(CSJ.M. UNIVERSITY KANPUR, M-Se. (Previous) CHEMISTRY ‘There shall be five writen Papers and a Practical amination ea tallowe- Paper 1 Inorganic Chemistry 29 Papert Onganie Chemistry 0 Papers Physical Cheritry 20 Paper1V Group Theory and Spectrseopy 100 Paper-V (a) Mathematics for Chemists or Blog Stents) on » Biology or Chemiste (®) Computers for Chemists ~ See Practical 0 !andldates wil be required to passin Theory and Practical separately Paper-1 Inorganie Chemistry 1 Stereochemistry and Ronding in Main Group Compounds LVSEPR, Walsh diagrams (rand penta atomic molecule, dp, Ronda, Bent rule and energetics of some simple reactions of eovletly bondedwn | Mse.- Chemistry Previous) ‘Mtal-Ligand Puilibria in Solution Stepise and overall formation constants and. Uhir Interaction, trends i stepwie constants, factors alti the staiy of metal compleace with reference tothe ature of metal toa and ligand, chelate lfc and ite ‘thermodynamic eign, determination of biary formation ‘constant by pl-metry and spetrophotometr. ‘Reaetion Mechanism of Transition Metal complexes nergy prof ofa reaction, reactivity of metal crplenes, ners and Table complexes, netic apletin of lene ‘Metal Ligand Bonding Limitation of erysta eld theory, molclar otal theory, ‘ctahedra, ttraedral and square planar complexes, ‘Ehonding and molecular orbital hry [Electronic Spectra and Magnetic Properties of _ Transition Metal complexes Spectroscopic rund. states, correlation, Orgl_and ‘Tague Sugano diagrams fr irnaiton metal complexes (2a? sata), caletations of Da, B and parameter, ‘hang transfor spectra, specteeeope method of lssgnment of abolte coatigeration Ia otal active {Beta chelates end. thelr stereochemical information, ftomalous magnetic) moments, magutie xchange ‘ruling and spin crossover ooks Supeested ‘Waincn, John Wiley. 2, Inorganic Chemisty Habey, Harp Ro 3. Chemistry of the Elements, NN Greenwood and ‘ABarashow, Pergamon. 4. Inorganic Electronic Sprteacopy, ALP Lever Elsevier 5. Magnetchemistry, R1- Carlin, Springer Verlag 6 Comprehensige Coordisation Chemistry Ps GwWikiaca, RD. Gilarsand JA MeCleverty, Perganon.M.S. Chemie Previous) “Aromat in benzenoid and now-tensenid comprand, ‘ternant and nowalterant hydrocarbons, Huck ral, foergy level of molecular orbitals, annulenes, Sudromatisty, v-aromatiaty, home aromatic, PHO appre Bonds weaker than covalent: dition compounds, orn ster cwmplers and cryplands, aceon, ‘ompounde cyclen catenanes ad reasanes Stereochemistry . Confrmatioal analysis of platkanes,dealins ect of ‘eofermation oa react, confermation of sugar, serie ‘train doe to unaveiable crowding lements of symmetry, chirality, molecules with more ‘than ane chiral cote, Urea eythr mers, methods of relation, optical” purty, enantitopie and Aiatertope atom, groups and Tes, serogpetc an ‘ereosective ythesin,Axyrmeticsyatesin- Opin {icity in the amene of chiral carton phenyl alenes ‘tod piranes chirality de hil shape ‘Sterechemsty of the compounds containing stron, sulphur and phosphorus enetion Mechanism: Structure and Reactivity ‘Types af mechanisms, types of eations, thermodynamic fit Kinetic requirements, kinetic and’ thermodynamic Contr, Hamaond’ postulate. Cuti- Hamme privcpe. Potestial energy diagrams, transition states and Intermediates, methods ef termining mechanisms, ‘tape effets Hard and sf acids and bases Generation, structure, lability and reactivity of ‘arboatons, cartnnions, Gee radials, carbenes and Efectofstracture on reactivity: Resonance and Sl feta, seri effec, unttaive retnene. The Hammett aqution and linear fre energy relationship, sbattoent tind reaction constant, Tat uation. w vu CS.54 Unversity Kanpur 5 ‘iphaie Nucleophilie Substitution ‘The SRFPEN,, mised SN, and SN, and SET mechaiams, ‘The aeighbouringsroup mechanism, newaring group parscipation by and @ bunds, anchimeic nara, ‘Clusia and nencanial carbocations, phonon ios, orbooyl system, common carbocation rearrangements, ‘Appleation of NMI spectroscopy in the detection of ‘catbocations. ‘The BX mechaniem, [Noclopilesubstitation at an alii, aliphai trigonal snd a vinylic carbo. Reactivity effets of substrate structure, attacking osepil, leaving group and resction medium, phase ‘wansfreatlynis and ultrasvund, ambient auccopie, occ Aliphatic leetrophilic Substitation Bimolecular mechaniem- SE, and SE, The SEI ‘oechaniam, clectopie sobrtation secompaniod By double bond shift Eft of subetaten, lowing gro and ‘he solvent polarity onthe eatvity. Aromatic Klectrophilie Substitution ‘The arenlum ion mechaniam,erentatin and reastiviy, ‘oerg pelle dlagrams, The rtolpara ratio pec atc. ‘ticnaton in other ring ayetems. Quanttatre treatment reactivity in substrate nad slectropiles, Dimi Coupling Vile reaction, Gattermann Koch reaction Aromatic Nucleophile Substitution The SNAr , SN, bemgne and SRN, mechanians Reactivity fet of wobtrtesroctr, leaving group and stacking. miceopbile The Von Richter, Sommelt- ‘use, and sales rearrangements