PHN BA

GII THIU KIM TRA

Chng 1 & 2 KIM TRA 15 PHT- CACBOHIRAT (cho cc vng kh khn)
Hy chn cu ng. 1. Mt trong nhng d kin thc nghim dng chng minh c cu to mch h ca glucoz l A. glucoz cho phn ng trng bc. B. glucoz c phn ng este ho. C. 1 mol glucoz chy sinh ra 6 mol CO2 v 6 mol H2O. D. khi c xc tc enzim, dung dch glucoz ln men to etanol. Mt cacbohirat (X) c cc phn ng din ra theo s sau :
Cu(OH)2 / OH t X dung dch xanh lam kt ta gch. Vy X khng th l A. glucoz. B. saccaroz. C. fructoz. D. mantoz.
o

2.

3.

4.

5.

Glucoz ha tan c Cu(OH)2 v glucoz A. c tnh axit. B. c nhiu nhm OH k nhau. C. c nhm CHO. D. c lin kt cng ho tr phn cc. Cht no sau y thuc loi isaccarit ? A. Glucoz. B. Tinh bt. C. Saccaroz. D. Xenluloz. Cacbohirat l A. hp cht a chc, c cng thc chung l (C6H10O5)n. B. hp cht tp chc, a s c cng thc chung l Cn(H2O)m.
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C. hp cht cha nhiu nhm hiroxil v nhm cacboxil. 6. D. hp cht a chc, a s c cng thc chung l Cn(H2O)m. Pht biu no di y khng chnh xc ? A. isaccarit l nhng cacbohirat khi thy phn u sinh ra hai loi monosaccarit. B. isaccarit l nhng cacbohirat khi thy phn sinh ra hai phn t monosaccarit. C. Polisaccarit l nhng cacbohirat khi thy phn sinh ra nhiu phn t monosaccarit. D. Tinh bt, mantoz v fructoz ln lt l polisaccarit, isaccarit v monosaccarit. Glucoz khng c tnh cht no di y ? A. Tnh cht ca nhm anehit. B. Tnh cht ancol a chc. C. Tham gia phn ng thy phn. D. Tc dng vi CH3OH trong HCl. 8. Pht biu no di y v xenluloz l khng ng ? A. Xenluloz c trong cc loi rau, c, qu. B. Xenluloz c dng iu ch mt s loi t. C. Xenluloz c dng lm nguyn liu sn xut ancol etylic. D. Xenluloz lm thc phm cho con ngi. Cho 3 kg glucoz c cha 10% tp cht ln men thnh ancol etylic. Trong qu trnh ch bin lng ancol b hao ht mt 10%. Khi lng ancol thu c l A. 1,242 kg. B. 1,533 kg. C. 1,423 kg. D. 1,380 kg. Pht biu no sau y khng ng ? A. Tinh bt phn ng vi dung dch iot cho mu xanh tm. B. T xenluloz c th iu ch t. C. Tinh bt c th tham gia phn ng trng gng. D. Xenluloz b thy phn thnh glucoz.

7.

9.

10.

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p n Cu p n 1 A 2 C 3 B 4 C 5 B 6 A 7 C 8 D 9 A 10 C

KIM TRA 15 PHT- CACBOHIRAT (cho cc vng thun li)

Hy chn cu ng. 1. Mantoz v fructoz u A. tham gia phn ng thy phn. B. c 1 nhm OH hemiaxetal. C. cho phn ng trng bc. D. lm mt mu nc Br2. 2. Mt cacbohirat X c cc phn ng din ra theo s sau :
Cu(OH)2 /OH t X dung dch xanh lam kt ta gch. Vy X c th l A. glucoz, mantoz hay saccaroz. B. glucoz, mantoz hay fructoz. C. glucoz hay saccaroz. D. glucoz, mantoz hay tinh bt. Cho cc dung dch : glucoz, mantoz, saccaroz, fructoz, h tinh bt, ancol etylic. C bao nhiu dung dch c th ha tan c Cu(OH)2 ? A. 3. B. 4. C. 5. D. 6. Nhn xt no sau y ng ? A. Trong dung dch, saccaroz c th m vng cn mantoz th khng. B. Saccaroz c nhm OH hemixetal v mantoz c nhm OH hemiaxetal.
o

3.

4.

C. Saccaroz v mantoz u to ra hai phn t C6H12O6 khi b thy phn. D. Saccaroz v mantoz u cho phn ng vi dung dch Ag[(NH3)2]OH. 5. nhn bit cc l mt nhn ng cc dung dch : saccaroz, mantoz, etanol, fomalin, axit axetic, c th dng
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A. Cu(OH)2/OH. C. nc Br2. 6.

B. dung dch Ag[(NH3)2]OH. D. Na v Cu(OH)2/OH.

7.

Cho 200 gam dung dch cha glucoz tc dng vi dung dch AgNO3/NH3 d, khi lng Ag sinh ra cho vo dung dch HNO3 m c thy sinh ra 0,2 mol kh NO2. Gi s phn ng xy ra hon ton, nng % ca glucoz trong dung dch ban u l A. 9%. B. 18 %. C. 27%. D. 36%. Fructoz phn ng c vi tt c cc cht sau: A. nc Br2 ; Cu(OH)2 / OH ; Ag[(NH3)2]OH. B. H2O/H+ ; Cu(OH)2 ; Ag[(NH3)2]OH. C. Ag[(NH3)2]OH ; HNO3 c/ H2SO4 c ; Cu(OH)2. D. Ag[(NH3)2]OH ; HNO3 c/ H2SO4 c ; CH3OH/HCl.

8.

phn bit glucoz v fructoz th nn chn thuc th no di y ? A. Dung dch AgNO3 trong NH3. B.. Cu(OH)2 trong mi trng kim. C. Nc Br2. D. Dung dch Br2 trong CCl4.

9.

10.

Qu trnh thy phn tinh bt bng enzim to ra cc cht : A. extrin, fructoz, glucoz. B. extrin, mantoz, glucoz. C. mantoz, fructoz, glucoz. D. extrin, saccaroz, glucoz. Cho 6,84 gam hn hp saccaroz v mantoz tc dng vi lng d dung dch AgNO3 trong NH3 thu c 1,08 gam Ag kim loi. S mol saccaroz v mantoz trong hn hp ln lt bng A. 0,005 mol v 0,015 mol. B. 0,010 mol v 0,010 mol. C. 0,015 mol v 0,005 mol. D. 0,050 mol v 0,150 mol. 1 C 2 B 3 B 4 C 5 A 6 A 7 C 8 C 9 B 10 C

p n Cu p n

KIM TRA 15 PHT - CACBOHIRAT

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(Chng trnh chun)

Hy chn cu ng. 1. iu no sau y khng ng khi ni v xenluloz ? A. Tan trong dung dch [Cu(NH3)4](OH)2 B. C th dng iu ch ancol etylic C. Dng sn xut t enang D. Phn ng vi hn hp HNO3 c v H2SO4 c 2. Glucoz v fructoz khng phn ng vi A. H2O (xc tc H+, to). C. Cu(OH)2. 3. B. H2 (xc tc Ni, to). D. dd AgNO3 / NH3.

Cho dy chuyn ho : X tinh bt glucoz Y. Cc cht X, Y ln lt l A. CO2 v C2H5OH. C. C2H5OH v CH3COOH. B. CH3OH v CO2. D. CH3CHO v C2H5OH.

4.

5.

6.

Tnh cht no di y m saccaroz v glucoz khng ng thi c c ? A. Tnh cht ca ancol a chc. B. Tnh cht ca anehit. C. Phn ng chy. D. Tan tt trong nc. Lng kt ta Ag hnh thnh khi tin hnh trng gng hon ton dung dch cha 9 gam glucoz l A. 1,08 gam. B. 2,70 gam. C. 5,04 gam. D. 10,80 gam. Cho dy chuyn ho :
2 4 ln men r u Glucoz X Y 170o C

H SO 98%

7.

Ch xt sn phm chnh th Y trong dy chuyn ho trn l A. kh etilen. B. imetyl ete. C. ancol etylic. D. axit axetic. ng dng no sau y khng ng ?
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115

8.

9.

10.

A. Trong cng nghip, ngi ta dng saccaroz trng gng. B. Dung dch saccaroz c truyn vo tnh mch cho ngi bnh. C. Xenluloz dng sn xut vi may mc. D. T g ngi ta sn xut ancol etylic. Cp cht no sau y u thuc loi isaccarit ? A. glucoz, mantoz. B. fructoz, saccaroz. C. saccaroz, mantoz. D. mantoz, xenluloz. Nhn nh no sau y khng ng ? A. Tinh bt c phn ng vi dung dch iot cho mu xanh tm. B. Xenluloz khng tham gia phn ng este ho. C. Tinh bt tham gia phn ng trng gng. D. Tinh bt d b thy phn thnh glucoz. Khi lng glucoz cn iu ch 0,1 lt ancol etylic (D = 0,8 g/ml) vi hiu sut 80% l A. 185,6 g. B. 196,5 g. C. 190 g. D. 200 g. 1 C 2 A 3 A 4 B 5 D 6 A 7 B 8 C 9 C 10 B

p n Cu p n

KIM TRA 1 TIT Chng trnh nng cao (Dnh cho vng thun li)
I. Trc nghim khch quan 1. Khi thy phn este vinyl axetat bng dung dch NaOH v un nng ngi ta thu c A. CH3COONa v CH3CHO B. CH3COONa v CH2=CHOH C. CH3COONa v C2H5OH D. CH3COONa v CH3OH
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2.

3.

4.

Pht biu no sau y khng ng ? A. Cht bo lng l cht bo m phn t cha gc axit bo khng no. B. Du m thc vt v du bi trn my u l lipit. C. Tt c cht bo u khng tan trong nc. D. Cht bo l este ca glixerol vi axit bo. Nhn nh no sau y khng ng v tnh cht ca este ? A. C th l cht lng hoc cht rn. B. D tan trong nc. C. Nhit si thp. D. a s c mi thm. Cho phn ng : CH3COOH + C2H5OH CH3COOC2H5 + H2O. tng hiu sut ca phn ng trn, tc ng no sau y hp l ? A. Tng nng CH3COOH, thm H2SO4 m c, tch CH3COOC2H5. B. Tng nng CH3COOC2H5, tch CH3COOH, thm H2SO4 m c. C. Tch H2O, tch CH3COOH, thm H2SO4 m c. D. Tng nng C2H5OH, tch CH3COOC2H5, gim nng C2H5OH.

5.

Sn phm ca phn ng kh CH3COOCH2CH3 bi LiAlH4 l A. CH3CH2OH v CH3COOH C. CH3CH2COOH v CH3OH B. CH3CH2OH D. CH3COOH.

6.

Phn ng no sau y c dng iu ch phenyl axetat ? A. C6H5OH + CH3COOH C6H5OOCCH3 + H2O B. C6H5OH + (CH3CO)2O C6H5OOCCH3 + CH3COOH C. C6H5COOH + CH3OH C6H5OOCCH3 + H2O D. C6H5Cl + CH3COOH C6H5OOCCH3 + HCl

7.

Trong cc ng dng sau, ng dng no khng phi ca este ? A. Este c dng lm dung mi ho tan cc hp cht hu c. B. c dng lm thu tinh hu c, cht do v dc phm. C. Dng trong cng nghip thc phm v lm m phm. D. Dng iu ch cht bo lng.
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8.

Hai ng phn X v Y c cng thc phn t C3H6O2. X v Y u phn ng c vi dung dch NaOH, X phn ng vi natri kim loi gii phng H 2, cn Y th khng nhng Y tham gia phn ng trng bc. Cng thc cu to ca X v Y ln lt l A. CH3CH2COOH v HCOOCH2CH3. B. CH3CH2COOH v HOCH2CH2CHO. C. CH3COOCH3 v HOCH2CH2CHO. D. CH3COOCH3 v HCOOCH2CH3.

9.

10.

trung ho 2,8 gam mt cht bo cn 3 ml dung dch KOH 0,1M. Vy ch s axit ca cht bo l A. 4. B. 5. C. 6. D. 7. Pht biu no sau y ng ? A. Lipit l este ca glixerol v cc axit bo. B. Cht bo l cc triglixerit C. M ch cha cc gc axit bo cao no. D. Cht bo rn t tan trong nc, cht bo lng d tan trong nc. t chy hon ton este X thu c s mol CO2 bng s mol H2O. Vy X l este A. n chc, mch h, c mt ni i C=C. B. no, n chc, mch h. C. no, hai chc, mch h. D. n chc, mch h, c mt ni i C=C hay n chc, mt vng no. Cho s chuyn ho :
+ NaOH + NaOH, t X Y CH4
o

11.

