-^ ': 'Otc": :Q

r-{ c'{- <_

iraap,
.la,a{
ei' Ele. t

::"1

H, L c

I
'
'i@.
ss+

* 8
.2V{
0 .592
LtY5t{5
\J v v a ,. +
U .Lv
v
;!.U ?v
.1t'{
,
2.2Wj.+? l1i7
,i "i-- u.J
z t- 7l t"i.6W
75.i
l W 1.
-*
66.8i
'
ri
-' 1 r0"3I,5/?57.i i :X ,' i
2.2W6" ..62.E !1/i tr

c-{ al

*j

,4 .j

i Ii - i Si ,
D:-

4..,

t' -

+ 110" 2F,/,+ 67.IV ' i ,.+ 72.6F1+ .586W ; r!.1 .!r

F s s = 5 ' 7 ' i- h 0 . tr4 /T
* 2 3 .4 W 6 - 4 3 0 .9 i /?+ 85.2vi g - 82.2W e+ 65.5i 4/1
-' ?6.1.l i l :'

The s,;ha'uscl-t-;:
...

-r,lneye
effict'ene;rt.'i
?99.9 = temperatui'e fc'r 39-9f,i'.iestr'u,c'bioc1

, ,

^l ^.-.,

flqg = iempel'ailire fo'997c destructia' ef.ficiencv, 'F

i/y'1= i1.fuei:
o car:'[rn a[o'ts
"'.tirt?
= tr'ao*atrc cornpot.inrlfiag 0 = nc, l =',eti)
ringWl = '1.=C (douible i-.cnd) flag-ncri. to-l;:'iing lhe ;'it:oraea.'tlc
(i l = rrc ,i = V e S)
'9s/,= ftL1-r.rrber
of nitrogen atorns
-il,/5= soi*nition teanperature, 'F

r,/Lref'e j:1 .
,.113::
'ili:e ila:

caici;.Late*
'-Tl:.eact:,',
-rr;eigh.l.
a:

Ws = nllm':en o'oxygen aton:s

W7 = n*mi:er of sulf'ur aon:.s

i.l,ltai.

l{/.q= illyo.r'6gen/carhoillatio
iVg= ail:,.i.i2-pi:c'peri"vi)comlollncl fiag ( = i1i.,',1 ='-'8i)
irt'ieractron i0 = r,', i = -''r;)
i'ij.,r car'!tn.4,rtr-i-'ic-Ll,,rr,:.I-rtric,i'tne
!:-.:
.,''-.'= :,:. ; r-,.:
-,: ?,::-:.i:t-.:i' l=Sll e:Ie i':ltlli l :lea:
lacpc:. iriie'. al:- ilve:"ca:r:p i1982) rc::btrtei coiiisiot ir'::l''"'
da'a a*c p::oposecXa me'LhoCfor predicti'ng an "ef,fr:c'
with enrp,rc;.catr
'i.ive" first-order rate cnstant, & for h;rclrocarhon iiicineratoll ove;i Lne
]"ange frour 9+0'co Xi4& K. Tl'reir meihoi depencis oir f-rqelnoieculer
weight anri tl'le L3pe cr{'ttte F{C. Once & is "ourlcJ,the dltesigllbr^iYlperatre can be ohtained. Recail that the rate constant, ft car he wri'ulen as
lz - Ao

iliRT

{i i"n5

where
E = acitvarin energy, cal"l:roi
' L:

/J

,' :

a.) l:;:' - ,- ..- .--

"

cor:is'tfrilt,X.387 ce-.i/.lrrci.-"K
iiear g-.as]i,a,r.r

7' = a'bsohilte te:r-r-.rpera.iue,

"i{-

T'he pre-e:i'ponential fct'or carr'te gi.ven ht'

l

E'Sv,, F

,J'/

(11.16)
nsrt ,

vtlXetre
Z'= crllision vat,eaci.Err
= s*t1* fac'r,cr
-S

;i:;t:!!!t'riii

iliesrcd ;-.des'f,l''r-rc'i.
-,inliel',1e:rt:,

-,;irhg-r:'e I ,

:eciicn

,3i)

4.1

ii:;=

33i

Tirecl,'

= li']s freali.c"r,'x-'-geil in :he zlttrj:':"r;'e''

-rri.:,
F = a-rosiii.'ieuessre, at:]l
;?' = I' a s c oll $",a n li I 0 . I 2 0 5 L - a t rt-rl"l o i - " F''
Dq. (L j.i6) {a facicr to accclit,-r?or the {act
ti.l;.e s**eyic fasitor: s re--r
Cji
re:.':Lic,:s D'':Rl.'rLse
ihat soil:e ccj,lsioaS are noL ef;'e;tve il proir-''cii^'g
rorll
I ar gexllie'in'l/) c6rl'i'be i a''lcui ae d
,:ili +rc,,r

u-*i'

