BI TP HA HC 12 Chng 7.

CROM, ST, NG & MT S KIM LOI KHC

BI TP ! ST & H"P CH#T C$A ST
Dng 1. ST TC %&NG 'I A(IT H
2
SO
)*+,-, ./.01
2 HNO
3
B45 16 7A8299:; Cho 6,72 g Fe vao 400 mL dd HNO
3
1M n p hoan toan thu oc khi NO (sp khu duy nht)va dd
X. Dung dich X co th hoa tan ti a m gam Cu. Tinh m. (1,92g).
B45 26 Hoa tan hoan toan 58 g hh gm Fe, Cu, Ag trong dd HNO
3
2M (d) thu oc 0,15 mol NO, 0,05 mol N
2
O va
dd X. Tinh khi long mui khan thu oc khi c can dd X. (110,7g)
B45 36 Cho m gam Fe vao dd chua 1,38 mol HNO
3
, un nong n kt thuc p thy con lai 0,75m gam cht rn khng
tan va co 0,38 mol hh khi NO, NO
2
thoat ra. Tinh m. (112g)
B45 )6 Hoa tan m gam hh Fe va Cu (trong o Fe chim 40 khi long) bng dd HNO
3
thu oc dd X, 0,448 lit NO
(sp khu duy nht, ktc) va con lai 0,65m gam kim loai khng tan. Tinh khi long mui trong dd X. (5,4g)
B45 )6 Hh X gm Cu va Fe co ti l khi long tong ung la 7:3. Ly m gam X p hoan toan voi dd chua 0,7 mol
HNO
3
. Sau p con lai 0,75m gam cht rn va co 0,25 mol khi Y gm NO va NO
2
. Tinh m. (50,4g)
B45 <6 7C82919; Cho a gam Fe vao 100 mL dd hh HNO
3
0,8M va Cu(NO
3
)
2
1M. Sau khi p xay ra hoan toan thu
oc 0,92a gam hh kim loai va khi NO (sp khu duy nht). Tinh a. (11g)
B45 =6 7A82919; Cho x mol Fe tan hoan toan trong dd chua y mol H
2
SO
4
(ti l x : y 2:5) thu oc 1 sp khu duy
nht va dd chi chua mui sunIat. Tinh s mol e do long Fe o trn nhong khi bi hoa tan. (y mol)
Dng 2. H>N H"P O(IT ST TC %&NG 'I A(IT H
2
SO
)*?@A.01
2 HC?
B45 B6 Cho 7,68 g hh FeO, Fe
2
O
3
, Fe
3
O
4
tac dung vua ht voi 260 mL dd HCl 1M thu oc dd X. Cho X tac dung
voi dd NaOH d ri loc kt tua nung trong kk n khi long khng i thu oc m gam cht rn. Tinh m. (8 g)
B45 C6 7A8299C; D hoa tan hoan toan 2,32g hh gm FeO, Fe
2
O
3
, Fe
3
O
4
(s mol FeO bng s mol Fe
2
O
3
) cn vua u
V lit dd HCl 1M. Tinh V. (0,08 lit)
B45 :6 7B8299C; Cho 9,12 g hh gm FeO, Fe
2
O
3
, Fe
3
O
4
tac dung voi dd HCl d. Sau khi cac p xay ra hoan toan thu
oc dd Y. C can dd Y thu doc 7,62g FeCl
2
va m gam FeCl
3
. Tinh m. (9,75g)
B45 196 7C8299:; Cho m gam hh X gm FeO, Fe
2
O
3
, Fe
3
O
4
vao long vua u dd HCl 2M thu oc dd Y co ti l
s mol Fe
2
va Fe
3
la 1:2. Chia Y thanh 2 phn bng nhau:
P1: c can thu oc m gam mui khan.
P2: Suc khi Cl
2
d vao ri c can dd sau p thu oc m` gam mui khan. Bit m` m 0,71. Tinh th tich dd HCl
dung.
Dng 3. H>N H"P ST & O(IT ST TC %&NG 'I A(IT H
2
SO
)*+,-, ./.01
2 HNO
3

B45 116 7A8299C; Hoa tan ht 11,36 g hh gm Fe, FeO, Fe
2
O
3
, Fe
3
O
4
bng dd HNO
3
d thu oc 1,244 lit khi NO
(sp khu duy nht) va dd X. C can dd X thu oc m gam mui khan. Tinh m. (38,72g)
B45 126 7B8299:; Hoa tan hoan toan 20,88 g mt oxit st bng dd H
2
SO
4
c, nong thu oc dd X va 3,248 lit khi
SO
2
(sp khu duy nht, ktc). C can dd X thu oc m gam mui sunIat khan. Tinh m. (58g)
B45 136 D khu hoan toan 3,04 g hh X gm FeO, Fe
2
O
3
, Fe
3
O
4
cn 0,05 mol H
2
. Tinh th tich khi SO
2
(ktc, sp khu
duy nht) thoat ra khi hoa tan ht X bng dd H
2
SO
4
c, nong, d. (224 mL)
Dng 4. (C DNH CENG THFC C$A O(IT ST
B45 1)6 Khu hoan toan 0,03 mol mt oxit st bng long CO d. Hn hop khi sau p oc dn vao dd noc vi
trong d thu oc 12g kt tua. Tim CT oxit st trn.
B45 1<6 Hoa tan hoan toan 0,02 mol mt oxit st bng 200 mL dd HCl 0,3M. Long axit d oc trung hoa boi 200
mL dd KOH 0,1M. Tim CT oxit st trn.
B45 1=6 7B82919; Khu hoan toan m gam oxit st cn vua u 17,92 lit khi CO (ktc) thu oc a gam Fe. Hoa tan ht a
gam Fe nay bng dd H
2
SO
4
c, nong, d thu oc 20,16 lit khi SO
2
(sp khu duy nht). Tim CT oxit st trn.
B45 1B6 Hoa tan hoan toan 20,88 g mt oxit st bng dd H
2
SO
4
c, nong, d thu oc dd X va 3,248 lit khi SO
2
(sp
phu duy nht). Tim CT oxit st trn.
