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4541/1
4541/1
Chemistry/Trial
Paper 1
September2011
IK JAM
CHEMISTRY
FORM 5
Paper 1
Satu jam lima belas minit
JANGAN BUKA KERTAS SOALAN INI SEHINGGA DIBERITAHU
1.
2.
3.
The diagrams in the questions provided are not drawn to scale unless stated.
Rajahyang menglringi soalan tidakdttukls menglkutskala kecualldinyatakan.
4.
MllHakCtptaMPSMPahang
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4541/2
4541/2
NAME:
Chemistry /Trial
Paper 2
September 2011
CLASS:
2WJAM
CHEMISTRY
FORM 5
Paper 2
UntokkegunaanPemeriksa
dwibahasa.
Bahagian
Markahpenuh
10
10
11
11
20
20
20
10
Markah
Soalan
20
Dipcrolchi
semua
soalan
dalam
Jumlah
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4541/3
454173
Chemistry/"Mai
Kertas 3
September 2011
NAME: '
CLASS:
IK JAM
CHEMISTRY
TingkatanS
Paper 3
ljam 30minit
1.
KodPemeriksa
12
21
17
Markah
Diperoleh
3.
Markah
Penuh
2.
Soalan
4.
JUMLAH
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SULIT
4541/1(PP)
4541/1
Chemistry
Kertas 1
Sept 2011
Peraturan
Pemarkahan
CHEMISTRY
Kertas 1
PERATURAN PEMARKAHAN
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SULIT
Question
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
Answer
B
C
D
B
D
A
C
C
D
D
B
D
C
D
D
C
A
A
A
C
C
D
A
A
C
4541/1(PP)
Question
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
Answer
C
B
D
A
B
D
B
B
A
D
A
D
B
C
B
A
D
C
B
D
C
C
A
C
C
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SULIT
4541/2(PP)
4541/2(PP)
Chemistry
Kertas 2
Sept 2011
Peraturan
Pemarkahan
CHEMISTRY
Kertas 2
PERATURAN PEMARKAHAN
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SULIT
4541/2(PP)
Marking Criteria
Nucleon number is the total number of proton and number of
neutron
(ii) X and Y
Atoms have same proton number but different nucleon number
(iii) 4
(iv) 8
(v) Group 16 Period 2
(b)
(CH2O)n = 180 // n[12 + 2(1) + 16] = 180
n=6
C6H12O6
TOTAL
(a)
Answer : Group 16 Period 2
(b)
Answer: Q
(c) (i) DG2
(ii) Low melting and boiling points
Insoluble in water
Soluble in organic solvents
Cannot conduct electricity in any states
High volatility.
(choose either one)
(d) (i) J
(ii) Atomic size of J is larger // Distance between nucleus and
valence electron is further
Attractive force between nucleus and valence electron is
weaker // Atom J is easier to donate electron
(e) (i) H
(ii) Atom H has achieved stable/octet electron arrangement
TOTAL
(a)
Copper(II) ion , hydrogen ion // Cu2+ , H+
(b)
Experiment I
Cathode: Brown solid
deposited
Experiment II
Cathode: Brown solid
deposited
(c) (i) Oxygen
(ii) Insert a glowing splinter into the test tube. The glowing splinter
relights
(d) (i) Chloride ion // Cl- ion
Concentration of Cl- ion is higher than OH- ion
(ii) Correct formulae of reactant and products
Balanced equation
Marks
1
1
1
1
1
1
1
1
1
9
1
1
1
1
1
1
1
1
1
9
1
1
1
1
1
1
1
1
1
2 Cl- Cl2 + 2e
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SULIT
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SULIT
4541/2(PP)
TOTAL
Able to plot the graph of total volume of gas against time
correctly
(a)
1
10
Answer :
(b)
Answer :
Correct tangent at t = 20 s is shown in the graph
Calculation // Correct answer with unit
(40 16)cm3
(40 6)s
// 0.735 cm3 s-1
[Reject answer with no / wrong unit]
Able to give the reason why the decomposition of hydrogen
peroxide decreases with time
(c)
(d)
1
1
1
(i)
Answer :
Concentration of hydrogen peroxide decreases
Able to suggest a name of catalyst used in the reaction
Answer:
Manganese(IV) oxide // MnO2
[Reject: Manganese oxide]
1
1
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SULIT
4
(ii)
(a)
(b)
(c)
Answer:
Cu2+ + Zn Cu + Zn2+
(d) (i) = 50 4.2 5 // 1050 J // 1.05 kJ