( li i.T.7)

i:,ere &il-rli= ioi:.c.llar ii'eiglal 'cf t'he L'iC

.iactor Z' ca.r,he estinated ftofrn Flgure 11i"5for
"ji,hocciLj.sirrrri
raL:o
r.an 'heii }:e
thiee classe,sof an6polllcts.T'he pre-expsxien'r,ial'acto:A
ihe
'f"'erhurner'
in
of
ol{vgen
fi"actioi
moie
caic,;laied f,or al* estiula'teei
Th.c activatlon energy E (.,,nl..cavrnoi) is con:elatiedwit'ir r,liciec-1-1ar:
-"l-lcL"
ls:
weight as sircrn ln Figu,re 1l-.6, the eq.r-iatj.cnfor

(11.iE)

4.61
E = -C.00966i4W)-r
'-.
',.:.:
-.

- . .1. , ^:,

.l'", :

l'l:-1"

'j:l:'':::-'?-i '--'::'

:';:'

- :' r - ' ) l- .' ' :

t:'i''-'j'j-l:-3:'
'-:::

'tle
C.e::;,.;:loi e;"frclenC3r,ite rai, i:olll-larii, allrias
reititd
arL'
en{i
,1'rr;r:en'iieilL"

-:t:

z"tj;

r:risiLiennce'liClrea;e

l.{ .- ..1i)

.a:):y
:

l!'.'.r
--E !rl-^

at'L?"7
- 2 r:a-

, ,:,5)

,!eiq ;i = liC cles;':uc1;iotiefficie,ac'

a{., .1
AJthoLogil'chismetll,rci'rr;ionp{thier than tn-leme',hodof L,ee et
rlo
for
usefuL
he:'ng
i.,lLi<inetrc cofrslan's.!ll.lu-s,i. adclj.tion
dces :.esr-1l.,i,
in
t'he
c-ilescribctf
:ite lciea,i ese oi arjl lsotrxe.frlrai FFR, th'e approacl'
al
prec,eirngclilscusgicncan al sr-le usedl in the de-qignof a nonisoti:el-m
condiions.
ac'r'.lai
ateribur*er., wl.rich.is rrio.l.erexrr:esen'taiiveof
qi',ici<i"nela',;iretc co
of the vcc'..,vilj. citen occ'u"n,r
Tire dest:t;Lc.ij,o:l
"i'i:e
cac' "control"
ici
,:ies,ir."ui.llcn
" Tn sor,t l.:riances" c desiiruct
'rr';i'tevel'ai
;ias be,rc.ise:r,c,-i.i* afterirurriers
[J0, lrnoclilr:-iicL:,
cie.ql!ir.r.
bo,'
s';udLeo
iee.u
ha,ve
:li,.u r'',.eilcs oi CO desr,iric'i-,i,-Irr
,;:.v,.isr,i;e,ti..i,:u.
al'Ji
Wiinia:'s.
Ilo';ard-'
::iu|v'rcltlais D:,er:ar:rdGlassmarl 19?3;
;:r..:.ril;i
anct lv'forgan 1969)'
F:inel9?3; liilianis, l*-o'c'r,el.
pubiislied' by
Tne foliovviilg exilressjior for CC oxidation. \/as
sr'u'Cies;lt
ellilel"imentai
f lowarci et ai" (l-97t1)rxfliei:Ievievl of numerous
(840-2:-16
K')"
is vaXid oven'a r-ricierange oi'temperat'ures
1g"11/2{}i2l}i/2 {Ci
r:'r,ieot CLr = 1"l(lC114,-ti0'000/'5?'
i.'eci.rir,rci{-in
( riI "20)
.,,hei'ei i ic.ti.caee.ccolL+e.-:.t;i:,iticri
il lnolfc;rlrj

'
-

li^
_

,
,-:-..
-1aL.r-i

.:: ). tir,il "a' !"Jti ri.e: ,i.'::-'l

J,i,) ,c
:r iicr a a lr in l:i: -: ..c::..
,.- .- .
.
---- - .- :1..
1,,:.:jl:.;,ii;.ier'
rertrL-,.ir-'?-r,-.:':.rsI .:

.)'
[:rn'ti--;ie
i'',''

!:ir.:ii,1

$;':t::,1
F,::.::F:.:ii

,l

rl"-:- .
.,r.E

ffi.

ffi

rdi,itlre l,ie iirn:1te:-:-i'i,Lil.-"-?l:ljifci

:. _ .t:r" .,, r, ,:ilL,rgr,:it
;;;ii r.r''asrile ii,,ne r-r't.5 ser it gi.,,i::ll .t..ii
r'r'iirrir.'.i.1,.'
di!e;.ii.l_;au[i:
it'iorL.er,E. se the i.ri"re mr'rhc.:,i:rcirscrrrssecrrr:i ..r,!s s,,ircir,ait.
!ic,iil rl :

i"r;
!i

irr - .l:,i-;' .- ,.ilirtr3 ,ir._; , l.,t i, ,;

*'-'5:

.,,-:lll;;:t:t

- ,,,'::r .

