PART–I

SECTION - I
Straight Objective Type
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONLY ONE is correct.

Atomic masses :
[H = 1, Li = 7, N = 12, O = 16, Na = 23, Al = 27, S = 32 , Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55,
Fe = 56, Zn = 65]
Assume 1 mole of an ideal gas occupies 22.4 lt volume at N.T.P or S.T.P.

1. CH3COOH dimerise in benzene according to reaction

2CH3COOH (CH3COOH)2
If 60% mole of CH3COOH goes in dimer formation and remaining is in monomer form then what is average
molecular mass of CH3COOH.
(A) 90 (B) 60 (C) 85.71 (D) 96

2. KO2 + H2O  KOH + H2O2 + O2

14.2 gm KO2 when treated with excess H2O, it gives only 1.7 gm H2O2. So % yield of H2O2 should be :
(A) 20% (B) 30% (C) 40% (D) 50%

3. How many number of moles of MnO4– and MnO2 form respectively by disproportionation of 1 mole MnO42–.
1 1 1 2 2 1
(A) , (B) , (C) , (D) 1, 2
3 3 3 3 3 3

4. How much volume of 63% w/w aq. HNO3 solution (d = 1.5 g/ml) is diluted with sufficient water to prepare
1 L of 3 M HNO3 solution
(A) 200 ml (B) 300 ml (C) 120 ml (D) 150 ml

5. A chemist decided to determine the Emprical formula of an unknown compound. He collects following
informations :
(I) Compound contains 2 : 1 ratio of 'H' and 'O' atoms(number of atoms).
(II) Compound has 40% C by mass
(III) Compound contains C, H and O only.
What is the empirical formula of the compound :
(A) CH3O (B) CH2O (C) C2H2O (D) CH3O2
6. Professor I.L. Finar instructed his student to convert the -Amino acid (X) into a new compound (Y) in which
the —NH2 group is replaced by —COOH group. The student was confused in writing the correct IUPAC
names of these two compounds. The correct IUPAC names of X and Y will be respectively.

(X) =

(A) 2-Ethyl-2-amino ethanoic acid, 2-Ethyl-2-carboxy ethanoic acid

(B) 2-Amino butanoic acid, Ethylpropanedioic acid
(C) 2-Amino butanoic acid, 2-Carboxybutanoic acid
(D) 2-Carboxypropan-1-amine, Propane-1, 1-dicarboxylic acid
7. Ethoxyethene is written as follows, H2C = CH – O – CH2 – CH3.
The structure of 2-chloro-1-ethoxyethene (incorrect name) with correct numbering will be
 1 2 1 2
(A) H2C  CH – O – CH2 – CH2 – Cl (B) CH2  CH – O – CH – CH3
|
Cl

2 1 1 2
(C) H2C  C – O – CH2 – CH2 – Cl (D) Cl – CH  CH – O – CH2 – CH3
|
Cl

8. Ethyl methanoate and methyl ethanoate are

(A) homologs (B) stereoisomers (C) metamers (D) chain isomers

SECTION - II
Multiple Correct Answer Type
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE is/are correct.

9. Which of the following contains the same number of molecules ?

(A) 1g of O2, 2g of SO2
(B)1g of CO2, 1g of N2O
(C) 112 ml of O2 at STP, 224 ml of He at 0.5 atm and 273 K
(D) 1g of oxygen, 1g of ozone

10. Which of the following molarity values of ions in an aqueous solution of 5.85 % w/v NaCl, 5.55% w/v CaCl2
and 6% w/v NaOH are correct
(A) [Cl–1] = 2M (B) [Na+] = 1M (C) [Ca2+] = 0.5 M (D) [OH–] = 1.5 M
–
11. In the reaction, 2Al(s) + 6HCl(aq)  2Al3+(aq) + 6Cl (aq) + 3H2(g).
(A) 6L HCl(aq) is consumed for every 3 L H2(g) produced.
(B) 33.6 L H2(g) is produced regardless of temperature and pressure for every mole Al that reacts.
(C) 33.6 L H2(g) at STP is produced for every 27 gm Al that reacts.
(D) 11.2 L H2(g) at STP is produced for every mole HCl(aq) consumed.

