S Giao duc & ao tao Lam ong E KIEM TRA CHAT LNG HOC KY I Trng THPT Chuyen Thang

Long MON THI: HOA HOC Lp 10 Chuyen Hoa To Hoa Hoc Thi gian: 60 phut (khong ke thi gian phat e) ******* Ngay thi . 01.2006 Cau 1 (2 iem) Hoan thanh va can bang cac phng trnh phan ng sau bang phng phap thang bang electron va phng phap ion electron: a. KClO3 + Cr2(SO4)3 + KOH b. MaOb + CnHmOz CO2 + MpOq + H2O Cau 2 ( 2 iem) Cho biet trang thai lai hoa cua nguyen t trung tam, cau truc hnh hoc cua cac phan t va ion sau: SF6, XeF4, HSO3-, Cu(NH3)42+, Ni(CN)42-, BF3, I3-, ClF3. Cau 3 (2 iem) Cho bo bon so lng t cua electron cuoi cung cua nguyen t cac nguyen to sau: A: n = 1, l = 0, m = 0, s = +1/2 D: n = 2, l = 1, m = -1, s = -1/2 X: n = 3, l = 1, m = 0, s = -1/2 a. Xac nh cac nguyen to A, B, C. Neu v tr trong bang HTTH va tnh chat c ban cua chung. b. Viet cong thc cau tao cua cac chat tao ra t ca 3 nguyen to A, B, C. c. So sanh tnh oxi hoa va tnh axit cua cac hp chat tren va giai thch. Cau 4. (2 iem) Cho a gam sat ra ngoai khong kh, sau mot thi gian bien thanh hon hp A co khoi lng 75,2 gam gom 4 chat. Hoa tan hoan toan hon hp A trong dung dch H 2SO4 am ac, nong thu c 6,72 lt kh SO2 (kc). a. Viet cac phng trnh phan ng xay ra. b. Tnh a? Cho: Fe = 56, O = 16, Al = 27, Cu = 64, Zn = 65, S = 32, Na = 23. Cau 5 (2 iem) a. Tnh hang so can bang Kp, Kc 3250C va cac gia tr Go, S0 cua phan ng: NO (k) + O2 (k) NO2 (k) 0 Biet D H = - 56,484 KJ va Kp = 1,3.106 350C. Gia s S va H khong phu thuoc vao nhiet o trong khoang nhiet o ang xet. b. Xet phan ng: 2NO2 + F2 = 2NO2F

Co toc o phan ng tnh theo bieu thc la: 2 a1. v = k. CNO .CF ; a2. v = k. C .CF Hoi bieu thc toc o phan ng nao ung vi c che phan ng? Neu bac cua phan ng.
2 2 NO2 2

(Hoc sinh khong c phep s dung bang HTTH cac nguyen to hoa hoc)

HNG DAN CHAM HOA LP 10 CHUYEN HOA Cau 1 (2 iem) Hoan thanh va can bang moi phng trnh ung c 0,5 iem cho moi phng phap. Cau 2 ( 2iem) Neu ung trang thai lai hoa, cau truc hnh hoc cua moi hat c 0,25 iem Cau 3 (2 iem) 1. Xac nh ung A: H, B: O, D: Cl Neu c cau tao va tnh chat c ban cua H, O, Cl (0,5 iem) 2. Viet cong thc cau tao cua 3 hp chat HClO, HClO2, HClO3, HClO4 (0,5 iem) 3. So sanh tnh axit: HClO < HClO2 < HClO3 < HClO4 So sanh tnh oxi hoa: HClO > HClO2 > HClO3 > HClO4 Giai thch hp ly 1 iem Cau 4 (2 iem) 1. Cac phng trnh phan ng (1 iem) 2Fe + O2 = 2FeO 3Fe + 2O2 = Fe3O4 4Fe + 3O2 = 2Fe2O3 2Fe + 6H2SO4 = Fe2(SO4)3 + 3SO2 + 6H2O 2FeO + 4H2SO4 = Fe2(SO4)3 + SO2 + 4H2O 2Fe3O4 +10H2SO4 = 3Fe2(SO4)3 + SO2 + 10H2O Fe2O3 + 3H2SO4 = Fe2(SO4)3 + 3H2O 2. Tnh a (1 iem) Theo nh luat bao toan khoi lng ta co: mO2 = mOxit m Fe = 75,2 a g nO2 =
75,2 a mol 32 6,72 = 0,3mol 22,4

So mol SO2: nSO2 =

Qua trnh oxi hoa: Fe 3e = Fe3+ Qua trnh kh: O2 + 4e = 2O2S+6 + 2e = S+4 Ap dung nh luat bao toan so mol electron ta co; 4nO2 + 2nSO2 = 3nFe

75,2 a a + 2.0,3 = 3. 32 56 a = 56 gam Cau 5. (2 iem) a. Kp (0,25 iem), Kc (0,25 iem), G0 (0,5 iem), S0 (0,25 iem) b. C che phan ng (0,5 iem), Bac cua phan ng (0,25 iem) Suy ra: 4.