ELGHZIZALS SCRIBD DOCUMENTS

@ @b@@@ b@ -@ @pbnbi@a@pzna@Z@@b
101(2007 
 )2  
  :
 

V =
/-.
SB
&'(
)
&'*+,
25C

 !
#$!
%
(
CH3NH2 (S)




)





m




.
CB
0123
500ml


:
<,'!
012
=>>'?,
/@
SA
&'(
9
'$:$; 3
VB = 50,0ml
$8/-.

SB
&'5

67



+
1
1

)+!
G6


$8
*5
HI$,?

J.
D$EF

;
pH
B$ 
=,C3
H 3O A = 1,0.10 mol.l

:
<,$, pH = f (VA )



L$M




N
)
&
O,
$

(1

L$;!
$P,
I$/?,
,Q$;!

(2

(
<
RS
#$!
T
L$ ,
$P2
N
UF
R )

E
XD$?,

W$V.F
Q.

(3

m
/M
.
V

CB
1Y,
/M
H9

(4

#$!
T



$P2
N
SB
&'5 pH

9\ [

'

(5

.
<
RS

D$EF

L$;!
$P,
Xmax
)*M] ^
,
Q.

(6

VA=10,0mL

a,
bP
)
`
V
VA = 10,0mL
-@
D$EF


[CH 3 NH 2 ]q
CH 3 NH 3 +
q

1Y,
a


pKA 3
pH

,_

`

(7

Xq
/M
H9
V




Xq
,_

H2
C$
.
VA=10,0mL
-+,
a,$
L$;!
$P,
Xf
<I$8, ^

,
/M
.

(8

(8)
[$,&
X,
c

'$8/M
[D'2
:

L$;!
$P,
Nd',
$V
.

(9

25C
:
<;

pK A (CH 3 NH 3 + / CH 3 NH 2 ) = 10, 7
pK e = 14
M ( H ) = 1g.mol 1 ; M ( N ) = 14 g.mol 1 ; M (C ) = 14 g.mol 1

 

12 C #$%& 0% .. . ! . C #$%&$ ( + AH C6H8O6  !   

. . +4 6
+
pKA(H2O/HO )=14 pKA(H3O /H2O) = 0 pKA(AH/A ) = 4 M(AH) = 176g.mol-1 : 17(!

 


# 

  

4,2 - 6,2
3 - 4,6
7,2 - 8,8
1

25C .:; Ke=1,0.10-14

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ELGHZIZALS SCRIBD DOCUMENTS

(I

*  /
0' 
,' -.*+( ' & ) 3 34& (

12 B+. ! %A  ?;$&%> =  #  AH  CA = 2,88.10-2mol.l-1 B0 

 . CB = 2,00.10-2mlo.l-1 HI  1F.G> VA =10ml ?(% !( #; G HI.;$A . VB
(11$( M%  ?;$&%$?.
#VB=7,2ml +OP!(12 ;25C .:
+
$6(112 pH S0T; pH = 4,0 R7> M  12 H 3 O  S0T10;$&%
(212 U%:%  HV HO > nf(HO-) M $ !$ .4> . ;$4! .: . ?;$&%
(312 H.I & 1:1$%

)A- (aq

)HO- (aq

)HA(aq

37



'
 .3

H2O
9

9

;: /
07

9

'
 <
.

(412?  ?;$&%$? 10 . ; ?0 ?  #;$% + $I!\ ?;$&% ($ 

 .4> .
.
(5120 pKA 6 # ]A AH/A
(13 .( HV G> %$V M% +4 K % ?  12 I%: = ]2 (12

>7 (II /
07
pH ) pH7(
!>] 6  4 12 C500 #$%2 # ($: !+ # ?06 12 aG$  a0A:! HV 7A R HI
100ml!$$ H% 0 7A ;0 R0 S S# VA =10ml +OP! . VS = 100ml aI!($ 0 B
  CB = 2,00.10-2mol.l-1 =G%  c. pH HI.;$A $b  SO # # R::1$%
; (12 . d2$%
(22.  7 #%&0%T #%A.7A! 1%V
. E d2$%
?0; (32 A 1%+OP .:; pHE $.d2$%
eO (42 ($  ?(I: % %pH
  $0& # 10ml $:$  7A
  7 ; R:: R0($
? MI ! 6. jA B+ 2$b

