Professional Documents
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Revision date-06/10/2009
BACTRON SK-5085
EMERGENCY TELEPHONE
2 HAZARDS IDENTIFICATION
Harmful by inhalation and if swallowed. Irritating to respiratory system. Causes burns. May cause sensitisation by inhalation and skin contact. May cause harm to the unborn child. Very toxic to aquatic organisms. CLASSIFICATION Repr. Cat. 2;R61. Xn;R20/22. R42/43. C;R34. Xi;R37. N;R50.
3 COMPOSITION/INFORMATION ON INGREDIENTS
Name WATER GLUTARAL Quaternary ammonium compound TETRAKISHYDROXYMETHYLPHOSPHONIUM SULPHATE ETHANEDIOL 259-709-0 203-473-3 EC No. 231-791-2 203-856-5 CAS-No. 7732-18-5 111-30-8 61789-71-7 55566-30-8 107-21-1 Content 30-60% 10-30% 10-30% 1-10% 1-10% Classification T;R23/25 C;R34 R42/43 N;R50 Xn;R22. C;R34. N;R50. T;R23. Repr. Cat. 2;R61. Xn;R22. Xi;R41. N;R50. R43. Xn;R22
4 FIRST-AID MEASURES
INHALATION Move the exposed person to fresh air at once. Rinse nose and mouth with water. If respiratory problems, artificial respiration/oxygen. Get medical attention. INGESTION NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Immediately rinse mouth and drink plenty of water (200-300 ml). DO NOT induce vomiting. Get medical attention immediately. SKIN CONTACT Remove affected person from source of contamination. Promptly wash contaminated skin with soap or mild detergent and water. Promptly remove clothing if soaked through and wash as above. Get medical attention immediately. EYE CONTACT Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Immediately transport to hospital or eye specialist.
5 FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA Use: Water spray, fog or mist. Foam. Carbon dioxide (CO2). Dry chemicals, sand, dolomite etc. SPECIAL FIRE FIGHTING PROCEDURES Use special protective clothing. Regular protection may not be safe. Keep up-wind to avoid fumes. Cool containers exposed to flames with water until well after the fire is out. Avoid water in straight hose stream; will scatter and spread fire. Keep run-off water out of sewers and water sources. Dike for water control. 1/ 5
Bactron SK-5085
UNUSUAL FIRE & EXPLOSION HAZARDS May develop highly toxic or corrosive fumes if heated. SPECIFIC HAZARDS Oxides of: Carbon. Nitrogen. Sulphur. PROTECTIVE MEASURES IN FIRE Wear full protective clothing. Use air-supplied respirator during fire fighting.
Name ETHANEDIOL GLUTARAL WEL = Workplace Exposure Limit. Sk = Can be absorbed through skin. Sen = Capable of causing occupational asthma. INGREDIENT COMMENTS WEL = Workplace Exposure Limits PROTECTIVE EQUIPMENT
PROCESS CONDITIONS Use engineering controls to reduce air contamination to permissible exposure level. ENGINEERING MEASURES Provide adequate general and local exhaust ventilation. RESPIRATORY EQUIPMENT Respiratory protection must be used if air contamination exceeds acceptable level. Use chemical cartridge protection with appropriate cartridge. Chemical respirator with organic vapour cartridge. HAND PROTECTION Use protective gloves made of: Rubber, neoprene or PVC. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. Be aware that the liquid may penetrate the gloves. Frequent change is advisable.
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Bactron SK-5085
EYE PROTECTION Use approved safety goggles or face shield. OTHER PROTECTION Wear appropriate clothing to prevent any possibility of skin contact. HYGIENE MEASURES Wash at the end of each work shift and before eating, smoking and using the toilet. Promptly remove any clothing that becomes contaminated. DO NOT SMOKE IN WORK AREA! When using do not eat, drink or smoke.