12.

Cc cht phn ng vi nhau theo t l mol 1 : 1. Cng thc khng ph hp vi cht X l A. CH3OOCCH3. C. CH3COONH4. 13. D. HCOOCH3. B. CH3COOH.

Sp xp theo chiu tng dn v nhit si ca cc cht : (1) C3H7COOH, (2) CH3COOC2H5 v (3) C3H7CH2OH, ta c th t : A. (1), (2), (3). B. (2), (3), (1). C. (1), (3), (2). D. (3), (2), (1).

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14.

Khi thu phn hon ton 265,2 gam cht bo bng dung dch KOH thu c 288 gam mt mui kali duy nht. Tn gi ca cht bo l A. glixerol tristearat (hay stearin). B. glixerol tripanmitat (hay panmitin). C. glixerol trioleat (hay olein). D. glixerol trilinoleat (linolein). Glucoz ha tan c Cu(OH)2 v A. glucoz c tnh axit yu. B. glucoz c nhm CHO. C. glucoz c nhiu nhm OH k nhau. D. glucoz c tnh kh. Nhn xt no sau y khng ng ? A. Saccaroz v mantoz u thuc nhm isaccarit. B. Saccaroz v mantoz c cng cng thc phn t. C. Saccaroz v mantoz u to ra hai phn t glucoz khi b thy phn. D. Saccaroz khng phi ng kh, mantoz l ng kh. Nhn xt no sau y ng ? A. Trong dung dch mantoz c th m vng cn saccaroz th khng. B. Saccaroz v mantoz u c nhm OH hemiaxetal. C. Saccaroz v mantoz u to ra hai phn t glucoz khi b thy phn. D. Saccaroz v mantoz u c phn ng vi dung dch Ag[(NH3)2]OH. Trong cc cht : saccaroz ; tinh bt ; xenluloz ; mantoz ; fructoz ; extrin, s cht c th tham gia phn ng thy phn l A. 3. B. 4. C. 5. D. 6. Pht biu no sau y khng ng ? A. Saccaroz c dng trong cng nghip trng gng. B. Glucoz v saccaroz c sinh ra khi thy phn xenluloz. C. Glucoz v mantoz c sinh ra khi thy phn tinh bt. D. Xenluloz l nguyn liu sn xut ancol etylic. Tinh bt, xenluloz, saccaroz, mantoz u c kh nng tham gia A. phn ng vi [Cu(NH3)4](OH)2.
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15.

16.

17.

18.

19.

20.

B. phn ng kh vi Cu(OH)2 khi un nng. C. phn ng thy phn. D. phn ng vi Cu(OH)2 nhit phng. II. Trc nghim t lun (5 im) Cu 1 : (2,5 im) Vit cc phng trnh ho hc thc hin dy chuyn ho :
+ HCN + H2O,H H2SO4,180 C CH3CHO A B D E poli(metyl acrylat) Cu 2 : (1 im) Bng phng php ho hc, hy phn bit ba l mt nhn cha ring bit cc cht lng sau : du thc vt, dung dch saccaroz, benzen, ancol etylic. Vit cc phng trnh ho hc (nu c). Cu 3 : (1,5 im) X phng ho hon ton 2,22 gam hn hp X hai este ng phn cn va 1,20 gam NaOH. Khi t chy hn hp hai este trn, ngi ta thu c CO 2 v hi H2O c s mol bng nhau. a) Tm cng thc phn t ca hai este. b) Tm cng thc cu to v gi tn hai este.
+ o

c) Cho 2,22 gam hn hp X phn ng hon ton vi dung dch AgNO3 trong NH3 thu c 2,16 gam bc. Vit phng trnh ho hc v tnh % khi lng ca mi este.

HNG DN GII I. Trc nghim khch quan 1 A 11 B 2 B 12 D 3 B 13 B 4 A 14 C 5 B 15 C 6 B 16 C 7 D 17 A 8 A 18 C 9 C 19 B 10 B 20 C

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II. Trc nghim t lun Cu 1.

xt, t CH3CHO + HCN CH3CH(OH)CN H3O , t CH3CH(OH)CN CH3CH(OH)COOH H2SO4c,180 C CH3CH(OH)COOH CH2=CHCOOH + H2O c, CH2=CHCOOH + CH3OH SO4 CH2=CHCOOCH3 + H2O H 2 t
o o + o o

n CH2=C H OCOCH3

xt, t , p

CH2

CH OCOCH3 n

Cu 2. Cho cc mu th vo nc : Hai mu th tan to dung dch ng nht l saccaroz v ancol etylic. Cho Cu(OH)2 vo 2 mu th ny, mu th to dung dch xanh lam l saccaroz. 2C12H22O11 + Cu(OH)2 (C12H21O11)2Cu + 2H2O Hai mu th khng tan (c s phn lp) l du thc vt v benzen. Cho dung dch NaOH d vo 2 mu th ny ri un nng, mu th no tan l du thc vt RCOO CH2 CH OH
2

RCOO RCOO Cu 3. a) nNaOH =

CH CH2

NaOH

3RCOONa + CH CH2

OH OH

1 ,20 = 0,03 (mol) 40

Hn hp este chy thu c s mol CO2 bng s mol H2O este thuc loi n chc no mch h : CnH2nO2 Ta c : 1 mol este n chc phn ng vi 1 mol NaOH 2,22 = 74 (g/mol) n este = n NaOH = 0,03 mol M este = 0,03
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14n + 32 = 74 n = 3 CTPT : C3H6O2 b) C3H6O2 c 2 ng phn este CH3COOCH3 : metyl axetat HCOOCH2CH3 : etyl fomat 2,16 nAg = = 0,02 (mol) 108

c)

HCOOCH2CH3 + 2[Ag(NH3)2]OH NH4OCOCH2CH3 + 2Ag + 3NH3 + H2O 0,01 0,02 Khi lng etyl fomat = 0,01.74 = 0,74 gam 0,74 100% = 33,33% % mHCOOCH2CH3 = 2,22 % mCH3COOCH3 =66,67%

KIM TRA 1 TIT Chng trnh nng cao ( Dnh cho vng kh khn)

I. Trc nghim khch quan

1. Pht biu no sau y khng ng ? A. Cht bo lng l cht bo m phn t cha gc axit bo khng no. B. Du m thc vt v du bi trn xe my u l lipit. C. Lipit khng tan trong nc. D. Cht bo l este ca glixerol vi axit bo. Nhn nh no sau y khng ng v tnh cht ca este ? A. C th l cht lng hoc cht rn. B. D tan trong nc. C. Nhit si thp. D. a s c mi thm. Este khng c ng dng no sau y ?

2.

3.

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4.

A. Lm dung mi ho tan cc hp cht hu c. B. Sn xut thu tinh hu c, cht do v dc phm. C. Dng trong cng nghip thc phm v lm m phm. D. Dng lm keo dn v cht t nh cn v cn kh. Pht biu no sau y ng ? A. Lipit bao gm cht bo, sp, cacbohirat, steroit ... B. Cht bo l cc triglixerit. C. M ch cha cc gc axit bo cao no. D. Cht bo rn t tan trong nc, cht bo lng d tan trong nc. Sp xp theo chiu tng dn v nhit si ca cc cht : (1) C3H7COOH, (2) CH3COOC2H5 v (3) C3H7CH2OH, ta c th t : A. (1), (2), (3). B. (2), (3), (1). C. (1), (3), (2). D. (3), (2), (1). Nhn nh no sau y ng ? A. Thy phn cht bo trong mi trng axit l phn ng x phng ho. B. Phn ng ca glixerol vi HNO3 c to ra glixerol trinitrat l phn ng este ho. C. C th dng cht git ra tng hp git o qun trong nc cng. D. X phng lm sch vt bn v cho phn ng ho hc vi cht bn. Cacbohirat l A. hp cht a chc, c cng thc chung l Cn(H2O)m. B. hp cht tp chc, a s c cng thc chung l Cn(H2O)m. C. hp cht cha nhiu nhm hiroxil v nhm cacboxil. D. hp cht ch c ngun gc t thc vt.

5.

6.

7.

8.

Glucoz ha tan c Cu(OH)2 v glucoz A. c tnh axit yu. B. c nhm CHO. C. c nhiu nhm OH k nhau. D. c tnh kh. Cch thc hin vic git ty no sau y ng ?
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9.

10.

11.

12.

13.

14.

A. lm sch vt du, m dnh trn o ta nn dng nc Giaven. B. lm sch vt mc dnh trn o ta nn dng cht git ra tng hp. C. lm sch vt du, m dnh trn o ta nn dng x phng. D. lm sch tt c cc vt bn ta nn dng cht git ra tng hp. Qu trnh thy phn tinh bt bng enzim khng to ra A. extrin. B. saccaroz. C. mantoz. D. glucoz. Pht biu no sau y khng ng ? A. Saccaroz c dng trong cng nghip trng gng. B. Glucoz v saccaroz c sinh ra khi thy phn xenluloz. C. Glucoz v mantoz c sinh ra khi thy phn tinh bt. D. Xenluloz l nguyn liu sn xut ancol etylic. Trong cc cht sau : xenluloz, fructoz, fomalin, mantoz, glixerol, tinh bt, c bao nhiu cht c th phn ng vi Cu(OH)2 iu kin thch hp ? A. 2 B. 3 C. 4 D. 5 iu ch xenluloz axetat trong cng nghip, ngi ta cho xenluloz tc dng vi A. axit axetic. B. anhirit axetic C. anehit axetic. D. etyl axetat. Nhn nh no sau y v etyl fomat khng ng ? A. C cng thc phn t C3H6O2. B. L ng phn ca axit axetic. C. C th cho phn ng trng bc. D. C 1 ng phn este khc. Dung dch glucoz khng c phn ng no sau y ? A. Ho tan Cu(OH)2 thnh dung dch xanh lam. B. Kh Cu(OH)2 khi un nng to kt ta gch. C. Tc dng vi AgNO3/NH3 to kt ta bc. D. To kt ta trng khi tc dng vi dung dch brom.

15.

16.

Nhn xt no sau y khng ng ?

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A. Trong dung dch, mantoz c th m vng cn saccaroz th khng. B. Saccaroz v mantoz c cng cng thc phn t. C. Saccaroz v mantoz to ra hai phn t glucoz khi b thy phn. D. Saccaroz v mantoz u c phn ng vi dung dch Ag[(NH3)2]OH. 17. Dy gm cc dung dch u ho tan c Cu(OH)2 nhit phng l A. glucoz, fructoz, mantoz v saccaroz. B. glucoz, fructoz, mantoz v xenluloz. C. glucoz, fructoz, saccaroz v tinh bt. D. glucoz, fructoz, mantoz v tinh bt. Khi lng glucoz cn dng to ra 1,82 gam sobitol vi hiu sut 80% l A. 2,25 gam. B. 1,44 gam. C. 22,5 gam. D. 14,4 gam Cho cc cht sau : (1) Saccaroz ; (2) Tinh bt ; (3) Fructoz ; (4) Xenluloz ; (5) Mantoz. Nhng cht c th tham gia phn ng thy phn l A. (1), (2), (3). B. (2), (4). C. (1), (2), (4). D. (1), (2), (4), (5). Nhn nh no sau y khng ng ? A. Tinh bt c phn ng vi dung dch iot cho mu xanh tm. B. Xenluloz c phn ng este ho. C. Tinh bt tham gia phn ng trng gng. D. Tinh bt d b thy phn thnh glucoz.

18.

19.

20.

II. Trc nghim t lun (5 im) Cu 1 : (2 im) Vit cc phng trnh ho hc thc hin dy chuyn ho : Glucoz etanol axit axetic anhirit axetic xenluloz triaxetat. Cu 2 : (1 im)
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Trnh by phng php ho hc phn bit cc cht lng sau : etyl axetat, axit axetic, h tinh bt, ancol etylic. Cu 3 : (2 im) Cho 8,8 g mt este n chc, no, mch h X tc dng va vi 100 ml dung dch NaOH 1M to mt mui v ancol Y. a) Xc nh CTPT ca X. b) Vit cc CTCT ph hp ca X, gi tn. c) Xc nh CTCT ng ca X, bit rng khi b oxi ho Y to hp cht khng tham gia phn ng trng bc.

