S GD-T BC GIANG TRNG THPT NG S LIN

THI TH I HC MN: HA HC KHI A,B (Thi gian lm bi 90 pht )

M thi: 321

H, tn th sinh:.................................................................. S bo danh:................................phng thi............................

Cho bit khi lng nguyn t (theo vC) ca cc nguyn t: H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; Si =28; P =31; S = 32; Cl = 35,5; K = 39;Ca = 40; Cr = 52; Fe = 56; Ni = 59; Cu = 64; Zn = 65; Br = 80; Ag = 108; I = 127; Ba = 137; Sn = 118,7; I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1. Trong cc ho cht Cu, C, S, Na 2SO3, FeS , O2, H2SO4 c. Cho tng cp cht phn ng vi nhau trong iu kin thch hp th s cp cht c phn ng to ra kh SO2 l A. 6 B. 7 C. 9 D. 8 Cu 2. Thc hin cc th nghim sau: (1) Sc kh SO2 vo dung dch KMnO4. (5) Cho MnO2 vo dung dch HCl c, nng. (2) Sc kh SO2 vo dung dch H2S. (6) Cho Fe2O3 vo dung dch H2SO4 c, nng. (3) Sc hn hp kh NO2 v O2 vo nc. (7) Cho SiO2 vo dung dch HF. (4) Cho Fe2O3 vo dung dch HI. S th nghim c phn ng oxi ha- kh xy ra l: A. 4 B. 6 C. 5 D. 3 Cu 3. Hn hp T gm hai axit cacboxylic no mch h. - Th nghim 1: t chy hon ton a mol hn hp T thu c a mol H2O. - Th nghim 2: a mol hn hp T tc dng vi dung dch NaHCO3 d thu c 1,6 a mol CO2. Phn trm khi lng ca axit c phn t khi nh hn trong T l A. 40,00%. B. 46,67%. C. 31,76%. D. 25,41%. Cu 4. Ho tan hon ton 74 gam hn hp X gm FeO, Fe3O4, Fe2O3 bng dd H2SO4 long d sinh ra 178 gam mui sunfat. Nu cng cho 74 gam hn hp X trn phn ng vi lng d kh CO nhit cao v dn sn phm kh qua dd nc vi trong d th khi lng kt ta thu c l (cc phn ng xy ra hon ton) A. 130 g B. 150 g C. 180 g D. 240 g Cu 5 Thy phn hon ton 1mol este X cn dng 3 mol KOH. Hn hp sn phm thu c gm glixerol, mui ca axit oleic v axit panmitic. Tng s ng phn ca X l: A. 18 B. 3 C. 2 D. 6. Cu 6. Hn hp kh X gm H2 , anken A, ankin B c t khi so vi He l 3,9 ( A v B c cng s nguyn t C). Dn hn hp X qua bt Ni nung nng, sau khi phn ng xy ra hon ton thu c hn hp kh Y c t khi so vi hn hp ban u l 20/9. CTPT ca A, v B l: A. C2H4 v C2H2 B. C3H6 v C3H4 C. C4H8 v C4H6 D. C5H10 v C5H8 Cu 7 Cho cc cht sau: Fe, Mg, Cu, AgNO3, CuCl2, Fe(NO3)2. S cp cht tc dng vi nhau l? A. 8. B. 6 C. 9 D. 7. Cu 8. Cho phenol lng phn ng ln lt vi cc cht: Na, NaOH, NaHCO 3, HCl, C2H5OH, Br2, HNO3 (H2SO4 xt). S phn ng xy ra l A. 6 B. 4 C. 3 D. 5 Cu 9. Cc nguyn t t Natri n Clo, theo chiu tng ca in tch ht nhn th: (1) bn knh nguyn t tng. (2) m in gim. (3) nng lng ion ho th nht tng dn. (4) tnh baz ca oxit v hiroxit gim dn. (5) tnh kim loi tng dn. (6) tnh phi kim gim dn. S nhn nh ng l A. 2. B. 3 C. 1. D. 4.
1