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1
BI TP HA HC 12 Chng 7. CROM, ST, NG & MT S KIM LOI KHC
B45 1C6 7B82919; Hoa tan hoan toan 2,44 g hh bt X gm Fe
x
O
y
va Cu bng dd H
2
SO
4
c, nong, d. Sau p thu
oc 0,504 lit khi SO
2
(sp khu duy nht, ktc) va dd chua 6,6 g hh mui sunIat. Tim CT oxit st trn va tinh khi
long cua Cu trong X. (26,23)
BI TP TRC NGHIGM
CHI 1:Sp xp dd cac mui : FeSO
4
, Fe
2
(SO
4
)
3
, KNO
3
va Na
2
CO
3
theo thu tu tng dn pH (cac dd mui co cung
nng mol la:
A. Fe
2
(SO
4
)
3
FeSO
4
KNO
3
Na
2
CO
3
B: FeSO
4
Fe
2
(SO
4
)
3
KNO
3
Na
2
CO
3
C: Na
2
CO
3
KNO
3
FeSO
4
Fe
2
(SO
4
)
3
D: KNO
3
Na
2
CO
3
FeSO
4
Fe
2
(SO
4
)
3
CHI 2: Cho 12 gam Mg vao 1 lit dd chua CuSO
4
0,25M va FeSO
4
0,3 M. Khi long cht rn thu oc sau phan
ung la: A: 30 gam B: 32,5 gam C: 22 gam D: 16 gam
CHI 3 Dn chm V lit (ktc) hh hai khi H
2
va CO qua ng su ung 20,8 gam hh gm: CuO, MgO va Fe
2
O
3
, un
nong, phan ung xay ra hoan toan. Hn hop khi, hoi thoat ra khng con H
2
cung nh CO va hh khi hoi nay co khi
long nhiu hon khi long V lit hh hai khi H
2
, CO luc u la 4,64 gam. Trong ng su con chua m g hn hop cac
cht rn.
J Tri s cua m o cu trn la
A6 15,46 B6 12,35 gam C6 16,16 gam %6 14,72 gam
KL Tri s cua V la: A6 3,584 lit B6 5,600 lit C6 2,912 lit %6 6,496 lit
CHI ): D iu ch Fe trong cng nghip nn dung phong phap:
A: Khu Fe
2
O
3
bng CO o nhit cao B: Din phn dd FeCl
2
C: Khu Fe
2
O
3
bng Al
D: Mg tac dung voi FeCl
2
cho ra Fe
CHI <:Cho mt inh st vao dd Fe
3
thi mau cua dd chuyn tu vang Fe
3
sang luc nhat (Fe
2
). Fe cho tac dung Cu
2
lam phai mau xanh cua Cu
2
nhng Fe
2
cho vao dd Cu
2
khng lam phai mau xanh cua Cu
2
. Tu kt qua trn, cac
cht khu Fe, Fe
2
, Cu theo thu tu manh tng dn oc sp xp la:
A: Fe
2
Cu Fe B: Fe
2
Fe Cu C: Fe Cu Fe
2
D: Cu Fe Fe
2

CHI =6 Cho 28 gam Fe hoa tan trong 256 ml dd H
2
SO
4
14 (co khi long ring 1,095g/ml), co khi hiro thoat ra.
Sau khi kt thuc phan ung, em c can dd thi thu oc m gam mt tinh th mui ngm 7 phn tu noc (n
mui
: n
noc

1 : 7). Tri s cua m la:
A6 116,8 gam B6 70,13 gam C6 111,2 gam %6 139 gam
CHI B: Trong 3 cht Fe, Fe
2
, Fe
3
, cht chi th hin tinh khu, cht chi th hin tinh oxh tong ung la:
A: : Fe
2
, Fe
3
B: Fe, Fe
3
C: Fe
3
, Fe
2
D: Fe, Fe
2
E: Fe
2
CHI C: Dt nong m gam bt st cho n khi chuyn ht thanh oxit ta oc mt hn hop oxit nng 1,2 m gam. Hn
hop oxit nay gm:
A: FeO, Fe
2
O
3
, Fe
3
OB: FeO, Fe
2
O
3
C: FeO, Fe
3
O
4
D: Tt ca u sai va du kin khng hop li
CHI :: Dt nong mt hn hop gm bt Al va Fe
3
O
4
trong mi trong khng co khng khi. Nhung cht con lai sau
phan ung, nu cho tac dung voi dd NaOH d s thu oc 6,72 lit H
2
(ktc).Nu cho tac dung voi dd HCl d s thu
oc 26,88 lit H
2
lit(ktc). S gam mi cht co trong hn hop dung la:
A: 27 g Al va 69,6 g Fe
3
O
4
B: 5,4 g Al va 69,6 g Fe
3
O
4
C: 21,6 g Al va 69,6 g Fe
3
O
4
D: 5,4 g Al va 2,32 g Fe
3
O
4
CHI 19:Trong hai cht FeSO
4
, Fe
2
(SO
4
)
3
, cht phan ung oc voi dd KI, dd KMnO
4
o mi trong axit la:
A: FeSO
4
voi dd KMnO
4
; Fe
2
(SO
4
)
3
voi dd KI B: FeSO
4
, Fe
2
(SO
4
)
3
u tac dung voi KMnO
4
C: FeSO
4
, Fe
2
(SO
4
)
3
u tac dung voi KI D:FeSO
4
voi dd KI ; Fe
2
(SO
4
)
3
voi dd KMnO
4
CHI 11: Dun nong hn hop gm 28 g Fe va 3,2 g S thu oc hn hop X. Cho hn hop X p ht voi dd HCl thu oc
hh khi Y va dd Z
(hiu sut phan ung t 100). Thanh phn phn trm theo th tich cua hn hop khi X la:
A:20 va 80 B: 60 va 40 C: 55 va 45 D: Kt qua khac
CHI12: CHI 3=L Mt oxit st co khi long 25,52 gam. D hoa tan ht long oxit st nay cn dung vua u 220 ml
dung dich H
2
SO
4
2M (long). Cng thuc cua oxit st nay la:
A6 Fe
3
O
4
B6 FeO
4
C6 Fe
2
O
3
%6 FeO
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BI TP HA HC 12 Chng 7. CROM, ST, NG & MT S KIM LOI KHC
CHI 13:Mt soi dy Cu ni tip voi mt soi dy Al trong khng khi m. Hin tong nao s xay ra o ch ni cua
hai dy kim loai trn sau mt thoi gian:
A: Dy Al bi mun va ut troc, sau o Cu cung mun va ut B:Khng co hin tong gi
C: Dy Cu bi mun va ut, sau o dy Al cung mun va ut D: Ca hai dy Al va Cu cung bi mun va ut cung mt luc
CHI1):Khu 39,2 g mt hn hop A gm Fe
2
O
3
va FeO bng khi CO thu oc hn hop B gm FeO va Fe. B tan vua
u trong 2,5 lit dd H
2
SO
4
0,5M cho ra 4,48 lit khi (ktc).Khi long Fe
2
O
3
va khi long FeO trong hn hop A la:
A: 32 g Fe
2
O
3
; 7,2 g FeO B; 16 g Fe
2
O
3
; 23 g FeO C: 18 g Fe
2
O
3
; 212 g FeO D: 20 g Fe
2
O
3
; 19,2 g FeO
CHI 1<: Khi em nung mt mui nitrat khan cua mt kim loai n khi long khng i. Phn rn con lai la oxit
kim loai, co khi long giam 66,94 so voi khi long mui troc khi nhit phn. Kim loai trong mui nitrat la:
A6 Zn B6 Cr C6 Cu %6 Fe
CHI 1BL Thuc hin phan ung nhit nhm giua 6,48 gam Al voi 17,6 gam Fe
2
O
3
. Chi co phan ung nhm khu oxit
kim loai tao kim loai. Dem hoa tan cht rn sau phan ung nhit nhm bng dung dich xut d cho n kt thuc phan
ung, thu oc 1,344 lit H
2
(ktc). Hiu sut phan ung nhit nhm la:
A6 70 B6 90,9 C6 83,3 %6 100
CHI 1CL Cho a mol Zn vao dd co hoa tan b mol Fe(NO
3
)
3
. k lin h giua a va b sau khi kt thuc p ung khng co
kim loai.:A6 a _ 2b B6 b ~ 3a C6 b _ 2a %6 b 2a/3
CHI 1:L Cho so chuyn hoa sau: A HCl B D; B Cl
2
F ; E NaOH H NaNO
3
;
A HNO
3
E NO D; B NaOH G NaCl; G I D H ; Cac cht A, B va H la:
A. Mg, MgCl
2
va Mg(OH)
2
B. Fe, FeCl
2
va Fe(OH)
3
C. Pb, PbCl
2
va Pb(OH)
4
D. Cu, Cu(OH)
2
va CuOH
CHI 29L Mt long bt kim loai st khng bao quan tt bi oxi hoa tao cac oxit. Hn hop A gm bt st bi oxi
hoa gm Fe, FeO, Fe
3
O
4
va Fe
2
O
3
. D tai tao st, ngoi ta dung hidro khu o nhit cao. D khu ht 15,84 gam
hn hop A nhm tao kim loai st thi cn dung 0,22 mol H
2
. Nu cho 15,84 gam hn hop A hoa tan ht trong dung
dich H
2
SO
4
m c, nong, thi s thu oc bao nhiu th tich khi SO
2
o iu kin tiu chun ?