HNG DN GII I. Trc nghim khch quan 1 B 11 B 2 B 12 C 3 D 13 B 4 B 14 B 5 B 15 D 6 C 16 D 7 B 17 A 8 C 18 C 9 C 19 D 10 B 20 C

II. Trc nghim t lun Cu 1 : (2 im)

enzim C6H12O6 2C2H5OH + 2CO2

C2H5OH + O2 CH3COOH + H2O

P2O5 2CH3COOH (CH3CO)2O + H2O

enzim

[C6H7O2(OH)3]n + 3n(CH3CO)2O[C6H7O2(OCOCH3)3]n + 3nCH3COOH Cu 2 : (1 im) + Dng qu tm nhn bit axit axetic. + Dng dung dch I2 nhn bit h tinh bt. + Dng Na kim loi nhn bit ancol etylic + Cn li l etyl axetat. Cu 3 :
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a) nNaOH = 0,1 1 = 0,1(mol) Este thuc loi n chc no mch h : CnH2nO2 1 mol este n chc phn ng vi 1 mol NaOH 1 mol mui v 1 mol ancol. n este = nmui = n ancol = nNaOH = 0,1 mol 8,8 = 88 (g/mol) 14n + 32 = 88 n = 4 Meste = 0,1 CTPT : C4H8O2 b) Cc CTCT : HCOOCH2CH2CH3 : propyl fomat HCOOCH(CH3) CH3COOCH2CH3 : isopropyl fomat : etyl axetat

CH3CH2COOCH3 : metyl propionat c) Ancol Y khi b oxi ho to ra sn phm khng cho phn ng trng bc Y khng phi l ancol bc I CTCT ca Y : (CH3)2CHOH CTCT ca X : HCOOCH(CH3)2

KIM TRA 1 TIT (Chng trnh chun)

I. Trc nghim khch quan 1. Thy phn n cng tinh bt trong dung dch axit v c long s thu c A. fructoz. B. glucoz. C. saccaroz. D. mantoz. Pht biu no sau y khng ng ? A. Glucoz v fructoz u tc dng c vi Cu(OH)2 to thnh dung dch mu xanh lam. B. Glucoz v fructoz phn ng vi H2 u to ra ancol c 6 nhm OH. C. Khi un nng glucoz vi Cu(OH)2 cho kt ta gch.
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2.

3.

4.

5.

D. Fructoz khng tham gia phn ng trng bc v khng c nhm CHO. Cht no sau y c phn ng trng bc ? A. Saccaroz. B. Mantoz. C. Tinh bt. D. Xenluloz. Khi un nng dung dch saccaroz vi dung dch axit thu c dung dch c phn ng trng gng v A. trong phn t saccaroz c nhm chc anehit. B. saccaroz b thu phn thnh glucoz v fructoz. C. saccaroz b thu phn thnh cc anehit n gin. D. trong mi trng axit saccaroz chuyn ha thnh mantoz. Fructoz khng phn ng vi A. dung dch AgNO3/ NH3. C. H2 (xt Ni, to). B. H2O (xt H+, to). D. Cu(OH)2.

6.

7.

Cn bng ho hc ca phn ng este ho gia ancol v axit hu c s dch chuyn theo chiu thun, khi ta A. pha long hn hp bng nc. B. thm dung dch NaOH vo hn hp. C. chng ct tch este ra khi hn hp. D. cho thm este vo hn hp. Cho cc cht sau : (1) CH3CH2CH2OH ; (2) CH3COOCH3 ; (3) CH3CH2COOH. Th t nhit si tng dn l : A. (3) < (2) < (1). B. (1) < (3) < (2). C. (2) < (1) < (3). D. (1) < (2) < (3). Cho s chuyn ho sau : C2H5OH X Y CH3COOCH3 X, Y ln lt l A. CH3CHO, CH3COOH.

8.

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B. CH3COOH, CH3CHO. C. CH3CHO, CH3CH2OH. D. C2H4, CH3CH2OH. 9. Sn phm thu c khi thu phn este CH3COOCH=CHCH3 trong mi trng axit l A. CH3COOH v CH3CH2CHO. B. CH3COOH v CH2=CHCHO. C. CH3COOH v CH3CH2CH2OH. D. CH3COOH v CH2=CHCH2OH. 10. Pht biu no sau y khng ng ? A. Cht bo l este ca glixerol vi cc axit bo. B. Cht bo c cha gc khng no thng l cht lng iu kin thng. C. un nng cht bo trong NaOH s thu c x phng. D. Du thc vt, du bi trn my, m ng vt u l cht bo. Thu phn cht X trong mi trng axit, un nng khng to ra glucoz. X l cht no trong cc cht sau y ? A. saccaroz B. xenluloz C. tinh bt D. protein Este X phn ng vi dung dch NaOH un nng to ra ancol metylic v natri propionat. Cng thc cu to ca X l A. CH3COOCH3. C. C2H5COOCH3 13. A. Cu(OH)2 /NaOH, to. B. Dung dch AgNO3/NH3. C. Nc brom. D. Cu(OH)2. 14. Pht biu no di y v xenluloz l khng ng ? A. G, giy, l cy u c cha xenluloz. B. Xenluloz l polime thin nhin.
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11.

12.

B. HCOOCH3. . D. CH3COOC2H5.

phn bit glucoz v fructoz th nn chn thuc th no di y ?

15.

C. Xenluloz ch tan trong nc nng. D. Trong phn t xenluloz ch c 3 nguyn t C, H,O. Cho chuyn ho : Kh cacbonic X Y ancol etylic. Mi mi tn biu th 1 phn ng. X, Y c th l A. cacbon oxit, metanol. B. tinh bt, glucoz. C. cacbon, etilen. D. axit cacbonic, anehit axetic. C4H8O2 c s ng phn este l A. 2. B. 3. C. 4. D. 5.

16. 17.

18.

Hp cht C2H5COOCH3 c tn gi l A. etyl axetat. B. metyl axetat. C. metyl propionat. D. propyl axetat. im chung ca x phng v cht git ra tng hp l A. lm sch cht bn m khng phn ng ho hc vi cht bn. B. u c iu ch t cht bo. C. u khng gy nhim mi trng. D. u to kt ta vi Ca2+ v Mg2+. Trt t tng dn nhit si ca cc cht : (1) C2H5COOH, (2) CH3COOCH3 v (3) C2H5CH2OH l A. (1), (2), (3). B. (2), (3), (1). C. (1), (3), (2). D. (3), (2), (1). Pht biu no sau y ng ? A. Cc cht c cng thc chung Cn(H2O)m u l cacbohirat. B. Du m ng, thc vt v sp u l lipit. C. Cht bo lng ch tan trong nc nng. D. Lipit do nhiu cht bo khc nhau hp thnh.

19.

20.

II. Trc nghim t lun (5 im) Cu 1 : (2 im)

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Vit cc phng trnh ho hc xy ra (nu c) : a) Axit axetic + axetilen b) Tristearin + NaOH c) Saccaroz + Cu(OH)2 d) Glucoz + AgNO3 + NH3 Cu 2 : (1 im) Bng phng php ho hc hy phn bit cc l mt nhn cha ring bit cc cht lng : etyl axetat, dung dch glucoz, h tinh bt. Cu 3 : (2 im) T khi hi ca este A no, n chc mch h i vi H2 bng 37. a) Xc nh CTPT ca A, vit cc CTCT ca A v gi tn. b) Thc hin phn ng x phng ho 7,4 gam A vi dung dch NaOH n khi phn ng xy ra hon ton thu c 6,8 gam mui. Xc nh CTCT ng ca A. HNG DN GII I. Trc nghim khch quan 1 B 11 D 2 D 12 C 3 B 13 C 4 B 14 C 5 B 15 B 6 C 16 C 7 C 17 C 8 A 18 A 9 A 19 B 10 D 20 B

II. Trc nghim t lun (5 im) Cu 1 : (2 im) Cc phng trnh ho hc : a) b) c) d) CH3COOH + CH CH CH2=CHOCOCH3
t (CH3[CH2]16COO)3C3H5 + 3NaOH
o

3CH3[CH2]16COONa + C3H5(OH)3 2C12H22O11 + Cu(OH)2 (C12H21O11)2Cu + 2H2O C5H11O5CHO + AgNO3 + NH3 + H2O
131

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C5H11O5COONH4 + NH4NO3 + Ag Cu 2 : (1 im) Phn bit cc cht lng : etyl axetat, dung dch glucoz, h tinh bt. + Dng dung dch I2 nhn ra h tinh bt. + Dng dung dch AgNO3 trong NH3 nhn ra glucoz. + Cn li l etyl axetat. Cu 3 : a) Cng thc chung ca este no, n chc mch h : CnH2nO2 MA= 37.2 = 74 (g/mol) 14n + 32 = 74 n =3 CTPT ca A : C3H6O2 Cc CTCT : HCOOCH2CH3 : etyl fomat CH3COOCH3 : metyl axetat 7,4 nA = =0,1(mol) b) 74 t cng thc ca A l RCOOR RCOOR + NaOH RCOONa + ROH 0,1 0,1 6,8 M RCOONa = = 68 (g/mol) 0,1 R + 67 = 68 R = 1 R l H CTCT ca A l HCOOCH2CH3.

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Chng 3 & 4 KIM TRA 15 PHT Chng trnh nng cao (cho cc vng kh khn)
Hy chn cu ng. 1. Phenol v anilin cng phn ng vi A. dung dch H2SO4. C. Na. 2. B. dung dch NaOH. D. dung dch HNO3 c.

Tn thay th ca CH3CH2NHCH3 l A. propylamin. B. etylmetylamin. C. metyletylamin. Amin bc II l amin D. N-metyletanamin.

3.

A. c to thnh khi thay th 2 nguyn t H trong NH3 bng 2 gc hirocacbon. B. c 2 nhm NH2 trong phn t. C. c 2 nhm NH2 gn vo cng nguyn t C. D. c nhm NH2 gn vo cng nguyn t C bc II. 4. Tn gi no sau y khng ng cho hp cht thm c cng thc C6H5NH2 ? A. Phenylamin B. N-Metylanilin C. Benzenamin D. Anilin Anilin khng tc dng vi A. NH3. C. dung dch HCl. 6. B. dung dch Br2. D. HNO2/HCl ( 0 oC 5oC).

5.

Dy no sau y c sp xp theo chiu tng dn tnh baz ? A. (CH3)2NH < CH3NH2 < C6H5NH2 < NH3 B. CH3NH2 < (CH3)2NH < C6H5NH2 < NH3 C. C6H5NH2 < NH3 < CH3NH2 < (CH3)2NH D. CH3NH2 < (CH3)2NH < NH3 < C6H5NH2

7.

Cng thc C3H9N ng vi s ng phn :

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133

8.

A. 3. B. 4. C. 5. Tnh cht no sau y khng ng cho protein ? A. ng t khi un nng hay gp axit v kim. B. Thu phn khi un nng vi dung dch axit, baz. C. To kt ta vng vi HNO3 c.

D. 2.

D. Tc dng vi dung dch CuSO4 to thnh dung dch c mu tm. 9. Trong 4 cht : NH2CH2COOH, ClNH3CH2COOCH3, Br3C6H2NH2. Cht tan nhiu nht trong nc l A. NH2CH2COOH. C. ClNH3CH2COOCH3. 10. B. C6H5NH2. D. Br3C6H2NH2. C6H5NH2,

Cho hp cht : NH2CH2CONHCH(CH3)CONHCH2COOH. Tn gi c vit gn ca cht ny l A. Gly-Ala-Gly B. Ala-Gly-Gly C. Gly-Gly-Ala D. Gly-Gly-Gly 1 D 2 D 3 A 4 B 5 A 6 C 7 B 8 D 9 A 10 A

p n Cu p n

KIM TRA 15 PHT (cho cc vng thun li)

Hy chn cu ng. 1. Phenol v anilin cng tc dng vi A. dung dch HCl . C. Na. 2. D. dung dch Br2. Tn thay th ca CH3CH2CH2CH2NH2 l A. butylamin. B. butyl-1-amin. C. butan-1-amino. D. butan-1-amin. Anilin c tnh baz yu hn NH3 l do A. nhm C6H5 y electron. B. nhm C6H5 ht electron.

