4 / 1 :

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)2007 (
:

4 :
8 :

0.50
0.75

) 6 (
3 ) 1 (
25 0 C . Ke = 10 14
1 pH ) (S A AH C A = 10 2 mol.l 1 pH = 3.12
1 1 AH .
2 1 pK A . AH / A
3 1 pK A / .

0.25
0.50

0.25
0.25
0.50

0.50
0.50
1.00

0.50
0.50

C 6 H 5 COOH / C 6 H 5 COO

pK A
4.20

HCOOH / HCOO
CH 2 ClCOOH / CH 2 ClCOO

3.75
2.86

NH 4+ / NH 3

9.20

1 3 1 . AH
2 3 1 .
2 V A = 20ml ) (S A V B

) (S B

C B = 10 2 mol.l 1 ) (S ) . pH = pK A (AH / A
1 2 .
2 2 ) . (S
3 2 . V B
3 ) 2 (
) (D . C 3 H 6 O2 :

1 ) (D 700 0 P4 O10
.
1 1 .
2 1 .
- 2 ) (D .
.
3 ) ( A . NH 3
- 1 3 .
2 3 0.2mol ) ( A
. 80 0 0 M (O ) = 16 g .mol 1 M (C ) = 12 g.mol 1 M (H ) = 1g .mol 1 :

 4 / 2 :

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) 14 (

5.5 ) 1- (
g = 10m.s . = 10
) (S 1 :
r = 5cm MN = 2 L = 40cm
G . " + "
) ( . G ) ( . J
) ( f ) (S1
m = 0.8kg . G1 ) (S1
= 30 0 .
) ( f .
r
t = 0 G1 O ) . (O.i G1 . x
2

0.75

1 a ) (S1 r J m :
. g
2
2 2 ) (S . V = f ( x ) : x
1 2 a && " + "
2 2 ) (S1 B x B = 0.8m
I ) ( h = 1m . B

0.75
0.50

1 2 2 I . BX .BY
2 2 2 M ) (S1 .
L
3 ) (S1 M = MM
2
K = 50 N .m 1 " . " 3
r
MN G1 O . O; k
1 3 l .
2 3 ) (S1 d = 1m
" + " 0 . t = 0

0.75

) (

0.75

4 / 3 :

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) (

1.50

r
t G1 z . O; k .
1 2 3 G1
2

K .L
z = 0 :
) 4(mr 2 + J

0.50

0.50
0.50

0.50
0.50
1.00
0.50

. &z& +

) (

r
O O; k
.
2 2 3 ) z = f (t 10
. t = 5s
3.5 ) 2 (
1 L C = 2 AB AB
A . p
1 1 L . f
2 1 AB :
AB .
AB f . 2. f
2 = 0.620m
) (R . L
1 2 D L E
.
2 2 a ) (R k
. k Z
3 2 n ) (R
+1 1 . x = 4cm :
4 2 .
5 ) 3 (
1 :
) (D . R = 500
) (b L . r
) (G .
:
Y1 u D ) (D
Y2 u b ) . (b

 4 / 4:

0.50
1.00

1.50

1.00
1.00

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0.2ms / div Y1 Y2 0.5V / div

2-
di
L .r
1 1 u b ) (b i :
dt
2 1 2 r . L = 150mH
2 ) (D ) (b . C
MN ) u MN (t U = 6V

f ) . i(t ) = I . 2 cos(2. . f .t . 3
1 2 f1 = 500 Hz ) i (t
) u MN (t . cos = 0.86
I C .
2 2 f f 0 .
1 2 2 U C U .
2 2 2 f f 0 f = f 0 (1 + ) :
. pp 1

pp 1 . (1 + ) 1 + n.
n

2. .U C
Z = R. 1 +
Z :
U

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1-

0.50

- 1 1 H 3 O + C A
1

= 7.58.10 mol.l

3.12

] = 10

AH :
0.75

H 3 O
+
) ( aq

H 3O

]< C

) ( aq

- 2 1 pK A AH / A :
H O + . A
:
KA = 3
] [AH
= 7.58.10 4 mol.l 1

] []

