S GD&T NGH AN TRNG THPT ANH SN I thi chnh thc

HI THI GIO VIN DY GII BC THPT NM HC 2013 2014 Mn thi: HA HC Thi gian lm bi: 120 pht (Khng k thi gian giao )

Cu 1. (5,0 im) Anh (ch) hy nu: 1. Vn tt cu trc ca ma trn kim tra, cc khu c bn trong khi thit k ma trn kim tra? 2. Chun kin thc k nng khi dy bi: Glucz (SGK Ha hc 12 c bn). Cu 2. Anh (ch) hy gii cc bi tp sau: Bi 1: (6,0 im) 1. Trnh by phng php cn bng cc phng trnh ha hc sau theo phng php thng bng electron. Na2SO3 + KMnO4 + NaHSO4 Na2SO4 + MnSO4 + K2SO4 + H2O. Fe(NO3)2 + HCl Fe(NO3)3 + FeCl3 + NO + H2O. 2. Bnh kn A cha khng kh (ch gm N2 v O2) v mt t bt Mg. Nung nng bnh nhit cao mt thi gian thu c cht rn B, ha tan hon ton B trong dung dch H3PO4 thu c dung dch C (khng c kt ta to thnh). Xc nh thnh phn ca B, C v vit phng trnh ha hc ca cc phn ng xy ra. Bi 2: (4,0 im) 1. Hn hp X gm Na, Ba, Na2O v BaO. Ha tan hon ton 21,9 gam X vo nc, thu c 1,12 lt kh H2 (ktc) v dung dch Y, trong c 20,52 gam Ba(OH)2. Hp th hon ton 6,72 lt kh CO2 (ktc) vo Y, thu c m gam kt ta. Tnh gi tr ca m. 2. Cho 2,76 gam cht hu c X (ch cha C, H, O v c cng thc phn t trng vi cng thc n gin nht) tc dng vi dung dch NaOH va , sau chng kh th thu c hi nc v phn rn cha hai mui ca natri c khi lng 4,44 gam. t chy hon ton 4,44 gam hn hp hai mui ny trong oxi th thu c 3,18 gam Na2CO3 ; 2,464 lt CO2 ( ktc) v 0,9 gam nc. T m cng thc phn t, vit cng thc cu to c th c ca X. Cu 3. (5,0 im) 1. Anh (ch) hy trnh by cch tin hnh th nghim iu ch v th tnh tan ca HCl trong phng th nghim? 2. Trong phng th nghim c cc ha cht: cc dung dch CaCl2, MgCl2, NaOH, HCl, kh CO2, H2O. Hy nu v gii thch phng php iu ch CaCO3, MgCO3. Cho H = 1, C = 12, N = 14, O = 16, Na = 23, Mg = 24, Fe = 56, Cu = 64, Ba = 137 --- Ht --H v tn: S bo danh: