LÝ THUYẾT

Cu 34: Cho cc cht sau: axetilen, etilen, benzen, buta-1,3-ien, stiren, toluen, anlyl benzen, naphtalen. S cht tc d n!
"#c $%i dun! d&ch n"%c bro' l( A. ) B. 3 C. * D. + Cu 35: Cho s, - ph.n /n!: + CH 3OH 2 H 1 SO+ + O1 2 xt + Cl1 2*33 o C + NaOH 2 t o + CuO 2 t o 0 4 7 'etyl acrylat. 5 6 4, 5, 6, 7 l( cc s.n ph8' ch9nh c:a cc ph.n /n!. t;n !<i c:a 0 $( 5 l( A. propen $( ancol anlylic B. propen $( andehit acrylic C. propin $( propan-1-ol D. xiclopropan $( ancol anlylic Cu 40: Cht "#c d=n! > t8y tr?n! !iy $( b@t !iy tron! cAn! n!hiBp l( A. CC1. B. SC1. C. D1C. D. DC1. 3 Cu 41: Eun nFn! 1,3-i'etylpentan-1-ol $%i G1SC+ Hc, 1I3 C, thu "#c s.n ph8' ch9nh l( A. JCG3K1CLCJCG3K-CG1-CG3. B. CG3-CGLCJCG3K-CGJCG3K1. . C. CG3-CG1-CGJCG3K-CJCG3KLCG1. D. CG1LCG-CGJCG3K-CGJCG3K1. Cu 43: Mht bi>u n(o sau Ny l( On!: A. 6, nilon-),) thu@c loPi t, polia'it, "#c iQu chR bSn! ph.n /n! -n! tr=n! h#p cc 'ono'e t",n! /n!. B. Tncol o-hiroxibenzylic l( s.n ph8' trun! !ian tron! Uu trVnh iQu chR nhWa no$olac tX phenol $( Yo'anehit. C. 6, $isco, t, xenluloz, axetat, t, nitron c=n! thu@c loPi t, nhNn tPo. D. Cao su buna-S thu "#c Zhi cho cao su buna tc d n! $%i l"u hu[nh. Cu 49: Cho cNn bSn! hFa h<c: D1 JZK \ 3G1JZK 1DG 3 JZK, JG ] 3K. E> t^n! hiBu sut t_n! h#p DG 3 ta c`n ph.i: A. 6^n! p sut, !i.' nhiBt @. B. ai.' p sut, !i.' nhiBt @. C. 6^n! p sut, t^n! nhiBt @. D. ai.' p sut, t^n! nhiBt @. Cu 50: Cho cc pht bi>u sau: J1K 6ron! '@t chu ZV, theo chiQu t^n! c:a iBn t9ch hPt nhNn thV bn Z9nh n!uy;n tb !i.' d`n. J1K 6ron! '@t nhF' T, theo chiQu t^n! d`n c:a iBn t9ch hPt nhNn thV @ N' iBn t^n! d`n. J3K ci;n ZRt hFa h<c !ida '@t Zi' loPi nhF' eT $( '@t phi Zi' nhF' feeT luAn l( li;n ZRt ion. J+K D!uy;n tb D tron! DG3 $( tron! DG+\ cF c=n! c@n! hFa tr& l( 3. J*K S oxi hFa c:a Cr tron! g1Cr1CI l( \). S pht bi>u On! l( A. 1 B. 3 C. + D. * Cu1:Cho cc poli'e:J1Kpolietilen,J1KpoliJ'etyl'etacrilatK,J3Kpolibutaien,J+Kpolisitiren,J*K poliJ$inylaxetatK h J)K t, nilon-),)h .6ron! cc poli'e tr;n cc poli'e b& th:y phNn tron! dun! d&ch axit $( tron! dun! d&ch ZiQ' l(: A. J1K,J+K,J*K,J3K B. J1K,J1K,J*KhJ+K C. J1K,J*K,J)K, D. J1K,J3K,J)Kh Cu 4:Cho CuJ d"K tc d n! $%i dun! d&ch ieJDC 3K3 "#c dun! d&ch 0. Cho T!DC3 d" tc d n! $%i dun! d&ch 0 "#c dun! d&ch 4. Cho ie Jd"K tc d n! $%i dun! d&ch 4 "#c hjn h#p Zi' loPi 5. S ph",n! trVnh ph.n /n! x.y ra l( A. ) B. I C. * D. + Cu 5: Cho cc ph.n /n! oxi ho- Zhb sau: J1K 3e1 \ 3G1C GeC3 \ *Ge J1K 1G!C 1G! \ C1 J3K +g1SC3 3g1SC+ \ g1S J+K DG+DC3 D1C \ 1G1C J*K 1gClC3 1gCl \ 3C1 J)K 3DC1 \ G1C 1GDC3 \ DC JIK +GClC+ 1Cl1 \ IC1 \ 1G1C JkK 1G1C1 1G1C\ C1 JlK Cl1 \ CaJCGK1 CaCCl1 \ G1C J13K 1gmnC+ g1mnC+ \ mnC1 \ C1 6ron! s cc ph.n /n! oxi ho- Zhb tr;n, s ph.n /n! oxi ho- Zhb n@i phNn tb $( tW oxi ho- tW Zhb l`n l"#t l( A. * $( * B. ) $( + C. k $( 1 D. I $( 3
Cu 6: Cho ) !a' Zn' hPt $(o cc Wn! dun! d&ch G 1SC+ 1m o nhiBt @ th"pn!. qiRn _i ZhAn! l(' thay _i tc @ ph.n /n! l( A.t^n! th> t9ch dun! d&ch G1SC+ 1m l;n 1 l`n B. thay ) !a' Zn' hPt bSn! ) !a' Zn' b@t C. thay dun! d&ch G1SC+ 1m bSn! dun! d&ch 1m D.t^n! nhiBt @ l;n Rn *33C Cu 7: Cho s, - chuy>n hFa: t3 gCG, t3, GCl gCG, GCl CG3CGJCG3KCG1CG1Cl T T qq C r ancol ancol qiRt cc cht T, q, C, r l( cc s.n ph8' ch9nh.6;n !<i c:a r l( A. 1-clo-3-'etylbutan B. 3-'etylbut-1-en C. 1-clo-1-'etylbutan D. 1-'etylbut-1-en Cu 8: G#p cht hdu c, 0 cF cAn! th/c phNn tb CkG1+C+. Cho 0 thWc hiBn cc th9 n!hiB' J1K 0 \ 1DaCG s 01 \ 01 \ G1C. J1K 01 \ G1SC+ s 03 \ Da1SC+. J3K n03 \ n0+ s nilon ),) \ nG1C. J+K 101 \ 03 s 0* \ 1G1C. CAn! th/c cu tPo ph= h#p c:a 0 l( A. CG3CCCtCG1u*CCCG. B. CG3CCCtCG1u+CCCCG3. C. CG3CG1CCCtCG1u+CCCG. D. GCCCtCG1u)CCCG. Cu 10: 6hWc hiBn cc ph.n /n! sau Ny: J1K DhiBt phNn DG+ClC+ J1K Cr1C3 \ gDC3 \ gCG J3K DG3 \ qr1 J+K mnC1 \ gCl \ gGSC+ J*K e1 \ Da1S1C3 J)K G1C1C+ \ gmnC+ \ G1SC+ JIK ieCl1 \ G1C1 \ GCl JkK Dun! hjn h#p Ca3JMC+K1 \ SiC1 \ C Mh.n /n! tPo ra ,n cht l(: A. J1KhJ)KhJIKhJkK B. J1KhJ+KhJIKhJkK C. J1Kh J3KhJ+Kh JkK D. J1KhJ3KhJ*KhJkK Cu 14: S?p xRp cc cht sau Ny theo trVnh tW !i.' d`n nhiBt @ sAi: CG3CCCG J1K, GCCCCG3 J1K, CG3CG1CCCG J3K,CG3CCCCG3 J+K, CG3CG1CG1CG J*K. A. J3K v J1K v J+K v J*K v J1K. B. J1K v J3K v J+K v J*K v J1K. C. J3K v J1K v J*K v J+K v J1K. D. J3K v J*K v J1K v J1K v J+K. Cu 15: rwy !-' cc Zi' loPi Qu tc d n! "#c $%i dd ieCl3 l(: A. Tu, Cu, Tl, m!, 5n B. ie, 5n, Cu, Tl, m! C. Cu, T!, Tu, m!, ie D. ie, m!, Cu, T!, Tl Cl1 Br1 HCl NaOHdd Cu 16: CF s, - sau : Cr + x + x + x + X . 0 l( h#p cht n(o c:a Cro'x A. CrJCGK3. B. Da1CrC+. C. Da1Cr1CI. D. DaCrC1. Cu 17: qraiZinin cF tc d n! l(' !i.' huyRt p. EF l( '@t nonapeptit cF cAn! th/c l(: Tr!-Mro-Mro-aly-Mhe-Ser-Mro-Mhe-Tr!. ghi thuy phNn ZhAn! ho(n to(n, s tripeptit cF ch/a phenyla'in JMheK l(: A. ) B. k C. I D. * + qr1 J1:1K 3 NaOH ,t + CuO ,t + T!DC3 2 DG 3 + 5 6. +33 C Cu 19: Cho s, - quta-1,3 -ien 0 4 qiRt cc cht tr;n 'zi t;n l( s.n ph8' ch9nh h6 cF th> l( cht n(o sau Ny x A. CGC-CGLCGCGC B. DG+CCC-CGLCG-CCCDG+ C. CG3CGtCGCuCGtCGCuCG3 D. GCCC-CC-CGLCG1 Cu 20: Cho cc cht: p-crezol, anilin, benzen, axit acylic, axit Yo'ic, andehit 'etacrylic, axetilen. S cht tc d n! $%i dun! d&ch qr1 Jd"K o iQu ZiBn th"pn! theo ty lB 'ol 1 : 1 l( A. *. B. ). C. 1 D. 3 Cu 22: Cho cc cht sau : qaJGSC3K1 h CrJCGK1h SnJCGK1h DaGSh DaGSC+h DG+Clh CG3CCCDG+h C)G*CDah ClG3DCG1CCCG. S cht $Xa tc d n! $%i DaCG $Xa tc d n! $%i GCl l( A. * B. ) C. + D. I Cu 30: Cho cc th9 n!hiB' sau: J1K S c Zh9 CC1 Jd"K $(o dun! d&ch ch/a 1 'ol qaJCGK1. J1K Cho dun! d&ch qaJCGK1 Jd"K $(o dun! d&ch ch/a 1 'ol DaGCC3. J3K S c Zh9 DG3 Jd"K $(o dun! d&ch ch/a 1 'ol TlCl3. J+K S c Zh9 DG3 Jd"K $(o dun! d&ch ch/a 1 'ol CuCl1. J*K Cho dun! d&ch GCl Jd"K $(o dun! d&ch ch/a 1 'ol DatTlJCGK+u J)K Cho dun! d&ch qaJCGK1 Jd"K $(o dun! d&ch ch/a 1 'ol Da1CC3. JIK S c Zh9 CC1 Jd"K $(o dun! d&ch ch/a 1 'ol DatTlJCGK+u Mh.n /n! thu "#c l"#n! ZRt t:a nhiQu nht l( A. J1K, J)K. B. J)K. C. J1K, JIK. D. J1K, J3K.
Cu 32: Cho cc cht sau : axetilen, axitYo'ic, saccaroz, ,!lucoz,, $inylaxetilenh phenylaxetilen axit axetic, 'etyl axetat , 'antAz,, a'oni Yo'at, axeton, phenyl Yo'at. S cht cF thR tha' !ia phn /n! $%i T!DC32DG3: A. k B. * C. I D. ) 1 1 1SC + + e 1 Cu 36: Cho ph.n /n! : S1Ck + 1e DRu ban ù n-n! @ c:a ion e bSn! 1,333 m $( n-n! @ sau 13 !iNy l( 3,I*1 m thV tc @ trun! bVnh c:a ph.n /n! tron! thpi !ian n(y l( A. ),1.13{3 'ol2l.s B. -11,+.13{3 'ol2l.s C. 1+,k.13-3 'ol2l.s D. 11,+.13{3 'ol2l.s Cu 38: 6hWc hiBn cc ph.n /n! sau: J1K ie \ GCl J1K gmnC+ \ GCl J3K Cl1 \ Gqr J+K gmnC+ \ Da1SC3 \ G1SC+ J*K Cu \ GDC3 J)K DhiBt phNn GDC3 Mh.n /n! tron! F axit ch| Fn! '@t $ai tr} l( A. J1K, J3K, J+K B. J3K, J+K, J)K C. J1K, J*K, J)K D. J1K, J1K, J*K Cu 40: Cho cc cht J0K: n { qutanh J4K: n { Gexanh J5K: isohexan , J6K : neohexan. Cc cht "#c xRp theo chiQu !i.' d`n nhiBt @ sAix A. 4, 5, 0, 6 B. 6, 5, 4, 0 C. 4, 5, 6, 0 D. 4, 0, 5, 6 B S 21 Cu 7: qiRt rSn! T tc d n! $%i dun! d&ch DaCG, cA cPn dun! d&ch sau ph.n /n! thu "#c cht r?n q $( hjn h#p h,i C. Ch"n! ct C thu "#c r, r trn! bPc tPo s.n ph8' ~. ~ tc d n! $%i dun! d&ch DaCG lPi thu "#c q. CAn! th/c cu tPo c:a T l( A. GCCCCG1CGLCG1 B. CG3CCCCGLCG1 C. GCCCCGLCG-CG3 D. GCCCCGLCG1 Cu 12: Mht bi>u sai l( A. Da1CC3 l( n!uy;n liBu Uuan tr<n! tron! cAn! n!hiBp s.n xut th:y tinh. B. nhiBt @ th"pn!, tt c. Zi' loPi ZiQ' th_ Qu tc d n! "#c $%i n"%c. C. DhA' bQn tron! 'Ai tr"pn! ZhAn! Zh9 $( n"%c l( do cF '(n! oxit Tl1C3 bQn $dn! b.o $B D. 6heo chiQu t^n! d`n c:a iBn t9ch hPt nhNn, nhiBt @ nFn! ch.y c:a Zi' loPi ZiQ' !i.' d`n Cu 13: Cho ph.n /n!: 1Tl \ 1G1C \ 1CG- s 1TlC-1 \ 3G1. Cht oxi hFa l( A. CGB. Tl C. G1C D. G1C $( CGCu 16: 6ron! sA cac phat bi;u sau $; anilin J1K Tnilin tan it tron! n",c nh"n! tan nhi;u tron! dun! dich DaCG. J1K Tnilin co tinh baz,, dun! dich anilin ZhAn! la' Ai 'au Uuy ti'. J3K Tnilin dun! ; san xuNt ph8' nhu@', d"#c ph8', poli'e. J+K Tnilin tha' !ia phan "n! th; bro' $(o nhNn th,' d; h,n benzen. Cac phat bi;u un! la A. J1K, J3K, J+K B. J1K, J1K, J3K C. J1K, J1K, J+K D. J1K, J3K, J+K Cu 22: S, - iQu chR MfC tron! cAn! n!hiBp hiBn nay l( Cl1 HCl TH ,t , Pcao A. C1G) C1G*Cl C1G3Cl MfC o HCl TH ,t , Pcao 1*33 C B. CG+ C1G3Cl MfC C1G1 Cl1 TH ,t , Pcao C. C1G+ C1G3Cl MfC Cl1 HCl TH ,t , Pcao D. C1G+ C1G+Cl1 C1G3Cl MfC Cu 23: 6r"pn! h#p thu "#c ZRt t:a cF khi lng ln nht l( A. Cho fJl9tK dun! d&ch GCl 1m $(o f Jl9tK dun! d&ch DaTlC1 1m B. Cho fJl9tK dun! d&ch TlCl3 1m $(o f Jl9tK dun! d&ch DaTlC1 1m C. Cho fJl9tK dun! d&ch DaCG 1m $(o f Jl9tK dun! d&ch TlCl3 1m D. Cho fJl9tK dun! d&ch GCl 1m $(o f Jl9tK dun! d&ch DaTlC1 1m Cu 24: Cho cc cNn bSn! : J1K G1JZK \ e1JZK 1GeJZK J1K 1DCJZK \ C1JZK 1DC1 J1K J3K CCJZK \Cl1JZK CCCl1JZK J+K D1 JZK \ 3G1JZK 1DG3JZKJ+K J*K CaCC3 JrK CaC JrK \ CC1JZK Cc cNn bSn! chuy>n d&ch theo chiQu thun Zhi t^n! p sut l(
A. 1, 1, 3 B. 1, 3, + Cu 25: Cho hai 'ui 0, 4 tha 'wn iQu ZiBn sau: 0 \ 4 ZhAn! x.y ra ph.n /n! 0 \ Cu ZhAn! x.y ra ph.n /n! 4 \ Cu ZhAn! x.y ra ph.n /n! 0 \ 4 \ Cu x.y ra ph.n /n!
C. 1, 3
D. 3, +, *
0, 4 l( A. ieJDC3K3 $ ( DaGSC+. B. DaDC3 $( DaGCC3. C. m!JDC3K1 $( gDC3. D. DaDC3 $( DaGSC+. Cu 26: 6_n! s proton tron! hPt nhNn n!uy;n tb 0 $( 4 l( 1*. 4 thu@c nhF' feeT. iQu ZiBn th9ch h#p ,n cht 0 tc d n! $%i 4. Mht bi>u On! l( A. 0 l( Zi' loPi, 4 l( phi Zi'. B. trPn! thi c, b.n 0 cF 1 electron @c thNn C. CAn! th/c oxit cao nht c:a 0 l( 01C D. CAn! th/c oxit cao nht c:a 4 l( 41CI Cu 27: Cho cc poli'e sau: t, nilon-),)h poliJ$inyl cloruaKh th:y tinh plexi!lash teYlonh nhWa no$olach t, $isco, t, nitron, cao su buna. 6ron! F, s poli'e "#c iQu chR bSn! ph.n /n! tr=n! h#p l( A. I B. + C. ) D. * Cu 28: Cho ph",n! trVnh ho h<c: ieSC+ \ gmnC+ \ gGSC+ ie1JSC+K3 \ mnSC+ \ g1SC+ \ G1C. 6_n! hB s J s n!uy;n t, ti !i.nK c:a cc cht cF tron! ph",n! trVnh ph.n /n! l( A. *+ B. *1 C. +3 D. +k Cu 29: ghi thuy phNn 1 peptit, ch| thu "#c cc ipeptit alu-Gis h Tsp-alu h Mhe-fal $( fal-Tsp. Cu tPo peptit e' thuy phNn l( A. Mhe-fal-Tsp-alu-Gis. B. Gis- Tsp- alu-Mhe-fal-Tsp-alu. C. Tsp-alu-Mhe-fal-Tsp-Mhe-fal-Tsp. D. alu-Mhe-fal-Tsp-alu-Gis-Tsp-fal-Tsp. Cu 30: Mht bi>u khn !"n l( A. 6ron! 'ji phNn tb protit, cc a'inoaxit "#c s?p xRp theo '@t th/ tW xc &nh B. MhNn tb cF hai nhF' - CC-DG- "#c !<i l( ipeptit, ba nhF' thV "#c !<i l( tripeptit C. Cc peptit cF tX 13 Rn *3 ,n $& -a'ino axit cu th(nh "#c !<i l( polipeptit D. Dhdn! h#p cht hVnh th(nh bSn! cch n!"n! t hai hay nhiQu -a'inoaxit "#c !<i l( peptit Cu 32: DhF' cc cht Qu cF Zh. n^n! tha' !ia ph.n /n! trn! !",n! l( : A. alucoz,, axit Yo'ic, anehit oxalic, 'antoz,. B. alucoz,, axit axetic, anehit oxalic, 'antoz,. C. iructoz,, axit Yo'ic, anehit oxalic, saccaroz,. D. iructoz,, axit Yo'ic, Yor'anehit, etylen !licol. Cu 37 . CF cc cht tripan'itin,tristearin, triolein $( 1,1,3-triclopropan.S cht bSn! '@t ph.n /n! trWc tiRp tPo ra !lixerol l( A .1 B .1 C.3 D .+ Cu 39: 6hWc hiBn cc th9 n!hiB' $%i hjn h#p !-' T! $( Cu Jhjn h#p 0K: J1K Cho 0 $(o bVnh ch/a '@t l"#n! d" Zh9 C3 Jo iQu ZiBn th"pn!K J1K Cho 0 $(o '@t l"#n! d" dun! d&ch GDC3 JHcK J3K Cho 0 $(o '@t l"#n! d" dun! d&ch GCl JZhAn! cF 'Ht C1K J+K Cho 0 $(o '@t l"#n! d" dun! d&ch ieCl3 S th9 n!hiB' '( Cu b& oxi hFa c}n T! ZhAn! b& oxi hFa l( A. 1 B. 1 C. 3 D. + Cu 40: 6hWc hiBn cc th9 n!hiB' sau: JaK Dun! DG+DC3 r?n. JbK Eun nFn! DaCl tinh th> $%i dun! d&ch G1SC+ JHcK JcK S c Zh9 Cl1 $(o dun! d&ch DaGCC3. JdK S c Zh9 CC1 $(o dun! d&ch CaJCGK1 Jd"K. JeKS c Zh9 SC1 $(o dun! d&ch gmnC+. J!K Cho dun! d&ch gGSC+ $(o dun! d&ch DaGCC3 JhK Cho MbS $(o dun! d&ch GCl Jlown!K. JiK Cho Da1SC3 $(o dun! d&ch G1SC+ Jd"K, un nFn!. S th9 n!hiB' sinh ra cht Zh9 l( A. 1 B. ) C. * D. +
Cu 41: E> tch "#c CG3CCCG tX h_n h#p !-' CG3CCCG $( C1G*CG ta d=n! ho cht n(o sau Nyx A. Da $( dun! d&ch GCl B. CaJCGK1 $( dun! d&ch G1SC+ C. CuC JtoK $( T!DC32DG3 d" D. G1SC+ Hc Cu 42: Cho cNn bSn! sau tron! bVnh Z9n: 1DC1 JZK D1C+ JZK. J'(u nNu K JZhAn! '(uK qiRt Zhi hP nhiBt @ c:a bVnh thV '(u nNu nhPt d`n. Mh.n /n! thun cF: A. G v 3, ph.n /n! ta nhiBt B. G v 3, ph.n /n! thu nhiBt C. G ] 3, ph.n /n! thu nhiBt D. G ] 3, ph.n /n! ta nhiBt Cu 43: CF + cht 0, 4, 5, 6 cF cAn! th/c phNn tb dPn! C1G1Cn Jn 3K -0, 4, 5 Qu tc d n! "#c $%i dun! d&ch T!DC32DG3 -5, 6 tc d n! "#c $%i DaCG -0 tc d n! "#c $%i n"%c ai tr& n c:a 0, 4, 5, 6 l`n l"#t l( A. 3,+,3,1 B. +,3,3,1 C. 3,1,3,+ D. 1,3,3,+ Cu 44: Cho cc cht: 5n, Cl1, DaCG, DaCl, Cu, GCl, DG3, T!DC3. S cht tc d n! "#c $%i dun! d&ch ieJDC3K1 l( A. I B. ) C. * D. + Cu 45: G#p cht hdu c, 0 tc d n! "#c $%i dun! d&ch DaCG $( dun! d&ch bro' nh"n! ZhAn! tc d n! $%i dun! d&ch DaGCC3. 0 l( A. 'etyl axetat. B. axit acrylic. C. phenol. D. anilin. Cu 49: m@t h#p cht th,' 0 cF C6M6 CIGkC tc d n! "#c $%i dun! d&ch DaCG. S -n! phNn tc d n! "#c $%i dun! d&ch qr1 tron! n"%c l(: A. + B. * C. ) D. 3 B S 22 Cu 1: rwy cc cht Qu l(' 't '(u dun! d&ch thuc t9' l( A. qenzen, but-1-en, axit Yo'ic, p-xilen B. ~tilen, axetilen, anehit Yo'ic, toluen C. Txeton, etilen, anehit axetic, cu'en D. 0iclobutan, but-1-in, '-xilen, axit axetic Cu 2: rwy !-' cc cht cF th> iQu chR trWc tiRp JbSn! '@t ph.n /n!K tPo ra axit axetic l(: A. CG3CG, C1G*CG, CG3CGC. B. C1G+JCGK1, CG3CG, CG3CGC. C. CG3CGC, C)G11C) J!lucoz,K, CG3CG. D. CG3CGC, C1G*CG, C1G*CCCCG3. Cu 3: 6_n! s hPt c:a '@t n!uy;n tb 0 l( 1k. 0 l( A. C B. D C. i D. De Cu 4: rwy !-' cc cht n(o sau Ny Qu cF t9nh l"n! t9nh x A. TlCl3, G1C, DaGCC3, 5nJCGK1, 5nC B. 5nCl1, TlCl3, DaTlC1, DaGCC3, G1DCG1CCCG C. Tl, DaGCC3, DaTlC1, 5nC, qeJCGK1 D. G1C, 5nJCGK1, CG3CCCDG+, G1DCG1CCCG, DaGCC3 Cu 5: Cho ),+ !a' dun! d&ch r"#u T cF n-n! @ I1,kI* tc d n! $%i l"#n! d" Da thu "#c 1,k l9t G1 JZtcK. S n!uy;n tb G cF tron! cAn! th/c phNn tb r"#u T l( A. ) B. 13 C. + D. k Cu 6: Cho a 'ol b@t Zn' $(o dun! d&ch cF h}a tan b 'ol ieJDC 3K3. 6V' iQu ZiBn liBn hB !ida a $( b > sau Zhi ZRt thOc ph.n /n! ZhAn! cF Zi' loPi. A. b v 3a B. a 1b C. b 1a D. b L 1a23 Cu 7: Cho '@t lu-n! Zh9 CC i Uua n! s/ Wn! ' !a' ie 1C3 nun! nFn!. Sau '@t thpi !ian thu "#c 13,++ !a' cht r?n 0 !-' ie, ieC, ie1C3 $( ie3C+. G}a tan hRt 0 tron! dun! d&ch GDC3 Hc, nFn! thu "#c +,3)k l9t DC1 Js.n ph8' Zhb duy nht o iQu ZiBn chu8nK. ai tr& c:a ' l( A. 13.k B. 1+ C. 11 D. 1) Cu 8: Cho cc cht sau : axetilen, axit Yo'ic, Yo'anehit, phenyl Yo'at, !lucAz,, anehit axetic, 'etyl axetat, 'antAz,, natri Yo'at, axeton. S cht cF th> tha' !ia ph.n /n! trn! !",n! l( A. k B. I C. ) D. * Cu 9: Cho tX tX 1*3 'l dd GCl 1m $(o *33 'l dun! d&ch T !-' Da1CC3 $( DaGCC3 thV thu "#c 1,33k l9t Zh9 JZtcK $( dun! d&ch q. Cho dun! d&ch q tc d n! $%i dun! d&ch qaJCGK 1 d" thV thu "#c 1l,** !a' ZRt t:a. D-n! @ 'ol c:a Da1CC3 $( DaGCC3 tron! dun! d&ch T l`n l"#t l(:
A. 3,1km $( 3,1)m B. 3,11m $( 3,31m C. 3,11m $( 3,1km D. 3,1m $( 3,+m Cu 10: Cho tXn! cht ie, ieJCGK1, ieJCGK3, ie3C+, ie1C3, ieJDC3K1,ieJDC3K3, ieSC+, ie1JSC+K3 , ieCC3 l`n l"#t tc d n! $%i G1SC+ Hc nFn! . S ph.n /n! thu@c loPi oxi hFa { Zhb l(. A. k B. ) C. I D. * Cu 11: Cho ph",n! trVnh ho h<c: Tl \ GDC3 TlJDC3K3 \ DC \ D1C \ G1C JqiRt t| lB th> t9ch D1C: DC L 1 : 3K. Sau Zhi cNn bSn! ph",n! trVnh ho h<c tr;n $%i hB s cc cht l( nhdn! s n!uy;n, ti !i.n thV hB s c:a GDC3 l( A. )+ B. )) C. )3 D. )1 Cu 12: Et chy ho(n to(n +,kI1 !a' '@t Girocacbon 0, hp th to(n b@ s.n ph8' chy bSn! dun! d&ch n"%c $Ai tron!. Sau ph.n /n! thu "#c 1I,l3 !a' ZRt t:a $( thy Zhi l"#n! dun! d&ch !i.' *,*k) !a'. CAn! th/c phNn tb c:a 0 l( A. C3G) B. C+Gk C. CG+ D. C+G13 Cu 13: Cho dwy cc cht: CG+, C1G1, C1G+, C1G*CG, CG1LCG-CCCG, C)G*DG1 JanilinK, C)G*CG JphenolK, C)G) JbenzenK, CG3CGC. S cht tron! dwy ph.n /n! "#c $%i n"%c bro' l( A. ) B. * C. k D. I Cu 14: E"a '@t hjn h#p Zh9 D1 $( G1 cF ty lB 1: 3 $(o thp t_n! h#p, sau ph.n /n! thy th> t9ch Zh9 i ra !i.' 1213 so $%i ban ù. 69nh th(nh ph`n ph`n tr^' $Q th> t9ch c:a hjn h#p Zh9 sau ph.n /n!. A. 11.11, )).)I, 11.11 B. 33, )3, 13 C. 13, )3, 13 D. 33.33, *3, 1).)I Cu 15: EiBn phNn 1 l9t dun! d&ch h_n h#p !-' DaCl $( CuSC + Rn Zhi G1C b& iBn phNn o hai cWc thV dXn! lPi, tPi catt thu 1,1k !a' Zi' loPi $( anAt thu 3,33) l9t Zh9 Jo ZtcK. Coi th> t9ch dun! d&ch ZhAn! _i thV pG c:a dun! d&ch thu "#c bSn! A. 11 B. 3 C. 1 D. 13 Cu 16: E> nhn biRt ba l< 't nhwn: phenol, stiren, ancol benzylic, n!"pi ta d=n! '@t thuc thb duy nht l( A. D"%c bro' B. CaJCGK1 C. run! d&ch DaCG D. Da Cu 17: Cht bo T cF ch| s axit l( I. E> x( ph}n! ho 13 Z! T, n!"pi ta un nFn! nF $%i dun! d&ch ch/a 1,+13 Z! DaCG. Sau Zhi ph.n /n! x.y ra ho(n to(n > trun! ho( hjn h#p, c`n d=n! *33'l dun! d&ch GCl 1m. ghi l"#n! x( ph}n! JZ!K thu "#c l( A. 13,3++* B. 13,3+3* C. 13,3+1* D. 13,3+** Cu 18: Cho 1l,k !a' hjn h#p 1 a'in ,n ch/c ZR tiRp tc d n! hRt $%i dun! d&ch GCl, l(' ZhA dun! d&ch thu "#c *1,I !a' 'ui Zhan. CAn! th/c phNn tb 1 a'in l( A. C1GID $( C3GlD B. CG*D $( C1GID C. C3GlD $( C+G11D D. C3GID $( C+GlD Cu 19: Cho 3,1 !a' Cu tc d n! $%i 133'l dun! d&ch hjn h#p GDC 3 3,km $( G1SC+ 3,1m, s.n ph8' Zhb duy nht l( Zh9 DC. S !a' 'ui Zhan thu "#c l( A. *,)+ B. I,l3 C. 13,3k D. k,k+ Cu 20: CF + dun! d&ch tron! sut , 'ji dun! d&ch ch| ch/a '@t cation $( '@t loPi anion. Cc loPi ion tron! c. + dun! d&ch !