11 TOXICOLOGICAL INFORMATION
TOXIC DOSE 1 - LD 50 TOXIC DOSE 2 - LD 50 INHALATION May cause sensitisation by inhalation. May cause respiratory allergy. Vapour may affect central nervous system and cause headache, discomfort, vomiting or intoxication. May cause damage to mucous membranes in nose, throat, lungs and bronchial system. Irritating to respiratory system. Harmful by inhalation. INGESTION Causes burns. May cause chemical burns in mouth, oesophagus and stomach. SKIN CONTACT Causes burns. May cause sensitisation by skin contact. Corrosive. Prolonged contact causes serious tissue damage. EYE CONTACT Causes burns. ROUTE OF ENTRY Inhalation. Skin absorption. Ingestion. Skin and/or eye contact. TARGET ORGANS Eyes. Respiratory system, lungs. Skin. MEDICAL SYMPTOMS Extreme irritation of eyes and mucous membranes, including burning and tearing. Upper respiratory irritation. Severe skin irritation. MEDICAL CONSIDERATIONS Splash in eye requires examination by eye specialist. SPECIFIC EFFECTS Contains a substance/a group of substances which may cause harm to the unborn child. Name
Quaternary ammonium compound 400 (analogy) mg/kg (oral rat) 3300(analogy) mg/kg (oral-rbt)
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Bactron SK-5085
12 ECOLOGICAL INFORMATION
ECOTOXICITY Very toxic to aquatic organisms. BIOACCUMULATION The product does not contain any substances expected to be bioaccumulating. DEGRADABILITY There are no data on the degradability of this product.
13 DISPOSAL CONSIDERATIONS
GENERAL INFORMATION Recover and reclaim or recycle, if practical. DISPOSAL METHODS Absorb in vermiculite or dry sand, dispose in licensed hazardous waste. Dispose of waste and residues in accordance with local authority requirements. WASTE CLASS For this product, in accordance with the European Waste Catalogue (EWC), a catalogue number cannot be given because the customer has to lay down the purpose first. The catalogue number has to be given according to the local waste removal processes.
14 TRANSPORT INFORMATION
PROPER SHIPPING NAME AIR TRANSPORT NOTES UN NO. ROAD ADR CLASS HAZCHEM CODE IMDG CLASS EMS AIR CLASS
CORROSIVE LIQUID, ACIDIC, ORGANIC, n.o.s. (Contains Glutaraldehyde) PACKING INSTRUCTION (PASSENGER) 818 - 5 LITRES PACKING INSTRUCTION (CARGO) 820 - 60 LITRES 3265 Class 8: Corrosive substances. 2X 8 F-A S-B 8 ADR CLASS NO. ADR PACK GROUP UN NO. SEA IMDG PACK GR. UN NO. AIR AIR PACK GR. 8 III 3265 III 3265 III
15 REGULATORY INFORMATION
LABELLING
Toxic
Corrosive
CONTAINS
RISK PHRASES
Harmful by inhalation and if swallowed. Causes burns. Irritating to respiratory system. May cause sensitisation by inhalation and skin contact. Very toxic to aquatic organisms.
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Bactron SK-5085
R61 SAFETY PHRASES S23 S25 S26 S36/37/39 S38 S45 S53 S57 S60 S61 P11 UK REGULATORY REFERENCES Approved Supply List. STATUTORY INSTRUMENTS Chemicals (Hazard Information and Packaging) Regulations. APPROVED CODE OF PRACTICE Classification and Labelling of Substances and Preparations Dangerous for Supply. Safety Data Sheets for Substances and Preparations. GUIDANCE NOTES Workplace Exposure Limits EH40. Approved guide to the classification and labelling of substances and preparations dangerous for supply. Do not breathe vapour/spray. Avoid contact with eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing, gloves and eye/face protection. In case of insufficient ventilation, wear suitable respiratory equipment. In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). Avoid exposure - obtain special instructions before use. Use appropriate containment to avoid environmental contamination. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. Restricted to professional users. May cause harm to the unborn child.
16 OTHER INFORMATION
REVISION COMMENTS Revision to Section 2 Revision of classification ISSUED BY KH REVISION DATE REV. NO./REPL. SDS GENERATED RISK PHRASES IN FULL NC R22 R23 R23/25 R34 R37 R41 R42/43 R43 R50 R61 Not classified. Harmful if swallowed. Toxic by inhalation. Toxic by inhalation and if swallowed. Causes burns. Irritating to respiratory system. Risk of serious damage to eyes. May cause sensitisation by inhalation and skin contact. May cause sensitisation by skin contact. Very toxic to aquatic organisms. May cause harm to the unborn child. 06/10/2009 1
DISCLAIMER The information provided in this SDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process unless specified in the text. 5/5