[Reject answer without unit]
(ii)
0.5 50
// 0.025
n=
1000
(iii) Correct calculation
1.05
1050
//
DH =
0.025
0.025
(e)
4541/2(PP)
1
1
1
1
[max 3]
10
1
1
1
1
1
1
1
1
1
Answer:
Energy
Cu2+ + Zn
Cu + Zn2+
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SULIT
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SULIT
(f)
6
(a)
(b)
(c)
(d)
(e)
(f)
4541/2(PP)
1
11
1
1
1
1
1
1
1
1
1
1
1
11
(ii)
Marking Criteria
Label of axes with units
All points are transferred correctly
Correct shape of the graph and constant scale
2.5 cm3
[Reject answer without unit]
1.0 2.5
// 0.0025
1000
1.0 5
Moles of I- ions =
// 0.005
1000
1
1
1
1
1
1
(i)
Salt J
X oxide
Gas Y
Gas Z
Marks
1
1
1
[3 m]
1
[7 m]
1
1
1
1
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SULIT
6
Yellow precipitate
(ii)
(a)
(i)
Nitrate ion
Add sulphuric acid
Add iron(II) sulphate solution
Slowly and carefully add concentrated sulphuric acid
Brown ring formed
TOTAL
Synthetic polymer does not biodegradable/degrade easily/
not easily degraded by bacteria/microorganism
Synthetic polymer product are disposed into drainage
system cause blockage
Release carbon dioxide / sulphur dioxide / toxic gas /
acidic gas when burns
Gas released / carbon dioxide gas causes greenhouse
effect/increase global temperature
Sulphur dioxide/carbon dioxide / acidic gas causes acid
rain
Acid rain corrodes buildings / increase acidity of soil /
water
(b)
Recycle
Reduce usage
Reuse
Produce biodegradable synthetic polymer product
Burn in special incinerators
Sort / separate garbage
(ii)
(c)
4541/2(PP)
[Any 4]
Made of silica, sodium carbonate and calcium carbonate
Good heat insulator
Electric insulator
Manufacturing special outfit for astronauts/fireman
(i)
(ii)
Construction:
Electronic field:
Medical field:
Astronomy field:
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1
[5 m]
1
1
1
1
1
[5 m]
20
1
1
1
1
1
1
[6 m]
1
1
1
1
1
1
[4m]
1
1
1
1
[4 m]
1
1
[2m]
1
1
1
1
[4 m]
20
SULIT
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SULIT
4541/2(PP)
(b)
H H H
| |
|
HCCCH
| |
|
OH H H
Marking Criteria
H H H
|
|
|
HCCCH
|
|
|
H OH H
Marks
1+1
[2 m]
1+1
Propyl methanoate
O
H H H
||
|
|
|
HCOCCCH
|
|
|
H H H
OR
Propyl ethanoate
H O H H H
|
|| |
|
|
HCOCCCH
|
|
|
|
H
H H H
OR
Propyl propanoate
H H O
H H H
|
| ||
|
|
|
HCCCOCCCH
|
|
|
|
|
H H
H H H
(c)
(i)
[Any one]
1. Put glass wool into a combustion/boiling tube // Soak glass
wool in propanol
2. Add propanol to the glass wool // Put soaked glass wool
into combustion / boiling tube
3. Put porcelain chips into the boiling tube
4. Heat strongly the porcelain chips
5. Heat / warm the propanol
6. Functional apparatus
7. Label
[2 m]
1
1
1
1
1
1
1
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SULIT
4541/2(PP)
Porselain chip
Glass
Glass
wool
wool
Soaked in
Soaked in
propanol
propanol
Heat
Wate
Water
8. Chemical equation
C3H7OH C3H6 + H2O
(ii)
Propanoic acid
Carboxyl group // COOH
1
[8 m]
1
1
[2 m]
1
1
1
10 (a)
(i)
TOTAL
Able to name solvent X and Y
Solvent X:
Solvent Y:
(ii)
tetrachloromethane // methylbenzene
// (name any organic solvent)
water
1
1
1
[6 m]
20
1
1
[2 m]
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SULIT
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SULIT
4541/2(PP)
Procedure
1. Add 1 spatula of zinc/magnesium/aluminium.
(solid metal carbonate can be used to replace metals
above)
2. into the beakers containing hydrogen chloride in solvent X
and solvent Y
3. No changes in beaker A
4. Gas bubbles formed in beaker B
5. Hydrogen chloride in solvent X / tetrachloromethane /
methylbenzene does not show acidic property/H+ is
absent.
6. Hydrogen chloride in water shows acidic property/H+ is
present.