-': Ca1\, m!1\, Mb1\, Da\, SC+1-, Cl-, CC31-, DC3-. EF l( + dun! d&ch !Vx A. qaCC3, m!SC+, DaCl, MbJDC3K1 B. qaCl1, MbSC+, m!Cl1, Da1CC3 C. qaCl1, m!SC+, Da1CC3, MbJDC3K1 D. m!JDC3K1, qaCl1, Da1CC3, MbSC+ Cu 21: Go( tan hRt ' !a' Tl1JSC+K3 $(o n"%c "#c dun! d&ch T . Cho 333 'l dun! d&ch DaCG 1m $(o T, thu "#c a !a' ZRt t:a. mHt Zhc, nRu cho +33 'l dun! d&ch DaCG 1m $(o T, czn! thu "#c a !a' ZRt t:a. ai tr& c:a ' l( A. +1,I*. B. 1I,1. C. 11,3I*. D. 11,k Cu 22: Gwy cho biRt, ph.n /n! n(o sau Ny GCl Fn! $ai tr} l( cht oxi hFax A. ie \ 1GCl ieCl1 \ G1 B. DaCG \ GCl DaCl \ G1C C. mnC1 \ +GCl mnCl1 \ Cl1 \ 1G1C D. ie \ gDC3 \ +GCl ieCl3 \ gCl \ DC \ 1G1C Cu 23: Go( tan *,+ !a' b@t Tl $(o 1*3 'l dun! d&ch T ch/a ieJDC 3K3 1m $( CuJDC3K1 1m. gRt thOc ph.n /n! thu "#c ' !a' r?n. ai tr& c:a ' l( A. 13,k3 B. 1*,13 C. 13,l* D. 13,13 Cu 24: Et chy ho(n to(n '@t hjn h#p T J!lucAz,, anehit Yo'ic, axit axeticK c`n 1,1+ l9t C 1 JZtcK. rn s.n ph8' chy Uua bVnh Wn! dun! d&ch CaJCGK1, thy Zhi l"#n! bVnh t^n! ' !a'. ai tr& c:a ' l(
A. 3.1 B. ).1 C. 11.+ D. +.+ Cu 25: Cho cc cAn! th/c phNn tb sau : C3GICl , C3GkC $( C3GlD. Gwy cho biRt sW s?p xRp n(o sau Ny theo chiQu t^n! d`n s l"#n! -n! phNn /n! $%i cc cAn! th/c phNn tb Fx A. C3GICl ] C3GkC ] C3GlD B. C3GkC ] C3GICl ] C3GlD C. C3GkC ] C3GlD ] C3GICl D. C3GICl ] C3GlD ] C3GkC Cu 26: Cho hjn h#p Zi' loPi m!, 5n, ie $(o dun! d&ch ch/a T!DC3 $( CuJDC3K1.. Sau Zhi ph.n /n! x.y ra ho(n to(n thu "#c dun! d&ch 0 !-' 3 'ui $( cht r?n 4 !-' ba Zi' loPi. qa 'ui tron! 0 l( A. m!JDC3K1, 5nJDC3K1, CuJDC3K1 B. m!JDC3K1, ieJDC3K3, T!DC3 C. m!JDC3K1, 5nJDC3K1, ieJDC3K1 D. m!JDC3K1, 5nJDC3K1, ieJDC3K3 Cu 27: run! d&ch 0 !-' Tl3\, ie3\, 3,1 'ol Da\, 3,1 'ol SC+1-, 3,3 'ol Cl-. Cho f lit dun! d&ch DaCG 1m, $(o dun! d&ch 0 > thu "#c ZRt t:a l%n nht thV !i tr& f l(. A. 3,k B. 3,I C. 3,) D. 3,* Cu 28: Cho cc cht: a'oniac J1Kh anilin J1Kh p-nitroanilinJ3Kh p-'etylanilin J+K h 'etyla'in J*K h i'etyla'in J)K . Gwy ch<n sW s?p xRp cc cht tr;n theo th/ tW lWc baz t^n! d`n . A. J3K ] J1K ] J+K ]J1K ] J*K ] J)K B. J1K v J3K v J+K v J1K v J*K v J)K C. J1K ] J3K ] J+K ] J1K ] J*K ] J)K D. J3K ] J1K ] J+K ] J1K ] J*K ] J)K Cu 29: Cho cc Zi' loPi: Cr, , ie , Cu , Cs . S?p xRp theo chiQu t^n! d`n @ c/n! tX tri san! ph.i l( A. Cs ] Cu ] ie ] ] Cr B. Cs ] Cu ] ie ] Cr ] C. Cu ] Cs ] ie ] ] Cr D. Cu ] Cs ] ie ] Cr ] Cu 30: T l( hjn h#p Zh9 !-' SC 1 $( CC1 cF ty Zhi h,i so $%i G 1 l( 1I. rn a 'ol hjn h#p Zh9 T Uua bVnh Wn! 1 l9t dun! d&ch DaCG 1,*a m, sau ph.n /n! l(' bay h,i c8n thn dun! d&ch thu "#c ' !a' 'ui. qi>u th/c li;n hB !ida ' $( a l( A. 'L133,*a B. 'L13*a C. 'L1+1a D. 'L11)a Cu 31: ghi nhiBt phNn ho(n to(n 133 !a' 'ji cht sau: gClC 3 JxOc tc mnC1K, gmnC+, gDC3 $( T!DC3. Cht tPo ra l"#n! C1 9t nht l( A. gDC3 B. T!DC3 C. gClC3 D. gmnC+ Cu 32: Et chy 1,) !a' '@t este ~ ,n ch/c "#c 3,*1 !a' CC 1 $( 1,1*1 !a' G1C. DRu cho 13 !a' ~ tc d n! $%i 1*3'l dun! d&ch DaCG 1m , cA cPn dun! d&ch sau ph.n /n! thu "#c 1) !a' cht r?n Zhan . fy cAn! th/c c:a axit tPo n;n este tr;n cF th> l( A. CG1LCJCG3K-CCCG B. GCCC-CG1-CGJCGK-CG3 C. CG1LCG-CCCG D. GCCCJCG1K3CG1CG Cu 33: S c f l9t CC1 J ZtcK $(o 133 'l dun! d&ch 0 !-' qaJCGK 1 1m $( DaCG 1m . Sau ph.n /n! thu "#c 1l,I !a' ZRt t:a, !i tr& c:a f l( A. *,) $( 1,1 B. 1,1+ $( 11,1 C. 1,1+ $( +,+k D. ),I1 $( +,+k Cu 34: Cho 1,+) !a' hjn h#p !-' GCCCG, CG3CCCG, C)G*CG, G1DCG1CCCG tc d n! $Xa : $%i +3 'l dun! d&ch DaCG 1m. 6_n! Zhi l"#n! 'ui Zhan thu "#c sau Zhi ph.n /n! l( A. 3,*1 !a' B. 3,3+ !a' C. k,+1 !a' D. ),+* !a' Cu 35: Go( tan ho(n to(n hjn h#p 0 J !-' x 'ol ie, y 'ol Cu, z 'ol ie 1C3 $( t 'ol ie3C+ K tron! dun! d&ch GCl ZhAn! thy Zh9 cF Zh9 bay ra Zhi Zhi bVnh, dun! d&ch thu "#c ch| ch/a 1 'ui . mi Uuan hB !ida s 'ol cc cht cF tron! hjn h#p 0 l(. A. x\y L1z \3t B. x\ y L 1z \1t C. x\y L1z \1t D. x \y L z \t o t Cu 36: GB s /n! tr"%c cht b& oxi hFa c:a ph.n /n! iexCy \ CC ie'Cn \ CC1 Zhi ph",n! trVnh cNn bSn! l(: A. nx { 'y. B. ' C. 'x { 1ny. D. 'y { nx. Cu 37: "#u 0, anehit 4, axit cacboxylic 5 cF c=n! s n!uy;n tb G tron! phNn tb, thu@c cc dwy -n! n! no ,n ch/c 'Pch ho. Et ho(n to(n hjn h#p 3 cht n(y JcF s 'ol bSn! nhauK thu "#c t| lB 'ol CC1:G1CL11:11 . fy cAn! th/c phNn tb c:a 0, 4, 5 l(: A. C1G)C, C3G)C, C3G)C1 B. C+G13C, C*G13C, C*G13C1 C. CG+C, C1G+C, C1G+C1 D. C3GkC, C+GkC, C+GkC1 Cu 38: Cho cc nhn xt sau: J1K. CF th> tPo "#c ti a 1 ipeptit tX ph.n /n! tr=n! n!"n! hjn h#p Tlanin $( alyxin J1K. ghc $%i ax9t axetic, ax9t a'ino axetic cF th> tha' !ia ph.n /n! $%i axit GCl hoHc ph.n /n! tr=n! n!"n! J3K. ain! $%i ax9t axetic, a'inoax9t cF th> tc d n! $%i baz, tPo 'ui $( n"%c
J+K. Tx9t axetic $( ax9t -a'ino !lutaric cF th> l(' _i '(u Uu[ t9' th(nh J*K. 6h:y phNn ZhAn! ho(n to(n peptit: aly-Mhe-6yr-aly-cys-aly-Mhe-6yr cF th> thu "#c ) tripeptit cF ch/a aly J)K. Cho GDC3 Hc $(o n! n!hiB' ch/a anbu'in thy tPo dun! d&ch '(u t9' CF bao nhi;u nhn xt On!x A. + B. ) C. * D. 3 Cu 39: C/ +*,I* !a' cao su buna-S ph.n /n! $Xa hRt $%i 13 !a' bro' tron! CCl+. 6| lB '?t x9ch butaien $( stiren tron! cao su buna-S l( A. 3 : * B. 1 : 1 C. 1 : 3 D. 1 : 3 Cu 40: G}a tan ho(n to(n hjn h#p !-' x 'ol G! 1S $( 3,3+ 'ol ieS1 bSn! dun! d&ch GDC3 ' Hc, un nFn!, ch| thu cc 'ui sunYat Zi' loPi cF hFa tr& cao nht $( cF Zh9 f l9t DC1 thot ra JZtcK. 6r& s c:a f l(: A. 1I,l1 l9t B. k,l) l9t C. 13,1) l9t D. 1,1+ l9t Cu 41: CF cc nhn &nh sau: 1KCu hVnh electron c:a ion 01\ l( 1s11s11p)3s13p)3d). 6ron! b.n! tu`n ho(n cc n!uy;n t ho h<c, n!uy;n t 0 thu@c chu ZV +, nhF' feeeq. 1KCc ion $( n!uy;n tb: De , Da\ , i cF i>' chun! l( cF c=n! s electron. 3Kghi t chy ancol no thV ta cF nJG1CK : nJCC1Kv1. +Krwy !-' cc n!uy;n t "#c s?p xRp theo chiQu !i.' d`n bn Z9nh n!uy;n tb tX tri san! ph.i l( g, m!, Si, *K69nh baz, c:a dwy cc hiroxit: DaCG, m!JCGK1, TlJCGK3 !i.' d`n. Cho: D J5 L IK, i J5LlK, De J5L13K, Da J5L11K, m! J5L11K, Tl J5L13K, g J5 L 1lK, Si J5 L 1+K. S nhn &nh On!: A. 3. B. *. C. +. D. 1. Cu 42: Ch<n pht bi>u On!: A. 69nh oxi hFa c:a T!\ v Cu1\ v ie3\ v Di1\ v ie1\ B. 69nh oxi hFa c:a T!\ v e1 v ie3\ v Cu1\ v 1S C. 69nh Zhb c:a g v m! v 5n v Di v ie v G! D. 69nh Zhb c:a g v ie v Cu v e- v ie1\ v T! Cu 43: Cho Cacbon JCK l`n l"#t tc d n! $%i Tl, G 1C, CuC, GDC3 Hc, G1SC+ Hc, gClC3, CC1 o iQu ZiBn th9ch h#p. S ph.n /n! '( tron! F C Fn! $ai tr} l( cht Zhbx A. + B. I C. * D. ) Cu 44: Cho 0 Jch/ C, G, CK ch| ch/a 1 loPi nhF' ch/c.Et chy 0 thV thu "#c s 'ol G 1C !p 1,* 'ol CC1. Cho 3,1* 'ol 0 tc d n! $Xa : Da thu "#c ' !a' r?n $( 3,3) lit G1JZtcK. ai tr& ' l(. T.1*,l q.1*,) C.1k,3 r.13,1 Cu 45: Ch| d=n! '@t thuc thb phNn biBt cc Zi' loPi sau: m!, 5n, ie, qax A. run! d&ch G1SC+ lown! B. D"%c C. run! d&ch DaCG D. run! d&ch GCl Cu 46: Cho 1l,1 !a' Cu $(o *33 'l dun! d&ch DaDC3 1m, sau F th;' $(o *33'l dun! d&ch GCl 1m . gRt thOc ph.n /n! thu "#c dun! d&ch 0 $( Zh9 DC duy nht, ph.i th;' bao nhi;u 'l dun! d&ch DaCG 1m $(o 0 > ZRt t:a hRt ion Cu1\ A. 113 B. +33 C. )33 D. k33 Cu 47: Cho Da d" tc d n! $%i a !a' dun! d&ch CG3CCCG. gRt thOc ph.n /n!, thy Zhi l"#n! G1 sinh ra l(
11a . 1+3