A6 2,912 lit B6 3,36 lit C6 1,792 lit %6 2,464 lit
CHI 21L Hoa tan hh X gm 11,2 gam kl (M) va 69,6 gam oxit M
x
O
y
cua kl o trong 2 lit dd HCl, thu oc dd A va
4,48 lit khi H
2
(ktc). Nu cung hoa tan hn hop X o trong 2 lit dd HNO
3
thi thu oc dd B va 6,72 lit khi NO
(ktc).
a)Kim loai M la: A. Fe B. Cu C. Ca D. Na
b)Cng thuc M
x
O
y
: A. CaO B. Fe
2
O
3
C. Fe
3
O
4
D. FeO
CHI 22L Dem hoa tan 5,6 gam Fe trong dd HNO
3
long, sau khi kt thuc phan ung, thy con lai 1,12 gam cht rn
khng tan. Loc ly dung dich cho vao long d dung dich AgNO
3
, sau khi kt thuc phan ung, thy xut hin m gam
cht khng tan. Tri s cua m la:
A6 4,48 B6 8,64 C6 6,48 %6 19,36
CHI 23L Mt hn hop X gm 2 kim loai A, B co ti l khi long la 1:1 . Trong 44,8 gam hn hop X, hiu s v s
mol cua A va B la 0,05 mol. Mt khac khi long nguyn tu cua A lon hon B la 8 gam. Kim loai A va B co th la:
A. Na va K B. Mg va Ca C. Fe va Cu D. Kt qua khac
CHI 2)L Hoa tan 7,2 gam mt hn hop gm 2 mui sunIat cua 2 kim loai hoa tri (II) va (III) vao noc oc dung
dich X (Gia thit khng co phan ung phu khac). Thm vao dung dich X mt long BaCl
2
vua u kt tua ion SO
4
2
thi thu oc kt tua BaSO
4
va dung dich Y. Khi in phn hoan toan dung dich Y cho 2,4 gam kim loai. Bit s mol
cua mui kim loai hoa tri (II) gp i s mol cua mui kim loai hoa tri (III), bit ti l s khi long nguyn tu cua
kim loai hoa tri (III) va (II) la 7/8. Xac inh tn hai loai:
A. Ba va Fe B. Ca va Fe C. Fe va Al D. Cu va Fe
CHI 2<L Co 100 ml dung dich hn hop 2 axit H
2
SO
4
HCl co nng tong ung la 0,8 M va 1,2 M. Thm vao o
10 gam bt hn hop Fe, Mg, Zn. Sau phan ung xong, ly long khi sinh ra cho i qua ng su ung a gam CuO
nung nong. Sau phan ung xong hoan toan, trong ng con 14,08 gam cht rn. Khi long a la:
A. 14,2 gam B. 30,4 gam C. 15,2 gam D. 25,2 gam
CHI 2=L dd chua ng thoi 0,01 mol NaCl; 0,02 mol CuCl
2
; 0,01 FeCl
3
; 0,06 mol CaCl
2
. Kl u tin thoat ra o
catot khi pdd trn la: A. Fe B. Zn C. Cu D. Ca
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BI TP HA HC 12 Chng 7. CROM, ST, NG & MT S KIM LOI KHC
CHI 2BL Thuc hin phan ung nhit nhm hoan toan m gam hn hop gm Al va Fe
3
O
4
. D hoa tan ht cac cht tan
oc trong dung dich KOH thi cn dung 400 gam dung dich KOH 11,2, khng co khi thoat ra. Sau khi hoa tan
bng dung dich KOH, phn cht rn con lai co khi long 73,6 gam. Tri s cua m la:
A6 91,2 B6 103,6 C6 114,4 %6 69,6
CHI 2CL Hoa tan hoan toan hn hop Fe va Mg trong mt long vua u dung dich H
2
SO
4
long thu oc dung dich
A. Dem c can dung dich A thu oc hai mui kt tinh u ngm 7 phn tu noc. Khi long hai mui gp 6,55 ln
khi long hai kim loai. Thanh phn phn trm mi kim loai trong hn hop u la:
A. 50 Fe va 50 Ca B. 40 Fe va 60 Cu C. 30 Cu va 70 Fe D. 30 Fe va 70 Cu
CHI 2:L Khi cho 17,4 gam hop kim Y gm st, ng, nhm phan ung ht voi H
2
SO
4
long d ta oc dung dich
A; 6,4 gam cht rn; 9,856 lit khi B o 27,3
0
C va 1 atm. Phn trm khi long mi kim loai trong hop kim Y la:
A. Al: 30; Fe: 50 va Cu: 20 B. Al: 30o; Fe: 32 va Cu: 38
C. Al: 31,03; Fe: 32,18 va Cu: 36,79 D. Al: 25; Fe: 50 va Cu: 25
CHI 39L Din phn dung in cuc tro dung dich mui sunIat kim loai hoa tri 2 voi cong dong 3A. Sau 1930
giy thy khi long catot tng 1,92 gam. Cho bit tn kim loai trong mui sunIat?
