Chemistry Olympiad 2 000 Mark Scheme

Q1

i)

2 Cu

2+

+ 4I 2 CuI + I2
2-

(1) (1)

ii) 2S2 O3 + I2 2I + S4O6 (Ignore state symbols)

+ 2-

2-

iii) 2H + CO3 H2O + CO2 or Na2 CO3 + 2HNO3 2NaNO3 + H2O + CO2 iv) moles of Cu v) 67.5%
2+

(1)

= 0.0298

(1) (1)
TOTAL 5 MARKS

Q2

i)

2NaN3 to 0.4 KNO3 3.22 :1 (or 130 :40.4) by mass

3

(1) (1) (1)

ii) Either 60 dm N2 = 2.5 mol or use of PV = nRT 133g or 130.5g iii) N-N-O N-N-N iv) Cycle ?Hf (NaN3 ) = + 361.7 KJ mol ?H for reaction 1 = -723 KJ
-1

(1) both linear (1) (1) (1) (1) (1)

TOTAL 9 MARKS

Q3

i)

340 moles 2H2 + O2 2H2 O CH4 + 2O2 CO2 + 2H2 O H2 S + 1O2 H2O + SO2

(1) (1) (1) (1) (1)

ii) 51 moles iii) Black Red Gold

iv) Black Red Gold v) Black

none or -8.5 All 3 153 51 -2 x 10 kJ

4 4 4

(2)

(Any 2 =1)

All 3 (Any 2 =1)

(2)

Red Gold

-8.2 x 10 kJ -3.5 x 10 kJ
TOTAL 9 MARKS

Q4

i)

(1) (1) (1) (1) (1) (1) (1)

TOTAL 7 MARKS

ii) 28.50 x 0.2 = 0.00570 mole HCl 1000 100cm contained 5 x 0.00570 = 0.0285 mole NaOH = 1.14g 15.3 x 0.200 reacts with carbonate = 0.00306 mole 1000 so moles of carbonate = x 0.00306 = 0.00153 100cm solution contained 0.811g
3 3

Q5

Step 1
O H3 C C H3 C

O C H Cl

(2)

+
Cl

Step 2
H3 C

O O C H Cl H 3C C

(2) +
H

Cl

Step 3
H3 C C

+
H

H 3C

C H

(2)

Step 4 CH3CH2O + H (aq) CH 3CH 2OH (1)

TOTAL 7 MARKS

Q6

i)

E = Fe(OH)2 D = Fe
2+

F = [Fe(SCN)]

2+

(2) All 3 = 2 (Any 2 = 1)

ii) MnO4 Fe
2+

(aq) + 8H

+ 5e Mn e
-

2+

(aq) + 4H2 O(1)

(1) (1) (1)

(aq) 2-

Fe

3+ (aq) +

C2O4

(aq) -

2CO2(g) + 2e

iii) 3MnO4

+ (aq) + 24H (aq)

+ 5Fe

2+

2(aq) + 5C2O4 (aq)

3Mn (aq) + 5Fe (aq) + 10CO2(g) + 12H2 O(1) (1) (1)

2+

3+

iv)

/3 X no. of moles MnO4 -

v) x = 2

i.e. 2 mol H2O in 1 mol of Q

(1) (no mark)

TOTAL 8 MARKS

vi) FeC2O4 .2H2O

Q7 1 mark each
I=
OH N

G=
N

Cl

C4H 11NO

C4 H10 NCl

J=

C10 H14 S
S

K=
Ph

C17 H18 SO

L=
Ph

OH

C17H 20SO
S

M=
Ph

N=
NH2 Cl NH2

C17H 19SCl
S

H=
Ph O

O=
SH

C17 H20S
NH2 NH2

O H2 C CH 2

CH3

+ HN(CH3)2
HO

CH 3

SOCl2
CH3 N SH Cl CH 3

F /C + C4H 9Cl
C4 H 9 C S Cl

- HCl

C O

NaBH4 L
C H OH C4 H 9 S C4 H 9 S

SOCl2
C4 H 9 S C Cl H NH 2

C NH 2

M OHC4 H9 S C SH H

ionic i nterm ediate as shown

H
NH 2 O C NH 2

TOTAL 9 MARKS

Q8

i)

H3 AsO3 + I3 + H2O H3 AsO4 + 3I + 2H

(1) (1) (1) (1) (1) (1)

ii) 1 constant life iii) H3 AsO3 , 1, (double concentration, double rate) H , -1,(double concentration, halve rate) I , -2, Reasons not needed iv) Rate = K [H3 AsO3 ] [H ]
1 + -1 - -2 +

[I ]

(1) or ecf

K = 0.112 Units mol dm s

2 -6 -1

(1) (1)
TOTAL 9 MARKS

TOTAL FOR PAPER = 63 MARKS

FILE :

L:/SANDRA/ OLYMPIAD/ QUESTION/ QUESTION 2000/ ROUND 1

MARK SCHEME.