= ij-:r':.- -,;-':'ii : , ': ;'; - i., -r ,i

'.:,1),.:
,.,.5i,i, :,'-::/,(.r, :),
, . : : : t l l . r, . . , " , _ , l _ i . : : . l -. . : , \ r t :
i :;,)

:1.:

= _.,::.: :,,

t.

.
'l

F:.-

- - , ' : i - . " 1 i r i '; - - l i . 2 . n C , , l C 3 , , . 'l 2 G : *

- Li -' E5 2i j" j:-), r,1- irr- ?6.]- ,n I jj)
l69 ii'
-. i

-,:,

:li.:
i tl
t:'

,'.t,".

'?t,: i'it,', ic t;elwc,:lt 1'',r;j,l i',

,, $11r. :.:-: t:,1,..1., i9 .f pL.i_rXji:,a.e.
'
e i ri,-ier
r-'ar./ei:'agil: a.rri ial:.,i.f . T i:r'rrst.
l 'g g ; =': i 'i '! E : ;
: l :.ii,1

l ::t', .:i -r:, ,;,,r,., rr

-:,r.:l ,",l :)

--l l i '-

-l j r-.t'f1l ,
ii;

-i rr,r Jr

f,i i:),

:.-r:l,tirtrl:t
i:i a.-.
"';e
i:,, ,= - 1- u'lr9616(9.r,i-:4lr I = {5.. ir-,-,-,,,_,'i.,.
',-Crll
.i: il
,iil. :rit.,r ,:,. ,::t:-;jstrr:ittc ,' 1-.rl liigrr,.i-r l:ri,i

ar)

{:
,ii

.'

t-

-,i:-."';::l

.1. ,-.i..j=:

. -l

-r/' /

,i//i
i'
i/"

i
I
;

,i;'

I' i .5
i":iaf il: I 3
f
i
i

:,r
r-r
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-r-q ,l i e ;i.e ia tt;. i'r lr',a'i ":ls rllic

I
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Er
F' ""i
Fl
t.

r::

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:11

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:.-=:>.:_j.

.,'lti:r: !:,i

::: l!{ll{*:lii:l

- .- ;

t1

,, ir,lalt:r:rilt::

,,-

:i5 i-'--r''--

i--.. .-- ,:---

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i af

.'.a'.::.':

-'';:
Arl,uatirn er'iei'Ql5ii*r hyirciarb^
i3i" lill_tlfrj..

.'1;

. .r---!---,|---l---;-t'
i:..!

,1,.i1

2::f.l

': *:i-

illCir^reral,icn
as 3 ilinCii!0r'iOf rilLrlt:c:;'r

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i i i 'r :i - l r

i:

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! lri-',:rJivi.rtl

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iri

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1-. i . :
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i Fr s,';r:rJ'si rL '3 I :i f';i 'r
i -y'n:i :;i t'i i ;" ga:'c:r-i l ' -r';r''
jr 2 !' l| a { t!} .P'tt ':,i t'':i t
: : . i .lii( ) t.- r L ir i ,t!' k' ,L .i.il
"tse'!'f
r":t r:'!:l'i'r:ri'' ;tiiii' r"
:i-i
l:iL.ll.r:i:e
t-le
Lrl!1-
i,t ,.rir,i trii;lOii,
:,-:.1):,irlli'.r:t
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ti'i
'.i'iii :l '-i.1.,;':"j .tf :1,:,"::;1,,:;i;l . Oi'li.; l Jrl'rlt'
ir.,,1.i.rr9 5lll:lt; +A.S .;i,.:'lr:t.
ti'ilt"'
fi]ili
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r:,jlc\tf.
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l {O'ti t:"tel ''
e , ,.:li' :i,::r , Ji' ij, f it. t- r r ji;:.L ii:i
-tfre'i i -OC ,,ri (i i ''ai '-i 4r.trj i rl -l e''i ''i i
{! i -: !:rt|'Ii :
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t151.!rr'l;
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