CLASS TEST - 7

(ORGANIC)

CHEMISTRY

IIT-JEE

P. JOY

Q.1 Choose the correct statement(s) for the compounds shown below :

Q.5 Which enol form is more stable for the compound shown below : O2N

O
I. II.

CH2 C CH2 || O
CH = C CH2 | OH

(A) Compound I have two enol tautomers and both enol forms are chiral (B) Compound I has two enol tautomers & only one enolic form is chiral (C) Compound II have two enol tautomers and both enolic form are chiral. (D) Compound II have two enol tautomers and neither enol form is chiral. Q.6 Q.2 What should be the product (s) of the following reaction + HBr

(A) O2N

CH2 C = CH | OH (C) Both have equal stability (D) Can't be predicted

(B) O2N Which of the following rxn does not yield a 3 alcohol after hydrolysis-

O || (A) R C OR + RMgX(1mol) O || (B) R C Cl + RMgX (xs)

O || (C) R C R + RMgX O || (D) R C OR + RMgX(xs)

Br
(A)

Br Br

(B)

(C)

(D) All of the above Q.7

Q.3 In the following structure, which is better site for the attack of H+

Which of the following ethers cannot be used to store organometals (A) CH3 O CH2 CH2 OH (B) (C)

NH

(A) Oxygen atom (B) Nitrogen atom (C) Both oxygen and nitrogen atom have equal potential for protonation (D) None of these Q.8

SH O (D) CH3CH2 O C CH

Which CH3CH2MgBr + X is(A) An aldehyde (C) 1 alcohol

O
Q.4
(A) 2. H O +
3

1. RMgX

(B) Ketone (D) 2 alcohol

(A) is(A) an aldehyde (C) 2 alcohol

(B) a ketone (D) 3 alcohol

Q.9 For the compound cyclohexa-2, 4-dienone; which form is more stable(A) Enol (B) Keto (C) Can't be predicted (D) Compound does not show tautomerism

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Name : .......................................................................................................... 1 2 3 A B C D E 4 5 6 A B C D E 7 8 9

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Date : .................................. A B C D E

CHEMISTRY IIT JEE (CLASS TEST - 7) (ORGANIC) A N S W E R K E Y