SCH4U Hess's Law

Hess's Law Worksheet

1. Calculate L1H for the reaction: C2H4 (g)+ H2 (g)~C 2 H 6 (g), from the following
data.
C2H4 (g)+ 3 02 (g) ~2 C02 (g)+ 2 H20 (I)

L1H = -1411. kJ

C2H6 (g) + 3Yz 02 (g) ~2 C02 (g) + 3 H20 (I)

L1H = -1560. kJ
L1H

2.

3.

4.

=-285.8 kJ

Calculate L1H for the reaction 4 NH 3 (g)+ 5 0 2 (g) 1111114 NO (g)+ 6 H20 (g), from
the following data.
N2 (g) + 02 (g) ~2 NO (g)

L1H = -180.5 kJ

N2 (g)+ 3 H2 (g) ~2 NH3 (g)

L1H

=-91.8 kJ

2 H2 (g) + 02 (g) ~2 H20 (g)

L1H

=-483.6 kJ

Find L1H for the reaction 2H 2(g) + 2C(s) + 0 2(g) ~ C2H5 0H(I), using the following
thermochemical data.
C2H 5 0H (I)+ 2 0 2 (g) ~2 C02 (g)+ 2 H20 (I)

L1H = -875. kJ

C (s) + 02 (g) ~C02 (g)

L1H = -394.51 kJ

H2 (g) + Yz 02 (g) ~H20 (I)

L1H = -285.8 kJ

Calculate li!H for the reaction CH 4 (g)+ NH 3 (g) ~HCN (g)+ 3 H2 (g), given:
N2 (g)+ 3 H2 (g) ~2 NH3 (g)

L1H = -91.8 kJ

C (s) + 2 H2 (g) ~CH4 (g)

L1H = -74.9 kJ

H2 (g) + 2 C (s) + N2 (g) ~2 HCN (g)

L1H

=+270.3 kJ

SCH4U Hess 's Law

7. Given the following reactions and their enthalpy changes, calculate the enthalpy
change for

I Change in Heat Energy

j Equations
N2(g) + 2 02(g) ~ 2 N02(g)

67.8 kJ

Nz(g) + 2 02(g) ~ N204(g)

9.67 kJ

8. Given the following reactions and their enthalpy changes, calculate the enthalpy
change for

IChange in Heat Energy

!Equations
i

] Ca(g) + 2 C(s)
I

~ CaC2(S)

ICaC03(s) + C02(g) ~ CaC2(s) + 5/2 02(g)

-62.8 kJ

394 kJ

1538 kJ

9. Calculate the heat change for the formation of l.OOmol of strontium carbonate from
its elements. Given the following experimental information:

1
Sr(s)+-02 (g)
2
SrO(s) + C0 2 (g)

SrO(s)

/ill = -592kJ

SrC0 3

11H = -234kJ

C(graphite) + 0 2 (g)

C02 (g)

/ill= -394kJ

10. Calculate the D. Ht for 6 C(s) + 6 H2 (g) + 3 0 2 (g) -------tC6H12 06 (s) given that:
C6H1206 (s) + 6 Oz (g)
>6 C02 (g)+ 6 H20 (g) ~He= -2537.3 kJ
Hz (g) + 1/2 02 (g) ~H20 (g) D,. Ht = -241.8 kJ
0
C (s) + 02 (g) ~ C02 (g) ~Ht = -393.5 kJ

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