Cu 10. Cho phng trnh ion thu gn sau: a Al + b NO 3 + c OH + d H2O e [Al(OH)4] + g NH3 . Tng h s (s nguyn ti gin) cc cht tham gia phn ng l A. 45 B. 32 C. 30 D. 34 Cu 11. Thi t t n d kh X vo dd Ba(OH) 2 thy c kt ta, sau kt ta tan. Kh X c th l: A. SO2 hay H2S B. H2S hay NO2 C. CO2 hay SO2 D. CO2 hay NO2 Cu 12. Cc cht kh sau: SO2, NO2, Cl2, N2O, CO2.Cc cht kh khi tc dng vi ddNaOH ( nhit thng) lun to ra 2 mui l: A. Cl2, NO2 B. NO2, SO2 , CO2 C. SO2, CO2 D. CO2, Cl2, N2O Cu 13. Dy gm cc kim loi u tc dng c vi dung dch FeCl3 l: A. Au, Cu, Al, Mg, Zn B. Fe, Zn, Cu, Al, Mg C. Cu, Ag, Au, Mg, Fe D. Fe, Mg, Cu, Ag, Al Cu 14. Cho 0,2 mol mt anehit n chc, mch h X phn ng va vi 300 ml dung dch cha AgNO3 2M trong NH3. Sau khi phn ng xy ra hon ton thu c 87,2 g kt ta. Cng thc phn t ca anehit l A. C4H5CHO B. C3H3CHO C. C4H3CHO D. C3H5CHO Cu 15. Khi thu phn CH2=CH-OOC-CH3 trong dd NaOH thu c sn phm l: A. CH3-CH2OH v CH3COONa B. CH3-CH2OH v HCOONa C. CH3OH v CH2=CH-COONa D. CH3-CHO v CH3-COONa Cu 16. Ha tan 16,8g hn hp gm 2 mui cacbonat v sunfit ca cng 1 kim loi kim vo dd HCl d, thu c 3,36 lit hn hp kh (kc). Kim loi kim l A. Na B. Li C. K D. Rb Cu 17. Thu phn 51,3 gam mantoz trong mi trng axit vi hiu sut phn ng t 80% thu c hn hp X. Trung ho X bng NaOH thu c dd Y. Cho Y tc dng ht vi lng d dd AgNO3 trong NH3 un nng, sinh ra m gam Ag. Gi tr ca m l A. 58,32. B. 58,82. C. 51,84. D. 32,40. 2+ Cu 18. Ion X c tng s ht p,e,n bng 80. K hiu ha hc ca nguyn t X l 59 64 56 58 Co Cu Fe Ni A. 27 B. 29 C. 26 D. 28 Cu 19. Xt cc cht: imetylete (1), ancol metylic (2), ancol etylic (3), axit axetic (4). Cc cht trn c xp theo nhit si tng dn (t tri sang phi) l: A. 1, 2, 3, 4 B. 2, 3, 4, 1 C. 2, 3, 1, 4 D. 1, 3, 2, 4. 2+ + Cu 20. Trn dung dch X cha Ba , OH (0,17 mol), Na (0,02 mol) vi dung dch Y cha HCO3 , CO32 (0,03 mol), Na+( 0,1 mol) thu c m gam kt ta. Gi tr ca m l. A. 14,775 B. 13,79 C. 5,91 D. 7,88 Cu 21. X l mt tripeptit c to thnh t 1 aminoaxit no, mch h c 1 nhm -COOH v 1 nhm -NH2 .t chy hon ton 0,3 mol X cn 2,025 mol O 2 thu c sn phm gm CO 2 ,H2O , N2. Vy cng thc ca amino axit to nn X l A. H2NCH2COOH B. H2NC3H6COOH C. H2N-COOH D. H2NC2H4COOH Cu 22. Cho 27,4 gam hn hp M gm axit axetic v hai ancol n chc ng ng k tip tc dng ht vi 13,8 gam Na thu c 40,65 gam cht rn. Nu cho ton b lng M trn phn ng vi dd NaHCO3 (d), kt thc phn ng sinh ra 6,72 lt CO2 (ktc). Cng thc ca hai ancol trong M l A. C7H15OH v C8H17OH. B. C2H5OH v C3H7OH. C. CH3OH v C2H5OH. D. C3H5OH v C4H7OH. Cu 23. Khi ha tan SO2 vo nc ln lt c cc cn bng sau: SO2 + H2O H2SO3 (1) H2SO3 H+ + HSO3- (2) HSO3- H+ + SO32- (3) Nng cn bng ca SO2 s A. gim khi un nng dd hoc thm HCl hoc thm NaOH . B. tng khi un nng dd hoc thm NaOH v gim khi thm HCl.
2