B. dung dch NaOH.

3.

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C. anilin t tan trong nc. 4.

D. phn t khi anilin ln.

5.

Tn gi no sau y khng ng cho hp cht thm c cng thc C6H5NH2 ? A. Phenylamin B. N-Metylanilin C. Benzenamin D. Anilin Anilin khng tc dng vi A. dung dch NH3. C. CH3I. B. dung dch Br2. D. HNO2.

6.

Dy cht no sau y c sp xp theo chiu tng dn lc baz ? A. (CH3)2NH < CH3NH2 < C6H5NH2 < NH3 B. CH3NH2 < (CH3)2NH < C6H5NH2 < NH3 C. C6H5NH2 < NH3 < CH3NH2 < (CH3)2NH D. CH3NH2 < (CH3)2NH < NH3 < C6H5NH2

7. 8.

Hp cht C4H11N c s ng phn cu to l A. 5. B. 6. C. 7. Tnh cht no sau y khng ng cho protein ? A. ng t khi un nng hay gp axit v kim. B. Thu phn khi un nng vi dung dch axit, baz. C. To kt ta vng vi HNO3 c.

D. 8.

D. Tc dng vi dung dch CuSO4 to thnh cht c mu xanh tm. 9. Mt hc sinh tin hnh th nghim bng cch cho dung dch NaOH vo dung dch phenylamoni clorua. Hin tng quan st c l A. c kt ta trng khng tan. B. c s phn lp. C. c kt ta v kt ta tan. D. c bt kh bay ra. Cho hp cht :

10.

H2NCH2CONHCH(CH3)CONHCH[(CH3)CH(C2H5)]COOH. Tn gi c vit gn ca cht ny l A. Gly-Ala-Leu. B. Ala-Gly-Leu. C. Gly-Ala-Isoleu. D. Ala-Gly-Isoleu.

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p n Cu p n 1 D 2 D 3 B 4 B 5 A 6 C 7 D 8 D 9 B 10 C

KIM TRA 15 PHT Chng trnh chun

1. Phenol v anilin u phn ng vi A. dung dch HCl. B. dung dch NaOH. C. Na. 2. D. dung dch Br2. Tn thay th ca CH3CH2CH2CH2NH2 l A. butylamin B. butyl-1-amin C. butan-1-amino D. butan-1-amin Dy c sp xp theo chiu tng dn tnh baz l : A. (CH3)2NH < CH3NH2 < C6H5NH2 < NH3 B. CH3NH2 < (CH3)2NH < C6H5NH2 < NH3 C. C6H5NH2 < NH3 < CH3NH2 < (CH3)2NH D. CH3NH2 < (CH3)2NH < NH3 < C6H5NH2 4. 5. S ng phn amin bc 2 ca hp cht C4H11N l A. 4. B. 2. C. 5. D. 3. Pht biu no sau y ng ? A. Khi thay th nguyn t H trong amoniac bng gc hirocacbon ta c amin. B. Amin la hp cht hu c c cha mt hay nhiu nguyn t nit. C. Cng thc tng qut ca amin no, n chc, mch h l CnH2n+2N. D. Bc ca amin l bc ca nguyn t cacbon lin kt trc tip vi nhm amin. 6. Bc ca amin (C2H5)2NC6H5 l A. I. C. III. B. II. D. II v I.

3.

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7.

t chy hon ton hn hp 2 amin no, n chc, mch h, ng ng lin tip thu c 0,1 mol kh CO2 va 0,2 mol H2O. Cng thc ca 2 amin l A. CH3NH2 v C2H5NH2. B. C2H5NH2 v C3H7NH2. C. C3H7NH2 v C4H9NH2. D. C4H9NH2 v C5H11NH2. B. H3NCH2COO. D. H2N+CH2COO.

8.

Trong dung dch, glyxin ch yu tn ti dng A. H2NCH2COOH. C. H3N+CH2COO.

9.

10.

Cho hn hp gm 0,05 mol metylamin v 0,1 mol anilin phn ng vi dung dch HCl d. Khi lng cht rn thu c sau khi c cn dung dch l A. 19,25 gam. B. 3,375 gam. C. 16,325 gam. D. 19,825 gam. S lng tripeptit c to thnh t glyxin v alanin l A. 3. B. 4. C. 5. D. 6. 1 D 2 D 3 C 4 D 5 A 6 C 7 A 8 C 9 C 10 D

p n Cu p n

KIM TRA 1 TIT Chng trnh nng cao (cho cc vng kh khn)
I. Trc nghim khch quan 1. Pht biu no sau y ng ? A. Mi loi polime c mt nhit nng chy nht nh. B. Protein n gin l nhng protein c to thnh t cc gc - v -amino axit. C. Cc thnh phn trong vt liu compozit phn tn vo nhau m khng tan vo nhau. D. Amino axit l hp cht hu c tp chc, phn t cha mt nhm NH 2 v mt nhm COOH.

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137

2.

3.

Cho cc dung dch : H2NCH2COOH ; H2N[CH2]4CH(NH2)COOH ; C6H5NH2 ; CH3NH2 ; HOOC[CH2]2CH(NH2)COOH. S dung dch lm giy qu tm ho xanh l A. 1. B. 2. C. 3. D. 4. nhn bit cc l mt nhn ng cc cht lng : glixerol, glucoz, anilin, alanin, anbumin ta ln lt dng cc ho cht sau A. dng Cu(OH)2, un nng nh, sau dng dung dch Br2. B. dng dung dch CuSO4, dung dch H2SO4, dung dch Br2. C. dng dung dch Ag[(NH3)2]OH, dung dch HCl, dung dch Br2. D. dng dung dch Br2, HNO3 c, qu tm.

4.

Cht no sau y c th trng hp thnh cao su ? A. CH3CH=CH2 B. CH3CH=C=CH2 C. CH2=C(CH3)CH=CH2 D. CH2=CHClCH2CH3

5.

6.

Pht biu no sau y khng ng ? A. Khi thay th nguyn t H ca amoniac bng gc hirocacbon ta c amin. B. Bc ca amin l bc ca nguyn t cacbon lin kt vi nhm amino. C. Ty thuc cu trc ca gc hirocacbon c th phn bit amin thnh amin bo v amin thm. D. Cc amin trong phn t c t hai nguyn t cacbon tr ln c ng phn cu to. t chy hon ton mt amin n chc, no, mch h bc II ngi thu c t l mol nCO2 : nH2O = 6 : 9. Cng thc ca amin l A. (CH3)2NCH3. C. (CH3)2NH. B. CH3CH2CH2NH2. D. CH3NHCH2CH3.

7.

8.

Tn thay th ca CH3CH2CH2NH2 l A. N-propylamin. B. propyl-1-amin. C. propylamin. D. propan-1-amin. Phn ng no di y khng th hin tnh baz ca amin ?

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A. CH3NH2 + H2O CH3NH3+ + OH B. C6H5NH2 + HCl C6H5NH3Cl C. Fe3+ + 3CH3NH3 + 3H2O Fe(OH)3 + 3CH3NH3+ D. CH3NH2 + HNO2 CH3OH + N2 + H2O 9. Tn gi no sau y khng ng cho hp cht thm c cng thc C6H5NH2 ? A. Phenylamin B. Benzenamin C. Anilin D. Benzylamin S ng phn cu to tripeptit cha ng thi ba amino axit l A. 3. B. 4. C. 5. D. 6. Hp cht X c cng thc : H2N CH2 CO NH CH CO NH CH CO NH CH2 COOH CH2 COOH CH2 C6H5 Vy X l A. pentapeptit. B. tetrapeptit. C. tripeptit. D. triamit. Thy phn tng phn mt pentapeptit thu c cc ipeptit v tripeptit sau : Gly - Ala ; Val - Glu ; Ala - Val ; Glu - Phe ; Ala - Val - Glu. Trnh t ca cc aminoaxit trong pentapeptit trn l : A. Gly - Ala - Glu - Phe - Val. B. Val - Glu - Phe - Gly - Val. C. Ala - Val - Glu - Gly - Phe. D. Gly - Ala - Val - Glu - Phe. c im cu to ca monome tham gia phn ng trng ngng l phi c A. lin kt bi. B. t 2 nhm chc tr ln. C. vng khng bn. D. lin kt bi hay vng khng bn. T nilon-6 c iu ch bng cch A. trng hp caprolactam. B. trng ngng NH2[CH2]6COOH. C. trng ngng NH2[CH2]6NH2 v HOOC[CH2]4COOH.
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139

10. 11.

12.

13.

14.

15.

D. trng ngng axit -aminohexanoic. Nha PS (polistiren) c iu ch bng cch A. ng trng hp benzen v etilen. B. trng hp vinylbenzen. C. ng trng hp benzen v axetilen. D. ng trng hp buta-1,3-ien v stiren. Khi cho anilin, phenol, toluen, benzen tc dng vi dung dch Br2 ta thy A. c 4 cht u phn ng. B. anilin, phenol, toluen phn ng. C. ch c anilin v phenol phn ng. D. ch c anilin phn ng. Anilin tc dng c vi tt c cc cht trong dy no sau y ? A. dd Br2, dd HCl, dd H2SO4. B. dd Br2, dd HCl, qu tm. C. dd HNO3, dd CuSO4, qu tm. D. dd HNO3, dd CuSO4, dd NaOH.

16.

17.

18.

19.

20.

Pht biu no sau y khng ng ? A. T nilon-6,6 l polime c hnh thnh do cc lin kt peptit. B. T lapsan c tng hp t axit terephtalic v etylen glicol. C. T nitron thuc loi t vinylic. D. Len, bng l cc loi polime thin nhin. Polime c dng trng ln cho lm cht chng dnh l A. PVC [poli(vinyl clorua)]. B. PMMA [(poli(metyl metacrylat)]. C. PVA [poli(vinyl axetat)]. D. Teflon (politetrafloetilen). Cho 3,1 gam mt amin n chc, no, mch h A phn ng va vi 50 ml dung dch HCl 2M. Cng thc phn t ca A l A. CH3NH2. C. C3H7NH2. B. C2H5NH2. D. C6H5NH2.

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II. Trc nghim t lun (5 im) Cu 1 : (2,5 im) Vit cc phng trnh ho hc thc hin dy chuyn ho : NH3 C2H5NH2 C2H5OH CH3COOH CH2=CHOCOCH3 polime Cu 2 : (1 im) Polime l g ? Cho 3 v d v s to thnh polime t cc phn ng : trng hp, ng trng hp, trng ngng. Cu 3 : (1,5 im) Cho 100ml dung dch -amino axit X 0,2M (dng H2NRCOOH) phn ng va vi dung dch NaOH to 22,2 gam mui Y. a) Xc nh CTCT v gi tn ca X theo 2 cch. b) Cho ton b mui Y phn ng vi dung dch HCl d ri c cn. Tnh khi lng mui khan to thnh. HNG DN GII I. Trc nghim khch quan Cu p n Cu p n 1 C 11 B 2 B 12 D 3 A 13 B 4 C 14 A 5 B 15 B 6 D 16 C 7 D 17 A 8 D 18 A 9 D 19 D 10 D 20 A

II. Trc nghim t lun Cu 1 : (2,5 im) Cc phng trnh ho hc thc hin dy chuyn ho : NH3 + C2H5I C2H5NH2 + HI C2H5NH2 + HNO2 C2H5OH + N2 + H2O
enzim C2H5OH + O2 CH3COOH + H2O

CH3COOH + CHCH CH2=CH-OOCCH3 n CH2 CH OOCCH3

xt, to, p

CH2 CH OOCCH3 n
141

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Cu 2 : (1 im) + Polime l nhng hp cht c phn t khi rt ln do nhiu n v nh lin kt vi nhau. + Cc v d : Polime to ra t phn ng trng hp : nCH2 = CH2 (CH2 CH2 )n Polime to ra t phn ng ng trng hp : nCH2=CH-CH=CH2 + CH=CH2
xt, t , p
o

xt,to,p

CH2-CH=CH-CH2 CH-CH2

Polime to ra t phn ng trng ngng : nNH2 [CH2]6 COOH ( NH [CH2]2 CO)n + H2O Cu 3 : (1,5 im) a) nX = 0,1.2 = 0,2 (mol) H2NRCOOH + NaOH H2NRCOONa + H2O 0,2 0,2 (16 + R + 67) 0,2 = 22,2 R = 28 R l C2H4
xt,to

CTCT ca X : NH2CH(CH3)COOH Tn gi ca X : axit 2-aminopropanoic hay axit -aminopropionic b) Mui Y l NH2CH(CH3)COONa NH2CH(CH3)COONa + 2HCl ClH3NC2H4COOH + NaCl 0,2 0,2 0,2 Khi lng mui to thnh = 0,2.125,5 + 0,2.58,5 = 36,8 (gam).

