) Baeyer
   →
's reagent
Meso product (b) (B) Peroxy
  → meso product
formic acid
(c) both (d) None.
3. An alkene (A) on Sabatier-Senderens reduction gives lowest normal alkane which can perform sulphonation. (A)
on ozonolysis may give.
(a) n- butyraldehyde and ethanal (b) propionaldehyde (c) acetone & formaldehyde (d) both (a) & (b).
4. 2 – butene on reaction with O3/ CCl4 gives : O–O O–O
(a) Me CHO (b) Me COOH (c) Me CH CH Me (d) Me C – C Me..
O O
5. elect the wrong statement : (a) Cis – 3 – hexane on reaction with HCO3H gives racemic mixture
(b) trans -4- octene on reaction with Baeyer’s reagent gives racemic mixture
(c) Cis – 5 – decene on reaction with Baeyer’s reagent gives meso product
(d) trans-6-tridecene on reaction with HCO3H gives meso product.
6. The IUPAC name of : (a) t – pentyl neo hexyl methane is 2, 2, 6, 6 – tetra methyl octane
(b) least molecular wt. optically active enyne (CnH2n-4) but not containing tertiary carbon is 3- ethyl-3-methyl
pent-I-en-4-yne (c) both correct (d) None is correct.
7. Propene on reaction with B2H6 – THF followed by reaction with D2O2 - OD- gives (A) and on reaction with B2D6 -
THF followed by reaction with H2O2 - OH- gives (B). (A) and (B) are :
(a) same (b) primary alcohol racemic mixture
(c) Me CHD CH2OD, MeCHDCH2OH (d) MeCH2CH2OD, MeCH2CH2OH.
8. In which of the following triplets member has + M effect, second member has –I effect and third member is more
acidic than water : (a) - NH2, - F, CH ≡ CH (b) - OH, - NO2, MeOH (c) both (d) None.
9. An alkene (A) on hydroboration oxidation or oxymercuration demercuration gives (B). (B) can not be resolved into
enantiomers. (A) may be : (a) Propene (b) 2 - butane (c) 2 - pentene (d) Styrene.
10. In which of the following chiral centre is generated :
(a) Me CH = CH2 DBr / peroxide (b) Me CH = CH2 DCl / peroxide (c) both (d) None.
11. Maximum no. of carbonyl compounds are obtained in ozonolysis of :
(a) CH2 = CH - CH = CH - CH = CH - CH = CH2 (b) -Me
C Me
(c) (d) Me CH = C (D) CH
12. In which of the following product written is not correct :
(a) Me2 C = CHMe HOCl / H+ Me2C(OH) CHCl Me (b) Me2 C = CH2 NOCl Me2C(Cl) CH2NO

(c) Me CH = CHD DBr / peroxide MeCHDCHD Br (d) CH2 = CHCH2OH Cold dil. / KMnO4 H2 - CH - CHO.
13. Structural formula for Lewisite is :
(a) CHCl = CHAsCl3 (b) CH2 = CHAsCl3 (c) CHCl = CHAsCl2 (d) ClC ≡ C AsCl2.
14. Cetane number of following is assigned to be 100 :
(a) n-hexadecane (b) n-icosane (c) a-methyl napthalene (d) pyridine.
15. Following on reaction with ammonia will give pyrole under suitable conditions :
(a) Benzene (b) Cyclobutane (c) 1, 3 cyclobutadiene (d) Ethyne.