C. gim khi un nng dd hay thm NaOH v tng khi thm HCl. D. tng khi un nng dd hay thm HCl v gim khi thm NaOH. Cu 24. Hn hp X gm axit n chc A, ancol n chc B v este E iu ch t A v B. t chy 9,6 gam hn hp X thu c 8,64 gam H2O v 8,96 lt kh CO2 (ktc). Bit trong X th B chim 50% theo s mol. S mol ancol B trong 9,6 gam hn hp l: A. 0,06 B. 0,075 C. 0,08 D. 0,09 Cu 25. Nc clo c tnh ty mu v st trng l do A. Clo l cht oxy ha mnh B. Clo l cht kh tan trong nc C. c cha oxi nguyn t l tc nhn oxy ha mnh D. c cha axit hipoclor l tc nhn oxy ha mnh Cu 26. Cho 0,1 mol axit cacboxylic n chc X tc dng vi 0,15 mol ancol n chc Y thu c 4,5 gam este vi hiu sut 75%. Vy tn gi ca este l: A. etyl axetat B. etyl propionat C. metyl axetat D. metyl fomiat Cu 27. C 5 dung dch sau : Ba(OH) 2, FeCl2 , Pb(NO3)2, CuSO4, FeCl3. Khi sc kh H2S qua 5 dung dch trn, c bao nhiu trng hp c phn ng sinh kt ta ? A. 3. B. 2 C. 4 D. 1. Cu 28. Ho tan hon ton hn hp gm z mol Fe2O3 v t mol Fe3O4 vo dung dch HCl thu c dd X, sau cho thm x mol Fe v y mol Cu vo dd X khng thy kh c kh bay ra khi khi bnh, dung dch thu c ch cha 2 mui. Mi quan h gia s mol cc cht l A. x + y = 2z + 2t B. x + y = 2z +3t C. x + 2y = 2z + 2t D. x + y = z + t Cu 29. T 80 gam hn hp 3 ancol n chc, mch h em un nng vi H2SO4 c 1400C th thu c 58,4 gam hn hp cc ete c s mol bng nhau (Hiu sut phn ng 100%). S mol mi ancol ban u l: A. 2,4 B. 0,8 C. 0,6 D. 1,2 Cu 30. So snh tnh baz ca cc cht sau: (a) C 6H5NH2; (b) CH3-NH2; (c) CH3-C6H4-NH2; (d) O2N-C6H4-NH2 A. a> b > c > d B. a > b > d > c C. b > c > a > d D. b > c > d > a Cu 31. Chn pht biu ng: A. Tnh oxi ha ca Ag+ > Cu2+ > Fe3+ > Ni2+ > Fe2+ B. Tnh oxi ha ca Ag+ > Cu2+ > Fe3+ C. Tnh kh ca K > Fe > Cu > Fe2+ > Ag D. Tnh kh ca K > Mg > Zn > Ni > Fe > Hg Cu 32. S ipeptit c to nn t glyxin v axit glutamic l: A. 1 B. 2 C. 3 D. 4 Cu 33. Cho cc hp cht sau: (1) CH3-CH(NH2)-COOH (2) HO-CH2-COOH (3) CH2O v C6H5OH (4) C2H4(OH)2 v p-C6H4(COOH)2 (5) H2N[CH2]5NH2 v HOOC[CH2]4COOH Cc hp cht no c kh nng tham gia phn ng trng ngng? A. 3,5 B. 1, 2, 3, 4, 5 C. 1,2 D. 3,4 Cu 34. Dung dch A cha Ca(OH)2. Cho 0,06 mol CO2 vo A thu c 4m gam kt ta cn cho 0,08mol CO2 th thu c 2m gam kt ta. Gi tr m (g) A. 1,5 B. 2 C. 1 D. 3 Cu 35. Ha tan ht 26,5 gam hn hp bt gm Mg, Al, Al2O3 v MgO bng 800 ml dd hn hp gm HCl 0,5M v H2SO4 0,75M (va ). Sau phn ng thu c dd X v 4,48 lt kh H2 ( ktc). C cn dung dch X thu c khi lng mui khan l A. 88,7 gam. B. 95,2 gam. C. 86,5 gam. D. 99,7 gam. Cu 36 Hp cht hu c X ( cha C, H, O ) mch h c phn t khi l 60 vC. S hp cht tha mn X l A. 4 B. 5 C. 6 D. 3
3

Cu 37. Ho tan hon ton m gam bt Al vo 150 ml dung dch HCl 2M thu c dung dch X. Cho dung dch X tc dng vi 320 ml dung dch NaOH 1M thu c 4,68 gam kt ta. Tnh m A. 1,89 gam B. 2,16 gam C. 2,7 gam D. 1,62 gam Cu 38. Cho cc dd cha cc cht tan : glucoz, fructoz, saccaroz, mantoz, axit fomic, glixerol, vinyl axetat, anehit fomic. S dd va ho tan Cu(OH)2 va lm mt mu nc brom l A. 4. B. 3. C. 5. D. 6. Cu 39. Hn hp X gm Al, Fe xOy. Tin hnh phn ng nhit nhm hon ton m gam hn hp X trong iu kin khng c khng kh thu c hn hp Y. Chia Y thnh 2 phn. - Phn 1 cho tc dng vi dd NaOH d thu c 1,008 lt H2 (ktc) v cn li 5,04 g cht rn khng tan. - Phn 2 c khi lng 29,79 gam, cho tc dng vi dd HNO3 long d thu c 8,064 lt NO (ktc, l sn phm kh duy nht). Gi tr ca m v cng thc ca oxit st l: A. 39,72 gam v FeO B. 39,72 gam v Fe3O4 C. 38,91 gam v FeO D. 36,48 gam v Fe3O4 Cu 40. Cho cc cht: benzen, toluen, stiren, propilen, axetilen. S cht lm mt mu thuc tm nhit thng l: A. 4 B. 2 C. 3 D. 5 II. PHN RING [10 cu] Th sinh ch c lm mt trong hai phn (phn A hoc B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41. Mt dy st ni vi mt dy ng mt u, hai u cn li nhng vo dung dch mui n. Ti ch ni ca hai dy kim loi xy ra hin tng g? A. Electron di chuyn t Fe sang Cu. B. Ion Fe2+ thu thm 2e to ra Fe C. Ion Cu2+ thu thm 2e to ra Cu D. Electron di chuyn t Cu sang Fe Cu 42. Oxi ha m gam X gm CH3CHO, C2H3CHO , C2H5CHO bng oxi c xc tc sn phm thu c sau phn ng gm 3 axit c khi lng (m + 3,2 gam ). Cho m gam X tc dng vi lng d dd AgNO3/NH3 th thu c x gam kt ta. gi tr ca x l: A. 10,8 gam B. 21,6 g C. 32,4 g D. 43,2g Cu 43. Dy gm cc cht, ion va c tnh oxi ha va c tnh kh l : 2 A. O3, Fe2+, FeCl2, CrO3 B. NO2, Fe2+, Cl2, FeCl3, SO 3 C. FeO, H2S, Cu, 3+ HNO3 D. HCl, Na2S, NO2, Fe Cu 44. Hn hp X gm axit Y n chc v axit Z hai chc (Y, Z c cng s nguyn t cacbon). Chia X thnh hai phn bng nhau. Cho phn mt tc dng ht vi Na, sinh ra 4,48 lt kh H 2 ( ktc). t chy hon ton phn hai, sinh ra 26,4 gam CO 2. Cng thc cu to thu gn v % v khi lng ca Z trong hn hp X ln lt l A. HOOC-CH2-COOH v 70,87%. B. HOOC-CH2-COOH v 54,88%. C. HOOC-COOH v 60,00%. D. HOOC-COOH v 42,86%. Cu 45. Nhng mt thanh st nng 100 gam vo 100 ml dung dch hn hp gm Cu(NO 3)2 0,2M v AgNO3 0,2M. Sau mt thi gian ly thanh kim loi ra, ra sch lm kh cn c 101,72 gam (gi thit cc kim loi to thnh u bm ht vo thanh st). Khi lng st phn ng l A. 1,40 gam. B. 2,16 gam. C. 0,84 gam. D. 1,72 gam. Cu 46. Cho m gam hn hp gm Fe v Cu tc dng vi dd HNO3 sau khi phn ng kt thc th ch thu c 4,48 lt hn hp kh NO, NO2 l 2 sn phm kh (ktc) v cn li 13,2 gam rn gm 2 kim loi. Gi tr ca m l A. 17,12 gam B. 30 gam C. 24,96 gam D. 16 gam Cu 47. Cho cc hp cht hu c: C 2H2; C2H4; CH2O; CH2O2 (mch h); C3H4O2 (mch h, n chc). Bit C3H4O2 khng lm chuyn mu qu tm m. S cht tc dng c vi dd AgNO 3 trong NH3 to ra kt ta l A. 2. B. 5. C. 4. D. 3.
4