(III

*
7   
! # VA= 10ml +OP0 S> ]$(II
!($  B0 7 .> . 
b CB = 2,00.10-2mol.l-1 0 kl$
 B+4 M$:($ R0; ?! kb! $.:; d2$%
VB,E= 14,4ml
(13 H !$G(.  I% G>$I!\ 0(% B+
($  $40; $%Gm H?  >. 0(%
(23 0 kl$  # kl> A$ M$: B+($ )  # R:: !$(%c($ (
(33> M $   #10ml 120 ($ .
(43 U%:% 0% 6 12 .;$ ?0  R0; M%. .Vitamine C500
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ELGHZIZALS SCRIBD DOCUMENTS

@ @@@@
@ @b@@@ b@- @pbnbi@a@pzna@Zbna@y@
 


.
O$M


!
('&
NfD
3

pH0>7
(
L$;!
aM
)
VA = 0

L$;!)
+
&e6
 (1


:
L$;!
,Q$;
(2
CH 3 NH 2 + H 3 O +
CH 3 NH 3+ + H 2 O

'
 %  # &" ) 
 
 
   
!" # $
: ( 
!""  71 #+ ( )*
#" $   
 $  # 
(  * 
 
 
  ' " ,%" :   # 
/  90 " 88 #+ -. #" $  
  : 
 # 
: (



(
P;E
L$M

L>$a
$;!
g',
N]

/8
L$;!
,Q$;
?2
)


(
O' 
O'M
L$;
h $
CF
.3
8
?2
)
(pHE = 6 ; 25ml )
i

W$9$/!
[
:
XD$?,(

3

:
XD$?,(

4


:
m
c$.


















































































CB

;2









m
n M
CB = =
m = CB .V .M
V
V
V = 0, 5l
M = 12 + 14 + 5(1) = 31g .mol
m = 0, 775 g

C A .VA = CB .VB

012 (5

!3
#

  '4( +5 
!3
 6" '4

 '4 7"
CV
0,1 25
CB = A A =
= 5.102 mol.l 1
VB
50

( '
 8"( 9# : 
 '
 . 



)+!

$9?
l
$
':3
L$;!
aM
pH0
D;
j
,

L$;!
aM
&'+/,
9>Q
':

#$!
T

]
$P2
;ak
9>Q


pH = pK e + log CB


:
NfD
$
L$ ,?=
P2
N$
CF3
pH 11, 6
$ VA = 0
11, 6 14 + log 5.102 = 12, 7 :
[ +,

.
<
RS
#$!
T

]
$P2
NfD
<,$,$3

.( '
 8"( 9# : 
 '
 .  :
&X,
)
-,

<I$8, ^
,
a
c$.

&X,
:
)
$m,
3

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ELGHZIZALS SCRIBD DOCUMENTS

pH

$Me ?
@*'&
l
n,3
< a!
H3O+
LQ$
/
Xr
</,

Xf
\

?J
<I$8,
pH
/M

Xr

= H 3 O + VS = 10 pH .VS = 106 (25 + 50).103 = 7, 5.107 mol

f

X r = C A .VA X f

:


3

X f = C AVA X r
3

X f = 2,5.10 7, 5.10

2, 5.10 mol

Xm = CBVB = 5.10-2.50.10-3 = 2,5.10-3 mol @774 A CB.VB - Xm=0




&3o

xm
c$.

<
CF
L$;!
$P2

Xf
Xm

=1

q$9



37

CH

.3'


X=0

CB.VB

/
07 :;

.
<'


Xf

'
 &

Xm=

NH

+ H 3O

CH

NH

+
3

+ H

ni =CA.Vi A

9

ni(H3O+) - X

9

ni(H3O ) Xf

Xf

9

CB.VB - Xm ni(H3O+) Xm

Xm

9

CB.VB - X

CB.VB - Xf

CA.VA,E

Xm=

3
(
R?
XD$?,
aM
)
'+r!
$P!'
:
O' ,
/@
N'?
-@
8


VA = 10 ml

D$EF

)*M] ^
,(
6

Xm = CAVA = 10-1.10.10-3mol = 10-3mol =1mmol


:
$,

 D
!2$M3
s;E
/@
a,$(7
pH = pK A + log

[CH 3 NH 2 ]

CH 3 NH 3+



[CH 3 NH 2 ] 10 pH pK A = [CH 3 NH 2 ]
pH pK A = log
CH 3 NH 3+
CH 3 NH 3+

CBVB X q

[CH 3 NH 2 ]

CH 3 NH 3+
10 pH pK A =

CBVB X q
(VA + VB )
=
X q
X q
(VA + VB )

:

Nd',
3
[$,&
3o
3

CBVB X q
X q

/@

10ml
st
$

pH
/M


VA
,_
pH
WR,
/!)
+!


