101076 - BAKER PETROLITE WF-209

SAFETY DATA SHEET

BAKER PETROLITE WF-209

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY:

PRODUCT NAME: BAKER PETROLITE WF-209

PART No.: WF-209

APPLICATIONS: Waterflood Bactericide

EMERGENCY TELEPHONES: + 44 (0) 151 546 2855

SUPPLIER: Baker Petrolite

Kirkby Bank Road,
Knowsley Industrial Park
Liverpool. L33 7SY. UK
TELEPHONE: +44 (0)151-546-2855
FAX: +44 (0)151-547-3590

2. COMPOSITION/INFORMATION ON INGREDIENTS:

INGREDIENT NAME: EINECS CAS No.: CONTENT SYMBOL RISK:

FORMALDEHYDE 200-001-8 50-00-0 10-30 % T 23/24/25, 34, 40, 43
GLUTARALDEHYDE 203-856-5 111-30-8 5-10 % T,N 23/25, 34, 42/43, 50
METHANOL 200-659-6 67-56-1 5-10 % F,T 11, 23/24/25,
39/23/24/25

The full text for all R-phrases are shown in section 16

3. HAZARDS IDENTIFICATION:

Toxic by inhalation, in contact with skin and if swallowed. Causes burns. Irritating to respiratory system. Limited
evidence of a carcinogenic effect. May cause sensitisation by inhalation and skin contact. Harmful: possible risk of
irreversible effects through inhalation, in contact with skin and if swallowed. Carcinogen Category 3.

4. FIRST AID MEASURES:

INHALATION: Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get medical attention if any
discomfort continues. If respiratory problems, artificial respiration/oxygen.

INGESTION: DO NOT INDUCE VOMITING! Rinse mouth thoroughly. Drink plenty of water. Get medical attention
immediately! NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS!

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SKIN: Remove affected person from source of contamination. Wash the skin immediately with soap and water. Get medical
attention promptly if symptoms occur after washing.

EYES: Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get
medical attention.

5. FIRE FIGHTING MEASURES:

EXTINGUISHING MEDIA:
This material is not flammable. Use extinguishing media appropriate for surrounding fire.

SPECIAL FIRE FIGHTING PROCEDURES:

Use supplied air respirator if substance is involved in a fire. Cool containers exposed to flames with water until well
after the fire is out.

UNUSUAL FIRE & EXPLOSION HAZARDS:

No unusual fire or explosion hazards noted.

6. ACCIDENTAL RELEASE MEASURES:

PERSONAL PRECAUTION IN SPILL:

Wear suitable protective clothing, gloves and safety goggles.

PRECAUTIONS TO PROTECT ENVIRONMENT:

Dyke to prevent entering any sewer or waterway.

SPILL CLEANUP METHODS:

Clean-up personnel should use respiratory and/or liquid contact protection. Absorb in vermiculite, dry sand or earth
and place into containers. Collect and reclaim or dispose in sealed containers in licensed waste.

7. HANDLING AND STORAGE:

USAGE PRECAUTIONS:
Ventilate well, avoid breathing vapours. Use approved respirator if air contamination is above accepted level. Avoid
spilling, skin and eye contact.

STORAGE PRECAUTIONS:
The drums should be stored, with their seals intact, in conditions that avoid extremes of temperatures. If the product
is to be stored in bulk containers, please contact Baker Petrolite for advice on materials of construction of the
containers. Under these conditions the shelf life of the product should be approximately two years.

STORAGE CRITERIA:
Toxic storage. Corrosive storage.

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION:

INGREDIENT NAME: CAS No.: STD: LT EXP. 8 HRS: ST EXP. 15 MIN:

FORMALDEHYDE 50-00-0 MEL 2 ppm 2 ppm

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GLUTARALDEHYDE 111-30-8 MEL 0.05 ppm Sen 0.05 ppm Sen

METHANOL 67-56-1 OES 200 ppm(Sk) 250 ppm(Sk)

INGREDIENT COMMENTS:
OES = Occupational Exposure Standard. MEL = Maximum Exposure Limit.

PROTECTIVE EQUIPMENT:

PROCESS CONDITIONS:
Use engineering controls to reduce air contamination to permissible exposure level. Provide eyewash, quick drench.

VENTILATION: Well ventilated area. Provide corrosion-resistant local exhaust ventilation.

RESPIRATORS: Use chemical cartridge protection with appropriate cartridge. CCROVAGF, CCR with organic vapour and acid gas
cartridge and full facepiece.

PROTECTIVE GLOVES:
Use protective gloves made of: Neoprene, nitrile, polyethylene or PVC.

EYE PROTECTION:
Use safety goggles and face shield in case of splash risk.

HYGIENIC WORK PRACTICES:

Wash at the end of each work shift and before eating, smoking and using the toilet. Wash promptly with soap & water
if skin becomes contaminated.

9. PHYSICAL AND CHEMICAL PROPERTIES:

APPEARANCE: Liquid.
COLOUR: Colourless. Yellowish.
ODOUR/TASTE: Pungent.
SOLUBILITY DESCRIPTION: Soluble in water.
MELT./FREEZ. POINT (°C, interval): <-20
DENSITY/SPECIFIC GRAVITY (g/ml): 1.072 - 1.142 TEMPERATURE (°C): 16
VISCOSITY: <10 cSt TEMPERATURE (°C): 38
FLASH POINT (°C): Min. 62 METHOD: PM Closed cup.

10. STABILITY AND REACTIVITY:

STABILITY: No particular stability concerns.