Cu 48. Thuc th no trong cc trng hp sau c th dng phn bit c 5 kim loi: Mg, Zn, Fe, Ba, Ag. A. Dung dch NaOH B. Dung dch H2SO4 long C. Dung dch HCl D. H2O Cu 49. im ging nhau ca glucoz v saccaroz l A. u phn ng vi dung dch AgNO3 trong NH3 to Ag. B. u phn ng vi Cu(OH)2 to dd mu xanh lam. C. u b thu phn trong dung dch axit. D. u phn ng vi H2 c xc tc Ni nung nng cng thu c mt ancol a chc. Cu 50. t chy hon ton mt amin, no, n chc, mch h. Sn phm chy sau khi ngng t hi nc c t khi so vi H2 l 19,333. Cng thc phn t ca amin l A. CH3NH2 B. C2H5NH2 C. C3H7NH2 D. C4H9NH2 B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60) Cu 51. Cho cc cht tham gia phn ng : t t , xt (1) S + F2 (2) SO2 + H2S (d) (3) SO2 + O2 (d) . (4). S + H2SO4 (c, nng) (5) H2S + Cl2(d) +H2O S phn ng trong S b oxi ha ln mc oxi ha +6 l : A. 5 B. 3 C. 4 D. 2 2+ Cu 52. Oxi ha 16,8g anehit fomic bng oxi c mt Mn thu c hn hp X. Cho hn hp X tc dng vi dd AgNO3/NH3 d thu c 151,2g Ag. Hiu sut ca phn ng oxi ha anehit fomic l: A. 37,5% B. 80% C. 60% D. 75% Cu 53. Trong qu trnh hot ng ca pin in ho Cu- Ag nng ca cc Ion trong dd bin i nh th no A. [Ag+] tng dn v [Cu2+] tng dn . B. [Ag+ ] gim dn v [Cu2+] gim dn. C. [Ag+] tng dn v [Cu2+] gim dn. D. [Ag+] gim dn v [Cu2+] tng dn. Cu 54. Cho 52 gam hn hp X gm Ni, Cr, Sn (trong s mol Cr gp 2 ln s mol Ni) tc dng ht vi lng d dd HCl long, nng thu c dd Y v 13,44 kh H 2 (ktc). Nu cho 52 gam hn hp X tc dng hon ton vi O2 (d) to hn hp 3 oxit th th tch kh O2 (ktc) phn ng l A. 11,2 lt. B. 6,72 lt. C. 10,08 lt. D. 7,84 lt. Cu 55. Trong s cc loi t sau: t lapsan, t nitron, t visco, t nilon-6,6, t axetat, t capron, t nilon-7. C bao nhiu loi t thuc loi t nhn to ? A. 1. B. 3. C. 4. D. 2. Cu 56. Nu thy phn khng hon ton pentapeptit Gly Ala Gly Ala Gly th thu c ti a bao nhiu ipeptit khc nhau A. 4 B. 2 C. 3 D. 1 Cu 57. Hn hp M gm 2 axit cacboxylic u no, mch h A, B (B hn A mt nhm chc). Ha hi hon ton m gam M thu c th tch hi bng th tch ca 7 gam nit o cng iu kin nhit , p sut. Nu cho m gam M tc dng vi Na d thu c 4,48 lt H 2 (ktc). Khi t chy hon ton m gam M thu c 28,6g CO2. Cng thc phn t ca A v B l: A. C2H4O2 v C3H4O4. B. CH2O2 v C3H4O4 . C. C2H4O2 v C4H6O4 D. CH2O2 v C4H6O2. Cu 58. Ha tan ht 4 gam hn hp A gm Fe v 1 oxit st trong dd axit HCl d thu c dd X. Sc kh Cl2 cho n d vo X thu c dd Y cha 9,75 gam mui tan. Nu cho 4 gam A tc dng vi dd HNO3 long d, thu c V lt NO (sn phm kh duy nht, ktc). Gi tr ca V l A. 0,747 B. 0,896 C. 1,120 D. 0,726 Cu 59. nhn bit cc kh: CO2, SO2, H2S, N2 cn dng cc dung dch:
0 0