A. Fe B. Ca C. Cu D. Mg
CHI 31L Hoa tan hoan toan mt it oxit Fe
x
O
y
bng dung dich H
2
SO
4
c nong ta thu oc 2,24 lit SO
2
(o o ktc),
phn dung dich em c can thi thu oc 120 gam mui khan. Cng thuc Fe
x
O
y
la:
A. FeO B. Fe
2
O
3
C. Fe
3
O
4
D. Khng phu hop
CHI 32L Hoa tan ht mt khi long m gam Fe
x
O
y
bng dd H
2
SO
4
c nong ta thu oc khi A va dd B. Cho khi A
hp thu hoan toan boi dd NaOH d tao ra 12,6 g mui. Mt khac c can dd B thi thu oc 120 gam mui khan.
Cng thuc cua st oxit.
A. FeO B. Fe
3
O
4
C. Fe
2
O
3
D. Khng phu hop
CHI 33L Cho hn hop X gm 0,2 mol Al ; 0,1 mol Fe vao dung dich H
2
SO
4
co nng 2M va oc ly d 10
so voi long cn thit (th tich dung dich khng thay i). Hy tinh nng cac cht trong dung dich .
A. Al
2
(SO
4
)
3
0,40M va FeSO
4
0,45M B. Al
2
(SO
4
)
3
0,25M va FeSO
4
0,40M
C. Al
2
(SO
4
)
3
0,455M va FeSO
4
0,455M D. Kt qua khac.
CHI 3)L Tim cng thuc cua Fe
x
O
y
bit 4 gam oxit nay phan ung ht voi 52,14 ml dung dich HCl 10 (d
1,05g/cm
3
)
A. Fe
3
O
4
B. FeO C. Fe
2
O
3
D. khng phu h op
CHI 3<L Cho hn hop Y gm 2,8 gam Fe va 0,81 gam Al vao 200ml dung dich C chua AgNO
3
va Cu(NO
3
)
2
. Khi
phan ung kt thuc, thu oc dung dich D va 8,12 gam cht rn E gm 3 kim loai. Cho cht rn E tac dung voi dung
dich HCl d thi thu oc 0,672 lit khi H
2
(ktc). Nng mol cua AgNO
3
va Cu(NO
3
)
2
trong dung dich C la:
A. 0,075M va 0,0125M B. 0,3M va 0,5M C. 0,15M va 0,25M D. Kt qua khac
CHI 3=L Ngm 1 inh st sach vao 100ml dd CuSO
4
sau khi phan ung kt thuc ly inh st ra khi dung dich, rua
sach, lam kh thy khi long inh st tng thm 1,6g. Tinh C
M
dung dich CuSO
4
ban u?
A. 0,25M B. 2M C. 1M D. 0,5M
CHI 3BL Mt oxit kim loai (M
x
O
y
), trong o M chim 72,41 khi long. Khu ht oxit nay bng khi CO thu oc
16,8 gam kim loai M. Hoa tan ht long M bng HNO
3
c nong thu oc mui cua M hoa tri 3 va 0,9 mol khi NO
2
cng thuc cua kim loai oxit la:
A. Al
2
O
3
B. Fe
2
O
3
C. Fe
3
O
4
D. Cr
2
O
3
CHI 3CL Trong binh in phn thu nht ngoi ta hoa tan 0,3725 gam mui clorua cua mt kim loai kim vao noc.
Mc ni tip binh I voi binh II chua dung dich CuSO
4
sau mt thoi gian o catot binh II co 0,16 gam kim loai.bam
vao, con binh I thy chua mt dung dich co pH 13. Cho bit mui clorua cua kim loai kim la mui nao?
A. NaCl B. LiCl C. KCl D. FrCl
CHI 3:L Nhung thanh kim loai km vao mt dung dich chua hn hop 3,2g CuSO
4
va 6,24g CdSO
4
. Hi sau khi Cu
va Cd bi y hoan toan khi dung dich thi khi long thanh km tng hay giam bao nhiu?
A. Tng 1,39 gam B. Giam 1,39gam C. Tng 4 gam D. Kt qua khac.
CHI )9L Hn hop X gm st va st oxit co khi long 16,16 gam. Dem hn hop nay hoa tan hoan toan trong dung
dich HCl d ngoi ta thu oc dung dich B va 0,896 lit khi (o o ktc). Cho dung dich B tac dung voi NaOH d ri
un si trong khng khi ngoi ta thu oc kt tua C. Nung kt tua C o nhit cao n khi long khng i thi
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4
BI TP HA HC 12 Chng 7. CROM, ST, NG & MT S KIM LOI KHC
oc 17,6 gam cht rn. Cng thuc st oxit la:
A. FeO B. Fe
3
O
4
C. Fe
2
O
3
D. Cu C ung
CHI)16 Trong cac cu sau y, cu nao MNO.0 ung?
A. Crom la kim loai co tinh khu manh hon st B. Crom la kim loai nn chi tao oc oxit bao
C. Crom co nhung tinh cht hoa hoc ging nhm D. Crom co nhung hop cht ging hop cht cua lu hunh
CHI )26 Trong cac cu sau y, cu nao ung?
A. Crom la kim loai co tinh khu manh hon st B. Crom la kim loai nn chi tao oc oxit bao
C. Trong tu nhin, crom co o dang on cht D. Pp iu ch crom la in phn Cr
2
O
3
nong chay
CHI )36 Trong cac cu hinh electron cua nguyn tu va ion crom sau y, cu hinh electron nao MNO.0 ung
A.
24
Cr: (Ar)3d
5
4s
1
. B6
24
Cr: (Ar)3d
4
4s
2
. C.
24
Cr
2
: (Ar)3d
4
. D.
24
Cr
3
: (Ar)3d
3
.
CHI ))6 Trong cac cu hinh electron cua nguyn tu va ion crom sau y, cu hinh electron nao ung
A.
24
Cr: (Ar)3d
4
4s
2
. B.
24
Cr
2
: (Ar)3d
3
4s
1
. C.
24
Cr
2
: (Ar)3d
2
4s
2
. D.
24
Cr
3
: (Ar)3d
3
.
CHI )<6 Cho 100 gam hop kim cua Fe, Cr, Al tac dung voi dung dich NaOH d thoat ra 5,04 lit khi (ktc) va mt
phn rn khng tan. Loc ly phn khng tan em hoa tan ht bng dung dich HCl d (khng co khng khi) thoat ra
38,8 lit khi (ktc). Thanh phn khi long cac cht trong hop kim la
A. 13,66Al; 82,29 Fe va 4,05 Cr B. 4,05 Al; 83,66Fe va 12,29 Cr
C6 4,05 Al; 82,29 Fe va 13,66 Cr D. 4,05 Al; 13,66 Fe va 82,29 Cr
CHI )=6 Phat biu nao doi y MNO.0 ung?
A. Crom la nguyn t thuc thu 24, chu ki 4, nhom VIB, co cu hinh e Ar 3d
5
4s
1
B. Nguyn tu khi crom la 51,996; cu truc tinh th lp phong tm din.
C. Khac voi kim loai nhom A, crom co th tham gia lin kt bng e cua ca phn lop 4s va 3d.
D. Trong hop cht, crom co cac muc oxi hoa c trng la 2, 3 va 6.
CHI )B6 Phat biu nao doi y MNO.0 ung?