fy n-n! @ C dun! d&ch axit l( A. 3) B. 13 C. +.*k D. 1* Cu 48: 6h:y phNn ho(n to(n '@t l"#n! 'antoz,, sau F cho to(n b@ l"#n! !lucoz, thu "#c l;n 'en th(nh ancol etylic thV thu "#c 133 'l ancol +)3. ghi l"#n! ri;n! c:a ancol l( 3,k!a'2'l. Gp th to(n b@ Zh9 CC1 $(o dun! d&ch DaCG d" thu "#c 'ui cF Zhi l"#n! l( A. k+,k !a' B. 13) !a' C. 111 !a' D. 1)l,) !a' Cu 49: Et chy ho(n to(n 1 'ol ancol no, 'Pch ho T c`n 3.* 'ol C1. CAn! th/c phNn tb c:a T l( A. C3G)C1 B. C3GkC3 C. C1G)C D. C1G)C1 Cu 50: Cho 3,1 'ol cht 0 J CG)C3D1K tc d n! $%i dun! d&ch ch/a 3,1 'ol DaCG un nFn! thu "#c cht Zh9 l(' xanh !iy UuV t9' 8' $( dun! d&ch 4. CA cPn dun! d&ch 4 thu "#c ' !a' r?n Zhan. ai tr& c:a ' l( A. k,* B. 11,* C. 1* D. 11,k B S 23
Cu 1: Cho Cacbon JCK l`n l"#t tc d n! $%i Tl, G 1C, CuC, GDC3 Hc, G1SC+ Hc, gClC3, CC1 o iQu ZiBn th9ch h#p. S ph.n /n! '( tron! F C Fn! $ai tr} l( cht Zhbx A. ). B. *. C. +. D. I. Cu 2: Et chy ho(n to(n x 'ol axit cacboxylic ~, thu "#c 1x 'ol CC 1. Cho x 'ol ~ tc d n! $%i DaGCC3 d" thu "#c 1x 'ol CC1. 6;n c:a ~ l( A. axit aipic. B. axit oxalic. C. axit axetic. D. axit Yo'ic. Cu 3: Cho 11 !a' hjn h#p ie $( Cu $(o 133'l dun! d&ch GDC 3 1m, thu "#c '@t cht Zh9 Js.n ph8' Zhb duy nhtK ZhAn! '(u, hFa nNu tron! ZhAn! Zh9, $( cF '@t Zi' loPi d". Sau F cho th;' dun! d&ch G 1SC+ 1m, thy cht Zh9 tr;n tiRp t c thot ra, > ho( tan hRt Zi' loPi c`n 33,33'l. ghi l"#n! Zi' loPi ie tron! hjn h#p l( A. 1,k !a'. B. k,+ !a'. C. *,) !a'. D. 1,+ !a'. Cu 4: Cho dwy cc cht: DaCG, 5nJCGK1, DaGCC3, TlJCGK3, Tl, DaGSC+, CrJCGK3. S cht tron! dwy cF t9nh cht l"n! t9nh l( A. *. B. 3. C. +. D. 1. Cu 5: Cho ' !a' Da $(o 1)3 'l dun! d&ch !-' ie 1JSC+K3 3,11*m $( Tl1JSC+K3 3,1*m. 6ch ZRt t:a r-i nun! Rn Zhi l"#n! ZhAn! _i thV thu "#c *,1+ !a' cht r?n. Cc ph.n /n! ho(n to(n, !i tr& ' l( A. 11,*. B. l,+3. C. 13,3*. D. l,1. 3 Cu 6: c;n 'en '@t l"#n! !lucoz, th(nh ancol etylic thV thu "#c 133 'l ancol +) . ghi l"#n! ri;n! c:a ancol n!uy;n cht l( 3,k !a'2'l. Gp th to(n b@ Zh9 CC1 sinh ra tron! Uu trVnh l;n 'en $(o dun! d&ch DaCG d" thu "#c 'ui cF Zhi l"#n! l( Jcc ph.n /n! x.y ra ho(n to(nK A. k+,k !a'. B. 1)l,) !a'. C. 13) !a'. D. 111 !a'. Cu 7: Cho 1*,)* !a' 'ui !-' G1DCG1CCCDa $( G1DCG1CG1CCCDa tc d n! $Xa : $%i 1*3 'l dun! d&ch G1SC+ 1m. Sau ph.n /n! cA cPn dun! d&ch thV Zhi l"#n! 'ui do G1DCG1CCCDa tPo th(nh l( A. 1l,1* !a'. B. 1k,) !a'. C. 3I,l !a'. D. 11,+ !a'. Cu 8: Cho cc 'ono'e sau: stiren, toluen, 'etyl axetat, $inyl axetat, 'etyl 'etacrylat, 'etyl acrylat, propilen, benzen, axit etanoic, axit -a'inocaproic. S 'ono'e tha' !ia ph.n /n! tr=n! h#p l( A. k. B. I. C. *. D. ). Cu 9: Cho 13,k !a' cht hdu c, 0 cF cAn! th/c phNn tb C IGk tc d n! $%i '@t l"#n! d" dun! d&ch T!DC 3 tron! DG3, thu "#c +*,l !a' ZRt t:a. 0 cF bao nhi;u -n! phNn cu tPo tha 'wn t9nh cht tr;nx A. ). B. 1. C. *. D. +. Cu 10: Et chy ho(n to(n 1,3+ !a' hjn h#p !-' 'etyl axetat, etyl Yo'at $( $inyl axetat r-i hp th to(n b@ s.n ph8' chy $(o dun! d&ch CaJCGK1 d". Sau ph.n /n! thu "#c 13 !a' ZRt t:a $( dun! d&ch 0. ghi l"#n! 0 so $%i Zhi l"#n! dun! d&ch CaJCGK1 ban ù w thay _i nh" thR n(ox A. ai.' 3,lk !a'. B. 6^n! 3,lk !a'. C. ai.' 3,3k !a'. D. 6^n! 1,l1 !a'. Cu 11: Ch| d=n! '@t thuc thb phNn biBt cc Zi' loPi sau: m!, 5n, ie, qax A. run! d&ch G1SC+ lown!. B. run! d&ch DaCl. C. D"%c. D. run! d&ch DaCG. Cu 12: Cho cNn bSn! hFa h<c sau: D1 JZh9K \ 3G1 JZh9K 1DG3 JZh9K h G ] 3. Cho cc biBn php : J1K t^n! nhiBt @h J1K t^n! p sut chun! c:a hB ph.n /n!h J3K hP nhiBt @h J+K d=n! th;' cht xOc tc b@t ieh J*K !i.' n-n! @ DG3h J)K !i.' p sut chun! c:a hB ph.n /n!. Dhdn! biBn php n(o l(' cNn bSn! tr;n chuy>n d&ch theo chiQu thunx A. J1K, J1K, J+K, J*K. B. J1K, J3K, J+K, J)K. C. J1K, J3K, J*K. D. J1K, J1K, J+K. Cu 13: Cho 133 !a' dun! d&ch DG+GSC+ 11,* $(o 133 !a' dun! d&ch qaJCGK1 13,)k $( un nh. 69nh th> t9ch Zh9 '=i Zhai bay ra JZtcK $( Zhi l"#n! ZRt t:a thu "#cx A. 1,1+ l9t Zh9 $( 13,3 !a' ZRt t:a. B. 1,Il1 l9t Zh9 $( 1k,)+ !a' ZRt t:a. C. 1,1+ l9t Zh9 $( 1k,)+ !a' ZRt t:a. D. 1,3++ l9t Zh9 $( 1k,)+ !a' ZRt t:a. Cu 14: Cho esopren ph.n /n! c@n! $%i qr1 theo t| lB 'ol 1:1. S dn xut ibro' JZ> c. -n! phNn hVnh h<cK thu "#c l( A. 3. B. 1. C. *. D. +. Cu 15: Cho dwy cc cht: 'etyla'oni clorua, phenyl clorua, isopropyl clorua, '-crezol, ancol benzylic, natri phenolat, anlyl clorua. S cht tron! dwy tc d n! "#c $%i dun! d&ch DaCG lown!, un nFn! l(
A. +. B. ). C. 3. D. *. Cu 16: Cho cc nhn xt sau: J1K. CF th> tPo "#c ti a 1 ipeptit tX ph.n /n! tr=n! n!"n! hjn h#p Tlanin $( alyxin J1K. ghc $%i axit axetic, ax9t a'ino axetic cF th> tha' !ia ph.n /n! $%i axit GCl J3K. ain! $%i axit axetic, a'inoaxit cF th> tc d n! $%i baz, tPo 'ui $( n"%c J+K. Txit axetic $( axit -a'ino !lutaric ZhAn! l(' _i '(u Uu[ t9' th(nh J*K. 6h:y phNn ZhAn! ho(n to(n peptit: aly-Tla-aly-Tla-aly cF th> thu "#c ti a 1 ipeptit J)K. Cho CuJCGK1 $(o n! n!hiB' ch/a anbu'in thy tPo dun! d&ch '(u xanh th' S nhn xt khng ng l( A. +. B. *. C. ). D. 3. Cu 17: Gjn h#p 0 !-' C1G1 $( G1 cF c=n! s 'ol. cy '@t l"#n! hjn h#p 0 cho Uua cht xOc tc th9ch h#p nun! nFn!, thu "#c hjn h#p 4 !-' C1G+, C1G), C1G1 $( G1. S c 4 $(o dun! d&ch bro' d" thV Zhi l"#n! bVnh bro' t^n! ' !a' so $%i ban ù $( thot ra +,+k l9t hjn h#p Zh9 JZtcK cF t| Zhi so $%i G 1 l( k. E> t chy ho(n to(n 4 c`n 33,) l9t C1 JZtcK. ai tr& ' l( A. 1+,3. B. l,k. C. 13,k. D. 13,+. Cu 18: S.n ph8' hdu c, thu "#c Zhi cho h#p cht hdu c, 0 ch/a $}n! benzen $( cF cAn! th/c CG3CCCC)G+CG1Cl tc d n! $%i dun! d&ch DaCG lown!, d", un! nFn! l( A. CG3CCCG, GCC)G+CG1CG . B. CG3CCCDa, DaCC)G+CG1CDa. C. CG3CCCDa, GCC)G+CG1CG. D. CG3CCCDa, DaCC)G+CG1CG. Cu 19: Eun 1 'ol h_n h#p C1G*CG $( C+GlCG Jty lB 'ol t",n! /n! l( 3:1K $%i G1SC+ Hc o 1+3oC thu "#c ' !a' ete, biRt hiBu sut ph.n /n! c:a C1G*CG l( )3 $( c:a C+GlCG l( +3 . ai tr& c:a ' l( A. *3,I) !a'. B. 1l,3+ !a'. C. 1k,+ !a'. D. 13,I1 !a'. Cu 20: 6hWc hiBn cc th9 n!hiB' sau: J1K. S c Zh9 C1G+ $(o dun! d&ch gmnC+. J1K. S c CC1 d" $(o dun! d&ch DaTlC1 J3K. ChiRu sn! $(o hjn h#p Zh9 JCG+h Cl1K J+K. S c Zh9 G1S $(o dun! d&ch ieCl3. J*K. S c Zh9 DG3 $(o dun! d&ch TlCl3. J)K. S c Zh9 SC1 $(o dun! d&ch G1S. S th9 n!hiB' cF ph.n /n! oxi ho- Zhb x.y ra l( A. 1, 1, 3, +. B. 1, 3, +, ). C. 1, +, *, ). D. 1, 1, +, *. Cu 21: rwy !-' cc cht Qu cF th> l(' 't t9nh c/n! tP' thpi c:a n"%c l( A. gCl, CaJCGK1, Da1CC3. B. DaCG, Da3MC+, Da1CC3. C. GCl, CaJCGK1, Da1CC3. D. GCl, DaCG, Da1CC3. Cu 22: CF cc nhn &nh sau: J1K Cu hVnh electron c:a ion 01\ l( tTru3d). 6ron! b.n! tu`n ho(n, n!uy;n t 0 thu@c chu ZV +, nhF' feeeq. J1K Cc ion $( n!uy;n tb: De , Da\ , i cF i>' chun! l( cF c=n! s electron. J3K Cc n!uy;n t '( n!uy;n tb cF 1,1,3 electron l%p n!o(i c=n! Qu l( Zi' loPi J+K rwy cc n!uy;n t "#c s?p xRp theo chiQu !i.' d`n bn Z9nh n!uy;n tb tX tri san! ph.i l( g, m!, Si, D. J*K 69nh baz, c:a dwy cc hiroxit: DaCG, m!JCGK1, TlJCGK3 !i.' d`n. Cho: D J5LIK, i J5LlK, De J5L13K, Da J5L11K, m! J5L11K, Tl J5L13K, g J5L1lK, Si J5L1+K, Tr J5L1kK S nhn &nh ng: A. 3. B. +. C. *. D. 1. Cu 23: 6hWc hiBn cc th9 n!hiB' sau: J1K Et dNy s?t tron! Zh9 clo d". J1K Et nFn! hjn h#p b@t ie $( S JZhAn! cF oxiK. J3K Cho ieC $(o dun! d&ch GDC3 lown!. J+K Cho ie $(o dun! d&ch T!DC3 d". J*K Cho ie3C+ $(o dun! d&ch Ge Jlown!, d"K. CF bao nhi;u th9 n!hiB' tPo ra 'ui s?t JeeeKx A. 1. B. +. C. 1. D. 3. Cu 24: S cAn! th/c cu tPo c:a h#p cht hdu c, 0 cF cAn! th/c phNn tb l( C kG13C, cF ch/a $}n! benzen $( tc d n! "#c $%i dun! d&ch DaCG l( A. l. B. ). C. I. D. k. Cu 25: Cho cc dun! d&ch: C)G*DG1 JanilinK, CG3DG1, DaCG, C1G*CG, Da1CC3 $( G1DCG1CCCG. 6ron! cc dun! d&ch tr;n, s dun! d&ch cF th> l(' _i '(u phenolphtalein l( A. +. B. 3. C. *. D. 1.
