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3. Which of the following factors affect the rates of both homogeneous and heterogeneous
reactions.
A. N2O4(g) + 59 kJ 2NO2(g)
B. 2H2(g) + O2(g) 2H2O(l) + 572 kJ
C. 2BrCl(g) -29.3 kJ Br2(g) + Cl2(g)
D. 2H2(g) + O2(g) 2H2O(l) H = -572 kJ
5. Consider the potential energy diagram. The activation energy for the reverse reaction is
A. 30 kJ
B. 140 kJ
PE 170kJ 30kJ
(kJ)
C. 170 kJ
Progress of the reaction
D. 200 kJ
Practice Test#1 Chapter 1 - Kinetics
6. Consider the following mechanism: Step 1: Cl + O3 ClO + O2
Step 2: O + ClO Cl + O2
The reaction intermediate is
A. Cl C. O3
B. O2 D. ClO
9. Which of the following properties could be used to measure the rate of the following reaction in
a open container. Zn(s) + 2HCl(aq) ZnCl2(aq) + H2(g)
PE
(kJ)
I. Favourable geometry
II. Sufficient energy
III. Large H
When 1.0 g of KI is added to the H2O2, bubbles of O2 are produced at an increased rate, The KI
is a
A. product C. reactant
B. catalyst D. intermediate
A. product
B. catalyst
C. reactant
D. reaction intermediate
Practice Test#1 Chapter 1 - Kinetics
15. Consider the following potential energy diagram:
125
PE
(kJ) 100
75
50
25
A. 25 kJ C. 75 kJ
B. 50 kJ D. 125 kJ
A. Cu+ C. V3+
B. Cu2+ D. Fe3+
20. The minimum amount of energy needed to start a reaction is called the
21. An 8.00g piece of magnesium was placed into 6.0 M HCl. After 25 s, 3.50 g of unreacted
magnesium remained. The average rate at which magnesium was consumed is
A. 0.14 g/s
B. 0.18 g/s
C. 0.32 g/s
D. 4.50 g/s
22. In general rates double when the temperature is increased by 10 oC. The temperature of a
reaction is increased by 40 oC. The rate will increase by a factor of
A. 2 C. 8
B. 4 D. 16
25. Which combination of factors will affect the rate of the following reaction?
MgCO3(s) + 2HCl(aq) CO2(g) + H2O(l) + MgCl2(aq)
A. temperature and surface area only
B. temperature and concentration only
C. concentration and surface area only
D. temperature, concentration, and surface area only
Practice Test#1 Chapter 1 - Kinetics
A. heat is released
B. a reaction intermediate forms
C. kinetic energy changes into potential energy
D. potential energy changes into kinetic energy
Consider the following potential energy diagram for the next three five questions.
PE 2
4
1 3
Progress of reaction
A. 1 C. 3
B. 2 D. 4
A. 1 C. 3
B. 2 D. 4
A. 1 C. 3
B. 2 D. 4
A. 1 C. 3
B. 2 D. 4
A. 1 C. 3
B. 2 D. 4
Practice Test#1 Chapter 1 - Kinetics
32. When a catalyst is added to a reaction, H will
A. increase slowly
B. remain constant
C. decrease slowly
D. increase rapidly due to the alternate pathway
0 4.65 0 20
2 4.50 50 21
4 4.35 100 22
A. g/min C. min/mL
B. g/mL D. g/(mL)(oC)
34. When a lit match is touched to the wick of a candle, the candle begins to burn. When the match
is removed, the candle continues to burn, the match,
A. behaves as a catalyst
B. supplies the activation energy
C. is part of the rate determining step
D. lowers the activation energy barrier
38. Some reactants are more reactive than others because of their activation energy Ea. What graph
shows the relationship between Ea and rate.
A. B.
Ea Ea
Rate Rate
C. D.
Ea Ea
Rate Rate
A. stable and has low PE. C. unstable and has low PE.
B. stable and has high PE. D. unstable and has high PE.
PE
1. On the potential energy diagram above, clearly label the activation energy, heat of the reaction
(H), and the energy of the activated complex.
