Bi 1: Mt dd m gm CH3COOH 1M v CH3COONa 1M c PH=4,75=PKa.

Sau khi
pha trn 100ml dung dch m vi 10ml dd NaOH 0,1M.Tnh PH ca dd sau khi pha
thm.
Bi 2: Tnh PH ca dd NaHCO3 1M bit PK1=6,75;PK2=10,25
Cc thy c cho em hi nhng dng bi tp trn c thi i hc khng hay ch thi hc
sinh gii??Ti v em thy loi ny v d nh dung dch m hnh nh khng c trong
SGK??
Bi 1: Mt dd m gm CH3COOH 1M v CH3COONa 1M c PH=4,75=PKa.Sau khi
pha trn 100ml dung dch m vi 10ml dd NaOH 0,1M.Tnh pH ca dd sau khi pha
thm.
n gin ta coi nh trn 3 dung dch CH3COOH 1M , CH3COONa v NaOH 0,1M
vo nhau
nCH3COOH = 0,1 mol, nCH3COONa = 0,1 mol, nNaOH = 0,001 mol
CH3COOH + NaOH == > CH3COONa + H2O
0,001------------0,001---------0,001 mol
=>Nng CH3COOH sau p trn l CM,CH3COOH = (0,1-0,001)/0,11=0,9M
CM,CH3COO- = (0,1+0,001)/0,11 = 0,918M
Xt cn bng: CH3COOH ==> CH3COO- + H+
Ban u: 0,9---------------0,918--------0
Phn ng: x-------------------x------------x
Cn bng: 0,9-x-------------0,918+x-----x
Ta c: Ka = [CH3COO-][H+]/[CH3COOH] = x(0,918+x)/(0,9-x) = 10^-4,75
x = 1,74*10^-5 => pH = 4,76