KIM TRA 1 TIT Chng trnh nng cao (cho cc vng thun li)
I. Trc nghim khch quan
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1.

Pht biu no sau y ng ? A. Mi loi polime c mt nhit nng chy nht nh. B. Protein n gin l nhng protein c to thnh t cc gc - v -amino axit. C. Cc thnh phn trong vt liu compozit phn tn vo nhau m khng tan vo nhau. D. Amino axit l hp cht hu c tp chc, phn t cha mt nhm NH2 v mt nhm COOH.

2.

3.

Cho cc dung dch : H2NCH2COOH ; H2N[CH2]4CH(NH2)COOH ; C6H5NH2 ; CH3NH2 ; HOOC[CH2]2CH(NH2)COOH. S dung dch lm giy qu tm ho xanh l A. 1. B. 2. C. 3. D. 4. Cht no sau y c th trng hp thnh cao su ? A. CH3CH=CH2 C. CH2=C(CH3)CH=CH2 B. CH3CH=C=CH2 D. CH2=CHClCH2CH3 C. C4H11N B. HCl. D. HNO2. D. C5H13N

4. 5.

Amin no di y c bn ng phn cu to ? A. C2H7N A. H2O. C. dung dch FeCl3. B. C3H9N Amin khng th hin tnh baz khi phn ng vi

6. 7.

S hp cht tripeptit ti a to thnh t 2-amino axit l A. 3. B. 4. C. 5. D. 6. Dy cc cht c xp theo chiu tng dn lc baz l A. C6H5NH2 ; NH3 ; CH3NH2 ; (CH3)2NH. B. NH3 ; CH3NH2 ; (CH3)2NH ; C6H5NH2. C. (CH3)2NH ; CH3NH2 ; NH3 ; C6H5NH2. D. NH3 ; C6H5NH2 ; (CH3)2NH ; CH3NH2.

8.

T nilon-6 c iu ch bng cch A. trng hp caprolactam. B. trng ngng NH2[CH2]6COOH. C. trng ngng NH2[CH2]6NH2 v HOOC[CH2]4COOH.
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143

9.

10.

11.

D. trng ngng axit -aminohexanoic. Nha PS (polistiren) c iu ch bng cch A. ng trng hp benzen v etilen. B. trng hp vinyl benzen. C. ng trng hp benzen v axetilen. D. ng trng hp buta-1,3-ien v stiren. Pht biu no sau y khng ng ? A. T nilon-6,6 l polime c hnh thnh do cc lin kt peptit. B. T lapsan c tng hp t axit terephtalic v etylen glicol. C. T nitron thuc loi t vinylic. D. T tm l polime thin nhin. Cng thc no sau y l ca mt loi cao su ? Cl A. n B. n

C. n 12.

D. CN n

13.

14.

Polime c dng trng ln cho lm cht chng dnh l A. PVC [poli(vinyl clorua)]. B. PMMA [(poli(metly metacrylat)]. C. PVA [poli(vinyl axetat)]. D. Teflon (politetrafloetilen). Cho 4 dung dich c cng nng mol : axit aminoaxetic (I), axit axetic (II), amoniac (III) va etylamin (IV). Th t tng dn pH ca cc dung dch trn l A. (IV) <(III) < (II) < (I). B. (II) < (I) < (III) < (IV). C. (I) < (II) < (III) < (IV). D. (II) < (I) < (IV) < (III). Pht biu no sau y ng ? A. Xenluloz l polime c to thnh bi cc lin kt -1,6-glicozit.

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B. Amiloz l polime c to thnh bi cc lin kt -1,6-glicozit. C. Amilopectin l polime c to thnh bi lin kt -1,4-glicozit v -1,6- glicozit. D. Amiloz l polime c to thnh bi lin kt -1,6-glicozit. 15. Mt hp cht hu c X c cng thc C 3H9O2N. Cho X phn ng vi dung dch NaOH, un nh thu c mui Y v kh Z lm xanh giy qu tm t. Cho Y tc dng vi NaOH rn, un nng c CH4. X c cng thc cu to no sau y ? A. CH3CH2COONH4 C. CH3COOCH2NH2 16. B. H2NCH2COOCH3 D. HCOOCH2CH2NH2

17.

Cho -amino axit X c cng thc H2NR(COOH)2 phn ng ht vi 0,1 mol NaOH to 8,15 gam mui. X l A. axit 2-aminopropanioic B. axit 2-aminobutanioic C. axit 2-aminopentanioic D. axit 2-aminohexanioic Anilin tc dng c vi tt c cc cht trong dy no sau y ? A. dd Br2, dd HCl, dd HNO2. B. dd Br2, dd HCl, qu tm. C. dd HNO3, dd CuSO4, phenolphtalein. D. dd HNO3, dd CuSO4, dd NaOH.

18.

phn bit dung dch etylamin v etanol ta dng A. Na. B. dung dch NaOH. C. dung dch cha hn hp NaNO2 v HCl. D. dung dch HCl. Phn ng no di y ng ? A. C2H5NH2 + HNO2 + HCl C2H5N2+Cl + 2H2O
05 C B. C6H5NH2 + HNO2 + HCl C6H5N2+Cl + 2H2O 05 C C. C6H5NH2 + HNO3 + HCl C6H5N2+Cl + 2H2O 05 C D. C6H5NH2 + HNO2 C6H5OH + N2 + H2O
o o o

19.

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145

20.

Cho 0,1 mol -amino axit X trong phn t c cha mt nhm NH2 tc dng va vi dung dich HCl. C cn dung dch sau phn ng thu c 12,55 gam mui khan. X l A. alanin. B. glyxin. C. phenylalanin. D. valin.

II. Trc nghim t lun (5 im) Cu 1 : (1,5 im) T sn phm ca du m l kh etilen v cc cht v c cn thit hy vit 3 phng trnh ho hc lin tip nhau iu ch nha PVC Cu 2 : (1,5 im) Tch hn hp lng gm : phenol, anilin, benzen. Cu 3 : (2 im) trung ha 3,8 gam hn hp X gm 2 amin n chc l ng ng k tip cn dng 100 ml dung dch HCl 1M. a) Xc nh CTPT ca 2 amin. b) Cho 3,8 gam hn hp X tc dng vi lng d dung dch cha hn hp NaNO2 v HCl thu c 1,12 lt kh (ktc). Xc nh CTCT v gi tn 2 amin. HNG DN GII I. Trc nghim khch quan Cu p n Cu p n 1 C 11 C 2 B 12 D 3 C 13 B 4 B 14 C 5 D 15 C 6 D 16 A 7 A 17 A 8 A 18 C 9 B 19 B 10 A 20 A

II.Trc nghim t lun Cu 1 : (1,5 im) iu ch nha PVC CH2=CH2 + Cl2 CH2ClCH2Cl
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500 C CH2ClCH2Cl CH2=CH2Cl + HCl

nCH2=CH Cl

xt, t , p

CH2

CH Cl

Cu 2 : (1,5 im) Tch hn hp lng gm : phenol, anilin, benzen Cho hn hp tc dng vi dung dch HCl d v lc k ch c anilin tan, hn hp tch thnh 2 lp. Chit thnh 2 phn : Phn 1 : dung dch C6H5NH3Cl. Ti to anilin bng dung dch NaOH. Phn 2 : hn hp phenol, benzen : cho tc dng vi dung dch NaOH d v lc k, ch c phenol tan. Hn hp tch thnh 2 lp ta chit ly benzen. Dung dch cn li l C6H5ONa, ti to phenol bng dung dch HCl d. Cu 3 : (2 im) a) nHCl = 0,1.1 = 0,1 mol 3,8 M= = 38 (g/mol) 0,1

Mt trong 2 amin c phn t khi < 38 ch c th l CH5N amin ng ng k tip l C2H7N. b) CH5N 31 7 x x 7 38 y= 7 7 C2H7N 45 y 1,12 nN2 = =0,05 (mol) 22,4

x=y=

0,1 = 0,05 mol 2

CH5N c CTCT duy nht l CH3NH2 : metylamin CH3NH2 + HNO2 CH3OH + N2 + H2O 0,05 0,05 s mol N2 theo phn ng = s mol N2 cho ch c CH3NH2 to ra kh N2 C2H7N khng to ra kh N2
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147

 C2H7N khng phi amin bc I CTCT ca C2H7N l CH3NHCH3 : imetylamin.

KIM TRA 1 TIT Chng trnh chun

1. Nhm gm cc loi t c ngun gc xenluloz l A. t tm ; vi si ; len. B. len ; t nilon-6 ; t axetat. C. vi si ; t visco. D. t tm ; t axetat. Cho cc dung dch : H2NCH2COOH ; H2N[CH2]4CH(NH2)COOH ; C6H5NH2 ; CH3NH2 ; HOOC[CH2]2CH(NH2)COOH. S dung dch lm giy qu tm ho xanh l A. 1. B. 2. C. 3. D. 4. iu khng nh no sau y ng ? A. Cc amin lun phn ng vi H+. B. S nguyn t H ca mt phn t amin n chc lun l mt s chn. C. Cc amin c tnh baz nn lm qu tm ho xanh. D. Cc amin u tan tt trong nuc ging nh NH3. 4. Tn thay th ca CH3CH2CH2NH2 l A. N-propylamin. B. propyl-1-amin. C. propylamin. D. propan-1-amin. S ng phn cu to ca tripeptit cha ba -amino axit l A. 3. B. 4. C. 5. D. 6. (C2H5)2CHNH2 l amin bc A. I. B. II. C. III. D. IV. Cht no sau y l sn phm ca qu trnh ng trng hp ? A. Poli(vinyl clorua) B. Cao su buna-S C. Polistiren D. Cao su thin nhin Dy cc cht c xp theo chiu tng dn lc baz l :

2.

3.

5. 6. 7.

8.

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A. C6H5NH2 ; NH3 ; CH3NH2 ; (CH3)2NH. B. NH3 ; CH3NH2 ; (CH3)2NH ; C6H5NH2. C. (CH3)2NH ; CH3NH2 ; NH3 ; C6H5NH2. D. NH3 ; C6H5NH2 ; (CH3)2NH ; CH3NH2. 9. Tnh cht no sau y khng ng cho glyxin ? A. Tc dng vi NaOH v HCl. B. D tan trong nc do tn ti dng ion lng cc. C. Tc dng vi HCl v NaOH, khng tc dng vi CH3OH. D. Tc dng vi HNO2 v HNO3. 10. Polime c dng trng ln cho lm cht chng dnh l A. PVC [poli(vinyl clorua)]. B. PMMA [(poli(metyl metacrilat)]. C. PVA [poli(vinyl axetat)]. D. Teflon (politetrafloetilen). Dng ho cht no sau y phn bit dung dch metylamin v ancol etylic ? A. Na B. Dung dch NaOH C. Qu tm D. Dung dch HCl Cch phn loi no sau y ng ? A. Cc loi si vi, si len u l t thin nhin. B. T nilon-6 l t nhn to. C. T visco l t tng hp. D. T xenluloz axetat l t ho hc. Khi lng phn t trung bnh ca cao su t nhin l 105.000 vC. H s polime ho gn ng ca loi cao su trn l A. 1944. B. 1744. C. 1644. D. 1544. Cho 0,01 mol amino axit A phn ng va vi 0,01 mol HCl to ra 0,01 mol mui B v 0,01 mol mui B phn ng va vi 0,02 mol NaOH. Cng thc ca A c dng A. H2NRCOOH. C. H2NR(COOH)2. B. (H2N)2RCOOH. D. (H2N)2R(COOH)2.
149

11.

12.

13.

14.

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15.

Cho 3,1 gam mt amin n chc, no, mch h A phn ng va vi 50 ml dung dch HCl 2M. Cng thc phn t ca A l A. CH3NH2. C. C3H7NH2. B. C2H5NH2. D. C6H5NH2.

16.