A. Crom co mau trng, anh bac, d bi mo i trong khng khi. B. Crom la mt kl cung (chi thua kim cong),
ct oc thuy tinh.
C. Crom la kim loai kho nong chay (t
0
nc: 1890
o
C). D. Crom thuc kim loai nng (d 7,2 g/cm
3
).
CHI )C6 Cho mt long mui FeS
2
tac dung voi long d dd H
2
SO
4
long, sau khi kt thuc phan ung, thy con lai
mt cht rn. Cht rn nay la: A6 FeS B6 FeS
2
cha phan ung ht C6 S %6 Fe
2
(SO
4
)
3
CHI ):6 Hn hop A dang bt gm hai kim loai nhm va st. Dt 19,3 gam hn hop A trong ng su ri un nong ng
su mt luc, thu oc hn hop cht rn B. Dem cn lai thy khi long B hon khi long A la 3,6 gam (do kim loai
bi oxi cua khng khi oxi hoa tao hn hop cac oxit kim loai). Dem hoa tan ht long cht rn B bng dung dich
H
2
SO
4
m c, nong, co 11,76 lit khi duy nht SO
2
(ktc) thoat ra. Khi long mi kim loai co trong 19,3 gam hn
hop A la:
A6 4,05 g Al; 15,25 g Fe B6 8,64 g Al; 10,66 g Fe C6 8,1 g Al; 11,2 g Fe %6 5,4 g Al; 13,9g Fe
CHI <96 Hn hop A gm mu a vi (chua 80 khi long CaCO
3
) va mu qung Xierit (chua 65 khi long
FeCO
3
). Phn con lai trong a vi va qung la cac tap cht tro. Ly 250 ml dung dich HCl 2,8M cho tac dung voi
38,2 gam hn hopA6 Phan ung xay ra hoan toan. Kt lun nao doi y phu hop?
A6 Khng u HCl phan ung ht cac mui Cacbonat B6 Cac mui Cacbonat phan ung ht, do co HCl d
C6 Phan ung xay ra vua u %6 Khng u du kin kt lun
CHI <16 Tinh khi long bt nhm cn dung co th iu ch oc 78 gam crom bng phong phap nhit nhm.
A. 20,250 gam B. 35,695 gam C6 40,500 gam D. 81,000 gam
CHI <26 Giai thich ung dung cua crom nao doi y MNO.0 hop li?
A6 Crom la kim loai rt cung nht co th dung ct thuy tinh.
B. Crom lam hop kim cung va chiu nhit hon nn dung tao thp cung, khng gi, chiu nhit.
C. Crom la kim loai nh, nn oc su dung tao cac hop kim dung trong nganh hang khng.
D. Diu kin thong, crom tao oc lop mang oxit min, bn chc nn crom oc dung ma bao v thp.
CHI <36 Nhn xt nao doi y MNO.0 ung?
A. Hop cht Cr(II) co tinh khu c trng; Cr(III) vua oxi hoa, vua khu; Cr(VI) co tinh oxi hoa.
B. CrO, Cr(OH)
2
co tinh bao; Cr
2
O
3
, Cr(OH)
3
co tinh lt; C6 Cr
2
, Cr
3
co tinh tr tinh; Cr(OH)
4

co tinh bao.
D. Cr(OH)
2
, Cr(OH)
3
, CrO
3
co th bi nhit phn.
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5
BI TP HA HC 12 Chng 7. CROM, ST, NG & MT S KIM LOI KHC
CHI <)6 Thm 0,02 mol NaOH vao dd chua 0,01 mol CrCl
2
, ri trong khng khi n phan ung ht thi khlg kt tua
cui cung thu oc la: A. 0,86 gam B. 1,03 gam C. 1,72 gam D. 2,06 gam
CHI <<6 Long Cl
2
va NaOH tong ung oc su dung oxi hoa hoan hoan 0,01 mol CrCl
3
thanh CrO
2
4

la:
A. 0,015 mol va 0,08 mol B. 0,030 mol va 0,16 mol C. 0,015 mol va 0,10 mol D. 0,030
mol va 0,14 mol
CHI <=6 So sanh nao doi y MNO.0 ung?
A. Fe(OH)
2
va Cr(OH)
2
u la bao va la cht khu. B. Al(OH)
3
va Cr(OH)
3
u la cht l.tinh va vua co tinh oxh vua
co tinh khu.
C. H
2
SO
4
va H
2
CrO
4
u la axit co tinh oxh manh. D. BaSO
4
va BaCrO
4
u khng tan trong noc.
CHI <B6 Hin tong nao doi y oc m ta MNO.0 ung?
A. Thi khi NH
3
qua CrO
3
un nong thy cht rn chuyn tu mau sang mau luc thm.
B. Dun nong S voi K
2
Cr
2
O
7
thy cht rn chuyn tu mau da cam sang mau luc thm.
C. Nung Cr(OH)
2
trong khng khi thy cht rn chuyn tu mau luc sang sang mau luc thm.
D. Dt CrO trong khng khi thy cht rn chuyn tu mau en sang mau luc thm.
CHI <C6 Thi khi NH
3
d qua 1 gam CrO
3
t nong n phan ung hoan toan thi thu oc long cht rn bng:
A. 0,52 gam B. 0,68 gam C6 0,76 gam D. 1,52 gam
CHI <:6 Long kt tua S hinh thanh khi dung H
2
S khu dung dich chua 0,04 mol K
2
Cr
2
O
7
trong H
2
SO
4
d la:
A. 0,96 gam B. 1,92 gam C6 3,84 gam D. 7,68 gam
CHI =96 Long HCl va K
2
Cr
2
O
7
tong ung cn su dung iu ch 672 ml khi Cl
2
(ktc) la:
A. 0,06 mol va 0,03 mol B. 0,14 mol va 0,01 mol C. 0,42 mol va 0,03 mol D. 0,16 mol va
0,01 mol
CHI =16 Hin tong nao doi y oc m ta MNO.0 ung?
A. Thm d NaOH vao dung dich K
2
Cr
2
O
7
thi dung dich chuyn tu mau da cam sang mau vang.
B. Thm d NaOH va Cl
2
vao dung dich CrCl
2
thi dung dich tu mau xanh chuyn thanh mau vang.
C6 Thm tu tu dung dich NaOH vao dung dich CrCl
3
thy xut hin kt tua vang nu tan lai trong NaOH d.
D. Thm tu tu dung dich HCl vao dung dich NaCr(OH)
4
thy xut hin kt tua luc xam, sau o tan lai.
CHI =26 Giai phap iu ch nao doi y la MNO.0 hop l?
A. Dung phu khu K
2
Cr
2
O
7
bng than hay S iu ch Cr
2
O
3
. B. Dung phu cua mui Cr (II) voi dd kim d
iu ch Cr(OH)
2
.