Cu 26: Gjn h#p cht r?n 0 !-' qaCC3, ieJCGK1, TlJCGK3, CuC, m!CC3. Dun! 0 tron! ZhAn! Zh9 Rn Zhi l"#n! ZhAn! _i "#c hjn h#p r?n 4. Cho 4 $(o n"%c d" "#c dun! d&ch 5 ch/a 1 cht tan $( ph`n ZhAn! tan ~. ~ ch/a A. ie1C3, Cu, m!C. B. ieC, CuC, m!C. C. ie1C3, CuC, m!C D. ie1C3, CuC, m!C, Tl1C3. Cu 27: 6iRn h(nh cc th9 n!hiB' sau: J1K Cho dun! d&ch DaGSC+ $(o dun! d&ch qaJGCC3K1. J1K S c Zh9 axetilen $(o dun! d&ch T!DC3 tron! DG3. J3K S c Zh9 G1S $(o dun! d&ch m!Cl1. J+K S c Zh9 DG3 t%i d" $(o dun! d&ch CuCl1. J*K S c Zh9 CC1 t%i d" $(o dun! d&ch DaTlC1. J)K S c Zh9 SC1 $(o dun! d&ch gmnC+2G1SC+. Sau Zhi cc ph.n /n! ZRt thOc, cF bao nhi;u th9 n!hiB' thu "#c ZRt t:ax A. ). B. 3. C. +. D. *. Cu 28: Cho dwy !-' cc cht: Da, T!, C1, GCl, CuJCGK1, m!JGCC3K1, CuC, DaCl, C1G*CG, C)G*CG, C)G*DG1, CG3CDa, GCCCDa. S cht tc d n! "#c $%i dun! d&ch axit axetic Jtron! iQu ZiBn th9ch h#pK l( A. 13. B. 11. C. l. D. k. Cu 29: 6h;' tX tX tXn! !i<t c:a 133 'l dun! d&ch GCl 1m $(o 133 dun! d&ch ch/a Da1CC3 1,1m $( DaGCC3 3,)m, sau ph.n /n! ho(n to(n thu "#c dun! d&ch 0. Cho dun! d&ch n"%c $Ai tron! d" $(o dun! d&ch 0 thV thu "#c bao nhi;u !a' ZRt t:ax A. *,* !a'. B. 13 !a'. C. k !a'. D. * !a'. Cu 30: Gjn h#p 0 !-': GCGC, CG3CCCG, GCCCCG3 $( CG3CGJCGKCCCG. Et chy ho(n to(n hjn h#p 0 c`n f l9t C1 JZtcK sau ph.n /n! thu "#c CC 1 $( G1C. Gp th hRt s.n ph8' chy $(o n"%c $Ai tron! d" thu "#c 33 !a' ZRt t:a. fy !i tr& c:a f t",n! /n! l( A. k,+3 l9t. B. ),I1 l9t. C. I,k+ l9t. D. *,)3 l9t. Cu 31: ~ste 0 "#c tPo th(nh tX axit oxalic $( hai ancol ,n ch/c. 6ron! phNn tb este, s n!uy;n tb cacbon nhiQu h,n s n!uy;n tb oxi l( 1. ghi cho ' !a' 0 tc d n! $%i dun! d&ch DaCG d", sau Zhi ph.n /n! ho(n to(n cF l,) !a' DaCG w ph.n /n!. ai tr& c:a ' l( A. 1+,*. B. 1I,*. C. 1*,k+. D. 31,)k. Cu 32: Gjn h#p !-' hai axit cacboxylic no, 'Pch ho 0, 4. Et chy ho(n to(n 1 'ol 0 hay 1 'ol 4 Qu thu "#c 1 'ol G1C. DRu t chy ho(n to(n 13,) !a' hjn h#p 0, 4 thu "#c ),I1 l9t CC 1 JZtcK. 6run! ho( hjn h#p axit tr;n c`n f l9t dun! d&ch DaCG 1m. ai tr& c:a f l( A. 133 'l. B. +33 'l. C. )33 'l. D. 333 'l. Cu 33: Cho 3,1* 'ol G1DC3G*JCCCGK1 Jaxit !luta'icK $(o 1I* 'l dun! d&ch GCl 1m, thu "#c dun! d&ch 0. Cho DaCG d" $(o dun! d&ch 0. Sau Zhi cc ph.n /n! x.y ra ho(n to(n, s 'ol DaCG w ph.n /n! l( A. 3,I3. B. 3,*3. C. 3,)*. D. 3,**. Cu 34: Mht bi>u n(o sau Ny l( sai# A. 6hPch cao sn! J CaSC+.1G1CK "#c d=n! > bF b@t, Oc t"#n!. B. Da1CC3 l( n!uy;n liBu Uuan tr<n! tron! cAn! n!hiBp s.n xut th:y tinh. C. 6h(nh ph`n ch9nh c:a UuHn! olo'it l( CaCC3.m!CC3. D. Cc Zi' loPi ZiQ' Qu cF cu trOc 'Pn! tinh th> lp ph",n! tN' Zhi. Cu 35: Gjn h#p 0 cF C1G*CG, C1G3CCCG, CG3CGC tron! F C1G*CG chiR' *3 theo s 'ol. Et chy ho(n to(n ' !a' hjn h#p 0 thu "#c *,+ !a' G 1C $( *,k1+ l9t CC1 JZtcK. mHt Zhc, cho 1+,l !a' hjn h#p 0 tc d n! $%i l"#n! d" Da thu "#c f l9t Zh9 J ZtcK. ai tr& c:a f l( A. 1,)k. B. 1,1+. C. 1,11. D. 1,)kk. Cu 36: DhWa phenolYo'anehit "#c iQu chR bSn! cch un nFn! phenol d" $%i dun! d&ch: A. CG3CCCG tron! 'Ai tr"pn! axit. B. CG3CGC tron! 'Ai tr"pn! axit. C. GCCCG tron! 'Ai tr"pn! axit. D. GCGC tron! 'Ai tr"pn! axit. Cu 37: Cxi ho 1*,) !a' CG3CG JcF xOc tc th9ch h#pK thu "#c hjn h#p s.n ph8' 0 !-' JGCGC, GCCCG, G1C, CG3CG d"K. Chia 0 th(nh hai ph`n bSn! nhau. Mh`n 1, tc d n! $%i l"#n! d" dun! d&ch T!DC 3 tron! DG3 un nFn! thu "#c ' !a' T!. Mh`n 1, tc d n! $Xa : $%i 133'l dun! d&ch gCG 1m. GiBu sut Uu trVnh oxi ho CG3CG l( I*. ai tr& c:a ' l( A. 13k. B. 11l,). C. )+,k. D. 31,+. Cu 38: Cho 1,k !a' b@t s?t tc d n! ho(n to(n $%i f 'l dun! d&ch GDC 3 3,*m thu "#c s.n ph8' Zhb DC duy nht $( dun! d&ch 0. 0 cF th> tc d n! $Xa : $%i dun! d&ch ch/a 3,33 'ol T!DC3. ai tr& c:a f l(
A. +13 'l. B. 3+3 'l. C. 313 'l. D. 1k3 'l. Cu 39: rwy !-' cc cht Zh9 "#c l(' ZhA bSn! axit sunYuric Hc l( A. CC1, DG3, G1, Cl1. B. D1, SC3, CC1, SC1. C. SC3, G1S, CC1, C1. D. CC1, GCl, D1, SC1. Cu 40: Cho cc cht sau: i'etylete J1K, ancol etylic J1K, ancol 'etylic J3K, axit axetic J+K. Cc cht tr;n "#c xRp theo nhiBt @ sAi t^n! d`n JtX tri san! ph.iK l( A. +, 1, 3, 1. B. 1, 3, 1, +. C. 1, 3, +, 1. D. 1, 1, +, 3. Cu 41: EiBn phNn dun! d&ch !-' 11,I !a' DaCl $( 1k,1 !a' CuJDC 3K1 JiBn cWc tr,, '(n! n!^n xpK Rn Zh9 Zhi l"#n! dun! d&ch !i.' i 1*,1 !a' thV n!Xn! iBn phNn J!i. thiRt l"#n! n"%c bay h,i ZhAn! n! Z>K. ghi l"#n! Zi' loPi thot ra o cactot l( A. I,)k. B. ),+. C. l,). D. 1*,1. Cu 42: DRu $t l(' bSn! h#p Zi' ie-5n b& ^n '}n iBn ho thV tron! Uu trVnh ^n '}n A. gn' Fn! $ai tr} catot $( b& oxi ho. B. S?t Fn! $ai tr} anot $( b& oxi ho. C. gn' Fn! $ai tr} anot $( b& oxi ho. D. S?t Fn! $ai tr} catot $( b& oxi ho. Cu 43: Mht bi>u n(o sau Ny l( ngx A. CF th> d=n! cc chai lo th:y tinh > Wn! dun! d&ch Gi B. qn Z9nh n!uy;n tb c:a clo l%n h,n bn Z9nh n!uy;n tb c:a bro'. C. 69nh axit c:a Gi 'Pnh h,n t9nh axit c:a GCl. D. 69nh Zhb c:a ion qr- l%n h,n t9nh Zhb c:a ion Cl-. Cu 44: Cc Zh9 th.i cAn! n!hiBp $( c:a cc @n! c, A tA, xe 'y...l( n!uy;n nhNn ch: yRu !Ny ra '"a axit. Dhdn! th(nh ph`n hFa h<c ch: yRu tron! cc Zh9 th.i trWc tiRp !Ny ra '"a axit l( A. DC1, CC1, CC. B. DC, DC1, SC1. C. SC1, CC, DC. D. SC1, CC, DC1. Cu 45: Cho 1I,) !a' hjn h#p b@t 0 !-' ie $( m! tc d n! $%i *33 'l dun! d&ch CuSC + am. Sau Zhi ph.n /n! ho(n to(n thu "#c dun! d&ch 4 cF ch/a hai 'ui $( 1*,1 !a' cht r?n 5. Cho 4 tc d n! $%i dun! d&ch DaCG d", ly ZRt t:a e' nun! nFn! tron! ZhAn! Zh9 t%i Zhi l"#n! ZhAn! _i thu "#c 11,3 !a' cht r?n. ai tr& c:a a l( A. 1,*. B. 1,3. C. 3,I. D. 3,I*. Cu 46: Cho cc cht sau Ny: J1K CG 3CCCGh J1K C1G*CGh J3K C1G1h J+K CG3CCCDah J*K GCCCCGLCG1h J)K CG3CCCDG+. rwy !-' cc cht "#c tPo ra tX CG3CGC ch| bSn! '@t ph.n /n! l( A. 1, 1, +, ). B. 1, 1, 3, +, *, ). C. 1, 1. D. 1, 1, ). Cu 47: rwy !-' cc Zi' loPi Qu tc d n! "#c $%i dun! d&ch G 1SC+ lown! nh"n! ZhAn! tc d n! $%i dun! d&ch G1SC+ Hc, n!u@i l( A. ie, Tl, Cr. B. Cu, ie, Tl. C. ie, m!, Tl. D. Cu, Mb, T!. Cu 48: Go( tan ie3C+ tron! l"#n! d" dun! d&ch G1SC+ lown! thu "#c dun! d&ch 0. run! d&ch 0 tc d n! "#c $%i bao nhi;u cht tron! s cc cht sau: Cu, DaCG, qr1, T!DC3, gmnC+, m!SC+, m!JDC3K1, Tlx A. *. B. I. C. k. D. ). Cu 49: Cho 31,)+ !a' hjn h#p 0 !-' ieC, ie 3C+, ie1C3 tc d n! $%i dun! d&ch GCl d" thu "#c dun! d&ch cF ch/a )3,ll 'ui. DRu cho hjn h#p 0 tr;n tc d n! $%i l"#n! d&ch d&ch 4 cF ch/a GCl, G 1SC+ lown! $Xa :, thu "#c dun! d&ch cF ch/a I3,I+ !a' 'ui. Cc ph.n /n! ho(n to(n, t| lB 'ol !ida GCl $( G 1SC+ cF tron! dun! d&ch 4 l( A. 132l. B. l213. C. *23. D. 1I213. Cu 50: Cho )I1 'l Zh9 Clo JZtcK i Uua 133 'l dun! d&ch gCG o 1333C. Sau Zhi ph.n /n! x.y ra ho(n to(n thu "#c dun! d&ch 0 cF pG L 13. 6h> t9ch dun! d&ch ZhAn! thay _i tron! Uu trVnh ph.n /n!, l"#n! cht r?n thu "#c Zhi cA cPn dun! d&ch 0 l( A. ),3I !a'. B. 1,lI !a'. C. 3,3l !a'. D. +,l* !a'. B S 24 Cu 1: G}a tan hRt 1l,l !a' hjn h#p !-' Da, g, qa $(o n"%c thu "#c + l9t dun! d&ch 0 cF pG L 13. 6run! h}a dun! d&ch 0 bSn! axit G1SC+ $Xa : sau ph.n /n! thu "#c 13,3 !a' ZRt t:a. Mh`n tr^' Zhi l"#n! c:a Da tron! hjn h#p tr;n l( A. 11,*). B. 1). C. 1I,k. D. )1,**.