A. Nc brom v NaOH B. NaOH v Ca(OH)2 C. Nc brom v Ca(OH)2 D. KMnO4 v NaOH Cu 60. Cht X c cng thc phn t C3H5Br3, un X vi dd NaOH thu c cht hu c Y c kh nng tc dng vi Cu(OH)2. S cu to X tha mn l: A. 4 B. 2 C. 3 D. 5

1. 11. 21. 31. 41. 51.

B 2. C 12. A 22. C 32. A 42. B 52.

C 3. A 13. C 23. D 33. D 43. D 53.

D 4. B 14. C 24. B 34. B 44. D 54.

A 5. C 15. C 25. C 35. D 45. A 55.

P N C 6. D 16. D 26. A 36. A 46. D 56.

B 7. A 17. D 27. C 37. C 47. B 57.

A 8. A 18. A 28. B 38. C 48. A 58.

B 9. C 19. D 29. B 39. B 49. A 59.

A 10. A 20. B 30. B 40. B 50. C 60.

D B C C A A

S GD-T H NI TRNG THPT A PHC -----*****-----

THI TH I HC MN HA HC T 2 NM 2013 Thi gian: 90 pht (khng k thi gian pht )

6

( thi c 04 trang) Ngy thi 14/04/2013 H, tn th sinh:...................................................................... S bo danh:..................................... M : 188 Cu 1. Nu cho 1 mol mi cht: CaOCl 2, KMnO4, K2Cr2O7, MnO2 ln lt phn ng vi lng d dung dch HCl c, cht to ra lng kh Cl2 nhiu nht l A. CaOCl2. B. K2Cr2O7. C. KMnO4. D. MnO2. Cu 2. Hin tng no xy ra trong th nghim sau: Cho 0,1 mol Na vo 100 ml dung dch cha CuSO4 1M v H2SO4 1M (long)? A. Ch c kh bay ln. B. C kh bay ln v c kt ta mu xanh. C. C kh bay ln v c kt ta mu xanh sau kt ta li tan. D. Ch c kt ta. Cu 3. Cho hn hp A gm Al, Fe vo dung dch B c cha Cu(NO 3)2 v AgNO3. Sau khi phn ng xy ra hon ton thu c dung dch C; Cho dung dch NaOH d vo C c kt ta D gm hai hiroxit kim loi. Trong dung dch C c cha A. Al(NO3)3, Fe(NO3)2 v Cu(NO3)2 B. Al(NO3)3 v Fe(NO3)2 C. Al(NO3)3 v Fe(NO3)3 D. Al(NO3)3 v Fe(NO3)3 v Fe(NO3)2 Cu 4. t chy hon ton 2,24 lt (ktc) hn hp kh gm: CH 4, C2H4, C2H6, C3H8 thu c 6,16 gam CO2 v 4,14 gam H2O. S mol C2H4 trong hn hp trn l A. 0,03 mol. B. 0,08 mol. C. 0,01 mol. D. 0,09 mol. Cu 5. Fomalin hay fomon (dng bo qun xc ng vt chng thi ra) l A. Ancol C2H5OH 46o B. Dung dch HCHO 25%- 30% v th tch trong nc C. Dung dch CH3CHO 40% v th tch trong nc D. Dung dch HCHO 37%-40% v khi lng trong nc Cu 6. Hirocacbon X chay cho th tich hi nc gp 1,2 ln th tich CO 2 (o cung k). Khi tac dung vi clo tao mt dn xut monoclo duy nht. X co tn la A. isobutan. B. propan. C. etan. D. 2,2- imetylpropan Cu 7. Hp cht hu c X c cng thc phn t C 8H11N, X tan c trong axit. Cho X tc dng vi HNO2 to ra hp cht Y c cng thc phn t C 8H10O. un nng Y vi dung dch H 2SO4 c to ra hp cht Z. Trung hp Z thu c polistiren. S ng phn cua X thoa mn l A. 1 B. 2 C. 3 D. 4 Cu 8. Tng s proton trong ht nhn nguyn t X v Y l 25. Y thuc nhm VIIA. dng n gin n cht X tc dng vi Y. Khng nh no sau y ng? A. trng thi c bn X c 2 electron c thn. B. Cng thc oxit cao nht ca X l Y2O. C. Cng thc oxit cao nht ca X l XO3. D. X l kim loi, Y l phi kim. Cu 9. Cho dy cht: phenyl clorua, sec-butyl clorua, natri phenolat, phenylamoni clorua, tinh bt, amoni axetat, crezol. S cht trong dy khng tc dng vi dung dch NaOH long nhit thng l A. 5 B. 3 C. 6 D. 4 Cu 10. Hn hp A gm 2 axit cacboxylic n chc X, Y. Cho 13,4 gam A ha tan ht vo nc ri cho tc dng vi AgNO3/NH3 d c 21,6 gam Ag. Mt khc cng lng hn hp trn trung ha va vi 100 ml dung dch NaOH 2M. CTCT ca X, Y l A. HCOOH, C2H5COOH B. HCOOH, CH3COOH C. CH3COOH, C2H5COOH D. HCOOH, C3H7COOH Cu 11. A, B, D l 3 hp cht thm c cng thc phn t l C 7H6Cl2. Khi un nng vi dung dch NaOH long, th A phn ng theo t l mol 1: 2, B phn ng theo t l mol 1:1, cn D khng phn ng. S ng phn cu to ca A, B, D l
7

