TRNG THPT PHAN NH PHNG

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K THI CHN HC SINH GII CP TRNG LP 12 THPT NM HC 2010-2011 Mn: HO HC Thi gian : 180 pht (khng k thi gian giao ) ( thi c 2 trang)

CU 1: (2im) Trong phn t M2X2 c tng s ht proton, ntron, electron l 164, trong s ht mng in nhiu hn s ht khng mang in l 52. S khi ca M ln hn s khi ca X l 23 n v. Tng s ht proton, ntron, electron trong ion M+ nhiu hn trong ion X22- l 7 ht. Tm cng thc phn t M2X2. CU 2: (3im) B tc phn ng v hon thnh s sau, vit phng trnh phn ng ghi r iu kin. D E F G H C2H5OH A B I K L M N P (CH2-CH-) | COOCH3 Qaxeton CU 3:(3im) Cho 10 gam hn hp X gm Fe, FeO, Fe 2O3, Fe3O4. Ha tan ht hn hp X bng dung dch HNO3 thu c 2,8 lit(ktc) hn hp kh Y gm NO v NO2 v dung dch Fe(NO3)3, bit t khi ca Y so vi hiro bng 19. a/ Tnh khi lng mui Fe(NO3)3 thu c. b/ Nung ton b mui trn n khi lng khng i, dn ton b kh thu c qua 4,5 lt nc thu c dung dch A. Tnh pH ca dung dch A. CU 4:(2im) Nung hon ton 12,6 gam mui cacbonat ca mt kim loi nhm IIA, kh thu c dn qua dung dch hn hp cha 133ml dung dch Ba(OH)2 1M v 100ml dung dch NaOH 0,1M, thu c 24,822g kt ta. Xc nh cng thc mui cacbonat. CU 5:(2im) Ba cht hu c c cng cng thc phn t C2H4O2. Trong : A v B tc dng c vi Natri kim loi to thnh H2. B tc dng vi NaHCO3 to thnh kh CO2. C tc dng c vi dung dch NaOH to thnh mui v ancol. Lp lun xc nh cng thc cu to ca A, B, C v vit phng trnh ca cc phn ng. CU 6:(3im) X phng ha hon ton 8,8gam mt este bng NaOH c mt mui v mt ancol. Chng ct ly ancol nguyn cht khan ri cho ancol vo bnh Na ( khng c khng kh) thy khi lng bnh tng 4,5gam v thu c th tch kh H2 sinh ra bng th tch hi ancol ( o cng k nhit , p sut). Nu t chy hon ton lng mui trn thu c 5,3gam mui Na 2CO3. Bit phn t khi ca axit to thnh este nh hn 2,5 ln phn t khi ca ancol. Hy xc nh cng thc phn t v cu to ca este. CU 7:(2im) Cho hiro v mt anken c th tch bng nhau qua Ni nung nng thu c hn hp A. Bit rng t khi hi ca A i vi hiro l 23,2. Hiu sut phn ng hiro ha l 75%.

phenol

a/ Tm cng thc v gi tn anken trn. b/ t V(lit) hn hp A ni trn ri cho ton b sn phm chy qua 128gam dung dch H2SO4 98% sau th nghim nng dung dch H2SO4 l 62,72%. Tnh th tch V ktc. CU 8:(3im) t chy hon ton 7,68 gam mt hp cht hu c mch h, sn phm thu c dn qua nc vi trong thu c 40gam kt ta v 100ml dung dch mui 1M, dung dch ny c khi lng nh hn khi lng nc vi trong dng l 9,28gam. Bit 6,4gam A c cng th tch vi 3,2gam oxi o cng iu kin v 3,2gam A tham gia phn ng vi AgNO 3/NH3 thu c 8,55 gam kt ta. Vit cng thc cu to c th c ca A. (Cho C=12, H=1, O=16, Ag=108, Ba=137, N=14, Na=23, Ca=40, S=32, Fe=56, Mg=24) Ht.

P N THI HC SINH GII Cu 2. C2H5OH Cu 3. Fe C4H6 C4H10