Cu 2: Cho 13,11 !a' hjn h#p 0 !-' ie, ie3C+, ie1C3 $(o dun! d&ch GDC3 lown!, d" thu "#c s.n ph8' Zhb !-' hai Zh9 DC, D1C cF th> t9ch f l9t JZtcK $( cF t| Zhi so $%i G 1 l( 1k,*. mHt Zhc nRu cho c=n! l"#n! 0 tr;n tc d n! $%i Zh9 CC d" thV sau Zhi ph.n /n! ho(n to(n thu "#c l,k !a' ie. ai tr& c:a f l( A. 3,++k. B. 3,3). C. 1,1+. D. 3,13). Cu 3: CNu n(o sau Ny l( On! Zhi nFi $Q hiBu /n! nh( Z9nh $( '"a axitx A. gh9 !Ny ra hiBu /n! nh( Z9nh l( SC1 $( Zh9 !Ny ra '"a axit l( CC1h DC1 B. gh9 !Ny ra hiBu /n! nh( Z9nh l( DC1 $( Zh9 !Ny ra '"a axit l( SC1h CC1 C. gh9 !Ny ra hiBu /n! nh( Z9nh l( CC1 $( Zh9 !Ny ra '"a axit l( SC1h DC1 D. gh9 !Ny ra hiBu /n! nh( Z9nh l( SC1h CC1 $( Zh9 !Ny ra '"a axit l( DC1 Cu 4: Mht bi>u !"n l( A. D!"pi ta sb d n! ozon > t8y tr?n! tinh b@t $( dù ^n. B. C1 cF t9nh oxi hFa 'Pnh h,n C3 C. C1 $( C3 cF t9nh oxi hFa 'Pnh nh" nhau. D. trPn! thi r?n, DaCl t-n tPi d"%i dPn! tinh th> phNn tb. Cu 5: G}a tan ho(n to(n ' !a' hjn h#p !-' Da, qa, g $(o n"%c thu "#c x !a' Zh9 G 1. DRu cho ' !a' hjn h#p tr;n tc d n! $%i dun! d&ch GCl d", r-i cA cPn dun! d&ch sau ph.n /n! thV Zhi l"#n! 'ui Zhan thu "#c l( A. J' \ 3*,*xK !a'. B. J' \ 1+1xK !a'. C. J' \ 1I,I*xK !a'. D. J' \ I1xK !a'. Cu 6: qVnh Z9n cF th> t9ch ZhAn! _i l( 3,* l9t ch/a 3,* 'ol G 1 $( 3,* 'ol D1 o t3C, Zhi o trPn! thi cNn bSn! cF 3,1 'ol DG3 "#c tPo th(nh. ai tr& c:a hSn! s cNn bSn! g l( A. +,1*. B. 11,*. C. 3,31. D. 3,11*. Cu 7: CF bao nhi;u cht l( dn xut c:a benzen cF cAn! th/c phNn tb C kG13C Zhi b& oxi hFa boi CuC un nFn! cho s.n ph8' cF Zh. n^n! tha' !ia ph.n /n! trn! bPcx A. +. B. 3. C. *. D. 1. Cu 8: Cho CrJ5 L 1+K, CuJ5 L 1lK, ie J5 L 1)K, qr J5 L 3*K. Cu hVnh e sai l( A. Cr: 1s11s11p)3s13p)3d*+s1 B. qr: 1s11s11p)3s13p)3d13+s1+p) C. ie3\ : 1s11s11p)3s13p)3d* D. Cu\: 1s11s11p)3s13p)3dl+s1 Cu 9: Dun! nFn! a 'ol hjn h#p 0 !-' C 1G1 $( G1 tron! bVnh Z9n cF xOc tc th9ch h#p thu "#c hjn h#p Zh9 4. rn 4 Uua l"#n! d" dun! d&ch T!DC 3 tron! DG3, sau Zhi ph.n /n! ho(n to(n thu "#c 1+ !a' ZRt t:a $( hjn h#p Zh9 5. Gjn h#p 5 l(' 't '(u ti a +3 !a' bro' tron! dun! d&ch $( c}n lPi hjn h#p Zh9 6. Et chy ho(n to(n 6 thu "#c 11,I !a' n"%c. fy !i tr& c:a a l( A. 1. B. 3,l. C. 1,1*. D. 1,*. Cu 10: ghi th:y phNn ZhAn! ho(n to(n pentapeptit Tla-aly-fal-aly-Tla "#c ti a bao nhi;u tripeptit Zhc nhaux A. +. B. 3. C. 1. D. 1. \ ) Cu 11: Cation m cF cu hVnh electron o l%p $ n!o(i c=n! l( 1p . f& tr9 c:a m tron! b.n! tu`n ho(n l( A. chu ZV 3, nhF' eeeT B. chu ZV 1, nhF' feeT C. chu ZV 3, nhF' eeT D. chu ZV 3, nhF' eT Cu 12: Go(n tan ho(n to(n k,1 !a' Tl bSn! dun! d&ch ch/a ' !a' DaCG Jd"K thu "#c dun! d&ch 0 . Cho l33 'l dun! d&ch GCl 1m $(o 0 thu "#c 1*,) !a' ZRt t:a. ai tr& l%n nht c:a ' l( A. 31. B. +3. C. 1+. D. )3. Cu 13: m@t anehit 'Pch ho 0 cF t| Zhi h,i so $%i G1 nh h,n 33. 0 ph.n /n! ti a $%i G1 theo t| lB 'ol 1:3. Cho 3,1 'ol 0 tc d n! $%i dun! d&ch T!DC3 d" tron! DG3 thV thu "#c bao nhi;u !a' cht r?nx A. 1l,+ !a'. B. +1 !a'. C. 3l,3 !a'. D. 11,) !a'. 3 Cu 14: E> h}a tan hRt '@t 'u Zn' tron! dun! d&ch GCl o 13 C c`n ) phOt. Czn! 'u Zn' F tan tron! dun! d&ch axit nFi tr;n o 333C tron! 3 phOt. Gi > h}a tan hRt 'u Zn' F tron! dun! d&ch axit nFi tr;n o k33C c`n thpi !ian bao lNux A. l,+* !iNy. B. *,)1* !iNy. C. +* !iNy. D. 1* !iNy. Cu 15: 0( ph}n! hFa +.1! este hdu c, no ,n ch/c 0 bSn! dd DaCG d" thu "#c +.I)! 'ui. CAn! th/c c:a 0 l( A. GCCCCG3 B. C1G*CCCCG3 C. CG3CCCCG3 D. CG3CCCC1G*
Cu 16: S?p xRp cc Zi' loPi sau theo chiQu t9nh Zi' loPi t^n! d`n: 0J5 L 1lKh 4J5 L 3IKh 5J5 L 13Kh 6J5 L 11K. A. 6, 0, 5, 4. B. D. 4, 0, 5, 6. C. 4, 5, 0, D. 6, 5, 0, 4. Cu 17: Cxi hFa 3,1 'ol '@t ancol ,n ch/c 0 bSn! C 1 cF xOc tc ph= h#p thu "#c +,+ !a' hjn h#p !-' anehit, ancol d" $( n"%c. GiBu sut c:a ph.n /n! oxi hFa ancol l( A. )*. B. +3. C. I*. D. *3. Cu 18: Dhdn! ion n(o sau Ny c=n! t-n tPi "#c tron! '@t dd: + 3+ A. S1 , Da + , Cl , Cu 1+ B. SC 1 + , Da , ie , CG + 1+ C. DC3 , Da + , Cl , Tl3+ D. SC 1 , MC3 + , Da , 5n + Cu 19: G}a tan 1,*I !a' hjn h#p b@t Zi' loPi !-' Tl, 5n $(o 133 'l dun! d&ch hjn h#p T!DC 3 3,1m $( CuJDC3K1 3,3m. Sau Zhi ph.n /n! x.y ra ho(n to(n thu "#c cht r?n 0 $( dun! d&ch 4 ch| ch/a hai 'ui. D!N' 0 tron! dun! d&ch G 1SC+ lown! ZhAn! thy cF Zh9 thot ra. Cho dun! d&ch DG 3 d" $(o 4 thV thu "#c bao nhi;u !a' ZRt t:ax A. 1,*) !a'. B. 1,l) !a'. C. 1,I+ !a'. D. 3,Ik !a'. Cu 20: CF bao nhi;u cht hdu c, 'Pch ho cF cAn! th/c phNn tb C 3GyC '( bSn! '@t ph.n /n! tPo ra propan1-olx A. *. B. 1. C. +. D. 3. Cu 21: Cho cc dun! d&ch: !lucoz,, Yructoz,, 'antoz,, saccaroz,, phenol, axit Yo'ic, axetanehit, ancol anlylic, anilin. S dun! d&ch o tr;n l(' 't '(u dun! d&ch bro' $%i dun! 'Ai n"%c l( A. I B. k C. ) D. * Cu 22: m@t loPi tinh b@t cF phNn tb Zhi bSn! k13333. S '?t x9ch tron! phNn tb tinh b@t nFi tr;n l( A. +*33 B. *3333 C. *333 D. +333. 1 Cu 23: CF bao nhi;u n!uy;n t nhF' q cF l%p electron n!o(i c=n! l( +s x A. k. B. 1. C. 13. D. 3. Cu 24: Cho '@t s t9nh cht : l( cht ZRt tinh ZhAn! '(u J1K h cF $& n!<t J1K h tan tron! n"%c J3K h ho( tan CuJCGK1 J+K h l(' 't '(u n"%c bro' J*K h tha' !ia ph.n /n! trn! bPc J)K . Cc t9nh cht c:a saccaroz, l( A. J1K, J1K, 3K, J+K $( J*K. B. J1K, J1K, J3K $( J+K. C. J1K, J3K, J+K, J*K $( J)K. D. J1K, J1K, J3K, J+K, J*K $( J)K. Cu 25: Et chy ho(n to(n l,3 !a' hjn h#p 0 !-' hai este ,n ch/c tPo boi c=n! '@t axit cacboxylic $( hai ancol l( -n! n! ZR tiRp thu "#c 3,+* 'ol CC 1 $( 3,3* 'ol G1C. fy ph`n tr^' Zhi l"#n! c:a este cF phNn tb Zhi l%n h,n tron! 0 l( A. +),1+ B. *3,I). C. *3. D. )3. Cu 26: Dhn xt n(o sau Ny khn On!x A. 69nh axit t^n! d`n theo chiQu phenol, axit cacbonic, axit axetic, axit sunYuric. B. 69nh baz, t^n! d`n theo chiQu iphenyla'in, anilin, a'oniac, 'etyla'in. C. ci;n ZRt hiro !ida cc phNn tb axit axetic bQn h,n !ida cc phNn tb ancol etylic. D. CF th> d=n! dun! d&ch qaCl1 > phNn biBt hai Zh9 SC1 $( SC3. Cu 27: CF th> d=n! G1SC+ Hc > l(' ZhA cht n(o tron! cc cht sau Nyx A. Daqr. B. G1S. C. DG3. D. GCl. Cu 28: c"#n! d" dun! d&ch n(o sau Ny: J1K DaCGh J1K GCl, J3K T!DC 3h J+K ieJDC3K3 l(' sPch "#c T! cF ln Tl, 5nx A. Ch| J1K. B. Ch| J1K. C. J1K hoHc J1K hoHc J3K hoHc J+K. D. Ch| J3K. Cu 29: DhiBt phNn ho(n to(n ' !a' '@t 'ui a'oni c:a axit cacbonic sau F dn to(n b@ s.n ph8' $(o *3 !a' dun! d&ch G1SC+ 1l,) ch| tPo ra '@t 'ui axit. ai tr& c:a ' l( A. 1+,+. B. I,l. C. 11,1*. D. l,). Cu 30: Mht bi>u n(o sau Ny On!x A. Cho l}n! tr?n! tr/n! $(o CuJCGK1 cho ZRt t:a !Pch. B. 6ron! phNn tb peptit 'Pch ho ch/a n !c -a'inoaxit cF s li;n ZRt peptit bSn! n. C. ghAn! th> d=n! CuJCGK1 > phNn biBt dun! d&ch tripeptit $( dun! d&ch CG3CCCG. D. 6ron! phNn tb peptit 'Pch ho ch/a n !c -a'inoaxit cF s li;n ZRt peptit bSn! n-1.
Cu 31: Eun nFn! hjn h#p Zh9 0 !-' C 1G1, C1G+, CG1LCG-C-CG3, G1 tron! '@t bVnh Z9n dun! t9ch ZhAn! _i $( cF cht xOc tc th9ch h#p. Sau ph.n /n! "a bVnh $Q nhiBt @ ban ù thu "#c hjn h#p Zh9 4 ZhAn! ch/a G1 $( p sut tron! bVnh !i.' 13 so $%i ban ù. Mh`n tr^' th> t9ch G1 tron! hjn h#p ban ù l( A. *3. B. 33. C. 1*. D. 13. Cu 32: Cho cc cht: CG3CCCDa, Tl1JSC+K3, DaGSC+, Da1GMC+, Da1SC+, DaGCC3, Da1GMC3. CF bao nhi;u cht l( 'ui trun! h}ax A. *. B. 3. C. 1. D. +. Cu 33: Et chy ho(n to(n ' !a' hjn h#p 0 !-' hai ancol no, 'Pch ho JphNn tb h,n Z' nhau '@t nhF' -CGK thu "#c 3,3 'ol CC1 $( 3,* 'ol G1C. Cxi hFa ' !a' hjn h#p 0 thu "#c hjn h#p 4. Cho 4 tc d n! $%i l"#n! d" dun! d&ch T!DC3 tron! DG3 thu "#c a !a' T!. ai tr& l%n nht c:a a l( A. )+,k. B. +3,1. C. 13k. D. k),+. Cu 34: Eun nFn! hjn h#p !-' ie $( S cF t| lB 'ol 1:1 tron! bVnh Z9n ZhAn! ch/a ZhAn! Zh9 thu "#c hjn h#p 0 . Cho hjn h#p 0 tc d n! $%i dun! d&ch GCl d" Rn Zhi ph.n /n! x.y ra ho(n to(n thy Zhi l"#n! cht r?n !i.' )3. GiBu sut ph.n /n! !ida ie $( S l( A. *3. B. 1*. C. )3. D. k3. Cu 35: Cho ph.n /n!: CG3CGLCJCG3KCG3 \ g1Cr1CI \ G1SC+ s CG3CCCG \ CG3CCCG3 \ Cr1JSC+K3 \ g1SC+ \ G1C 6_n! cc hB s l( s n!uy;n nh nht /n! tr"%c cht Zhb $( cht oxi hFa > ph.n /n! tr;n cNn bSn! l( A. 1+. B. 1. C. ). D. *. Cu 36: Et chy '@t h#p cht hdu c, 0 Jch/a C,G,CK thu "#c G 1C $( CC1 cF s 'ol bSn! nhau thV 0 khn $h% l( A. axit cacboxylic no, 'Pch ho, ,n ch/c. B. ete no, 'Pch ho, a ch/c. C. este no, 'Pch ho, ,n ch/c. D. anehit no, 'Pch ho, ,n ch/c. Cu 37: 6ron! cc cht d"%i Ny, cht n(o l( ipeptit x A. G1D{CG1{CC{DG{CGJCG3K{CCCG. B. G1D{CG1{CC{DG{CGJCG3K{CC{DG{CG1{CCCG. C. G1D{CG1{CC{DG{CG1{CGJCG3K{CCCG. D. G1D{CGJCG3K{CC{DG{CG1{CG1{CCCG. Cu 38: m@t anehit 0 tron! F oxi chiR' 3I,11 $Q Zhi l"#n!. 1 'ol 0 tha' !ia ph.n /n! trn! bPc tPo ti a + 'ol T!. ghi l"#n! 