H2O Hot Iron CH3Cl

16. In the following reaction, the product (C) is : (a) CaC2 (A) Tube
(B) (C) :
AlCl3
ABC CLASSES126,2nd Floor , Kingsway Camp, Delhi-110009,Ph.No:011-47041845.
 (a) Benzene (b) Toulene (c) Ethylbenzene (d) n-propyl benzene.
17. (CH3)3CMgCl on reaction D2O produces :(a) (CH3)3CD (b) (CH3)3OD (c) (CD3)3CD (d) (CD3)3OD.
18. In the following groups - OAC(I), -OMe(II), -OSO2Me(III), -OSO2CF3(IV) the order of leaving group ability is :
(a) I >II>III>IV (b) IV>III>I>II (c) III>II>I>IV (d) II>III>IV>I.
19. 2-methyl but-1-ene reacts with mercuric acetate in presence of water to form a product, which on reduction with
NaBH4 yield :(a) 2 methyl butan-2-ol (b) 2 methyl butan-1-ol (c) 3 methyl butan-2- ol (d) None of these.
20. In the chlorination of propane , what would be the expected product ratio of n-propyl chloride to Isopropyl
chloride if all the H-atoms were abstracted at equal rates : (a) 1 : 1 (b) 2 :1 (c) 3 : 1 (d) 6 : 1.
21. Phthalic anhydride + benzene AlCl 3 1) Zn/Hg, HCl AlCl 3 Final compound. Write the final Compound :
O 2) PCl3
(a) (b) C (c) (d) (e) None of these.
COCl
O
22. Consider the following substaces -1)1, 3 di methyl benzene 2)1 ,4 dimethyl benzene3) Toulene 4) Benzene 5) 1, 3, 5
trimethyl benzene . Arrange these substances in decreasing order of their relative reactivity towards electrophile :
(a) 5 > 1 > 2 >3 > 4 (b) 1 > 2 > 5 >3 > 4 (c) 1 > 5 > 2 >3 > 4 (d) 2 > 1 > 5 >3 > 4.
OH CH3
23. CH3 H2SO4 Main product is : (a) CH3 (b) CH3 (c) CH3 (d) CH3 .
CH3 CH3 CH3 CH3
CH3
CH3 4 CH3 CH3
3 CH3
24. undergoes electrolyphilic substitution reaction preferentially :
2
N1
..
(a) at 2 position (b) at 3 position (c) at 4 position (d) at 2 & 4 position.
25. Identify the final product C6H5CH3 Cl2 NBS Mg(1 mole) 1) ethylene oxide final product.
+
Fe Ether 2) H3O
(a) pClC6H4CH2CH2CH2OH (b) pHOC6H4CH2CH2OH
(c) pClC6H4CH2CHOH (d)pClC6H4CH2CH2CH2OH
26. 3 mole mixture of 1 butyne and 2 butyne forms 11.2 It H2 gas at N.T.P. Hence mole fraction of 1-butyne is :
(a) 0.25 (b) 0.75 (c) 0.66 (d) 0.33.
27. CH ≡ C - C - OH HgSO 4 A A is : (a) CHOCH2COOH (b) CH CCOOH (c) (d) No reaction.
H2SO4
3 CH2=CH-C-OH
Alkaline O
28. CH3-C ≡ C - CH3 Lindlar’s (A) KMnO (B) : O
4
(a) A is cis - 2 butene, B is meso compound (b) A is trans 2 butene, B is reacemic mixture
(c) A is cis -2 butene, B is racemic mixture (d) A is trans2butene, B is meso compound.
29. Propyne is reacted with ammonical cuprous chloride and the product is treated with oxygen to obtain A, A is :
(a) CH3 - C ≡ C - OH (b) CH3C ≡ C - C≡ C - CH3 (c) CH3CH2CHO. (d) CH3COCH3.
30. CH ≡ CH + HCl → CH2 = CH - Cl + ∆ → ? (a) Chloroprene (b) P.V.C. (c) Bakelite (d) Neoprene.
31. Following will not yield a cyclic compound on heating :
CH2COOH COOH
(a) COOH (b) CH2COOH (c) (d)
CH2 COOH
CH2 CH COOH
CH2COOH 2
COOH
32. Cold & dil KMnO4 combines with but-2yne to form :
(a) butan-2one (b) butnane-2,3dione (c) butane-2,3diol (d) butane1,3diol.
33. 2 – butyne on reduction with H2-Lindlar’s catalyst gives (A). (A) on treatment with the Baeyer’s reagent gives (B).
Which of the following is correct :
(a) (A) is Cis-2-butene, (B) can be resolved (b) (A) is trans-2-butene, (B) is meso product
(c) (A) is cis-2butene, (B) is racemic mixture (d) None of these.
34. Acetylene on reduction with H2/ p – 2 catalyst gives (A) and on reduction with H2/ Pt catalyst gives (B). Which of
the following is correct : (a) (A) on reaction with Me3C – Cl in presence of AlCl3 gives Me3C – CH2CH2Cl.
(b) (B) on reaction with conc. HNO3 at about 5000C gives two products having difference in molecular wt. of 14.
(c) both (d) None.
35. In which of the following pairs both members can not be prepared by Sabatier Senderens method:
 (a) (isobutene, neopentane) (b) (neopentnae, 2,2,3,3-tetrametyhl butane) (c) both (d) None
36. In which of the following reaction the product written is not the major product :
(a) 1 – butene Cl
2 /  → 4-chloro – 1 - butene
high temp .
(b) 2 Me2 C = CH2 H 2 SO

4 → CH2 = C(Me) – CH2 CMe3
(c) both (d) None.
nd
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