Xq
/M
q$9

X
-,
CBVB
3

pKA3

pH


 $,
Me;,
%
u';

pH 10,2 :


1010,2 10,7 =

2, 5.103 X q

X q 2.103 mol

X q

X q (1 + 100,5 ) = 2, 5.103

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ELGHZIZALS SCRIBD DOCUMENTS

(5

%
&X,
)
$v3

%
$.
w
VA =10ml
D$EF


X f I$8,
/ ,(
8

= 1 Xf = Xm


:
$,

(9

:
3
10

pH pK A

[CH 3 NH 2 ]
CH 3 NH 3+

:
[a9
$x
$,
K =
1

CH 3 NH 3+
q

[CH 3 NH 2 ]q H 3 O + q

pK
10,7
10

[D
'$
':3
<
$P,
NfD

LRa
K
N
$y3 K = 10 pH pK . H O + = 10 pH pK .10 pH = 10 = 10 5.10
3 q


8
&X,
-
A

 
( &343*( ' & ) + ,' -.
 ' /
0 *


HA(aq)

HO- (aq)

A- (aq)

(I

H2O















(11

(21
+

[H3O ] = 10

-pH

= 10-4 mol/l

pH = 4

























(121

Ke
HO =
= 1010 mol.l 1













:
$,
(221
H 3 O +

nf(HO-) = [HO-]. (VA + VB) = 1,72.10-12 mol :a:

(321



.3'


37

HA(aq)
CAVA

HO- (aq)
CBVB

*

A- (aq)
0

H2O
9

/
07 :;

CAVA - X

CBVB - X

9

.
<'


CAVA - Xf

CBVB - Xf

Xf

9

Xf = CB.VB = 1,44.10 mol : A CBVB - Xf
=
0



NCF:

L$ ,'
:
+/z,
$P!
-4

<I$8, ^
,
a
c$.
(412

HO
n0 ( HO ) n f ( HO ) 2,88.102.10.103 1, 72.1012
reagit

=
=
=
1



n0 ( HO )
2,88.102.10.103
HO
0

=>'?9]
{
L$;!
$P,
:
Q$/<
,$,$3
<
$P,>
$a?
l

5

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ELGHZIZALS SCRIBD DOCUMENTS

6

pKA
/M

[ +,(
512

A

pH = pKA + Log

[ AH ]

:
*P,&
3o


AH
123

A-
12
Q+,
Xf

A
Xf
VA + VB
1, 44.104
=
=
=
=1
[ AH ] C AVA X f C AVA X f 2,88.102.10.103 1, 44.104
VA + VB



A
= 0 pH = pK A = 4
log
[ AH ]

K
Nd',
$V
(13
A
eq
K=
[ AH ]eq HO

eq

A . H 3O +
eq
eq
=
[ AH ]eq . HO . H 3O +
eq

eq

A
K
1
eq
=
.
= A = 1010

+
+
Ke
HO . H 3O [ AH ]eq . H 3 O
eq
eq
eq

.
 $,
W$$9_[
D
'$
':3

<
$P,>
$a?
l
CF

LRa
K

(7pH ) pH  
/
07> 7 (II

$P2
,Q$;!
 D
!'a9$,
We$;!

.

(||$;!
3
}$;!

)
$P!
#$P6

L$M

{
L$;
&e6
XD$?, [
+
(12


.
L$;!


:
N$ ,(

22


9$/! 
k 

)+!

XD$?,
-.
[D
':
[~!)
+! 
k 
dpH/dV :
,,
/!






'M
L$ 
s;E
/@
<:
L$;!
N]
pH>7 (32



$V
LQ$!
/
) a2
$/

<Ia,
1Y,
R2
 !
#$!
D$EF
(42


$t!
! 
#$!
/
M
+,
<Q
_
.
L$;!
%
#<

R_



  7*
( 
 III

 $a,( 
13

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ELGHZIZALS SCRIBD DOCUMENTS

XD$?,

k72
D$;
 
O,

&31?,'
{
:
9$!
N'!
s$?,
NfD
pH =8
N
$y(23

VA -@
%
LQ''!
/@
LQ$
/ (33

n(AH) =CAVA = 2.10-2.14,4 = 2,88.10-1 mmol

. . 6 12  0% ..(43
0,288mmol 1 10ml $( HI 12 $  +% MI -
. a $( .6 100ml 12 . 6  H .A
: 1$%$ n = 10(0,288mmol) 1 . 6 12  $  U%:%>!
m(AH)= n.M(AH) = 2,88.10-3.176=507.10-3g 500mg
500 a;,
)
T*!
L>$F
;
$
':3

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