'ui hdu c, sinh ra Zhi cho 3,1* 'ol 0 tc d n! $%i l"#n! d" T!DC 3 tron! dun! d&ch DG3 l( A. +1 !a'. B. 3+,* !a'. C. 33,1* !a'. D. 3k !a'. Cu 39: DhiBt phNn ho(n to(n hjn h#p 1 'ui gDC3 $( ieJDC3K1 sau ph.n /n! thu "#c hjn h#p 0 !-' hai Zh9 cF t| Zhi so $%i G1 bSn! 11,). Mh`n tr^' Zhi l"#n! c:a ieJDC3K1 l( A. )3. B. 3+,3. C. Ik,3l. D. +3. Cu 40: Gp th ho(n to(n 3,3) l9t Zh9 CC1 Jo ZtcK $(o ' !a' dun! d&ch hjn h#p ch/a 3,3* 'ol DaCGh 3,3* 'ol gCGh 3,3* 'ol qaJCGK1. run! d&ch sau ph.n /n! cF Zhi l"#n! A. J' - *,3*K !a'. B. J' \ ),)K !a'. C. J' - 11,)*K !a'. D. J' - 3,1*K !a'. Cu 41: 6ron! h#p cht sau Ny cF 'y li;n ZRt peptitx G1D-CG1-CC-DG-CG-CC-DG-CG-CC-DG-CG1-CG1-CCCG CG3 C)G* A. 1 B. 3 C. 1 D. + Cu 42: Cho k,** !a' dun! d&ch cacbohirat 0 tc d n! ho(n to(n $%i dun! d&ch GCl, r-i cho s.n ph8' thu "#c tc d n! $%i l"#n! d" T!DC 32DG3 tPo th(nh 13,k !a' T! ZRt t:a. 0 cF th> l( cht n(o tron! cc cht saux A. iructoz, B. alucoz, C. Saccaroz, D. 0enluloz, Cu 43: Gjn h#p 0 !-' G1 $( D1 cF Zhi l"#n! 'ol trun! bVnh bSn! I,1. Sau Zhi tiRn h(nh ph.n /n! t_n! h#p DG3 "#c hjn h#p 4 cF Zhi l"#n! 'ol trun! bVnh bSn! k, hiBu sut c:a ph.n /n! t_n! h#p l( x A. 1*. B. 13. C. 1*. D. 13. Cu 44: Cho *3 'l dun! d&ch ieCl1 1m $(o dun! d&ch T!DC3 d", Zhi l"#n! cht r?n thu "#c sau ph.n /n! l(: A. 1k,1*! B. 1l,I*! C. 1*,I*! D. 1+,3*!. 1\ 3 Cu 45: ghi cho cht n(o sau Ny tc d n! $%i G1C JG! h k3 CK tPo ra s.n ph8' l( xetonx
A. Mropilen B. Mropin C. ~tilen D. Txetilen Cu 46: Cho 3,1 'ol axit cacboxylic ,n ch/c 0 $( 133 'l dun! d&ch DaCG 3,km thV thu "#c dun! d&ch cF ch/a 1*,*1 !a' cht tan. fy cAn! th/c c:a axit cacboxylic 0 l( x A. CG3CCCG. B. GCCCG. C. C1G*CCCG. D. C1G3CCCG. Cu 47: Cho dun! d&ch qaJGCC3K1 l`n l"#t $(o cc dd sau: CaCl1 , CaJDC3K1 , DaCG, Da1CC3, gGSC+ , Da1SC+, CaJCGK1 , G1SC+, GCl s tr"pn! h#p cF ZRt t:a l( x A. I. B. +. C. ). D. *. Cu 48: gi' loPi Da "#c dun! l(' cht chuy>n $n nhiBt tron! cc l} hPt nhNn l( do: 1.gi' loPi Da d nFn! ch.y 1.Da dn nhiBt tt 3.Da cF t9nh Zhb rt 'Pnh A. Ch| cF 1 B. 1 $( 1 C. 1 $( 3 D. Ch| cF 1 Cu 49: S oxy ho c:a clo tron! cc h#p cht: GCl, gClC3, GClC, GClC1, GClC+ l`n l"#t l(: A. \1, \*, -1, \3, \I B. -1, \*, \1, -3, -I C. -1, \*, \1, \3, \I D. -1, -*, -1, -3, -I Cu 50: n! $%i cAn! th/c C3GkCn cF bao nhi;u -n! phNn ch| ch/a nhF' ch/c {CG tron! phNn tb cF th> ho( tan "#c CuJCGK1 x A. 1 B. 1 C. + D. 3 B S 25 Cu 1: Cho hjn h#p !-' ),+!a' Cu $( *,) !a' ie $(o cc Wn! dun! d&ch GCl lown! d". E> tc d n! hRt $%i cc cht cF tron! cc sau ph.n /n! $%i dun! d&ch GCl Js.n ph8' Zhb duy nht l( DCK, c`n 9t nht Zhi l"#n! DaDC3 l( A. 1,k!a'. B. 1I!a'. C. *,I!a'. D. k,*!a'. Cu 2: Et chy ho(n to(n 3,1 'ol cht hdu c, 0 l( dn xut c:a benzen thu "#c CC 1 cF Zhi l"#n! nh h,n 3*,1 !a'. qiRt rSn! a J'olK 0 ph.n /n! $Xa : $%i *33 'l dun! d&ch DaCG 1aJmK. CAn! th/c cu tPo c:a 0 l( A. GC-CG1-C)G+-CCCG. B. C)G*-CG1CG. C. GC-C)G+-CG1CG. D. C)G+JCGK1. Cu 3: Cho ph.n /n! oxi hFa - Zhb sau: 0 \ GDC3 Hc, nFn! s ... \ DC1 \ .... J1K. EHt Z L s 'ol DC1 2 s 'ol 0. DRu 0 l( : 5n, S $( ieS thV Z nhn cc !i tr& t",n! /n! l(: A. 1h )h I B. 1h *h l C. 1h )h l D. 1h )h I Cu 4: CF dun! d&ch 0 !-' Jge $( '@t 9t h- tinh b@tK. Cho l`n l"#t tXn! cht sau: C 3, Cl1, G1C1, ieCl3, T!DC3 tc d n! $%i dun! d&ch 0. S cht l(' dun! d&ch 0 chuy>n san! '(u xanh l( A. + cht B. * cht C. 3 cht D. 1 chNt Cu 5: Cho cc cht sau: phenol, Zh9 sunYur,, toluen, ancol benzylic, isopren, axit 'etacrylic, $inyl axetat, phenyl a'in, axit benzoic. S cht ph.n /n! "#c $%i dun! d&ch n"%c bro' o nhiBt @ th"pn! l( A. *. B. ). C. 3. D. +. Cu 6: rwy !-' cc cht n(o sau Ny Qu cF t9nh l"n! t9nh x A. TlCl3, G1C, DaGCC3, 5nJCGK1, 5nC B. G1C, 5nJCGK1, GCCC-CCCDa, G1DCG1CCCG, DaGCC3 C. Tl, DaGCC3, DaTlC1, 5nC, qeJCGK1 D. 5nCl1, TlCl3, DaTlC1, DaGCC3, G1DCG1CCCG Cu 7: Et chy ho(n to(n 1+,k !a' hjn h#p 0 !-' CG3CCCG, CxGyCCCG $( JCCCGK1 thu "#c 3,+ 'ol G1C $( ' !a' CC1. Czn! cho 1+,k !a' 0 tc d n! $%i l"#n! d" DaGCC3 thu "#c 3,1* 'ol CC1. ai tr& c:a ' l( A. 1),* B. 11 C. *,* D. 11 Cu 8: Cho hjn h#p !-' 3,1 'ol GCGC h 3,1 'ol GCC-CGCh 3,1 'ol GCC-CG 3 $( 3,1 'ol GCCCG tc d n! $%i l"#n! d" dun! d&ch T!DC32DG3 thu "#c Zhi l"#n! T! l(: A. 11l,)! B. k),+! C. 13k! D. 11)! Cu 9: G#p cht C1G+C1 cF 3 -n! phNn 'Pch ho. Cho cc -n! phNn F l`n l"#t tc d n! $%i: DaCG, Da, T!DC32DG3 thV s ph",n! trVnh ph.n /n! x.y ra l( A. * B. ) C. I. D. +. 3* 3I Cu 10: D!uy;n tb Zhi trun! bVnh c:a Clo bSn! 3*,*. Clo cF hai -n! $& 1I Cl $( 1I Cl . Mh`n tr^' Zhi l"#n! 3* c:a 1I Cl cF tron! axit pecloric l( !i tr& n(o sau Nyx Jcho GL1h CL1)K A. 1),11 B. 1I,1 C. 33,11 D. 1),l1
Cu 11: Cho 11,k !a' a'in ,n ch/c 0 tc d n! $Xa : $%i dun! d&ch GCl, sau Zhi ph.n /n! x.y ra ho(n to(n thu "#c dun! d&ch 4. c(' bay h,i dun! d&ch 4 "#c 1l,1 !a' 'ui Zhan. S cAn! th/c cu tPo /n! $%i cAn! th/c phNn tb c:a 0 l( A. * B. + C. ) D. 3 Cu 12: Gjn h#p 0 !-' 1 anehit ,n ch/c T, q. ghi cho 1,+1 !a' hjn h#p 0 $(o dun! d&ch T!DC 32DG3 d" thu "#c k,)+ !a' T!. Giro hFa ho(n to(n 1,+1 !a' hjn h#p 0 th(nh hjn h#p ancol 4. Cho to(n b@ hjn h#p 4 $(o bVnh Wn! Da d" thu "#c 3,33) l9t G1 JZtcK. CAn! th/c c:a T, q l`n l"#t l(. A. GCGC $( CG1LCG-CGC B. GCGC $( CG3-CG1-CGC C. CG3CGC $( CG1LCG-CGC D. CG1LCG-CGC $( CG3CGC Cu 13: Cho cc cht: T!DC3, CuJDC3K1, m!CC3, qaJGCC3K1, DG+GCC3, DG+DC3 $( ieJDC3K1. DRu nun! cc cht tr;n Rn Zhi l"#n! ZhAn! _i tron! cc bVnh Z9n ZhAn! cF ZhAn! Zh9, r-i cho n"%c $(o cc bVnh, s bVnh cF th> tPo lPi cht ban ù sau cc th9 n!hiB' l( A. 3. B. ). C. +. D. *. Cu 14: DhF' !-' tt c. cc cht cF Zh. n^n! l(' nhPt '(u dun! d&ch n"%c bro' l(: A. axit acrylic, !lucoz,, phenol, Yructoz,. B. axit acrylic, phenol, anZen, !lucozo. C. 'antoz,, saccaroz,, anilin, ancol anlylic. D. axit 'etacrylic, anZen, cu'en, andehit axetic. Cu 15: Cho 1I,3+ !a' hjn h#p r?n T !-' Ca, m!C, Da 1C tc d n! hRt $%i I13 'l dun! d&ch GCl 1m J$Xa :K thu "#c dun! d&ch T. ghi l"#n! 'ui DaCl cF tron! dun! dich T l( A. 1+,3+!. B. 1*,11!. C. +,)k!. D. k,II*! Cu 16: Cho 1 'ol Ca3JMC+K1 tc d n! $%i 1,I* 'ol GCl thV ph",n! trVnh ph.n /n! cF t_n! cc hB s n!uy;n ti !i.n bSn! bao nhi;ux A. B . 31 C . +1 D . *+ Cu 17: Et chy ho(n to(n hjn h#p !-' etanol $( phenol cF t| lB 'ol 3:1, cho to(n b@ s.n ph8' chy $(o bVnh Wn! dun! d&ch n"%c $Ai tron! thV thu "#c 1* !a' ZRt t:a, ly dun! d&ch sau ph.n /n! tc d n! $%i dun! d&ch DaCG d" thV thu "#c I,* !a' ZRt t:a nda. ghi l"#n! bVnh Wn! dun! d&ch n"%c $Ai sn A. t^n! 3,) !a' B. t^n! *,+ !a' C. t^n! 13,1 !a' D. t^n! 1k,) !a' Cu 18:Go( tan ho(n to(n 1+,+ !a' hjn h#p !-' ieCl 1 $( DaClJcF t| lB s 'ol t",n! /n! l( 1: 1K $(o '@t l"#n! n"%c d" thu "#c dun! d&ch 0. Cho dun! d&ch T!DC 3 d" $(o dun! d&ch 0, sau Zhi ph.n /n! x.y ra ho(n to(n sinh ra "#c ' !a' cht r?n. ai tr& c:a ' l(: A. 1k,I! B. *I,+! C. 13,k ! D. )k,1! Cu 19: Cho h,i n"%c i Uua than nFn! thu "#c Ik,+ l9t hjn h#p Zh9 0Jo ZtcK !-' Zh9 CC, CC 1, G1. ghb hRt 121 hjn h#p 0 bSn! CuC d" nun! nFn! thu "#c cht r?n 4. Go( tan ho(n to(n 4 tron! dun! d&ch GDC 3 lown! thu "#c 11,+l9t Jo ZtcK Zh9 DCJ s.n ph8' Zhb duy nhtK. Mh`n tr^' th> t9ch Zh9 CC tron! 0 l(: A. 1k,*I B. 1k,+1 C. *I,1* D. 1+,1k Cu 20: Et chy ho(n to(n +,kI1 !a' '@t hirocacbon 0, dn s.n ph8' chy Uua bVnh Wn! dun! d&ch n"%c $Ai tron!. Sau ph.n /n! thu "#c 1I,l3 !a' ZRt t:a $( thy Zhi l"#n! dun! d&ch !i.' *,*k) !a'. CAn! th/c phNn tb c:a 0 l( A. C3G) B. C+Gk C. CG+ D. C+G13 Cu 21: Go( tan hRt aJ!K oxit mC Jm cF ho tr& 1 ZhAn! _iK bSn! '@t l"#n! $Xa : dun! d&ch G 1SC+ 1I,* thu "#c dun! d&ch 'ui cF n-n! @ 13. Gwy cho biRt, Zhi cho Zh9 CC d" i Uua n! s/ Wn! 11 !a' oxit mC thu "#c bao nhi;u !a' cht r?n x A. 11. B. l,) !a' C. *,+ !a' D. I,1 !a' Cu 22: Et chy hRt ' !a' hjn h#p 0 !-' hai anehit ,n ch/c, 'Pch ho Jc m t li!n k"t #$i C % C trong &h'n t(K thu "#c fl9t Zh9 CC1 o Ztc $( a !a' G1C. qi>u th/c li;n hB !ida 'h a $( f l( *f la *f Ia +f Ia + + + A. ' L B. ' L C. ' L D. ' L + I + l * l +f la + * I Cu 23: Cho cc cht sau: toluen, etilen, xiclopropan, stiren, $inylaxetilen, etanal, i'etyl xeton, propilen. S cht l(' 't '(u dun! d&ch gmnC+ o nhiBt @ th"pn! l( A. I. B. *. C. ). D. +.