3. On the graph below, draw the potential energy diagram for an exothermic reaction and label the
activation energy.
PE
4. Nitric oxide (NO) is involved in the decomposition of ozone by the following mechanism:
Step 1: O3 + sunlight O2 + O
Step 2: O3 + NO NO2 + O2
Step 3: NO2 + O NO + O2
a) Write the net equation for the decomposition reaction
b) Identify a catalyst
a) Explain why the reaction is likely to involve more than one step.
7. The combustion of coal, C, produces carbon dioxide and water according to the following
equation: C(s) + O2(g) CO2(g) + 394 kJ
b) Using the collision theory, explain why a lump of coal does not react with oxygen at
room temperature and pressure.
c) Many coalmine disasters have resulted when a spark ignites coal dust in the air. Explain using
the collision theory.
8. State two reasons why some collisions may not result in a chemical reaction.
Practice Test#1 Chapter 1 - Kinetics
Property 1
Property 2
0.0 270.230
30.0 270.200
60.0 270.170 270.170
3. Which of the following factors affect the rates of both homogeneous and heterogeneous reactions.
A. I and IV only
B. II and III only
C. II, III, and IV only
D. I, II, III, and IV
A. N2O4(g) + 59 kJ 2NO2(g)
B. 2H2(g) + O2(g) 2H2O(l) + 572 kJ
C. 2BrCl(g) -29.3 kJ Br2(g) + Cl2(g)
D. 2H2(g) + O2(g) 2H2O(l) H = -572 kJ
Practice Test#1 Chapter 1 - Kinetics
5. Consider the potential energy diagram. The activation energy for the reverse reaction is
PE
A. 30 kJ (kJ)
B. 140 kJ
30kJ
170kJ
C. 170 kJ
D. 200 kJ
A. Cl
B. O2
C. O3
D. ClO
9. Which of the following properties could be used to measure the rate of the following reaction in a
open container. Zn(s) + 2HCl(aq) ZnCl2(aq) + H2(g)
A. mass of Zn
B. solubility of HCl
C. concentration of Cl-
Practice Test#1 Chapter 1 - Kinetics
D. colour of the solution
Practice Test#1 Chapter 1 - Kinetics
10. Consider the following potential energy diagram:
PE
(kJ)
11. Which of the following are necessary for successful collisions to occur?
I. Favourable geometry
II. Sufficient energy
III. Large H
A. I only
B. I and II only
C. II and III only
D. I, II, and III
When 1.0 g of KI is added to the H2O2, bubbles of O2 are produced at an increased rate, The KI is a
