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r050211802 Thermodynamics and Kinetics
r050211802 Thermodynamics and Kinetics
1
II B.Tech I Semester Regular Examinations, November 2007
THERMODYNAMICS AND KINETICS
(Metallurgy & Material Technology)
Time: 3 hours Max Marks: 80
Answer any FIVE Questions
All Questions carry equal marks
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2. (a) Claculate the work done for the following reversible process
i. Isobaric
ii. Adiabatic
(b) What are point and path functions ? Give some examples [8+8]
3. (a) Show that d ∆H
dp
s = ∆v
(b) Name the intensive and extensive parameters in the entropy representation .
Explain them.
(c) The entropy of hot baked potato decreases as it cools . is this a violation of
the increases of entropy principle ? Explain. [16]
5. (a) State and explain the third law of thermodynamics .what is its importance.
[6]
(b) Derive an expression to show variation of equilibrium constant with tempera-
ture. [10]
6. (a) What the relation between free energy and equilibrium constant for any reac-
tion and explain.
(b) At equilibrium of any reaction what is the relation of free energy change and
equilibrium constant and explain. [16]
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Code No: R050211802 Set No. 1
(b) Explain collision theory of chemical reaction. [16]
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Code No: R050211802 Set No. 2
II B.Tech I Semester Regular Examinations, November 2007
THERMODYNAMICS AND KINETICS
(Metallurgy & Material Technology)
Time: 3 hours Max Marks: 80
Answer any FIVE Questions
All Questions carry equal marks
⋆⋆⋆⋆⋆
5. (a) State and explain the third law of thermodynamics .what is its importance.
[6]
(b) Derive an expression to show variation of equilibrium constant with tempera-
ture. [10]
6. (a) ‘Fugacity of a component is equal to its activity for ideal solution’. Say true
or false and explain why is it so.
(b) Derive an expression for the change in the free energy when 1gram mole of a
pure substance goes in solution. [16]
8. (a) Explain the standard free energy change for any reaction. [6]
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Code No: R050211802 Set No. 2
(b) Determine the equilibrium constant at 250 c for the reaction
CH4 (g) + H2 O(l) → CO(g) + 3H2 (g)
Data: [10]
COMPONENT ∆0 G at 250 c
CO(g) -137.8 KJ/mole
CH4 (g) -50.09 KJ/mole
H2 O (1) -238.0 KJ/mole
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Code No: R050211802 Set No. 3
II B.Tech I Semester Regular Examinations, November 2007
THERMODYNAMICS AND KINETICS
(Metallurgy & Material Technology)
Time: 3 hours Max Marks: 80
Answer any FIVE Questions
All Questions carry equal marks
⋆⋆⋆⋆⋆
5. (a) State and explain the third law of thermodynamics .what is its importance.
[6]
(b) Derive an expression to show variation of equilibrium constant with tempera-
ture. [10]
6. (a) What the relation between free energy and equilibrium constant for any reac-
tion and explain.
(b) At equilibrium of any reaction what is the relation of free energy change and
equilibrium constant and explain. [16]
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Code No: R050211802 Set No. 3
(b) The vapor pressure P of liquid A is given by Log P (mm) = -2450/T +6.69
abd that of a solid A by log P(mm)=6947+10.8. Calculate the temperature
at which liquid and solid will have the same vapor pressure. [16]
8. (a) Bring out the important characteristic of a catalyst and explain its action.
(b) Explain the various factors affecting the rate of reaction. [16]
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Code No: R050211802 Set No. 4
II B.Tech I Semester Regular Examinations, November 2007
THERMODYNAMICS AND KINETICS
(Metallurgy & Material Technology)
Time: 3 hours Max Marks: 80
Answer any FIVE Questions
All Questions carry equal marks
⋆⋆⋆⋆⋆
1. (a) Name few macroscopic modes of energy and a few microscopic modes of energy.
(b) Distingush between study state and equilibrium.
(c) State and explain the criteria which the system should satisfy for it to be in
a thermodynamic equilibrium. [6+5+5]
3. Calculate the standard entropy of a pure iron at 16270C if it’s standard entropy
at 250 C is 6.50 Cal / deg / mole. The phase transformation in pure iron may be
represented as follows : [16]
< α − F e >→< β − F e >→ 9100 c < γ − F e >→ 14000 c < δ − F e >→ 15390 c{F e}
Given data:
Cp, < α − F e >= 4.18 + 5.92∗ 10−3 T cal/deg/mole
Cp, < β − F e > = 9.0 cal/deg/mole
Cp, < γ − F e >= 1.84 + 4.66∗ 10−3 T cal/deg/mole
Cp, < δ − F e > = 10.50 cal/deg/mole
Cp, {Fe} = 10.0 cal/deg/mole
0
< α − F e >→< β − F e >; ∆H760 0 c = 660 cal/ mole
0
< β − F e >→< γ − F e >; ∆H9100 c = 215 cal/mole
0
< γ − F e >→< δ − F e >; ∆H1400 0 c = 165 cal/ mole
0
< δ − F e >→ {F e}; ∆H15390 c = 3670 cal/mole
4. (a) What do you understand by the term free energy of a system. what is its
Significance?
(b) From the first principles, derive the equations for the Gibbs free energy ∆G =
∆H − T ∆S
(c) How can free energy change of a reaction determine experimentally. [16]
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Code No: R050211802 Set No. 4
(b) Discuss the use of third law of thermodynamics in evolution of ∆S O of a
reaction [8]
6. (a) Derive Van ‘thoff’s equation for the variation with temperature of equilibrium
constant.
(b) Explain how standard free energy of reaction related to the equilibrium con-
stant of a reaction. [16]
7. (a) Say true or false the following statements with suitable Explanation. Activity
of component can never be greater then unity in a system under equilibrium.
(b) State and explain Troutons rule. [16]
8. (a) Derive an expression for the rate constant of a first order reaction
(b) Discuss the importance of equilibrium constant and its effects on equilibrium
conversion. [16]
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