CONDITIONS TO AVOID:
Avoid contact with strong oxidisers.

HAZARDOUS POLYMERIZATION:
Will not polymerize.

MATERIALS TO AVOID:
Strong oxidizing agents.

HAZARDOUS DECOMP. PRODUCTS:

Vapours/gases/fumes of: Carbon dioxide (CO2). Carbon monoxide (CO).

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11. TOXICOLOGICAL INFORMATION:

INHALATION: Toxic by inhalation. Vapours are highly irritating to eyes, nose and respiratory system and may produce nausea,
headache and dizziness. Prolonged exposure may result in chemical pneumonitis and, in extreme cases, pulmonary
oedema. Repeated overexposure may produce an allergic sensitisation resulting in skin rashes or possibly
asthmatic-type response with moderate to severe breathing difficulty in extreme cases.

INGESTION: Toxic if swallowed. Corrosive. Causes severe irritation or burns to the mouth and digestive tract. ... May cause
gastrointestinal distress with nausea, vomiting and diarrhoea.

SKIN: Toxic in contact with skin. Systemic effects resulting from repeated or prolonged skin absorption may include kidney
and liver, as well as other organ damage. Corrosive. Contact with skin will produce severe irritation or burns with
possible in-depth injury. Repeated skin contact may produce allergic sensitisation. In such cases further contact may
cause allergic rashes.

EYES: Corrosive. Contact with eyes will cause permanent damage if not immediately removed.

OTHER HEALTH EFFECTS:

Formaldehyde is listed as a Category 3 Carcinogen.

12. ECOLOGICAL INFORMATION:

ECOLOGICAL INFORMATION:
Please contact Baker Petrolite for further information.

13. DISPOSAL CONSIDERATIONS:

DISPOSAL METHODS:
Place chemical residues and contaminated absorbent materials into a suitable waste container. Take to an approved
hazardous waste disposal site. Dispose of all residues in accordance with applicable waste management regulations.

14. TRANSPORT INFORMATION:

LABEL FOR CONVEYANCE:

ROAD TRANSPORT:
UN No. ROAD: 2927
ADR CLASS No.: Division 6.1:Toxic substances.
PROPER SHIPPING NAME I: Toxic Liquid, Corrosive, Organic, N.O.S.(contains formaldehyde and glutaraldehyde)

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RAIL TRANSPORT:
RID CLASS No.: 6.1

SEA TRANSPORT:
UN No. SEA: 2927
IMDG CLASS: 6.1
IMDG PACK GR.: II

AIR TRANSPORT:
UN No., AIR: 2927
ICAO CLASS: 6.1
AIR SUB CLASS: 8
AIR PACK GR.: II

15. REGULATORY INFORMATION:

LABEL FOR SUPPLY:

RISK PHRASES: R-23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
R-34 Causes burns.
R-37 Irritating to respiratory system.
R-40 Limited evidence of a carcinogenic effect.
R-42/43 May cause sensitisation by inhalation and skin contact.
R-68/20/21/22 Harmful: possible risk of irreversible effects through inhalation, in contact
with skin and if swallowed.

SAFETY PHRASES: S-23 Do not breathe gas/fumes/vapour/spray.

S-26 In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S-36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S-38 In case of insufficient ventilation, wear suitable respiratory equipment.
S-45 In case of accident or if you feel unwell, seek medical advice immediately (show the
label where possible).

EU DIRECTIVES: Dangerous Substance Directive 67\548. Dangerous Preparations Directive 88\379.

16. OTHER INFORMATION:

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USER NOTES: The information and recommendations contained herein are believed to be accurate and
reliable as of the date issued. However, we do not warrant their accuracy or reliability. We
only warrant you, but to no other persons, that the product referenced herein shall
conform to our quality assurance specifications for the product on the date of shipment to
you .WE EXPRESSLY DISCLAIM ALL OTHER WARRANTIES, EXPRESS OR
IMPLIED, INCLUDING THE IMPLIED WARRANTIES OF MERCHANTABILITY
AND FITNESS FOR A PARTICULAR PURPOSE. Any technical advice, information
or recommendation, given to you is given gratis without warranty whatsoever as to the
advice, information or recommendation given or the results obtained. You shall assume all
risks and shall be solely responsible for the results obtained from the storage, handling or
use of the product whether alone or in combination with other substances. UNDER NO
CIRCUMSTANCES SHALL WE BE LIABLE FOR ANY ECONOMIC
CONSEQUENTIAL (INCLUDING LOST PROFIT OR SAVINGS) OR INCIDENTAL
DAMAGES EVEN IF WE ARE INFORMED OF THEIR POSSIBILITY,
EXEMPLARY OR PUNITIVE DAMAGES, REGARDLESS OF THE FORM OF
ACTION WHETHER IN CONTACT OR TORT INCLUDING OUR SOLE OR JOINT
NEGLIGENCE AND STRICT LIABILITY.

REVISION COMMENTS: Revision has taken place in sections: 1, 2, 3, 10, 11, 12, 14, 15 and 16

REV. No./REPL. SDS GENERATED: Revision No. 2 / Replaces MSDS of 20 September 1997

R-PHRASES (Full Text) R-11 Highly flammable.

R-34 Causes burns.
R-40 Limited evidence of a carcinogenic effect.
R-43 May cause sensitisation by skin contact.
R-23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
R-23/25 Toxic by inhalation and if swallowed.
R-42/43 May cause sensitisation by inhalation and skin contact.
R-39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in
contact with skin and if swallowed.
R-50 Very toxic to aquatic organisms.

DATE: 30 April 2002

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