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June 2010
GCE
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Summer 2010
Publications Code UA023646
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© Edexcel Ltd 2010
Role of zinc
Reducing agent / Reduces / Reduction /
providing electrons (1)
Explanation
The Cr2+ / chromium(II) / Cr(II) (allow ‘blue
species’) is oxidized by (oxygen in) the air (1)
OH
O OH
Titres 8 9 8 9 9 (1)
used
(9 or
8)
Allow 23 / 23.0
TE from (c)(i)
Ignore SF except 1 SF
Ignore correct intermediate rounding of
calculated values
Allow 56 for Ar of iron (95.7 %)
Allow TE from (c)(i) and (ii)
Correct answers with no working score full
marks
Allow
Large number of H+ ions required in (titration)
equation
8 moles H+ ions required (per mol Fe2+ in
titration)
To prevent oxidation of Fe2+ by (oxygen in) air
or by water
To prevent hydrolysis
Ignore SF except 1 SF
Correct answer with no working scores full
marks
Mr values reversed scores max 1 only if a mole
calculation is clearly shown
To ensure
complete
reaction
Allow
reaction is vigorous
so that the temperature does not increase (too
much)
Ignore references to the reaction being violent,
dangerous, explosive etc
Mistake:
Flammable liquids are being heated with a
Bunsen/naked flame (1)
Correction
so the Bunsen burner should be replaced by a
hot plate (allow water bath) (1)
OR
Mistake:
Heating with a Bunsen too strong (so glass may
crack) (1)
Correction
Use micro-burner/gauze (1)
Alternatively
Moles phenylamine =9/93 = 0.0968
Moles N-phenylethanamide = 7.49/135 = 0.0555
(1)
Yield = 100 x .0555/.0968 = 57.3 % (1)
Ignore sf except 1 sf
Yields greater than 100 % score zero