Trong phng th nghim, ra sch l ng anilin ta nn A. cho vo mt t dung dch HCl, lc k ri trng li bng nc. B. cho vo mt t dung dch NaOH c, lc k ri trng li bng nc. C. cho vo mt t dung dch Br2, lc k ri trng li bng nc. D. trng nhiu ln bng nc nng. Nhn xt no di y khng ng ? A. Nh vi git dung dch glyxin vo ng nghim c cha dung dch NaNO2 v CH3COOH th thy c bt kh bay ra. B. Cho lng trng trng vo nc si th c s ng t. C. Cho dung dch CuSO4 vo lng trng trng ri thm vi git dung dch NaOH thy xut hin mu xanh tm. D. Nh vi git dung dch axit clohiric c vo lng trng trng thy xut hin kt ta mu vng. phn bit c cc dung dch : glucoz, glixerol, h tinh bt v lng trng trng, ta dng A. dung dch I2 v dung dch HNO3 c. B. dung dch I2 v dung dch AgNO3 trong NH3. C. Cu(OH)2 c thm dung dch NaOH. D. dung dch HNO3 c v dung dch AgNO3 trong NH3.

17.

18.

19.

20.

Cho cc cht sau : etilen, benzen, vinylbenzen, vinyl axetat, axit 6-aminohexanoic. S cht tham gia phn ng trng hp to polime l A. 2. B. 3. C. 4. D. 5. Nhm vt liu no sau y u c ch to t polime thin nhin ? A. T visco, t tm, cao su buna, gm. B. T visco, t tm, bng y t, giy. C. Cao su buna, t axetat, t tm, da thuc. D. thy tinh, t tm, gm.

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II. Trc nghim t lun (5 im) Cu 1 : (2 im) Hon thnh cc phng trnh ho hc sau : a) C6H5NH2 + H2SO4 NH2 b) + Br 2

c) CH3CH(NH2)COOH + NaOH d) NH2CH2COONa + HCl Cu 2 : (1 im) Trnh by v gii thch cc hin tng xy ra khi : a) Cho vo lng trng trng vi git dung dch CuSO4, sau cho thm vi git dung dch NaOH. b) Ngm qun o lm bng t tm trong dung dch x phng c kim cao th chng hng. Cu 3 : (2 im) a) Cho amino axit A (dng H2NRCOOH) tc dng va vi 100 ml dung dch HCl 1M, sau em c cn dd th c 12,55 gam mui khan. Xc nh CTPT ca A. b) Bit A l -amino axit, hy xc nh ng CTCT ca A v tnh th tch kh thot ra iu kin tiu chun khi cho 0,1 mol A phn ng vi dung dch HNO2 d. HNG DN GII I. Trc nghim khch quan Cu p n Cu p n 1 C 11 C 2 B 12 D 3 A 13 D 4 D 14 A 5 D 15 A 6 A 16 A 7 B 17 D 8 A 18 C 9 C 19 B 10 D 20 B

II. Trc nghim t lun

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151

Cu 1 : (2 im) Hon thnh cc phng trnh ho hc : a) hay : C6H5NH2 + H2SO4 C6H5NH3HSO4 2C6H5NH2 + H2SO4 (C6H5NH3)2SO4 NH2 b) + Br 2 Br NH2 Br + 3HBr

c)

Br CH3CH(NH2)COOH + NaOH CH3CH(NH2)COONa + H2O

d) NH2CH2COONa + HCl ClNH3CH2COOH + NaCl Cu 2 : (1 im) Trnh by v gii thch cc hin tng : a) Cho vo lng trng trng vi git dung dch CuSO 4 khng c hin tng g. Khi thm vi git NaOH vo th : CuSO4 + 2NaOH Cu(OH)2 + Na2SO4 Protein ca lng trng trng kt hp vi Cu(OH)2 to hp cht mu xanh tm. b) Ngm qun o lm bng t trong dung dch x phng c kim cao th chng hng v t l polime thin nhin c to thnh t cc lin kt amit d b thy phn trong mi trng kim. Cu 3 : (2 im) a) nHCl = 0,1.1 = 0,1 (mol) H2NRCOOH + HCl ClH3NRCOOH 0,1 0,1 0,1 (mol) 12,55 M mui = = 125,5 (g/mol) 0,1

35,5 + 3 + 14 + R + 45 = 125,5 R = 28 R l C2H4 CTPT ca A : C3H7NO2 b) CTCT ng ca A : NH2CH(CH3)COOH NH2CH(CH3)COOH + HNO2 HOCH(CH3)COOH + N2 + H2O 0,1 0,1
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Th tch kh N2 = 0,1.22,4 = 2,24 (lt).

Chng 5 KIM TRA 15 PHT Chng trnh nng cao (cho cc vng kh khn)
Phn dy in ho, in phn v iu ch kim loi 1. Trong cu mui ca mt pin in ho Zn - Cu c s di chuyn ca A. cc ion. B. cc electron. C. cc nguyn t Cu. D. cc nguyn t Zn. Phng php thch hp iu ch canxi kim loi l A. in phn dung dch CaCl2. B. dng H2 hay CO kh CaO nhit cao. C. in phn nng chy mui CaCl2. D. nhit phn CaCO3. 3. Cho trt t dy in ho sau : Zn2+/Zn < Fe2+/Fe < Cu2+/Cu < Fe3+/Fe2+ < Ag+/Ag Phn ng no sau y khng th xy ra ? A. Zn + 2Fe2+ Zn2+ + 2Fe3+ B. Cu + 2Ag+ Cu2+ + 2Ag C. Fe2+ + Ag+ Fe3+ + Ag D. Cu + 2Fe3+ 2Fe2+ + Cu2+ 4. Cho Eo ca cc cp oxi ho - kh : Cr3+/Cr = 0,74 V ; Au3+/Au = + 1,5 V ; Ni2+/Ni = 0,23 V ; Cu2+/Cu = + 0,34 V. Eo ca pin in ho Cr - Cu v Ni - Au ln lt l A. 0,40 V v 1,27 V B. 1,08 V v 1,73 V C. 0,40 V v 1,27 V D. 1,08 V v 1,73 V chng n mn kim loi, phng php no sau y khng ng ?
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153

2.

5.

6.

7.

8.

9.

A. V tu bin bng st c gn mt l thic lm vt hi sinh. B. M crom cc vt bng st. C. Ph mt lp nha ln cc vt bng st. D. Bi du m ln b mt kim loi Bng cch in phn dung dch mui c th iu ch c A. Mg, Fe, Cu. B. Al, Cu, Ag. C. Zn, Cu, Ag. D. Ca, Fe, Cu. Dy in ho ca kim loi l dy cc cp oxi ho - kh sp xp theo chiu A. tng dn tnh oxi ho ca cation kim loi v gim dn tnh kh ca nguyn t kim loi. B. tng dn tnh kh ca nguyn t kim loi v gim dn tnh oxi ho ca cation kim loi. C. tng dn tnh kh ca cation kim loi v gim dn tnh oxi ho ca nguyn t kim loi. D. tng dn tnh oxi ho ca ion v tnh kh ca nguyn t kim loi. Nguyn tc chung iu ch kim loi l A. kh cation kim loi thnh kim loi. B. oxi ho cation kim loi thnh kim loi. C. dng cht kh mnh kh kim loi ra khi cc oxit D. dng kim loi mnh y kim loi yu ra khi mui. Ni mt dy kim loi Cu vi mt dy kim loi Fe ri cng nhng vo dung dch HCl, ta thy A. Fe b n mn trc. B. Cu b n mn trc. C. Cu v Fe cng b n mn. D. Cu v Fe u khng b n mn. Cho hn hp gm hai kim loi Al v Zn vo dung dch AgNO3. Sau phn ng thu c hn hp hai kim loi v dung dch ch cha 1 mui. Hai kim loi v mui l A. Zn, Ag v Al(NO3)3. C. Al, Ag v Al(NO3)3. B. Al, Ag v Zn(NO3)2. D. Zn, Ag v Zn(NO3)2.

10.

p n
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Cu p n

1 A

2 C

3 A

4 B

5 A

6 C

7 A

8 A

9 A

10 A

KIM TRA 15 PHT (cho cc vng thun li)

Phn dy in ho, in phn v iu ch kim loi 1. Trong cu mui ca mt pin in ho Zn Cu c s di chuyn ca A. cc ion. B. cc electron. C. cc nguyn t Cu. D. cc nguyn t Zn. Nhn nh no sau y ng ? A. in phn dung dch mui M(NO3)n vi in cc tr, dung dch sau in phn lun c pH < 7. B. in phn dung dch mui MCln vi in cc tr c vch ngn, dung dch sau in phn lun c pH >7. C. in phn dung dch H2SO4 vi in cc tr, pH dung dch gim. D. in phn dung dch NaHSO4 vi in cc tr, pH dung dch khng i. 3. Phng php thch hp iu ch canxi kim loi l A. in phn dung dch CaCl2. B. dng H2 hay CO kh CaO nhit cao. C. in phn nng chy mui CaCl2. D. nhit phn CaCO3 n khi lng khng i. 4. Cho trt t dy in ho sau : Zn2+/Zn < Fe2+/Fe < Cu2+/Cu < Fe3+/Fe2+ < Ag+/Ag Phn ng no sau y khng th xy ra ? A. Zn + 2Fe2+ Zn2+ + 2Fe3+ B. Cu + 2Ag+ Cu2+ + 2Ag C. Fe2+ + Ag+ Fe3+ + Ag D. Cu + 2Fe3+ 2Fe2+ + Cu2+
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155

2.

5.

Khi in phn dung dch CuSO4 vi anot bng Cu kim loi, nhn nh no sau y ng ? A. pH ca dung dch tng dn. B. pH ca dung dch gim dn. C. pH ca dung dch khng i. D. Ban u pH ca dung dch tng ln sau gim. Cho Eo ca cc cp oxi ho - kh : Cr3+/Cr = 0,74 V ; Au3+/Au = + 1,5 V ; Ni2+/Ni = 0,23 V ; Cu2+/Cu = + 0,34 V. Eo ca pin in ho Cr - Cu v Ni - Au ln lt l A. 0,40 V v 1,27 V. B. 1,08 V v 1,73 V. C. 0,40 V v 1,27 V. D. 1,08 V v 1,73 V. chng n mn kim loi, cch lm no sau y khng ng ? A. V tu bin bng st c gn mt l thic lm vt hi sinh. B. M crom cc vt bng st. C. Ph mt lp nha ln cc vt bng st. D. Thng xuyn lau chi b mt kim loi. Bng cch in phn dung dch mui c th iu ch c A. Mg, Fe, Cu. B. Al, Cu, Ag. C. Zn, Cu, Ag. D. Ca, Fe, Cu. Ha tan 17,5 gam hon ton hn hp 3 kim loi X, Y, Z bng dung dch H2SO4 long d, ngi ta thu c 11,2 L kh ( ktc). Khi lng mui thu c trong dung dch l A. 65,5 gam. B. 66,5 gam. C. 64,5 gam. D. 52,5 gam. Tin hnh in phn dung dch AgNO3 vi in cc tr. Ti thi im c 5,4 gam Ag to ra, th th tch kh bay ra (ktc) l A. 0,28 lt. B. 0,56 lt. C. 2,8 lt. D. 5,6 lt.

6.

7.

8.

9.

10.

p n
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Cu p n

1 A

2 C

3 C

4 A

5 C

6 B

7 A

8 C

9 A

10 B

KIM TRA 15 PHT Chng trnh chun

Phn tnh cht chung ca kim loi 1. Kim loi c nhng tnh cht vt l chung l : A. tnh do, tnh dn nhit, tnh dn in, c nh kim. B. tnh do, tnh dn nhit, khng c tnh dn in, c nh kim. C. tnh do, nhit nng chy cao, tnh dn in, nh kim. D. tnh do, tnh dn nhit, khng c tnh dn in, cng ln. 2. Tnh cht ho hc c trng ca kim loi l A. tnh kh. B. tnh oxi ho. C. tnh axit. D. tnh baz. 3. Ha tan hon ton 2,8 gam mt kim loi bng dung dch H2SO4 (long), thu c 1,12 lt kh ( ktc). Kim loi trn l A. Na. B. Mg. C. Al. D. Fe. Ba kim loi X1, X2, X3 tng ng thuc cc nhm IA, IIA v IIIA trong cng mt chu k. Bn knh nguyn t tng ng ca cc kim loi ny s A. tng dn. B. gim dn. C. bng nhau. D. bin i khng theo quy lut. Cho 2 phn ng : Cu + FeCl3 CuCl2 + FeCl2 Fe + CuCl2 FeCl2 + Cu Nhn xt no sau y ng ? A. Cu y c Fe ra khi dung dch mui. B. Tnh oxi ho : Fe3+ > Cu2 + > Fe2+. C. Tnh oxi ho : Fe3+ > Fe2+ > Cu2+. D. Tnh kh : Cu > Fe > Fe2+. 6. Kim loi dn in do A. c cu to mng tinh th.
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157

4.