A. 1, 3, 5 B. 1, 2, 3 C. 1, 3, 4 D. 1, 3, 6 Cu 12. Thy phn hon ton mt cht bo bng dung dch NaOH, sau phn ng thu c 2,78 gam C15H31COONa; m2 gam C17H31COONa v m3 gam C17H35COONa. Gi tr ca m 2 v m3 ln lt l A. 3,02 gam v 3,05 gam B. 3,05 gam v 3,09 gam C. 3,02 gam v 3,06 gam D. 6,04 gam v 6,12 gam Cu 13. Cho 28,2 gam hn hp hai ancol n chc tc dng ht vi 11,5 gam Na, sau phn ng thu 39,3 gam cht rn. Nu un 28,2 gam hn hp trn vi H 2SO4 c 1400C, th thu c bao nhiu gam ete A. 19,2 gam B. 23,7 gam C. 24,6 gam D. 21,0 gam Cu 14. Cho x gam P2O5 tc dng ht vi 388 ml dung dch NaOH. C cn dung dch sau phn ng thu c 3x gam cht rn. Gi tr ca x l A. 14,2. B. 12,78. C. 11,36. D. 17,04. Cu 15. Cho Cacbon (C) ln lt tc dng vi Al, H 2O, CuO, HNO3 c, H2SO4 c, KClO3, CO2 iu kin thch hp. S phn ng m trong C ng vai tr l cht kh? A. 6. B. 4. C. 5. D. 7. Cu 16. Cho 8,04 gam hn hp hi gm CH 3CHO v C2H2 tc dng hon ton vi dung dch AgNO3/NH3 thu c 55,2 gam kt ta. Cho kt ta ny vo dung dch HCl d, sau khi kt thc phn ng cn li m gam cht khng tan. Gi tr ca m l A. 61,78 B. 21,6 C. 55,2 D. 41,69 Cu 17. X l este c to bi axit 2 chc, mch h v ancol no, 2 chc, mch h c cng thc n gin nht l C3H2O2. hidro ha hon ton 1 mol X (xt Ni, t0) cn bao nhiu mol H2? A. 2 mol B. 1 mol C. 3 mol D. 4 mol Cu 18. Cho cc dung dch sau: NaOH, BaCl2, KHSO4, Al2(SO4)3, (NH4)2SO4. phn bit cc dung dch trn, dng thuc th no trong s cc thuc th sau th s cn tin hnh t th nghim nht? A. KOH B. Qu tm C. H2SO4 D. Ba(OH)2 Cu 19. Trn 100ml dung dch c pH=1 gm HCl v HNO 3 vi 100ml dung dch NaOH nng a (mol/l) thu c 200ml dung dch c pH=12. Gi tr ca a l (bit trong mi dung dch [H +] [OH-]=10-14) A. 0,03 B. 0,30 C. 0,12 D. 0,15 Cu 20. Nung 13,4 gam hn hp 2 mui cacbonat ca hai kim loi ho tr 2, thu c 6,8 gam cht rn v kh X. lng kh X sinh ra cho hp th vo 75 ml dd NaOH 1M, khi lng mui khan thu c sau phn ng l A. 5,8 g B. 4,2 g C. 6,5 g D. 6,3 g 2+ Cu 21. Phn ng no sau y chng t Fe c tnh kh yu hn so vi Cu? A. Fe + Cu2+ Fe2+ + Cu B. Cu2+ + 2Fe2+2Fe3+ + Cu C. Fe2+ + CuCu2+ + Fe D. 2Fe3+ + Cu 2Fe2+ + Cu2+ Cu 22. C 5 dung dch ring bit l: CuCl2, FeCl3, AgNO3, HCl v HCl c ln CuCl 2. Nhng vo mi dung dch mt thanh Fe nguyn cht. S trng hp xut hin n mn in ha l A. 3 B. 4 C. 2 D. 1 Cu 23. Cho 17,9 gam hn hp gm Fe, Cu v Al vo bnh ng 200 gam dung dch H 2SO4 24,01%. Sau khi cc phn ng xy ra hon ton, thu c 9,6 gam cht rn v c 5,6 lt kh (ktc) thot ra. Thm tip vo bnh 10,2 gam NaNO3, khi cc phn ng kt thc th th tch kh NO (ktc, sn phm kh duy nht) to thnh v khi lng mui trong dung dch l A. 2,688 lt v 59,18 gam B. 2,24 lt v 56,3 gam C. 2,688 lt v 67,7 gam D. 2,24 lt v 59,18 gam Cu 24. Cho cc cht sau: CH3COOCH2CH2Cl, ClH3N-CH2COOH, C6H5Cl (thm), HCOOC6H5 (thm), C6H5COOCH3 (thm), HO-C6H4-CH2OH (thm), CH3CCl3, CH3COOC(Cl2)-CH3. C bao nhiu cht khi tc dng vi NaOH c d, nhit v p sut cao cho sn phm c 2 mui? A. 4 B. 5 C. 7 D. 6