1
1
1
1
1
[6m ]
(b)
(i)
(ii)
1
1
[2 m]
1
1
1
1
1
1
1
1
1
1
Note:
If zinc is used but P2 not mentioned, 2 marks given to P3
[10 m]
20
TOTAL
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SULIT
4541/3(PP)
4541/3(PP)
Chemistry
Kertas 3
Sept 2011
Peraturan
Pemarkahan
CHEMISTRY
Kertas 3
PERATURAN PEMARKAHAN
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SULIT
4541/3(PP)
Question 1(a)
Rubric
Able to state all observation correctly
Score
3
Sample answer:
Experiment
I
II
III
Observation
Lead(II) nitrate dissolves // Colourless solution is formed.
Calcium carbonate does not dissolve // Remains unchanged //
No changes
Copper(II) sulphate dissolves // Blue solution is formed
2
1
0
Question 1(b)
Rubric
Able to state the operational definition of soluble salt correctly
Score
3
Sample answer:
1. When a salt is added into water and dissolves to form a solution, it is a
soluble salt
2. When a salt dissolves in water to form a solution, it is a soluble salt.
Able to state the operational definition of soluble salt less correctly
Sample answer:
1. When a salt is added into water and forms a solution, it is a soluble salt.
2. When a salt dissolves to form a solution, it is a soluble salt.
3. Salt dissolves in water to form a solution.
Able to state any idea of operational definition of soluble salt
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SULIT
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SULIT
4541/3(PP)
Question 1(c)
Rubric
Score
3
Sample answer:
Potassium carbonate solution contains carbonate ions
Calcium ion combines with carbonate ion.
Able to give any idea about formation of insoluble salt
Sample answer:
Calcium carbonate salt is formed
Double decomposition reaction occurs.
No response or wrong response
Question 1(d)
Rubric
Able to classify all the solutions correctly
Score
3
Sample answer
Soluble salt
Potassium sulphate
Zinc sulphate
Insoluble salt
Lead(II) sulphate
Barium sulphate
2
1
0
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SULIT
4541/3(PP)
Question 2(a)
Rubric
Able to state the inference correctly
Score
3
Sample answer:
Water absorbed heat energy
Exothermic reaction
Able to state the inference less correctly
Sample answer:
Water temperature increases / rises
Methanol releases heat
Mercury expands
Able to state an idea of inference
Sample answer:
Water becomes hot.
No response given or wrong response
Question 2(b)
Rubric
Able to state all variables correctly
Score
3
Sample answer:
Manipulated variable:
Types of alcohol
Responding variable:
Heat of combustion
Fixed variable:
Volume of water // copper can
Able to state any 2 variables correctly
Able to state any 1 variable correctly
No response given or wrong response
2
1
0
SULIT
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SULIT
4541/3(PP)
Question 2(c)
Rubric
Able to state the relationship between the manipulated variable and the
responding variable with direction correctly
Score
3
Sample answer:
The higher the number of carbon atoms per molecule, the higher the heat
of combustion
When the number of carbon atoms per molecule increases, the heat of
combustion increases
Sample answer:
The higher the number of carbon atoms, the higher the heat of combustion.
Able to state an idea of hypothesis
Sample answer:
Different alcohols different heat of combustion
Type of alcohol affects heat of combustion
No response given or wrong response
Question 2(d)
Rubric
Able to state all the mass of alcohols and round off into two decimal places
correctly
Score
3
Sample answer:
Methanol = 1.54
Ethanol = 1.20
Propanol = 1.10
Butanol = 1.61
Able to state any three the mass of alcohols and round off into two decimal
places correctly
Able to state all the mass of alcohols in four decimal places correctly
Able to state any two the mass of alcohols and round off into two decimal
places correctly
No response given or wrong response
1
0
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SULIT
4541/3(PP)
Question 2(e)
Rubric
Able to calculate the heat of combustion of methanol by fulfill the following
criteria
(i)
(ii)
(iii)
Score
3
Sample answer:
Heat absorbed by water = 100 4.2 30 J // 12600 J __(X)
1.54
Number of mole =
// 0.048 __()
32
12600
Heat of combustion = J mol-1 // - 262500 J mol-1
0.048
// -262.5 kJ mol-1 __()
Able to calculate the heat of combustion of methanol by fulfill any one criteria
Sample answer:
Heat absorbed by water = 100 4.2 30 J // 12600 J __(X)
1.04
Number of mole =
// 0.0325 __(X)
32
12600
Heat of combustion = J mol-1 // - 387692 J mol-1
0.0325
-1
// - 387.692 kJ mol __()
[No response given or wrong response]
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4541/3(PP)
Question 2(f)
Rubric
Able to plot graph accurately which fulfill five criteria below:
Score
3
(i)
Axis with correct label and unit.