C. Dung phu cua mui Cr (III) voi dd kim d iu ch Cr(OH)
3
. D. Dung phu cua H
2
SO
4
c voi dd K
2
Cr
2
O
7

iu ch CrO
3
.
CHI =36 Hn hop A gm Fe va ba oxit cua no. Hoa tan ht m gam hn hop A bang dung dich HNO3 long, co 672
ml NO thoat ra (ktc) va dung dich D. Dem c can dung dich D, thu oc 50,82 gam mt mui khan. Tri s cua m
la:
A6 18,90 gam B6 15,12 gam C6 16,08 gam %6 11,76 gam
CHI =) Thuc hin phan ung nhit nhm voi 3,24 gam Al va m gam Fe
3
O
4
. Chi co oxit kim loai bi khu tao kim loai.
Dem hoa tan cac cht thu oc sau phan ung nhit nhm bng dung dich Ba(OH)
2
co d thi khng thy cht khi tao
ra va cui cung con lai 15,68 gam cht rn. Cac phan ung xay ra hoan toan. Tri s cua m la:
A6 10,44 gam B6 116,00 gam C6 8,12 gam %6 18,56 gam
CHI 65. Cho 2,236 gam hn hop A dang bt gm Fe va Fe3O4 hoa tan hoan toan trong 100mL dd HNO3 co nng
C (mol/L), co 246,4 mL khi NO (dktc) thoat ra. Sau phan ung con lai 0,448 gam kim loai. Tri s cua C la:
A6 0,5M B6 0,68M C6 0,4M %6 0,72M
CHI =B6 CHI 23L Sp theo thu tu pH tng dn cac dd mui co cung nng mol/l: (I): KCl; (II):FeCl
2
; (III):
FeCl
3
; (IV): K
2
CO
3
A6 (II) (III) (I) (IV) B6 (IV) (III) (II) (I) C6 (I) (II) (III) (IV) %6 (III) (II) (I) (IV)
CHI =:6 Phan ung nao sau y khng xay ra?
A6 FeS
2
2HCl FeCl
2
S H
2
S B6 2FeCl
2
Cl
2
2FeCl
3
C6 2FeI
2
I
2
2FeI
3
%6 FeS
2
18HNO
3
Fe(NO
3
)
3
2H
2
SO
4

15NO
2
7H
2
O
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BI TP HA HC 12 Chng 7. CROM, ST, NG & MT S KIM LOI KHC
CHI B16 Hoa tan ht hn hop gm a mol FeS2 va 0,1 mol Cu2S trong dung dich HNO3 long, chi thu oc hai mui
sunIat va co khi NO thoat ra. Tri s cua a la:
A6 0,2 B6 0,15 C6 0,25 %6 0,1
CHI B3. Cho m gam hn hop gm ba kim loai la Mg, Al va Fe vao mt binh kin co th tich khng i 10 lit chua
khi oxi, o 136,5C ap sut trong binh la 1,428 atm. Nung nong binh mt thoi gian, sau o a nhit binh v bng
nhit luc u (136,5C), ap sut trong binh giam 10 so voi luc u. Trong binh co 3,82 gam cac cht rn. Coi
th tich cac cht rn khng ang k. Tri s cua m la:
A6 2,46 gam B6 1,18 gam C6 3,24 gam %6 2,12 gam
CHI B=6 D m gam bt kim loai st ngoai khng khi mt thoi gian, thu oc 2,792 gam hn hop A gm st kim
loai va ba oxit cua no. Hoa tan tan ht hn hop A bng dd HNO3 long, thu oc mt mui st (III) duy nht va co
tao 380,8 mL khi NO duy nht thoat ra (ktc). Tri s cua m la: A6 2,24 gam B6 3,36 gam C6 2,8 gam %6
0,56gam
CHI BBL 44,08 gam mt oxit st Fe
x
O
y
oc hoa tan ht bng dung dich HNO
3
long, thu oc dung dichA6 Cho
dung dich NaOH d vao dung dich A, thu oc kt tua. Dem nung long kt tua nay o nhit cao cho n khi
long khng i, thu oc mt oxit kim loai. Dung H
2
khu ht long oxit nay thi thu oc 31,92 gam cht rn la
mt kim loai. Fe
x
O
y
la:
A6 FeO B6 S liu cho khng thich hop, co th Fe
x
O
y
co ln tap cht C6 Fe
3
O
4
%6 Fe
2
O
3
CHI B:6 Dem nung 116 gam qung Xierit (chua FeCO
3
va tap cht tro) trong khng khi (coi nh chi gm oxi va
nito) cho n khi long khng i. Cho hn hop khi sau phan ung hp thu vao binh ung dung dich noc vi co
hoa tan 0,4 mol Ca(OH)
2
, trong binh co tao 20 gam kt tua. Nu un nong phn dung dich, sau khi loc kt tua, thi
thy co xut hin thm kt tua nua. Ham long (Phn trm khi long) FeCO
3
co trong qung Xierit la:
A6 60 B6 80 C6 50 %6 90
CHI C16 Dem nung Fe(NO3)2 cho n khi long khng i, thi sau khi nhit phn, phn cht rn con lai s nh th
nao so voi cht rn troc khi nhit phn?
A6 Tng 11,11 B6 Giam 55,56 C6 Tuy theo em nung trong khng khi hay chn khng ma kt qua s khac
nhau %6 Giam 60
CHI C26 Thuc hin phan ung nhit nhm hoan toan m gam Fe
2
O
3
voi 8,1 gam Al. Chi co oxit kim loai bi khu tao
kim loai. Dem hoa tan hn hop cac cht thu oc sau phan ung bng dd NaOH d thi co 3,36 lit H
2
(ktc) thoat ra.
Tri s m la:
A6 24 gam B6 16 gam C6 8 gam %6 Tt ca u sai
CHI C36 Hn hop A chua x mol Fe va y mol Zn. Hoa tan ht long hn hop A nay bng dung dich HNO3 long, thu
uoc hn hop khi gm 0,06 mol NO, 0,01 mol N2O va 0,01 mol N2. Dem c can dung dich sau khi hoa tan, thu
oc 32,36 gam hn hop hai mui nitrat khan. Tri s cua x, y la:
A6 x 0,03; y 0,11 B6 x 0,1; y 0,2 C6 x 0,07; y 0,09 %6 x 0,04; y 0,12
CHI C)6 Hn hop A gm hai mui FeCO
3
va FeS
2
co ti l s mol 1 : 1. Dem nung hn hop A trong binh co th tich
khng i, th tich cac cht rn khng ang k, ung khng khi d (chi gm N2 va O2) cac mui trn bi oxi hoa
ht tao oxit st co hoa tri cao nht (Fe2O3). D ngui binh, a nhit binh v bng luc u (troc khi nung), ap
sut trong binh s nh th nao?