12. Select the correct statements about the given compound (P)

(P) : CH3 – CH = CH – O – CH = CH2

(A) The compound Q(CH3 – O – CH = CH – CH = CH2) is a metamer of (P).

(B) (P) has two geometrical isomers.
(C) (Q) has three stereoisomers.
(D) The IUPAC names of P and Q both have primary suffix diene.

SECTION - III
Comprehension Type
This section contains 2 groups of questions. Each group has 3 multiple choice questions based on a
paragraph. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is
correct.

Paragraph for Question Nos. 13 to 15

We know that balancing of a chemical equation is entirely based on law of conservation of mass. However
the concept of Principle of Atom Conservation (POAC) can also be related to law of conservation of mass in
a chemical reaction. So, POAC can also act as a technique for balancing a chemical equation. For example,
 for a reaction :
ABC3  AB + C2
n ABC3 n AB nC2
On applying POAC for A, B & C and relating the 3 equations, we get : = =
2 2 3
(nx : number of moles of X)
Thus, the coefficients of ABC3 , AB & C2 in the balanced chemical equation will be 2,2 & 3 respectively and
the balanced chemical equation can be represented as :
2ABC3  2AB + 3C2
Now answer the following questions :
13. Which of the following relation is correct regarding the numerical coefficients p,q,r in the balanced chemical
equation :
pA + qB2  rA2B5
(A) 2p = r (B) q = 1.25 p (C) r = 2q (D) q = 0.8p
14. If the weight ratio of C and O2 present is 1 : 2 and both of reactants completely consume and form CO and
CO2. What would be the mole ratio of CO and CO2 in mixture.
(A) 11 : 7 (B) 2 : 1 (C) 1 : 1 (D) 1 : 2
15. If the atomic masses of X and Y are 10 & 30 respectivetly, then the mass of XY3 formed when 120 g of Y2
reacts completely with X is :
Reaction X + Y2  XY3
(A) 133.3 g (B) 200 g (C) 266.6 g (D) 400 g

Paragraph for Question Nos. 16 to 18

Observe the following compound and answer the question 16 to 18.

CH3 – CH = CH

16. Which of the following cannot be its functional isomer,

(A) CH3 – CH = CH

(B) CH3 – CH = CH

(C) CH3 – CH = CH

(D) CH – CH = CH2

17. The total number of its geometrical isomers is

(A) 2 (B) 4 (C) 8 (D) 16

18. The degree of unsaturation of the compound is :

(A) 4 (B) 6 (C) 7 (D) 8
 SECTION - IV
Matrix - Match Type
This section contains 2 questions. Each question contains statements given in two
columns, which have to be matched. The statements in Column-I are labelled
A, B, C and D, while the statements in Column-II are labelled p, q, r, s and t. Any
given statement in Column-I can have correct matching with ONE OR MORE
statement(s) in Column-II. The appropriate bubbles corresponding to the answers
to these questions have to be darkened as illustrated in the following example.
If the correct matches are A-p, s and t ; B-q and r; C-p and q; and D-s and t; then the correct darkening of
bubbles will look like the following :

19. Column – I Column – II

(A) 4.1 g H2SO3 (p) 200 ml of 0.5 N base is used for complete neutralization
(B) 4.9 g H3PO4 (q) 200 milli moles of oxygen atoms
(C) 4.5 g oxalic acid (H2C2O4) (r) Central atom has its highest oxidation number
(D) 5.3 g Na2CO3 (s) May react with an oxidising agent
(t) 100 milli moles of hydrogen atoms

20. Match the relationship between the compounds of column-I with column-II.

Column I Column II
(p) Homologs

and

(A)

O O (q) Isomers

and
(B) NH NH

(r) Stereoisomers (geometrical)

and
(C)
N N

(s) Structural isomers

(D) N and N—H

(t) Functional isomers