A. product
B. catalyst
C. reactant
D. intermediate
Practice Test#1 Chapter 1 - Kinetics
13. Consider the following
A. I only
B. I and III only
C. I, III and IV only
D. I, II, III, and IV
14. Consider the following reaction mechanism: Step1: ICl + H2 HI + HCl slow
Step 2: ICl + HI HCl + I2 fast
A. product
B. catalyst
C. reactant
D. reaction intermediate
125
PE
(kJ) 100
75
50
25
A. 25 kJ
B. 50 kJ
C. 100 kJ
D. 125 kJ
Practice Test#1 Chapter 1 - Kinetics
16. Consider the following reactions:
I. N2 + O2(g) 2NO(g)
II. Mg(s) + O2(g) 2MgO(s)
III. CaCO3(s) + 2H+(aq) Ca2+ (aq) + H2O(l) + CO2(g)
Increasing the surface area will increase the reaction rate in
A. II only
B. I and III only
C. II and III only
D. I, II, and III
17. Consider the following reaction mechanism: Step 1: V3+ + Cu2+ V4+ + Cu+ slow
Step 2: Cu+ + Fe3+ Cu2+ + Fe2+ slow
The reaction intermediate is
A. Cu+
B. Cu2+
C. V3+
D. Fe3+
A. adding NaOH.
B. removing CO2
C. adding a catalyst
D. decreasing the pressure
20. The minimum amount of energy needed to start a reaction is called the
A. activation energy.
B. energy of reaction.
C. entropy of reaction
D. reaction mechanism energy
Practice Test#1 Chapter 1 - Kinetics
21. An 8.00g piece of magnesium was placed into 6.0 M HCl. After 25 s, 3.50 g of unreacted
magnesium remained. The average rate at which magnesium was consumed is
A. 0.14 g/s
B. 0.18 g/s
C. 0.32 g/s
D. 4.50 g/s
22. In general rates double when the temperature is increased by 10 oC. The temperature of a reaction
is increased by 40 oC. The rate will increase by a factor of
A. 2
B. 4
C. 8
D. 16
A. I only
B. II and III only
C. I, II and III only
D. I, II, III, and IV
25. Which combination of factors will affect the rate of the following reaction?
MgCO3(s) + 2HCl(aq) CO2(g) + H2O(l) + MgCl2(aq)
A. temperature and surface area only
B. temperature and concentration only
C. concentration and surface area only
D. temperature, concentration, and surface area only
Practice Test#1 Chapter 1 - Kinetics
26. As reactant molecules approach each other
A. heat is released
B. a reaction intermediate forms
C. kinetic energy changes into potential energy
D. potential energy changes into kinetic energy
Consider the following potential energy diagram for the next three five questions.
PE 2
4
1 3
Progress of reaction
A. 1
B. 2
C. 3
D. 4
A. 1
B. 2
C. 3
D. 4
A. 1
B. 2
C. 3
D. 4
Practice Test#1 Chapter 1 - Kinetics
30. The interval representing Ea for the forward reaction is
A. 1
B. 2
C. 3
D. 4
A. 1
B. 2
C. 3
D. 4
A. increase slowly
B. remain constant
C. decrease slowly
D. increase rapidly due to the alternate pathway
0 4.65 0 20
2 4.50 50 21
4 4.35 100 22
A. g/min
B. g/mL
C. min/mL
D. g/(mL)(oC)
34. When a lit match is touched to the wick of a candle, the candle begins to burn. When the match is
removed, the candle continues to burn, the match,
A. behaves as a catalyst
B. supplies the activation energy
C. is part of the rate determining step
D. lowers the activation energy barrier
A. 28 kJ
B. 139 kJ
C. 167 kJ
D. 195 kJ
38. Some reactants are more reactive than others because of their activation energy Ea. What graph
shows the relationship between Ea and rate.
A. B.
Ea Ea
Rate Rate
C. D.
Ea Ea
Rate Rate
Ea
PE
1. On the potential energy diagram above, clearly label the activation energy, heat of the reaction
(H), and the energy of the activated complex. (3 marks)
3. On the graph below, draw the potential energy diagram for an exothermic reaction and label the
activation energy. (2 marks)
PE Ea
4. Nitric oxide (NO) is involved in the decomposition of ozone by the following mechanism:
Step 1: O3 + sunlight O2 + O
Step 2: O3 + NO Progress
NO2 + of O
the
2 reaction
Step 3: NO2 + O NO + O2
a) Write the net equation for the decomposition reaction
b) Identify a catalyst
Practice Test#1 Chapter 1 - Kinetics
NO
NO2 and O
a) Explain why the reaction is likely to involve more than one step.
Reactions that have more than three reactant particles likely have mechanisms.
NO + N N2O
7. The combustion of coal, C, produces carbon dioxide and water according to the following equation:
C(s) + O2(g) CO2(g) + 394 kJ
H + -394 kJ
b) Using the collision theory, explain why a lump of coal does not react with oxygen at room
temperature and pressure. (1 mark)
c) Many coalmine disasters have resulted when a spark ignites coal dust in the air. Explain using the
collision theory. (2 marks)
The spark provides the Ea, the reaction is exothermic and has a high surface area and an
explosion results.
8. State two reasons why some collisions may not result in a chemical reaction.
(2 marks)
Practice Test#1 Chapter 1 - Kinetics
Not sufficient energy
0.0 270.230
30.0 270.200
60.0 270.170 270.170
60.0 s 0.060 g H2
Practice Test#1 Chapter 1 - Kinetics
1.00 g
- 0.740 g
= 0.26 g Note the loss of one sig fig.