SAHTECH

SAFETY AND HEALTH TECHNOLOGY CENTER

(GHS)
GHS


1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.

GHS

MSDS
MSDS

SAHTECH

SAFETY AND HEALTH TECHNOLOGY CENTER

1. GHS


GHS or Not GHS ?

Allyl butyrate
CAS No. : 2051-78-7

LD 50 : 250 mg/kg
(Rat, Oral)

(1)

(2)

GHS
Globally Harmonized System of Classification and
Labelling of Chemicals (GHS)
()
1992

200212()
20037GHS
2008GHS
2005(revised 1st edition)
7

GHS

Hazard Classification

Labelling
Material Safety Data Sheet,
MSDS/SDS

Classification Categories
8


(UNCED)

(IFCS)

1992

(OECD)

(UNSCETDG)

(ILO)

OECDUNSCETDG

(GHS)

200212

GHS

2006 2

GHS

200610

200710

GHS
GHS

(
)

ILO SAFEWORK
-Safe Chemicals Use
ILO
National Chemical
Management

Strategic
Approach to
International
Chemicals
Management
(SAICM) 2020

MSDS/SDS

GHS
GHS Guidance Document, UNITAR, 2005/OSHA, USA

10

SAHTECH

SAFETY AND HEALTH TECHNOLOGY CENTER

2.

11

96.10.19
88.6.29
81.12.28
80.5.17

63.4.16

MSDS
16

(
GHS
)

9611GHS
()(
)()
GHS
97.12.31
97.12.31 APEC
2008GHS

12

12

GHS

GHS

CNS6864
UNTDG

MSDS16

27

CNS15030
27CNS15030-1
CNS15030-27

MSDS
SDSSDS16

13

961019 3096045703

14

15

16

SAHTECH

SAFETY AND HEALTH TECHNOLOGY CENTER

3.

17

CNS 15030

18

Trichloromethane
1,1,2,2- 1,1,2,2-Tetrachloroethane
Tetrachloromethane
1,2- 1,2-Dichloroethylene
1,2- 1,2-Dichloroethane
Carbon disulfide

()

19

CNS 15030

127

15030

CNS 6864
20


MSDS
1.
2.CNS 15030

3.
4.
GHSMSDS

1.

3.

2.CNS 15030

4
MSDS
21

()
22

MSDS
()

23

OSHA HCS

()

24

SAHTECH

SAFETY AND HEALTH TECHNOLOGY CENTER

4.

25

GHS

UNCETDG

OECD

26

GHS
:
93

23 35
23 35
23 60

60 93

27

GHS

28

GHS
UN

GHS

29

GHS-27

30

GHS

31

GHS

32

SAHTECH

SAFETY AND HEALTH TECHNOLOGY CENTER

5.

33

34

GHS

1 2

35

GHS

36

GHS

Division
CategoryType

CNS15030
CNS15030
37

GHS

38

GHS

39

GHS
/

40

GHS

1.

2.

41

12
3GHS1.4.10.5.3.2

42

SAHTECH

SAFETY AND HEALTH TECHNOLOGY CENTER

6.

43

GHS
/
Step 1

CNS 15030GHS
/

Step 2

Step 3

Step 4

44

GHS(1)
Step 1CNS 15030GHS
/
LD50/

GHS

1040
LD50200mg/kg()
IARC2A

2
3
1
/2

45

GHS(2)
Step 2

46

GHS(3)
Step 3

GHS

3()

/2

47

GHS(4)
Step 4/

GHS

48

GHS

49

GHS

1
2

1
2
3()
4

1
2315
3(02)8725-9598

50

SAHTECH

SAFETY AND HEALTH TECHNOLOGY CENTER

7.

51

B
GHS
(Bridging Principle)

C
iii

GHS

52

bridging principles)
(Dilution)

(Batching)

53

(ATE)

54

55

--

/:
:

0.1 %

1.0%

56

--

I Ma

>25%

(M 10 I)+ II

>25%

II

(M 100 I)+(10 II)+ III >25%

III

I +II +III +IV

IV

>25%

L(E)C50

(M)

0.1 < L(E)C50 1

0.01 < L(E)C50 0.1

10

0.001 < L(E)C50 0.01

100

0.0001 < L(E)C50 0.001

1000

0.00001 < L(E)C50 0.0001

10000

(10 )
57

(ATE)

Ci = i
n i 1 n
ATEi = i

58

TMAH
TMAH 100%
GHS
1
1
1
1

GHS

GHS




59

 (TMAH 2.5%)

TMAH () 1
ATE=5

100

ATEmix

Ci

ATE
n

Ci = i
n i 1 n
ATEi = i

100 / (ATEmix) = 2.5 / 5, ATEmix = 200

2.5 %TMAH
() 2

60

TMAH

100 %

25 %

2.5 %

2.38

0.4 %

1
()
/

/
1

2()
4()
1()
3()
/ / /
1
1
1
/
/
/

1
1
1

GHS TMAH

GHS

61

GHS(1)
Step 1

62

GHS(2)
Step 2
Step 3

63

GHS(3)
Step 4
Step 5

64

SAHTECH

SAFETY AND HEALTH TECHNOLOGY CENTER

8.

65

66

67

68

()

69

()

70

()
71

GHS
CNS 6864

72

73


97.07.01 3 0970145566
16 2

2 3

84

74

SAHTECH

SAFETY AND HEALTH TECHNOLOGY CENTER

9. MSDS

75

76

1.0%

1.0%

1.0%

1.0%

0.1%

1.0%

0.1%

0.1%

1.0%

1.0%
77

GHSMSDS
ALD501000mg/kg
2

GHS1

MSDSMSDS
A

LD50 5000mg/kg

A
78


(1)

( CAS No.)()

79


(2)

pH
/

log Kow

80


(3)

81

()

82

SAHTECH

SAFETY AND HEALTH TECHNOLOGY CENTER

10. MSDS

83

MSDS

TMAHMSDS

MSDS
84

MSDS

()

85

MSDS

MSDS
MSDS
MSDS

86

MSDS

MSDS
87

MSDS

()

MSDS

88

MSDS
MSDS

MSDS
MSDS
MSDS

MSDS
89

SAHTECH

SAFETY AND HEALTH TECHNOLOGY CENTER

11.

90

91

92

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_________________________

93

()

33

94

GHS

95

GHS

2008
1231GHS
1094

GHS

96

9 3
27

PDCA

97


GHShttp://ghs.cla.gov.tw
1,650GHSMSDS

GHS
GHS
GHS
GHS

02-8590-2777
GHS 06-293-7770
98

981217

1062
971231
9911
1062

981217

1

1062

9911

()
99

100

981217

2

GHS

http://ghs.cla.gov.tw)
06-2937770

101

981217

GHS

1%

102

981217

GHS

1%

103

981217

104

981217

105