5.

7.

B. s chuyn ng ca cc ion dng kim loi ti cc nt mng. C. s chuyn ng d dng ca cc electron t do. D. kim loi c tnh do nn d ko thnh si. Tnh cht chung ca kim loi l A. d b kh. B. d b oxi ho. C. nng lng ion ho nh. D. m in nh. Kim loi no tc dng vi Cl2 v dung dch HCl to cng mt mui ? A. Cu B. Mg C. Fe D. Ag t nng kim loi trong O2 th cht rn thu c sau phn ng tng 38% khi lng so vi ban u. Kim loi l A. Cu. B. Ca. C. Al. D. Fe. S ph hu kim loi hoc hp kim do tc dng ca cc cht trong mi trng c gi l A. s n mn kim loi. B. s n mn ho hc. C. s n mn in ho hc. D. s kh kim loi.

8. 9.

10.

p n Cu p n 1 A 2 A 3 D 4 B 5 B 6 C 7 B 8 B 9 A 10 A

KIM TRA 1 TIT Chng trnh nng cao (cho cc vng kh khn)
I. Trc nghim khch quan 1. 2. Kim loi khng tc dng vi nc nhit thng l A. Sr. B. Ca. C. Be. D. Mg. Cc nguyn t thuc nhm IIA c cu hnh electron lp ngoi cng l A. np2. C. ns1np1. B. ns2. D. ns1np2.

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3.

4.

Cho 4 gam kim loi Ca tan trong lng nc d, sau khi phn ng kt thc thu c kh H2. Th tch kh H2 iu kin tiu chun l A. 2,24 lt. B. 1,12 lt. C. 3,36 lt. D. 4,48 lt. Cho s phn ng : X + Na[Al(OH)4] M + Y Y + AgNO3 AgCl +... X l A. CO2. B. NH3. C. SO2. D. HCl.

5.

6.

Ho tan hon ton 5,75 gam mt kim loi M vo nc thu c 2,8 lt kh ktc. Vy M l A. Na. B. K. C. Ba. D. Ca. Dung dch cha mui X khng lm i mu qu tm, dung dch cha mui Y lm qu tm ho xanh. Trn chung hai dung dch trn to kt ta. Vy X v Y c th l cp cht no trong cc cp cht di y ? A. Na2SO4 v BaCl2 C. KNO3 v Na2CO3 B. Ba(NO3)2 v Na2CO3 D. Ba(NO3)2 v K2SO4

7.

8.

Da vo khi lng ring ca nhm, ngi ta thng dng nhm A. ch to khung ca v cc trang tr ni tht. B. ch to cc thit b trao i nhit, dng c un nu trong gia nh. C. lm cc dng trang tr ni tht. D. lm hp kim dng ch to my bay, t, tn la. Nhm c iu ch bng cch A. in phn dung dch AlCl3 hay in phn nng chy Al(OH)3. B. in phn nng chy Al2O3. C. dng cacbon kh Al2O3 nhit cao. D. in phn nng chy Al(OH)3 hay dng Mg kh Al2O3.

9.

C 4 l mt nhn ng 4 dung dch sau : AlCl3, NaNO3, K2CO3, NH4NO3. phn bit 4 dung dch ch dng mt thuc th v ch th mt lt th thuc th l A. dung dch Ba(OH)2. B. dung dch H2SO4.
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C. dung dch AgNO3. 10.

D. dung dch Na2CO3.

Nhn nh no di y khng ph hp cc nguyn t nhm IA ? A. Cu hnh electron lp ngoi cng l ns1. B. Tinh th u c cu trc lp phng tm khi. C. u phn ng vi nc iu kin thng tr Li. D. Mc oxi ho c trng trong cc hp cht l +1. Dy gm cc nguyn t c xp theo chiu gim dn tnh kim loi l A. K, Na, Mg, Al. B. Al, Na, Mg, K. C. Na, K, Al, Mg. D. Mg, Al, K, Na. Nc cha ng thi cc mui no sau y thuc loi nc c tnh cng vnh cu ? A. NaCl v Ca(HCO3)2. C. NaHCO3 v Ca(NO3)2. B. CaSO4 v MgCl2. D. MgSO4 v CaCl2.

11.

12.

13.

lm kt ta hon ton nhm hiroxit t dung dch nhm sunfat cn dng lng d dung dch A. BaCl2. B. NaOH. C. Ca(OH)2. D. NH3. Ho tan hon ton m gam bt Al trong dung dch NaOH d, sau phn ng ta thu c 3,36 lt kh H2 (ktc). Gi tr ca m l A. 2,7. B. 5,4. C. 1,35. D. 4,05. Nh t t cho n d dung dch Na[Al(OH)4] vo dung dch HCl v lc lin tc. Hin tng xy ra l A. c kt ta xut hin, sau kt ta tan. B. c kt ta xut hin v kt ta khng tan C. khng c kt ta xut hin. D. c kt ta xut hin, sau kt ta tan, ri kt ta tr li. Hp kim no sau y khng phi ca Al ? A. Amelec B. Inox C. uyra D. Silumin Cht no sau y c dng b bt khi xng b gy ? A. Vi ti. B. vi. C. Tinh bt. D. Thch cao. Cp cht no sau y khi phn ng khng to ra hai mui ?

14.

15.

16. 17.

18.

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A. CO2 + dung dch NaOH d B. SO2 + dung dch Ba(OH)2 d C. Fe3O4 + dung dch HCl d D. dung dch Ca(HCO3)2 + dung dch NaOH d
o o 19. Cho : EFe2+ / Fe = 0,44 V ; E Ni2+ / Ni = 0,26 V. Sut in ng chun ca

20.

pin in ho Fe-Ni l A. + 0,70 V. B. 0,18 V. C. + 0,18 V. Nhm gm tt c cc cht u tan trong nc l A. K2O, BaO, Al2O3. C. Na2O, K2O, BaO.

D. 0,70 V.

B. Na2O, Fe2O3 ; BaO. D. Na2O, K2O, MgO.

II. Trc nghim t lun Cu 1 : (2 im) Vit cc phng trnh ho hc thc hin dy chuyn ho : NaCl NaOH NaHCO3 BaCO3 BaSO4 Cu 2 : (1 im) Phn bit cc l ng ring bit cc dung dch : NaCl, MgCl2, BaCl2, AlCl3. Cu 3 : (2 im) Cho 3,6 gam mt kim loi R ho tr II tc dng vi dung dch HNO 3 long d thu c 2,24 lt kh NO l sn phm kh duy nht (ktc) v dung dch X. a) Xc nh kim loi R. b) T dung dch X hy vit cc phng trnh ho hc ti to kim loi R.

HNG DN GII I. Trc nghim khch quan Cu p n Cu p n 1 C 11 A 2 B 12 A 3 A 13 D 4 D 14 A 5 A 15 D 6 B 16 B 7 D 17 D 8 B 18 A 9 A 19 C 10 C 20 C

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II. Trc nghim t lun Cu 1 : (2 im) Cc phng trnh ho hc :

pmn 2NaCl + 2H2O 2NaOH + H2 + Cl2

NaOH + CO2 NaHCO3 2NaHCO3 + Ba(OH)2 BaCO3 + Na2CO3 + 2H2O BaCO3 + H2SO4 BaSO4 + CO2 + H2O Cu 2 : (1 im) Phn bit cc l ng ring bit cc dung dch : NaCl, MgCl2, BaCl2, AlCl3 + Dng dung dch NaOH d : MgCl2 to kt ta trng keo khng tan AlCl3 to kt ta trng keo sau tan trong NaOH d + Dng dung dch H2SO4 nhn ra BaCl2 do to kt ta trng + Cn li l NaCl. Cu 3 : (2 im) a) Xc nh kim loi R 2,24 nNO = =0,1 (mol) 22,4 3R + 8HNO3 3R(NO3)2 + 2NO + 4H2O 0,15 0,1 (mol) 3,6 MR = = 24 (g/mol) R l Mg. 0,15 b) Cc phng trnh ho hc : Dung dch X cha Mg(NO3)2
t 2Mg(NO3)2 2MgO + 4NO2 + O2
o

MgO + 2HCl MgCl2 + H2O

pnc MgCl2 Mg + Cl2

KIM TRA 1 TIT

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(cho cc vng thun li)

1. Ho tan hon ton 5,75 gam mt kim loi M vo nc thu c 2,8 lt kh ktc. Vy M l A. Na. B. K. C. Ba. D. Ca. in phn nng chy mui clorua kim loi kim thu c 0,896 lt kh (ktc) anot v 3,12 gam kim loi catot. Vy kim loi kim l A. Li. B. Na. C. K. D. Rb. Cho Ca vo dung dch NaHCO3, hin tng quan st c l A. c kh thot ra to dung dch trong sut. B. c kh thot ra v xut hin kt ta trng khng tan. C. c kh thot ra, xut hin kt ta trng sau tan. D. c kt ta v khng c kh thot ra. Dung dch cha mui X khng lm i mu qu tm, dung dch cha mui Y lm qu tm ho xanh. Trn chung hai dung dch trn to kt ta. Vy X v Y c th l cp cht no trong cc cp cht di y ? A. Na2SO4 v BaCl2 B. KNO3 v Na2CO3 5. C. Ba(NO3)2 v Na2CO3 D. Ba(NO3)2 v K2SO4

2.

3.

4.

6.

Cho t t n d dung dch Na2CO3 vo dung dch AlCl3, ta thy A. c kt ta trng keo, sau kt ta tan. B. c kt ta trng keo v c kh bay ra. C. to kt ta trng keo sau chuyn thnh kt ta nu. D. khng c hin tng g. Gii thch no di y khng ng cho kim loi kim ? A. Nhit nng chy v nhit si thp do lc lin kt kim loi trong mng tinh th km bn. B. Khi lng ring nh do c bn knh ln v cu to mng tinh th km c kht. C. Mm do lc lin kt kim loi trong mng tinh th l yu. D. C cu to rng do c cu to mng tinh th lp phng tm din.

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163

7.

Ha tan hon ton hn hp gm Na2O, BaCl2, NaHCO3, NH4Cl c s mol mi cht bng nhau vo nc ri un nng nh. Sau khi kt thc th nghim c dung dch A. Dung dch A cha A. NaCl. B. NaOH, BaCl2, NaHCO3 v NH4Cl. C. Na2CO3 v NaOH. D. BaCl2, NaHCO3 v NaOH.

8.

Nc cha ng thi cc mui no sau y thuc loi nc c tnh cng ton phn ? A. CaCl2 v Ca(HCO3)2. C. NaHCO3 v Ca(NO3)2. B. CaSO4 v MgCl2. D. MgSO4 v CaCl2.

9.

Ho tan hon ton hn hp X gm a mol Al v b mol Na vo nc thu c dung dch A ch cha mt cht duy nht. Ta c kt lun no sau y ? A. a < b B. a > b C. a = b D. b = 2a Sc 2,24 lt CO2 (ktc) vo 150 ml dung dch NaOH 1M. Sau khi phn ng hon ton trong dung dch c A. Na2CO3 v NaHCO3. C. NaHCO3. B. Na2CO3. D. Na2CO3 v NaOH.

10.

11.

12.

sn xut c 1,08 tn nhm bng phng php in phn nng chy Al2O3 vi cc dng bng than ch v ton b oxi sinh ra oxi ho cacbon thnh kh cacbonic th lng cacbon lm cc dng cn dng l A. 0,36 tn. B. 3,6 tn. C. 0,72 tn. D. 7,2 tn. lm kt ta hon ton nhm hiroxit t dung dch nhm sunfat cn dng lng d dung dch A. HCl. B. NaOH. C. Ca(OH)2. D. NH3. Phng php no trong cc phng php sau y c th lm mm nc c tnh cng tm thi ? (I) un nng ; (II) Dng dung dch Ca(OH)2 va ; (III) Dng dung dch NaOH va ; (IV) Dng dung dch H2SO4 va . A. (I), (II), (IV) B. (II), (III) C. (I), (III) D. (I), (II), (III)

13.

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14.

15.

Nh t t cho n d dung dch Na[Al(OH)4] vo dung dch HCl v lc lin tc. Hin tng xy ra l : A. c kt ta xut hin, sau kt ta tan. B. c kt ta xut hin v kt ta khng tan C. khng c hin tng g. D. c kt ta xut hin, sau kt ta tan, ri kt ta tr li. Cht no sau y thng c dng lm gim cn au d dy do d dy d axit ? A. NaHCO3 C. KAl(SO4)2.12H2O B. CaCO3 D. (NH4)2CO3

16.

17.

18.

19.

Hp kim no sau y khng phi ca Al ? A. Amelec B. Inox C. uyra D. Silumin Kim loi kim (nhm IA), kim loi kim th (nhm IIA) v nhm c th iu ch trong cng nghip theo phng php no sau y ? A. Nhit luyn B. Thy luyn C. in phn nng chy D. in phn dung dch Cht c dng b bt khi xng b gy l A. vi ti. B. vi. C. tinh bt. D. thch cao. Trong cc trng hp sau, trng hp no kim loi b n mn in ho hc ? A. Kim loi Fe trong dung dch HCl. B. Thp thng trong khng kh m. C. t chy dy thp trong kh O2. D. Kim loi Cu trong dung dch AgNO3.

20.

Nung hn hp gm MgCO3 v BaCO3 c cng s mol n khi lng khng i thu c kh A v cht rn B. Ho tan B vo nc d, lc b kt ta thu c dung dch D. Hp th hon ton kh A vo dung dch D, sn phm sau phn ng l A. Ba(HCO3)2. C. BaCO3 v Ba(OH)2 d. B. BaCO3 v Ba(HCO3)2. D. BaCO3.
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II. Trc nghim t lun Cu 1 : (2 im) Vit cc phng trnh ho hc thc hin dy chuyn ho : Al2O3 Al Na[Al(OH)4] NaHCO3 Na2CO3 Al(OH)3 Ba[AlOH)4]2 BaCl2 Ba Cu 2 : (1,5 im) Chn mt thuc th vi mt lt th, hy phn bit cc l ring bit ng cc dung dch : H2SO4, NaOH, HCl, BaCl2. Cu 3 : (1,5 im) Trn m gam bt Al vi 8 gam bt Fe2O3 ri un nng n khi phn ng xy ra hon ton thu c hn hp rn X. Cho dung dch NaOH d vo hn hp X thu c 3,36 lt kh (ktc) v dung dch Y. a) Tnh m. b) Thi kh CO2 d vo dung dch Y, tnh khi lng kt ta thu c.

HNG DN GII I. Trc nghim khch quan Cu p n Cu p n 1 A 11 C 2 C 12 D 3 B 13 D 4 C 14 D 5 B 15 A 6 D 16 B 7 A 17 C 8 A 18 D 9 C 19 B 10 A 20 A

II. Trc nghim t lun Cu 1 : (2 im) Cc phng trnh ho hc :

pnc 2Al2O3 4Al + 3O2

2Al + 6H2O + 2NaOH 2Na[Al(OH)4] + 3H2 Na[Al(OH)4] + CO2 NaHCO3 + Al(OH)3

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t 2NaHCO3 Na2CO3 + H2O

3Na2CO3 + 2AlCl3 + 3H2O 2Al(OH)3 + 3CO2 + 6NaCl 2Al(OH)3 + Ba(OH)2 Ba[Al(OH)4]2 Ba[Al(OH)4]2 + 8HCl BaCl2 + 2AlCl3 + 8H2O BaCl2 Ba + Cl2 Cu 2 : (1,5 im) Phn bit cc l ring bit ng cc dung dch : H2SO4, NaOH, HCl, BaCl2. Chn thuc th l dung dch Ba(HCO3)2. + H2SO4 va to kt ta trng va c kh bay ra. + NaOH ch to kt ta trng. + HCl ch c kh bay ra. + BaCl2 khng c hin tng. Cu 3 : (1,5 im) a) Tnh m 3,36 nH2 = = 0,15 (mol) 22,4 8 nFe2O3 = = 0,05 (mol) 160 X tc dng vi dung dch NaOH d H2 X c Al Fe2O3 ht X gm : Al, Fe, Al2O3
t Fe2O3 + 2Al Al2O3 + 2Fe 0,05 0,1 0,05 (mol)
o

pnc

2Al (d) + 2NaOH + 6H2O 2Na[Al(OH)4]

0,1 0,1

+ 3H2
0,15 (mol)

Al2O3 + 2NaOH + 3H2O 2Na[Al(OH)4] 0,05 0,1 (mol) nAl = 0,1 + 0,1 = 0,2 (mol) mAl = 0,2.27 = 5,4 (gam) b) Tnh khi lng kt ta :
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167

 nNaAl( OH)

=0,1 +0,1 =0,2 (mol)

Na[Al(OH)4] + CO2 Al(OH)3 + NaHCO3 0,2 0,2 (mol) mAl( OH ) =78.0,2 =15,6 (gam).
3

KIM TRA 1 TIT Chng trnh chun

1. Dy gm cc nguyn t c xp theo chiu tng dn m in l A. K, Na, Mg, Al. B. Al, Na, Mg, K. C. Na, K, Al, Mg. D. Mg, Al, K, Na. Ho tan hon ton m gam bt Al trong dung dch NaOH d, sau phn ng ta thu c 3,36 lt kh H2 (ktc). Gi tr ca m l A. 2,7. B. 5,4. C. 1,35. D. 4,05. Dy cc ion kim loi u phn ng vi Zn l A. Cu2+, Mg2+, Pb2+. C. Ni2+, Pb2+, Cu2+. 4. B. Cu2+, Ag+, Na+. D. Pb2+, Ag+, Al3+.

2.

3.

5.

Ha tan hon ton 2,73 gam mt kim loi kim vo 100 gam nc thu c dung dch c khi lng 102,66 gam. Kim loi kim l A. K. B. Na. C. Li. D. Rb. lm gim tnh cng vnh cu ca nc, ta dng A. Ca(OH)2, nha trao i ion. B. Na2CO3 hay HCl. C. Na2CO3 hay Na3PO4. D. Na2CO3 hay Ca(OH)2.

6.

iu no khng ng khi ni v kim loi ? A. Bn knh nguyn t kim loi ln hn so vi phi kim cng chu k B. S electron ho tr thng t so vi nguyn t phi kim. C. Lc lin kt vi ht nhn ca cc electron lp ngoi cng tng i yu. D. m in ln hn so vi cc nguyn t khc trong cng chu k.

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7.

Dy cc cht tc dng c vi c dung dch NaOH v dung dch HCl l A. Be, Al2O3, Al. C. Al2O3, Fe2O3, CuO. B. Zn, Al, Fe. D. Al2O3, Fe2O3, Al.

8.

Tnh cht ho hc c trng ca kim loi l A. tnh kh. B. tnh oxi ho. C. tnh axit. D. tnh baz. Ha tan hon ton 1,4 gam mt kim loi X bng dung dch H2SO4 (long), thu c 0,56 lt kh (ktc). Kim loi X l A. Na. B. Mg. C. Al. D. Fe. Cho cc kim loi sau : Na, K, Mg, Al. Kim loi c tnh kh mnh nht l A. Na. B. K. C. Mg. D. Al. Nhm kim loi tc dng c vi nc nhit thng to dung dch kim l A. Na, K, Be. B. Na, Ca, Ba. C. K, Mg, Li. D. Na, K, Mg. Phng php dng iu ch c 3 kim loi Na, Ca, Al t 3 cht : NaCl, CaCl2, Al2O3 l A. in phn nng chy. B. in phn dung dch. C. nhit luyn. D. thy luyn. Cho 4,6 g Na vo 400 mL dung dch CuSO 4 4M. Khi lng kt ta thu c l A. 6,4 gam. B. 89 gam. C. 9,8 gam. D. 14,6 gam. Cht no sau y c dng b bt khi xng b gy ? A. Vi ti : Ca(OH)2 C. Tinh bt : (C6H10O5)n B. vi : CaCO3 D. Thch cao : 2CaSO4.H2O

9.

10. 11.

12.

13.

14.

15.

Nhn nh no di y khng ph hp cc nguyn t nhm IIA ? A. Cu hnh electron l : [kh him] ns2. B. u tan trong nc nhit phng. C. C tnh kh yu hn kim loi kim trong cng chu k. D. Mc oxi ho c trng trong cc hp cht l +2.
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169

16.

Cho s phn ng : X + Na[Al(OH)4] M + Y Y + AgNO3 AgCl +... Cht kh X l A. CO2. C. NaCl. B. NH3. D. HCl.

17.

Phng trnh ho hc no sau y khng ng ? A. 2Na + O2 Na2O2 B. 2Na + Cu2+ 2Na+ + Cu

pmn C. 2NaCl + 2H2O 2NaOH + H2 + Cl2

D. NaOH + CO2 NaHCO3 18. 19. Dung dch no di y khng lm i mu tm ? A. Mg(HSO4)2 B. NaHCO3 C. Na2CO3 D. AlCl3 Nhn nh no sau y khng ng vi nc cng ? A. Lm mt kh nng git ra ca cht git ra tng hp B. Lm gim cht lng thc phm khi ch bin. C. ng cn cc thit b c s dng nc nng. D. Lm cho qun o mau hng. Trong cc nhn nh v kim loi kim, kim th v nhm, nhn nh no sau y ng ? A. Cc kim loi kim, kim th v nhm u phn ng vi dung dch HCl. B. Ch c nhm mi phn ng vi dung dch NaOH. C. Cc kim loi kim, kim th u phn ng vi nc. D. Cc kim loi kim khi phn ng vi oxi d u to ra peoxit.

20.

II. Trc nghim t lun Cu 1 : (2 im) Vit cc phng trnh ho hc thc hin dy chuyn ho : Al2O3 Al NaAlO2 NaHCO3 BaCO3 Cu 2 : (1 im)
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a) Vit cc phng trnh ho hc chng t NaHCO3 l hp cht lng tnh. b) T CaCO3 hy vit cc phng trnh ho hc iu ch Ca. Cu 3 : (2 im) Ho tan 28,4 gam hn hp 2 mui cacbonat ca kim loi nhm IIA thuc 2 chu k lin tip bng dung dch HCl d th c 6,72 lt kh (ktc). a) Xc nh 2 kim loi. b) Tnh thnh phn % khi lng mi mui trong hn hp u. HNG DN GII I. Trc nghim khch quan Cu p n Cu p n 1 A 11 B 2 A 12 A 3 C 13 C 4 A 14 D 5 C 15 B 6 D 16 D 7 A 17 B 8 A 18 B 9 D 19 A 10 B 20 A

II. Trc nghim t lun Cu 1 : (2 im) Cc phng trnh ho hc :

pnc 2Al2O3 4Al + 3O2

2Al + 2H2O + 2NaOH 2NaAlO2 + 3H2 NaAlO2 + CO2 + 2H2O NaHCO3 + Al(OH)3 2NaHCO3 + Ba(OH)2 Cu 2 : (1 im) NaHCO3 + HCl BaCO3 + Na2CO3 + 2H2O

a) Cc phng trnh phn ng chng t NaHCO3 l hp cht lng tnh : NaCl + H2O + CO2 NaHCO3 + NaOH Na2CO3 + H2O b) iu ch Ca : CaCO3 + 2HCl CaCl2 + CO2 + H2O
pnc CaCl2 Ca + Cl2 Cu 3 : (2 im) a) Xc nh 2 kim loi.

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171

nCO2 =

6,72 =0,3 (mol) 22,4

RCO3 + 2HCl RCl 2 + CO2 + H2O 0,3 0,3 28,4 M= =94,66 (g/mol) R + 60 = 94,66 R = 34,66 0,3 Hai kim loi l Mg (M = 24) v Ca (M = 40). b) Tnh thnh phn % khi lng mi mui : x mol MgCO3 84 5,34 94,66 y mol CaCO3 100 % mCaCO3 = 10,66

x y

1 2

0,2 100 100% =70,42% 28,4

% mMgCO3 =29,58% .

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