(ii)
Consistent scale
(iii)
Size of graph: at least half of graph paper
(iv)
Transfer all points correctly
(v)
Straight line
Able to plot graph less accurately which fulfill any four criteria
Able to show minimum requirement of plotting graph
2
1
Criteria:
(i)
Axis with correct label / unit
(ii)
Transfer all points
(iii)
Straight line
No response given or wrong response
Question 2(g)
Rubric
Able to predict the heat of combustion of propanol correctly
Score
3
Criteria:
(i)
Dotted line is drawn on the graph
(ii)
Value based on graph
(iii)
Negative sign with correct unit
Able to predict the heat of combustion of propanol incompletely which fulfill
any two criteria
Able to give value of the heat of combustion of propanol which fulfill one
criteria only
No response given or wrong response
2
1
0
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4541/3(PP)
Question 2(h)
Rubric
Able to predict the heat of combustion of propanol correctly
Criteria:
(i)
Dotted line is drawn on the graph
(ii)
Value based on graph
(iii)
Negative sign with correct unit
Able to predict the heat of combustion of propanol incompletely which fulfill
any two criteria
Able to give value of the heat of combustion of propanol which fulfill one
criteria only
No response given or wrong response
Score
3
2
1
0
Question 3(a)
Rubric
Able to give the aim of the experiment correctly
Score
2
Sample answer:
To investigate the effect of X and Y metals in contact with iron on the rusting of
iron.
Note: If problem statement is written score 1
Able to state the aim of the experiment less correctly
Sample answer:
To investigate the effect of metals X and Y on rusting of iron.
To investigate the effect of metals X and Y.
No response or wrong response
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4541/3(PP)
Question 3(b)
Rubric
Able to state all the three variables correctly
Score
3
Manipulated variable:
Metal X and metal Y // Two different metals (one metals is less electropositive
and one is more electropositive than iron) // Pairs of metal X / iron and Y /
iron
Responding variable:
Rusting of iron // Iron rust // The formation of brown solid // Formation of blue
spot
Constant variables:
Iron nail // Jelly solution // Temperature
Able to state any two variables correctly
Able to state any one variable correctly
No response or wrong response
2
1
0
Question 3(c)
Rubric
Able to state the relationship between the manipulated variable and the
responding variable with direction correctly
Score
3
Sample answer:
When a more electropositive metal is in contact with iron, the metal inhibits
rusting
When a less electropositive metal is in contact with iron, the metal speeds up
rusting.
Note: If MV and RV is wrongly stated score 2
Able to state the relationship between the manipulated variable and the
responding variable and direction less correctly (no direction)
Sample answer:
A more electropositive metal will prevent iron from rusting. // A less
electropositive metal will cause iron to rust.
Able to state an idea of hypothesis
Sample answer:
Metal Y / metal X affects rusting (of iron)
No response or wrong response
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10
4541/3(PP)
Question 3(d)
Rubric
Able to list completely the material/substances and apparatus
Score
3
Sample answer:
Materials / substances and apparatus:
Two Iron nails, Magnesium / zinc / aluminium strip, tin / copper / lead / silver
strip, Potassium hexacyanoferrate(III) solution + phenolphthalein (Any suitable
electrolyte or water), Test tube / boiling tube, Sandpaper
Refer to the labelled diagram if not stated in the list: 4 from the list and 4 from
the labelled diagram
Able to list basic materials and apparatus
Sample answer:
Materials:
Metal above iron, Metal below iron, Iron nail, (Any suitable electrolyte)
Apparatus:
(Any suitable container)
Able to give an idea of the materials and apparatus
Sample answer:
Materials:
Iron, (any electrolyte)
Apparatus:
(Any suitable container)
No response or wrong response
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11
4541/3(PP)
Question 3(e)
Rubric
Score
3
Clean the iron nails and metals strip with sand paper.
Coil iron nails with magnesium ribbon and copper strips.
Put / place the coiled iron nail into different test tube.
Pour / add / fill the hot jelly solution containing potassium hexacyanoferrate
(III) solution and phenolphthalein into the test tube.
5. Leave the test tube in a test tube rack for few days.
6. Record the observation.
7. Steps 1 to 6 are repeated using different metal/Y with iron(if steps 2 does
not mention two different test tube).
Able to state the steps 2,4 and 6 correctly
Able to state steps 2 and 4 correctly // The idea combining iron and any
metals and any substances
No response or wrong response
2
1
0
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12
4541/3(PP)
Question 3(f)
Rubric
Able to present / exhibit a table to record the following items / information
correctly
Score
3
Sample answer:
Pairs of metals
Observation
Mg / Fe
Cu / Fe
Able to present / exhibit a table to record the following items / information
correctly
Sample answer:
Set
Observation
Mg / Fe
Able to give an idea on tabulation of data, at least one information stated in
the table
Sample answer:
Set
No response or wrong response
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