A6 Khng i B6 S giam xung C6 S tng ln %6 Khng khng inh oc
CHI C<6 Dem nung hn hop A, gm hai kim loai: x mol Fe va 0,15 mol Cu, trong khng khi mt thoi gian, thu oc
63,2 gam hn hop B, gm hai kim loai trn va hn hop cac oxit cua chung. Dem hoa tan ht long hn hop B trn
bng dung dich H
2
SO
4
m c, thi thu oc 0,3 mol SO
2
. Tri s cua x la:
A6 0,6 mol B6 0,4 mol C6 0,5 mol %6 0,7 mol
CHI 86 Cho dd FeCl
2
, ZnCl
2
tac dung voi dd NaOH d, sau o ly kt tua nung trong khng khi n khi long
khng i, cht rn thu oc la cht nao sau y? A. FeO va ZnO B. Fe
2
O
3
va ZnO C.
Fe
3
O
4
D. Fe
2
O
3
.
CHI 87 So phan ung nao sau y ung (mi mui tn la mt phan ung).
A. FeS
2
FeSO
4
Fe(OH)
2
Fe(OH)
3
Fe
3
O
4
Fe. B. FeS
2
FeO FeSO
4
Fe(OH)
2
FeO Fe.
C. FeS
2
Fe
2
O
3
FeCl
3
Fe(OH)
3
Fe
2
O
3
Fe.D. FeS
2
Fe
2
O
3
Fe(NO
3
)
3
Fe(NO
3
)
2
Fe(OH)
2
Fe.
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BI TP HA HC 12 Chng 7. CROM, ST, NG & MT S KIM LOI KHC
CHI 88 . Mt la st oc chia lam 2 phn bng nhau. Phn 1 cho tac dung voi Cl
2
d, phn 2 ngm vao dd HCl d.
Khi long mui sinh ra ln lot o thi nghim 1 va 2 la:
A. 25,4g FeCl
3
; 25,4g FeCl
2
B. 25,4g FeCl
3
; 35,4g FeCl
2
C. 32,5g FeCl
3
; 25,4 gFeCl
2
D. 32,5g FeCl
3
; 32,5g
FeCl
2
CHI 89 .Dung qung manhetit chua 80 Fe
3
O
4
luyn thanh 800 tn gang co ham long Fe la 95. ua trinh san
xut gang bi hao hut 1. Vy dung bao nhiu tn qung?
A, 1325,3 B. 1311,9 C. 1380,5 D. 848,126.
CHI 90 Hoa tan 6,76 gam hn hop ba oxit: Fe
3
O
4
, Al
2
O
3
va CuO bang 100 mL dung dich H2SO4 1,3M vua u thu
oc dung dich co hoa tan cac mui. Dem c can dd thu oc m gam hn hop cac mui khan. Tri s cua m la:
A6 16,35 B6 17,16 C6 15,47 %6 19,5
CHI 91 Cho 19,2 gam Cu tac dung ht voi dung dich HNO
3,
, khi NO

thu oc em hp thu vao noc cung voi
dong oxi chuyn ht thanh HNO
3
. Th tich khi oxi (ktc) tham gia vao qua trinh trn la:
A 2,24 lit B 3,36 lit C 4,48 lit D 6,72 lit
CHI 92 Khu hoan toan hn hop Fe
2
O
3
va CuO co phn trm khi long tong ung la 66,67 va 33,33 bng khi
CO, ti l mol khi CO
2
tong ung tao ra tu 2 oxit la:
A 9:4 B 3:1 C 2:3 D 3:2
CHI :3L Dem nung nong mt long qung hematit (chua Fe
2
O
3
, co ln tap cht tro) va cho lung khi CO i qua, thu
oc 300,8 gam hn hop cac cht rn, ng thoi co hn hop khi thoat ra. Cho hp thu hn hop khi nay vao binh
ung long d dung dich xut thi thy khi long binh tng thm 52,8 gam. Nu hoa tan ht hn hop cht rn trong
long d dung dich HNO
3
long thi thu oc 387,2 gam mt mui nitrat. Ham long Fe
2
O
3
( khi long) trong
loai qung hematit nay la:
A6 60 B6 40 C6 20 %6 80
CHI :)L Nung x mol Fe trong khng khi mt thoi gian thu oc 16,08 gam hn hop H gm 4 cht rn, o la Fe va 3
oxit cua no. Hoa tan ht long hn hop H trn bng dung dich HNO
3
long, thu oc 672 ml khi NO duy nht
(ktc). Tri s cua x la:
A6 0,21 B6 0,15 C6 0,24 %6 Khng th xac inh oc vi khng u du kin
CHI :<L H s ung troc cht bi oxi hoa bn tac cht phan ung
Fe
x
O
y
CO Fe
m
O
n
CO
2
cn bng s nguyn tu cac nguyn t la:
A6 mx 2ny B6 my nx C6 m %6 nx my
CHI :=L Hoa tan 0,784 gam bt st trong 100 ml dung dich AgNO
3
0,3M. Khuy u phan ung xay ra hoan toan,
thu oc 100 mL dung dich A. Nng mol/L cht tan trong dung dich A la:
A6 Fe(NO
3
)
2
0,12M; Fe(NO
3
)
3
0,02M B6 Fe(NO
3
)
3
0,1M C6 Fe(NO
3
)
2
0,14M %6 Fe(NO
3
)2 0,14M; AgNO
3
0,02M
CHI :BL Hoa tan ht m gam hn hop A gm Al va FexOy bng dung dich HNO3, thu oc phn khi gm 0,05 mol
NO va 0,03 mol N2O, phn lng la dung dich D. C can dung dich D, thu oc 37,95 gam hn hop mui khan. Nu
hoa tan long mui nay trong dung dich xut d thi thu oc 6,42 gam kt tua mau nu . Tri s cua m va FexOy la:
A6 m 9,72gam; Fe3O4 B6 m 7,29 gam; Fe3O4 C6 m 9,72 gam; Fe2O3 %6 m 7,29gam; FeO
CHI :CL Cho lung khi CO i qua ng su chua a gam hn hop A gm CuO, Fe
2
O
3
va MgO, un nong. Sau mt thoi
gian, trong ng su con lai b gam hn hop cht rn B. Cho hp thu hoan toan hn hop khi thoat ra khi ng su vao
dung dich Ba(OH)
2
d, thu oc x gam kt tua. Biu thuc cua a theo b, x la:
A6 a b 16x/197 B6 a b 0,09x C6 a b 0,09x %6 a b 16x/197nmm
CHI ::L Hoa tan ht hn hop A gm x mol Fe va y mol Ag bng dung dich hn hop HNO
3
va H
2
SO
4
, co 0,062 mol
khi NO va 0,047 mol SO
2
thoat ra. Dem c can dung dich sau phan ung thi thu oc 22,164 gam hn hop cac mui
khan. Tri s cua x va y la:
A6 x 0,07; y 0,02 B6 x 0,09; y 0,01 C6 x 0,08; y 0,03 %6 x 0,12; y 0,02
