Tuesday, October 02, 2012

Tuesday, October 02, 2012

Chng 3

AMIN AMINO AXIT PROTEIN

Tuesday, October 02, 2012

Bi 9
Tuesday, October 02, 2012

AMIN

1. Khi nim, phn loi a) Khi nim 3 2 Khi thay th mt hay nhiu nguyn t hiro trong Metylamin phn t NH3 bng mt hay nhiu gc hirocacbon ta c 5 6 amin. 2 3

CH NH

C H NH Amin NH
VD Amoniac Phenylamin CH3NH2 (Metylamin) CH3 NH CH3 (imetylamin) C6H5 NH2 (Phenylamin)

imetylamin

CH3-NH-CH3

Tuesday, October 02, 2012

I. KHI NIM, PHN LOI, DANH PHP & NG PHN

b) Phn loi GC HIROCACBON Amin bo: CH3NH2,

C2H5NH2, Amin thm: C6H5-NH2,

Amin bc 1: C6H5-NH2,

BC AMINAmin bc 2: CH3-NH-CH3
Amin bc 3: CH3-N-CH3 CH3

Tuesday, October 02, 2012

I. KHI NIM, PHN LOI, DANH PHP & NG PHN

2. Danh php
Hp cht
CH3NH2

Tn gc chc
Metylamin

Tn thay th
Metanamin

Tn thng

C2H5NH2
CH3CH2CH2NH2

Etylamin
Propylamin

Etanamin
Propan-1-amin

CH3CH(NH2)CH3 Isopropylamin
C2H5NHC2H5 ietylamin

Propan-2-amin
N-etyletanamin

C6H5NH2
H2N[CH2]6NH2

Phenylamin

Benzenamin

Anilin

Hexametyleniamin Hexan-1,6-iamin

Tuesday, October 02, 2012

I. KHI NIM, PHN LOI, DANH PHP & NG PHN

V d: C4H11N c cc ng phn nh sau:

(1) CH3-CH2-CH2-CH2-NH2
CH3

(2) CH3 CH2

CH NH2

CH3

(3) CH3

C NH2

CH3

CH3

(5) CH3
CH2 NH2

NH CH2

CH2 NH

CH2 CH2

CH3 CH3

(4) CH3

CH

(6) CH3

(8) CH3

N CH3

CH2

CH3

(7) CH3

CH CH3

NH

CH3

Tuesday, October 02, 2012

3. ng phn Gm c ng phn v mch cacbon, v v tr nhm chc, v bc amin.

II. TNH CHT VT L

- CH3NH2, CH3NHCH3, (CH3)3N: cht kh, mi khai, tan nhiu trong nc. - Cc amin c phn t khi cao hn l cht lng hoc rn, nhit si tng dn v tan trong nc gim dn theo chiu tng ca phn t khi. - Cc amin thm u l cht lng hoc rn, d b oxi ha chuyn t khng mu thnh mu en. - Cc amin u c.
Tuesday, October 02, 2012

III. CU TO PHN T - TNH CHT HA HC

1. Cu to phn t
N
H H H

N
H R H

N
R R H
R R

N
R

Amoniac

Amin bc 1

Amin bc 2

Amin bc 3

Tuesday, October 02, 2012

III. CU TO PHN T - TNH CHT HA HC

2. Tnh cht ha hc a) Tnh baz - Cc amin bo lm qu tm ha xanh, lm hng phenolphtalein. - Anilin v cc amin thm khng lm qu tm ha xanh, khng lm hng phenolphtalein. Sp xp tnh baz ca amin. (CH3)2NH>CH3CH2NH2>CH3NH2 >CH3CH2CH2NH2> (CH3)3N>NH3 > C6H5NH2 > (C6H5)2NH
Tuesday, October 02, 2012

III. CU TO PHN T - TNH CHT HA HC

2. Tnh cht ha hc b) Phn ng th nhn thm ca anilin
NH2 H H
NH2 Br Br

+ 3Br2
Br

+ 3HBr
Kt ta trng

Do nh hng ca nhm NH2 nn 3 nguyn t hiro v tr ortho v para d b thay th bi 3 nguyn t brom.

Tuesday, October 02, 2012

B. 12,95 (g)
C

C. 12,59 (g)

D. 11,85 (g)

Tuesday, October 02, 2012

Bi 1: Cho 9,3 gam anilin (C6H5NH2) tc dng va vi axit HCl. Khi lng mui thu c l A A. 11,95 (g)

Bi tp cng c:

A. Dd HCl

B. Nc brm
C. Qu tm D. Qu tm, nc brm

C
D

Tuesday, October 02, 2012

Bi 2:Thuc th dng nhn bit 3 cht lng ring bit anilin, metylamin v ancol etylic l

A. CH3-NH2 B. C6H5-NH2 C. NH3 D. CH3-NH-C2H5

Chon ap an ung.
a) A > B > D > C b) D > B > C > A c) D > A > C > B c) DB>>A >>C >>BD d) A C

Tuesday, October 02, 2012

B i 3:Sap xep tnh baz theo chieu tang dan

cua cac chat sau:

- Hc bi - Lm bi tp 1, 2, 3, 5, 6 SGK P4

Tuesday, October 02, 2012

Dn d