Cu 25. Nguyn t ca nguyn t X c electron mc nng lng cao nht l 3p. Nguyn t ca nguyn t Y cng c electron mc nng lng 3p v c mt electron lp ngoi cng. Nguyn t X v Y c s electron hn km nhau l 2. Nguyn t X, Y ln lt l A. kim loi v kim loi. B. kh him v kim loi. C. phi kim v kim loi. D. kim loi v kh him. Cu 26. Nhit si ca cc cht CH3Cl, CH3OH, HCOOH, CH4 tng theo th t l A. CH3Cl < CH4< CH3OH < HCOOH. B. CH4 < CH3Cl < CH3OH < HCOOH. C. CH4 < CH3OH < HCOOH < CH3Cl. D. CH3Cl < CH3OH < CH4 < HCOOH. 3+ 2+ Cu 27. Dung dch Y gm Al ; Fe ; 0,05 mol Na+; 0,1 mol SO42-; 0,015 mol Cl-. Cho V lt dung dch NaOH 1M vo dung dch Y thu c kt ta ln nht th gi tr ca V l A. 0,30. B. 0,40. C. 0,25. D. 0,35. Cu 28. in phn 100 ml dung dch CuSO4 1M vi in cc tr trong thi gian 25 pht 44 giy, cng dng in l 5A th dng li. Khi lng dung dch gim l A. 3,2 gam B. 2,56 gam C. 2,88 gam D. 3,84 gam Cu 29. Cho V lt (ktc) hn hp kh gm 2 olefin lin tip nhau trong cng dy ng ng hp nc (xc tc H+) thu c 12,9 gam hn hp X gm 3 ancol. un nng X trong H 2SO4 c 1400C thu c 10,65 gam hn hp Y gm 6 ete khan. Gi s hiu sut cc phn ng l 100%. Cng thc phn t ca 2 olefin v gi tr ca V l A. C2H4, C3H6, 5,6 lt B. C3H6, C4H8, 4,48 lt C. C4H8, C5H10, 5,6 lt D. C2H4, C3H6, 4,48 lt Cu 30. Khi lng tripeptit c to thnh t 178 gam alanin v 75 gam glyxin l A. 253 g B. 235g C. 217g D. 199g Cu 31. - Cho a gam Fe ( d) vo V1 lit Cu(NO3)2 1M thu c m gam rn. - Cho a gam Fe (d) vo V2 lit AgNO3 1M, sau phn ng thu c m gam rn. Mi lin h V1 v V2 l A. 10V1 = V2 B. V1 = 10V2 C. V1 = 2V2 D. V1 = V2 Cu 32. Cho kh H2S tc dng vi cc cht: dung dch NaOH, kh clo, nc clo, dung dch KMnO4/H+, kh oxi d un nng, dung dch FeCl 3, dung dch ZnCl2, Pb(NO3)2, KClO3. S trng hp xy ra phn ng v s trng hp trong lu hunh b oxi ha ln S+6 l A. 6 v 2 B. 9 v 3 C. 8 v 1 D. 6 v 1 Cu 33. Cho glixerol (glixerin) phn ng vi hn hp axit bo gm C 17H35COOH v C15H31COOH, s loi trieste c to ra ti a l A. 3. B. 8. C. 6. D. 4. Cu 34. Hn hp X gm Al, Fe2O3 c khi lng 21,67 gam. Tin hnh phn ng nhit nhm hn hp X trong iu kin khng c khng kh. Ha tan hon ton hn hp cht rn sau phn ng bng dung dch NaOH d thu c 2,016 lt H2 (ktc) v 12,4 gam cht rn khng tan. Hiu sut ca phn ng nhit nhm l A. 60% B. 75% C. 71,43% D. 80% Cu 35. Ngi ta iu ch etyl axetat t xenluloz v cc cht v c theo s sau: xenluloz glucoz ancol etylic axit axetic etyl axetat. Tnh khi lng xenluloz cn dng c th iu ch c 1 mol etyl axetat. Bit hiu sut chung ca qu trnh t 40%. A. 506,25 gam B. 405 gam C. 162 gam D. 202,5 gam Cu 36. Cho phn ng CO(k) + H2O(k) CO2 (k) + H2 (k) (H <0) Trong cc yu t: (1) tng nhit , (2) thm lng CO, (3) thm mt lng H 2, (4) gim p sut chung ca h, (5) dng cht xc tc. S yu t lm chuyn dch cn bng l A. 4. B. 5. C. 3. D. 2. Cu 37. Cho s sau:
+ NaOH