H 3O .
H 2O

[H O ] = [A ] = 10
[AH ] = C [A ] = C 10

pH

pH

= 9.24.10 3 mol.l 1 :
. pK A = log K A = 4.20 :
1
1 3 1 AH C 6 H 5 COOH / C 6 H 5 COO :
- 2 3 1 :
A

0.25
0.50

0.25
0.25
0.50

0.50
0.50

AH

+ OH C 6 H 5 COO

- 1 2 + H 2 O :
2 2 .
3 2 V B
C A .V A = C B .VBE :
V BE = 2.VB :
C V
. V B = A A = 10ml :
2.C B
2
- 1 1 ) (D :

- 2 1

C 6 H 5 COOH

1.00

- 2

0.50

: .
1 3

0.50

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2 3 0.2mol
)M ( Anhydride) m( A
= )m( Anhydride

) ( A :
)M ( A
r

)n( A) M ( Anhydride
= 0.35 g
r

= )m( Anhydride

0.75

:
-1

) : (S1
: ) (S1
:
r
r
r
: P1 R ) . T ( f
r r r
r
r
r
. . FAPP = m1 .a : . P1 + R + T = m1 .a :
r
. . ) (O; i m1 .g. sin T = m1 .a :

T = m1 .g. sin m1 .a :

)(1

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:
:
:
r
r
r
: P R ) . T ( f
r
. . M Fapp = J .&& : :
r
r
r
r
r
&& M P + M R + M T = J . M P = M R = 0
(2) T .r = J .&& :

) (

) (

) (
) (

) (

) (

T = T : :
a
m. sin
x
= && . ) (1 ) (2 :
= :
J
r
r
m + 2
r
V 2 = f ( x ) - 1 2 V 2 = K .x : K
a = g.

) (

0.75

dV
K 1 V2
. a= = .
2.V . = 2.5m.s 2 :
= K .V :
) 2 2 (x
dt
2.5
a
= = &&.
= 50rad .s 2 :
r 5.10 2
1 2 2 : I
V B
O B
) (S1 : B
V B = 2.a.x B = 2m.s 1

0.50

x = VB . cos( ).t

x
= t

) VB . cos(

1
y = .g .t 2 + VB . sin ( ).t
2

g
g
= y I = h
= y .x I2 + tan ( ).x I :
.x 2 + tan ( ).x
2
2
2
2
) 2.VB . cos (
) 2.VB . cos (
g

.x I2 + tan ( ).x I h = 0 :
2
2
) 2.VB . cos (
1.66.x I + 0.577.x I 1 = 0 : x I = 0.62m
x I = 0.62m

I
y I = 1m
2 2 2 M :
VB VM
=
&B = &M :
r
L
L
. VM = VB = 8m.s 1 :
r

www.madariss.fr

0.75

- 1 3 :
s r
) F = 0 : (S1 T1 = m1 .g . sin ( ) :

1.50

= 0 :

L
= T1.r
2

T . T = K .l T1 = T1

) m.g .r. sin (

:
K .L
1 2 3 " ) " (S

l = 2.

1
1
1
V
1
J
V
EC = .m.V 2 + .J .& 2 = .m.V 2 + .J . 2 = 2 + m
:
2
2
2
2
r
r
2
1
2
E Pe = .K (l + d ) + C te : C te = 0
2
L
d = . : :
2
2

1
1
1 L2 . 2 1
L
E Pe = .K l + . = .K .l 2 + K .
+ .K .l.
2
2
2
2
4
2
te
te
E PP = m.g .z + C : C = 0 E PP = m.g .z :
dE m
:
= 0 :
dt
dEC J
&&z