CHI 19L Cho m gam FexOy tac dung voi CO, un nong, chi co phan ung CO khu oxit st, thu oc 5,76 gam hn
hop cac cht rn va hn hop hai khi gm CO2 va CO. Cho hn hop hai khi trn hp thu vao long noc vi trong co
d thi thu oc 4 gam kt tua. Dem hoa tan ht 5,76 gam cac cht rn trn bng dung dich HNO3 long thi co khi
NO thoat ra va thu oc 19,36 gam mt mui duy nht. Tri s cua m va cng thuc cua FexOy la:
A6 6,4; Fe3O4 B6 9,28; Fe2O3 C6 9,28; FeO %6 6,4; Fe2O3
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BI TP HA HC 12 Chng 7. CROM, ST, NG & MT S KIM LOI KHC
CHI 191L Cho 6,48 gam bt kim loai nhm vao 100 ml dung dich hn hop Fe
2
(SO
4
)
3
1M va ZnSO
4
0,8M. Sau khi
kt thuc phan ung, thu oc hn hop cac kim loai co khi long m gam. Tri s cua m la:
A6 14,5 gam B6 16,4 gam C6 15,1 gam %6 12,8 gam
CHI 192L Hn hop A dang bt gm Fe
2
O
3
va Al
2
O
3
. Cho khi H
2
d tac dung hoan toan voi 14,12 gam hn hop A
nung nong, thu oc hn hop cht rn B. Hoa tan ht hn hop B bng dung dich HCl thi thy thoat ra 2,24 lit khi
hiro o iu kin tiu chun. Phn trm khi long mi cht trong hn hop A la:
A6 60 Fe
2
O
3
; 40 Al
2
O
3
B6 52,48 Fe
2
O
3
; 47,52 Al
2
O
3
C6 40 Fe
2
O
3
; 60 Al
2
O
3
%6 56,66 Fe
2
O
3
; 43,34 Al
2
O
3
CHI 193L Cho lung khi CO i qua m gam Fe
2
O
3
un nong, thu oc 39,2 gam hn hop gm bn cht rn la st kim
loai va ba oxit cua no, ng thoi co hn hop khi thoat ra. Cho hn hop khi nay hp thu vao dung dich noc vi trong
co d, thi thu oc 55 gam kt tua. Tri s cua m la:
A6 48 gam B6 64 gam C6 40 gam %6 Tt ca u sai, vi s khng xac inh oc.
CHI 19)L Cho mt inh st luong d vao 20 ml dung dich mui nitrat kim loai X co nng 0,1M. Sau khi phan
ung xay ra hoan toan, tt ca kim loai X tao ra bam ht vao inh st con d, thu oc dung dich D. Khi long dung
dich D giam 0,16 gam so voi dung dich nitrat X luc u. Kim loai X la:
A6 Dng (Cu) B6 Thuy ngn (Hg) C6 Niken (Ni) %6 Mt kim loai khac
CHI 19<L Hoa tan ht 17,84 gam hn hop A gm ba kim loai la st, bac va ng bng 203,4 ml dung dich HNO
3
20 (co khi long ring 1,115 gam/ml) vua u. Co 4,032 lit khi NO duy nht thoat ra (ktc) va con lai dung dich
B. Dem c can dung dich B, thu oc m gam hn hop ba mui khan. Tri s cua m la:
A6 60,27 gam B6 45,64 gam C6 51,32 gam %6 54,28 gam
CHI 19=L Hoa tan hoan toan hn hop gm x mol Hg2S va 0,04 mol FeS2 bng dung dich HNO3 m c, un
nong, chi thu cac mui sunIat kim loai co hoa tri cao nht va co khi NO2 thoat ra. Tri s cua x la:
A6 0,01 B6 0,02 C6 0,08 %6 0,12
CHI 19BL Ion icromat Cr
2
O
7
2
, trong mi trong axit, oxi hoa oc mui Fe
2
tao mui Fe
3
, con icromat bi khu
tao mui Cr
3
. Cho bit 10 ml dung dich FeSO
4
phan ung vua u voi 12 ml dung dich K
2
Cr
2
O
7
0,1M, trong mi
trong axit H
2
SO
4
. Nng mol/l cua dung dich FeSO
4
la:
A6 0,52M B6 0,82M C6 0,72M %6 0,62M
CHI 19CL Gia su gang cung nh thp chi la hop kim cua St voi Cacbon va St ph liu chi gm St, Cacbon va
Fe
2
O
3
. Coi phan ung xay ra trong lo luyn thp Martin la: Fe
2
O
3
3C
0
t
2Fe 3CO.Khi long St
ph liu (chua 40 Fe
2
O
3
, 1C) cn dung khi luyn voi 4 tn gang 5C trong lo luyn thp Martin, nhm thu
oc loai thp 1C, la:
A6 1,50 tn B6 2,15 tn C6 1,82 tn %6 2,93 tn
CHI 19:L Hoa tan hoan toan a gam Fe
x
O
y
bng dung dich H
2
SO
4
m c nong vua u, co chua 0,075 mol H
2
SO
4
,
thu oc b gam mt mui va co 168 ml khi SO
2
(ktc) duy nht thoat ra. Tri s cua b la:
A6 12 gam B6 9,0 gam C6 8,0 gam %6 6,0 gam
CHI 119L Khi long tinh th FeSO
4
.7H
2
O cn dung thm vao 198,4 gam dung dich FeSO
4
5 nhm thu oc
dung dich FeSO
4
15 la:
A6 65,4 gam B6 30,6 gam C6 50 gam %6 Tt ca u khng ung
CHI 111L Cho 19,5 gam bt kim loai km vao 250 mL dung dich Fe2(SO4)3 0,5M. Khuy u phan ung xay ra
hoan toan. Khi long cht rn thu oc sau phan ung la:
A6 9,8 gam B6 8,4 gam C6 11,2 gam %6 11,375 gam
CHI 112L Hoa tan Fe
2
(SO
4
)
3
vao noc, thu oc dung dichA6 Cho dung dich A tac dung voi dung dich Ba(NO
3
)
2
d,
thu oc 27,96 gam kt tua trng. Dung dich A co chua:
A6 0,08 mol Fe
3
B6 0,09 mol SO
4
2
C6 12 gam Fe
2
(SO
4
)
3
%6 B,C u ung
CHI 113L Hoa tan hn hop ba kim loai Zn, Fe, Cu bng dung dich HNO3 long. Sau khi phan ung xay ra hoan toan,
thu oc cht khng tan la Cu. Phn dung dich sau phan ung co chua cht tan nao?
A6 Zn(NO
3
)
2
; Fe(NO
3
)
3
B6 Zn(NO
3
)
2
; Fe(NO
3
)
2
; Cu(NO
3
)
2
C6 Zn(NO
3
)
2
; Fe(NO
3
)
2
%6 Zn(NO
3
)
2
; Fe(NO
3
)
3
; Cu(NO
3
)
2
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