Cht A trong s trn l

9

A. CH2=CHCOOC2H5 B. CH2=CHCOOC4H9 C. CH2=C(CH3)COOCH3 D. CH2=C(CH3)COOC2H5 Cu 38. Nung 8,42 gam hn hp X gm Al, Mg, Fe trong oxi sau mt thi gian thu c 11,62 gam hn hp Y. Ha tan hon ton Y trong dung dch HNO 3 d thu c 1,344 lt NO (ktc) l sn phm kh duy nht. S mol HNO3 phn ng l A. 0,72 mol B. 0,48 mol C. 0,56 mol D. 0,64 mol Cu 39. Ln men 45 gam glucoz thy c 4,48 lt CO 2 (ktc) bay ra v cn hn hp cht hu c X gm C2H5OH v glucoz d. t chy hon ton X th s mol CO2 thu c l A. 1,3 mol B. 1,2 mol C. 1,5 mol D. 1,15 mol Cu 40. Ha tan 19,5 gam hn hp gm Na2O v Al2O3 trong nc thu c 500 ml dung dch A trong sut. Thm dn dung dch HCl 1M vo dung dch A n khi xut hin kt ta th dng li thy th tch dung dch HCl cn dng l 100 ml. Phn trm s mol mi cht trong A ln lt l A. 25% v 75% B. 45% v 55% C. 30% v 70% D. 60 % v 40% Cu 41. t chy hon ton hn hp gm 2 este no, h, n chc cn 5,68 g kh oxi v thu c 3,248 lt kh CO2 (ktc). Cho hn hp este trn tc dng va vi KOH thu c 2 ancol l ng ng k tip v 3,92 g mui ca mt axit hu c. Cng thc cu to ca 2 este l A. HCOOCH3 v HCOOC2H5. B. C3H7COOCH3 v CH3COOC2H5. C. CH3COOCH3 v CH3COOC2H5. D. C2H5COOCH3 v C2H5COOC2H5. Cu 42. C bao nhiu cht hoc dung dch sau y cho phn ng vi nc brm: glucoz, fructoz, saccaroz, mantoz, ancol etylic, anehit axetic, axit fomic, axit benzoic, phenol v anilin? A. 6 B. 5 C. 8 D. 7 Cu 43. Ho tan ht m gam Al 2(SO4)3 vo nc c dung dch X. Cho 360 ml dung dch NaOH 1M vo dung dch X, thu c 2a gam kt ta. Mt khc, nu cho 400 ml dung dch NaOH 1M vo dung dch th thu c a gam kt ta. Cc phn ng xy ra hon ton, gi tr ca m l A. 20,52. B. 19,55. C. 15,39. D. 18,81. Cu 44. Hn hp X gm phenol v anilin. Ly m gam X tc dng va vi 200 ml dung dch HCl 1M thu c hn hp Y. Cho hn hp Y tc dng ht vi 500 ml dung dch NaOH 1M, ri c cn thy cn li 31,3 gam cht rn khan. Gi tr ca m l A. 65,6 B. 28 C. 18,7 D. 14 Cu 45. Phng php iu ch polime no sau y l ng? A. ng trng hp axit terephtalic v etylen glicol iu ch c poli(etylen-terephtalat) B. Trng hp caprolactam to t nilon-6 C. Trng hp ancol vinylic iu ch poli(vinyl ancol) D. ng trng ngng buta-1,3-ien v vinylxianua iu ch cao su buna-N Cu 46. xc nh ru ca dung dch ancol etylic (X) ngi ta ly 10ml dung dch X cho tc dng vi Na d thu c 2,564 lt H 2 (ktc). Tnh ru ca X (bit ancol etylic nguyn cht c d=0,8g/ml, nc c d=1g/ml). A. 85,580 B. 87,50 C. 91,00 D. 92,50 Cu 47. Cho cc phn ng ha hc sau: (1) (NH4)2SO4 + BaCl2 (2) CuSO4 + Ba(NO3)2 (3) Na2SO4 + BaCl2 (4) H2SO4 + BaSO3 (5) (NH4)2SO4 + Ba(OH)2 (6) Fe2(SO4)3 + Ba(NO3)2 Cc phn ng u c cng 1 phng trnh ion rt gn l A. (1), (2), (3), (6) B. (2), (3), (4), (6) C. (1), (3), (5), (6) D. (3), (4), (5), (6) Cu 48. Cc nguyn t thuc nhm IA, theo chiu tng dn ca in tch ht nhn th A. Bn knh nguyn t tng dn. B. m in tng dn. C. Nng lng ion ho tng dn. D. Tnh kh gim dn. Cu 49. Hn hp X gm axetilen, etilen v hidrocacbon A chy hon ton thu c CO 2 v H2O theo t l mol 1:1. Dn X i qua bnh ng dung dch brom d thy khi lng bnh tng ln 0,82 gam, kh thot ra khi bnh em t chy hon ton thu c 1,32 gam CO 2 v 0,72 gam H2O. % V ca A trong X l A. 50 B. 33,33 C. 75 D. 25
10

Cu 50. Cho Na tc dng vi 100ml dd AlCl3 thu c 5,6 lt H2(ktc) v kt ta. Lc kt ta ri em nung n khi lng khng i thu c 5,1 gam cht rn. Nng mol/l ca dd AlCl3 l A. 1,5M B. 2,5M. C. 2,0M. D. 1,0M. ---------------------------------HT-------------------------------Th sinh khng c s dng ti liu Cho: H=1, C=12, N=14, O=16, Na=23, Mg=24, Al=27, P=31, S=32, Cl=35,5 K=39, Cr=52, Fe=56, Cu=64, Br=80, Ag=108. P N

1B 11D 21D 31B 41C

2A 12C 22A 32C 42A

3A 13C 23C 33C 43D

4C 14C 24D 34B 44B

5D 15A 25C 35B 45B

6D 16A 26B 36C 46A

7B 17A 27A 37A 47A

8C 18D 28A 38D 48A

9D 19B 29A 39A 49D

10D 20D 30C 40D 50A

11