J
& z
= 2 + m .V .V& = 2 + m .x&.&x& = 2 + m

.
dt
r

r
) sin ( ). sin (

dE Pe
& .& K .l.L..
&L2 x x& K .l.L.x
= K .L2
+
= K. . . +
4
2
4 r r
dt
r
2
dE Pe
L
z
&z
&K .l.Lz
.
= K. .
+
dt
) 4 r. sin ( ) r. sin ( ) 2.r. sin (

dE PP
&= m.g .z
dt

www.madariss.fr
:
dE m J
&K .L2 .z.z
&K .L.l.z
& z&.&z
= 2 + m 2
+
+
m.g.z& = 0
2
2
dt
r
) sin ( ) 4.r . sin ( ) 2.r. sin (
K .L.l
:
= m.g :
) 2.r. sin (
dE m J
&K .L2 .z.z
& z&.&z
= 2 + m 2
+
=0
2
2
dt
r
) sin ( ) 4.r . sin (
K .L2
K .L2 .z
J

&z& +
.
z
=
0
&
&
:

m
z
+
.
+
= 0 :

2
4 J + m.r 2
4.r 2 .
r

K .L

= 02 .
4 J + m.r 2
2.
= 0
2 2 3 z = z m . cos( 0 .t + ) : = 4. rad .s 1 :
0.5
= 0 z = z m = d . sin ( ) t = 0 . z = 5.10 2. cos(4. .t ) :

0.50

0.50
0.50
0.50
0.50

1.00

1
C f 0 - 1 1 . = 10cm :
C
- 2 1
: .
: .
1 2 . D = f = 10cm :
-22
=f

k .
= a. sin ( ) = k . : :
a
3 2 n .
k . x k
= ) tan ( k ) = sin ( k
=

a
f
. f
= x +1
k = +1
a
. f
k = 1
x 1 =
a

= ) sin (

www.madariss.fr

0.50

1
x
2.. f
= x = x +1 x 1 = n = 322580 m 1 :
= 2.n.. f
a
2. . f
a
4 2
1
1
:
k+
1 sin ( ) +1 1 k .n. +1 :
.n
.n
. 5 k +5 . 11

=n

0.50
1.00

di
1 1 + r.i : u b
dt
21
r.i 0 r
di
:
u b L.
dt
u
u D = R.i : . i = D
R
d u
u b L. D :
dt R
. u b = L.

ub
= 150mH :
du D
dt
1.50

-12

: :
) U . cos(
= 0.01A :
R

1.00

. L = R

=I

I
L
C.

= ) sin ( :
: :
U
1
=C
= 4.1.10 7 F

2
.
.
.
f
U
1
4. 2 .L. f 12
) 1 cos 2 (
I

1 2 2 U C . U
:
I0
U

= U C U = R.I 0
=
C. 0 C.R. 0

1 L
1
=
= 1.2 :
R C R.C. 0

UC
= 1.2 :
U

=Q

R.I 2
U. 2

= ) cos(

www.madariss.fr
L=

2 2 2

1
1
1

=
: Z 2 = R 2 + L.

2
2 2
C.
C. 0 C.4. f 0

2. . f
1
Z = R +

2
2
4. . f 0 .C C.2. . f
2

2. . f 0 (1 + )
1

Z = R +

2
2

(
)
C
.
2
.

.
f
1

+
4
.

.
f
.
C
0
0

(1 + )

Z = R +

2. . f 0 .C C.2. . f 0 (1 + )
2

1
1
1 +
Z = R +

1+
2. . f 0 .C
U
1
1
=
= R C :
2 . f 0 .C C.
U
2

U2
1
Z = R + R C 1 +
:
U
1+
2
U C2
1
2
2
Z = R 1 + 2 1 +

U
1 +

2
2
(1 + )2 1
1
4. 2

1 + 2 1

2 pp 1 1 +
=
=
=
4. 2

1+
1 + 2.

1+
1+
2

2. .U C
Z = R 1+

:
2007/ 06 / 14

1.00