Cu 24: 6ron! s cc loPi t, sau: t, tS', t, $isco, t, nilon-),), t, axetat, t, capron, t, enan!. Dhdn! loPi t, n(o thu@c loPi t, nhNn tPo l(: A. 6, nilon { ),) $( t, capron. B. 6, tS' $( t, enan!. C. 6, $isco $( t, nilon-),). D. 6, $isco $( t, axetat. Cu 25: Dhdn! d n! c nh( bRp sau Zhi nu c, nu c th"pn! > lPi '=i tanh. E> loPi hRt '=i tanh '@t cch tt nht n;n d=n!: A. 0( ph}n! B. ai' Jaxit axeticK C. 0A a JDa1CC3K D. Tncoletylic Cu 26: 6huy phNn ho(n to(n 1 'ol pentapeptit T thV thu "#c 3 'ol !lyxinh 1 'ol alanin $( 1'ol $alin. ghi thuy phNn ZhAn! ho(n to(n T thV tron! hjn h#p s.n ph8' thy cF cc ipeptit Tla-alyh aly-Tla $( tripeptit aly-aly-fal. T'ino axit ù D, a'ino axit ù C o pentapeptit T l`n l"#t l(: A. Tla, fal. B. aly, aly. C. Tla, aly. D. aly, fal. Cu 27: D!uy;n t 0 cF I eletron p. D!uy;n t 4 cF t_n! s hPt 'an! iBn nhi;u h,n s hPt 'an! iBn c:a 0 l( k hPt. 6ron! h#p cht !ida 0 $( 4 cF bao nhi;u electronx A. *+ B. 33 C. 3) D. )+ Cu 28: Cho cc nhn xt sau: J1K G#p cht G 1D-CG1CG1CCDG-CG1CCDG-CG1CCCG ch/a 1 li;n ZRt peptitt h J1K MhNn tb Zhi c:a '@t a'ino axit ch/a 1 nhF' {DG 1 $( 1 nhF' {CCCG tron! phNn tb luAn l( s ln h J3K Cc peptit Qu tc d n! $%i CuJCGK1 tron! 'Ai tr"pn! ZiQ' tPo ra h#p cht '(u t9' h J+K 6ripeptit l( h#p cht '( phNn tb ch/a 3 li;n ZRt peptit h J*K dun! d&ch c:a anilin ZhAn! l(' xanh Uu[ t9'. S nhn xt On! l(: A. 1 B. 3 C. + D. * Cu 29: Cho ' !a' hjn h#p 1 a'ino axit Jtron! phNn tb ch| ch/a 1 nhF' a'ino $( 1 nhF' cacboxylK tc d n! $%i 133 'l dun! d&ch GCl 1,1m thu "#c dun! d&ch 0. E> ph.n /n! hRt $%i cc cht tron! dun! d&ch 0 c`n d=n! 133 !a' dun! d&ch DaCG 1),k thu "#c dun! d&ch 4. CA cPn dun! d&ch 4 thu "#c 3+,3I !a' cht r?n Zhan. ai tr& c:a ' l(: A. 1k,1 !a' B. 1I,1 !a' C. 1*,1 !a' D. 1),1 !a' Cu 30: Cation 03\ $( anion 41- Qu cF cu hVnh electron o phNn l%p n!o(i c=n! l( 1p ). f& tr9 c:a 0 $( 4 tron! b.n! tu`n ho(n l`n l"#t l(: A. 0 o chu ZV 1, nhF' eeT $( 4 o chu ZV 3, nhF' feT. B. 0 o chu ZV 3, nhF' eeeT $( 4 o chu ZV 1, nhF' feT. C. 0 o chu ZV 1, nhF' eeeT $( 4 o chu ZV 1, nhF' efT. D. 0 o chu ZV 3, nhF' eeT $( 4 o chu ZV 3, nhF' feT. Cu 31: Gjn h#p 0 cF C1G*CG, C1G*CCCG, CG3CGC tron! F C1G*CG chiR' *3 theo s 'ol. Et chy ' !a' hjn h#p 0 thu "#c 3,3) !a' G1C $( 3,13) l9t CC1 JZtcK. mHt Zhc 13,1 !a' hjn h#p 0 thWc hiBn ph.n /n! trn! bPc thy cF p !a' T! ZRt t:a. ai tr& c:a p l( A. 1,1). B. l,I1. C. k,)+. D. 13,k. \ 1\ 3\ 1Cu 32: m@t dun! d&ch T ch/a: g , m! , Tl $( SC+ . Cho I* 'l dun! d&ch T tc d n! l"#n! d" qaCl 1 tPo th(nh **,l1! ZRt t:a. qiRt cc cation tron! T cF t| lB 'ol 1 : 1 : 1. CA cPn I*'l dun! d&ch T "#c Zhi l"#n! 'ui Zhan l(: A. 1k,++ !a' B. 1*,33 !a' C. 13,3+ !a' D. 1l,kk !a' Cu 33: Go( tan hRt hjn h#p r?n !-' CaC1, Tl+C3 $( Ca $(o G1C thu "#c 3,3) l9t hjn h#p Zh9 0 cF t| Zhi so $%i hiro bSn! 13. rn 0 Uua Di un nFn! thu "#c hjn h#p Zh9 4. 6iRp t c cho 4 Uua bVnh Wn! n"%c bro' d" thV cF 3,Ik+ l9t hjn h#p Zh9 5 Jt| Zhi h,i so $%i Ge bSn! ),*K. Cc Zh9 o o iQu ZiBn ti;u chu8n. ghi l"#n! bVnh bro' t^n! l( A. 1,3* !a' B. 1,3l !a' C. 3,l1 !a' D. 3,+*!a' Cu 34: run! d&ch CG3CCCG cF @ iBn li L 1, n-n! @ CT, pG L a. run! d&ch DG3 cF @ iBn li L 3,1, n-n! @ Cq, pG L b. Cho b L a \ k.7uan hB CT2Cqx A. CT L Cq \k B. CTL 12Cq C. Cq L 13CT D. CT L kCq Cu 35: EiBn phNn cF '(n! n!^n *33 'l dun! d&ch ch/a hjn h#p !-' ieCl 3 3,1m $( CuCl1 3,3k m JiBn cWc tr,, hiBu sut iBn phNn 133K $%i c"pn! @ d}n! iBn *T tron! +* phOt 1 !iNy. 6Pi catot sau iBn phNn thu "#c A. 1,*)k lit Zh9 B. 3,)k !a' Zi' loPi C. 3,11 !a' Zi' loPi D. 1,k+ !a' Zi' loPi Cu 36: Cho cc cHp ph.n /n! sau:
a. SC1 \ C1 b. G1S \ Cl1 \ G1C c. SC1 \ G1S &. SC1 \ qr1 \ G1C e. S \ G1SC+ Hc nFn! '. S \ i1 S ph.n /n! tPo ra s.n ph8' ch/a l"u hu[nh o '/c oxi hFa \) l(: A. 1 B.3 C.+ D.* Cu 37: Cxi ho 1*,) !a' CG3CG JcF xOc tcK thu "#c hjn h#p s.n ph8' 0. Chia 0 th(nh hai ph`n bSn! nhau Mh`n 1 tc d n! $%i T!DC3 d" tron! DG3 un nFn! thu "#c ' !a' T!. Mh`n 1 tc d n! $Xa : $%i 133'l dun! d&ch gCG 1m. GiBu sut Uu trVnh oxi ho CG3CG l( I*. ai tr& c:a ' l( A. 11l,). B. )+,k. C. 31,+. D. 13k. Cu 38: Dun! nFn! hjn h#p !-' *,) !a' ie $%i + !a' b@t S tron! bVnh Z9n '@t thpi !ian "#c hjn h#p 0 !-' ieS, ieS1, ie $( S d". Cho 0 tan hRt tron! dun! d&ch G1SC+ Hc, nFn! d" "#c f l9t Zh9 JZtc K. ai tr& c:a f l( A. 11,I) B. k,l) C. 3,3) D. 11,)* Cu 39: 6hWc hiBn cc th9 n!hiB' sau: J1K S c Zh9 C1G+ $(o dun! d&ch gmnC+. J1K S c CC1 d" $(o dun! d&ch DaTlC1 J3K ChiRu sn! $(o hjn h#p Zh9 JCG+h Cl1K. J+K S c Zh9 G1S $(o dun! d&ch ieCl3. J*K S c Zh9 DG3 $(o dun! d&ch TlCl3. J)K S c Zh9 SC1 $(o dun! d&ch G1S. S th9 n!hiB' cF ph.n /n! oxi ho- Zhb x.y ra l( A. 1,+,*,). B. 1,1,+,* C. 1,3,+,). D. 1,1,3,+. Cu 40: m@t hjn h#p T !-' qa $( Tl. Cho ' !a' T tc d n! $%i n"%c d", thu "#c 1,3++ l9t Zh9, dun! d&ch q. Cho 1' !a' T tc d n! $%i dun! d&ch qaJCGK 1 d" thu "#c 13,k31 l9t Zh9. JCc ph.n /n! Qu x.y ra ho(n to(n, cc th> t9ch Zh9 o o iQu ZiBn ti;u chu8nK. ai tr& c:a ' l( A. 11,11 B. 13,1** C. 11,k** D. 1I,1 \ 1\ Cu 41: Cho Zi' loPi qa Jd"K $(o dun! d&ch cF ch/a cc ion: DG+ , GCC3 , SC+ , g . S ph",n! trVnh ph.n /n! JdPn! ion thu !<nK ti a cF th> x.y ra l( A. 3 B. ) C. * D. + Cu 42: Cho s, - biRn _i sau: JDG+K1Cr1CI Cr1C3 Cr CrCl1 CrJCGK1 CrJCGK3 g1CrC+ g1Cr1CI Cr1JSC+K3. 6_n! s ph.n /n! thu@c loPi oxi hFa - Zhb tron! dwy biRn _i tr;n l(: A. ) B. I C. * D. + Cu 43: mui T cF cAn! th/c l( C 3G13C3D1, ly I,31 !a' T ph.n /n! hRt $%i 1*3'l dun! d&ch gCG 3,*m. CA cPn dun! d&ch sau ph.n /n! thV "#c ph`n h,i $( ph`n cht r?n, tron! ph`n h,i cF 1 cht hdu c, bc 3, tron! ph`n r?n ch| l( cht $A c,. ghi l"#n! cht r?n l(: A. ),3) !. B. ),l3 !. C. 11,*1 !. D. l,+1 !. Cu 44: Cho -a'ino axit 'Pch thn! 0 cF cAn! th/c G1DJCCCGK1 ph.n /n! $Xa : $%i 3,1 'ol DaCG tPo l,** !a' 'ui. 0 l(: A. axit 1-a'inobutan#ioic B. axit 1-a'inopropan#ioic C. axit 1-a'inohexan#ioic D. axit 1-a'inopentan#ioic Cu 45: Dun! ' !a' hjn h#p 0 !-' gClC 3 $( gmnC+ thu "#c cht r?n 4 $( C 1. qiRt gClC3 phNn huy ho(n to(n, c}n gmnC+ ch| b& phNn huy '@t ph`n. 6ron! 4 cF 3,kl+ !a' gCl chiR' k,131 theo Zhi l"#n!. 6r@n l"#n! C1 o tr;n $%i ZhAn! Zh9 theo t| lB th> t9ch )O1 : )** L1:3 tron! '@t bVnh Z9n ta thu "#c hjn h#p Zh9 5. Cho $(o bVnh 3,*1k !a' cacbon r-i t chy hRt cacbon, ph.n /n! ho(n to(n, thu "#c hjn h#p Zh9 6 !-' 3 Zh9 C1, D1, CC1, tron! F CC1 chiR' 11,l1 th> t9ch. ai tr& ' J!a'K l( A. 11,l1 B. 11,*3 C. 11,I3 D. 11,*l Cu 46: 6_n! s -n! phNn cu tPo ch/c axit $( este c:a h#p cht cF cAn! th/c phNn tb C3G)C1 l( A. 1. B. 1. C. +. D. 3 Cu 47: Gjn h#p hai Zi' loPi m! $( g $%i t| lB s 'ol t",n! /n! 1 : 3 tc d n! $%i dun! d&ch GDC 3 d" tPo s.n ph8' duy nht do sW Zhb D \* l( D1C thV ph",n! trVnh ion thu !<n cF t_n! hB s n!uy;n ti !i.n c:a cc cht tPo th(nh l( : A. )k B. )I C. )1 D. I) Cu 48: Gjn h#p 0 cF 1 hirocacbon -n! n! li;n tiRp, cF t| Zhi h,i so $%i G 1 bSn! 1*,k. cy ),31 !a' 0 l@i $(o 133 !a' dun! d&ch ch/a xOc tc th9ch h#p thV thu "#c dun! d&ch 5 $( thy thot ra 1,)kk l9t Zh9 ZhA 4
o iQu ZiBn ti;u chu8n cF t| Zhi h,i so $%i G1 bSn! 1),*. qiRt rSn! dun! d&ch 5 ch/a anehit $%i n-n! @ C. ai tr& c:a C l(: A. 1,33* B. 1,+3I C. 1,13k D. 1,3+3 Cu 49: Cho Uu[ t9' $(o l`n l"#t cc dun! d&ch: CG 3CCCg, ieCl3, DG+DC3, g1S, 5nJDC3K1, Da1CC3. S dun! d&ch l(' _i '(u !iy Uu[ l( A. ) B. * C. 3 D. + Cu 50: Gjn h#p 0 !-' axetilen 3,1* 'ol, $inylaxetilen 3,1 'ol, etilen 3,1 'ol $( hiro 3,+ 'ol. Dun! 0 $%i xOc tc niZen '@t thpi !ian thu "#c hjn h#p 4 cF t| Zhi i $%i hiro bSn! 11,I. Gjn h#p 4 ph.n /n! $Xa : $%i dun! d&ch ch/a a 'ol qr1. a9a tr& c:a a l(: A. 3,3* B. 3,)* C. 3,+* D. 3,1* B S 26 Cu 1: 6run! ho( 13,l !a' hjn h#p phenol $( p-crezol c`n 133 'l dun! d&ch DaCG 1m. 6h(nh ph`n tr^' Zhi l"#n! c:a phenol tron! hjn h#p l( A. +,I. B. )I,*. C. 1*,3. D. 11,*. Cu 2: rwy !-' cc cht Qu cF nhiBt @ sAi cao nht so $%i cc -n! phNn c:a nF l(: A. axit axetic, etanol, axeton. B. etyl axetat, etanol, axeton. C. axit axetic, etanol, ancol anlylic. D. etyl axetat, etanol, propanal. Cu 3: Cht n(o sau Ny Zhi tc d n! $%i dun! d&ch qaJCGK1 !i.i phFn! Zh9x A. Tl. B. Cr1C3. C. Cr. D. Tl1C3. Cu 4: 6h/ tW b& Zhb o catot Zhi iBn phNn JbSn! cc iBn cWc tr,K dun! d&ch ch/a cc ion Cu 1\, ie3\, T!\, Tu3\ l`n l"#t l(: A. Tu3\, T!\, Cu1\, ie3\. B. Tu3\, T!\, ie3\, Cu1\. 3\ 3\ \ 1\ C. Tu , ie , T! , Cu . D. ie3\, Cu1\, T!\, Tu3\. Cu 5: Ei>' !in! nhau !ida li;n ZRt Zi' loPi $( li;n ZRt ion l(: A. EQu "#c tPo th(nh nhp cHp electron d=n! chun!. B. EQu "#c tPo th(nh bSn! lWc hOt tnh iBn !ida ion d",n! $( cc electron tW do. C. EQu "#c tPo th(nh bSn! lWc hOt tnh iBn !ida cc n!uy;n tb $( ion 'an! iBn t9ch tri du. D. EQu "#c tPo th(nh bSn! lWc hOt tnh iBn !ida cc ti>u phNn 'an! iBn t9ch tri du. Cu 6: D!uy;n t n(o sau Ny cF n^n! l"#n! ion ho nh nhtx A. g. B. Cs. C. ci. D. Da. Cu 7: Cho '@t s Hc i>' sau Ny nFi $Q n"%c c/n! tP' thpi $( n"%c c/n! $nh cbu: J1K 6Po ZRt t:a Zhi tc d n! $%i DaCG. J1K c(' hao tn x( ph}n! Zhi !iHt rba. J3K 6Po ZRt t:a Zhi tc d n! $%i Da3MC+. J+K CF ch/a cc cation m!1\, Ca1\. 6t c. nhdn! Hc i>' chun! c:a n"%c c/n! tP' thpi $( $nh cbu l(: A. J1K, J1K, J3K. B. J1K, J3K, J+K. C. J1K, J1K, J+K. D. J1K, J1K, J3K, J+K. Cu 8: Eun hjn h#p !-' !lixerol $%i hjn h#p cc axit: pan'itic, stearic, oleic JxOc tc G1SC+ HcK cF th> tPo ra bao nhi;u loPi este 3 ch/c A. 1k. B. 11. C. 1*. D. l. Cu 9: rwy !-' cc Zi' loPi n(o sau Ny Qu cF th> tan "#c tron! n"%c o nhiBt @ th"pn!x A. qa, g, Da, Sr. B. g, Da, ie, Tl. C. Da, g, m!, Ca. D. g, Da, 5n, Tl. Cu 10: Cho 11,l !a' este 0 cF cAn! th/c C +G)C1 tc d n! $%i 1*3 'l dun! d&ch DaCG 1,1*m. CA cPn dun! d&ch sau ph.n /n! "#c 1*,) !a' cht r?n Zhan. 6;n !<i 0 l( A. 'etyl acrylat. B. etyl acrylat. C. $inyl axetat. D. anlyl axetat. Cu 11: Cho 1* !a' Yo'alin tc d n! ho(n to(n $%i l"#n! d" CuJCGK 1 tron! dun! d&ch DaCG thu "#c *+,I1 !a' ZRt t:a !Pch. D-n! @ ph`n tr^' c:a cht tan tron! Yo'alin nFi tr;n l( A. +3. B. 3*. C. 3k. D. 3l. Cu 12: E> iQu chR 3,3) l9t Zh9 Cl1 JZtcK tX cc cht DaCl, G1SC+, mnC1 thV c`n ' !a' DaCl. ai tr& c:a ' l( A. 3),13. B. 1I,**. C. k,II. D. 3I,*3.
Cu 13: Cho 3I,k1 !a' cht hdu c, 0 cF cAn! th/c phNn tb l( C 3G11C3D1 tc d n! $%i 3*3 'l dun! d&ch gCG 1m un nFn!, sau Zhi ph.n /n! x.y ra ho(n to(n thu "#c '@t Zh9 4 cF Zh. n^n! l(' xanh !iy Uu[ t9' 8' $( dun! d&ch 5. CA cPn dun! d&ch 5 thu "#c Zhi l"#n! cht r?n Zhan l( A. +I,1) !a'. B. +3,Ik !a'. C. +1,3l !a'. D. +I,13 !a'. Cu 14: Cho cc cht 'etyl benzoat, natri phenolat, ancol benzylic, phenyla'oniclorua, !lixerol, protein. S cht tc d n! "#c $%i DaCG Zhi un nFn! l( A. *. B. 3. C. 1. D. +. Cu 15: CHp cht n(o d"%i Ny l( -n! n! c:a nhaux A. Tncol etylic JC1G)CK $( ancol anlylic JC3G)CK. B. Tncol etylic JC1G)CK $( etylen!licol JC1G)C1K. C. Tncol 'etylic JCG+CK $( ancol butylic JC+G13CK. D. Mhenol JC)G)CK $( ancol benzylic JCIGkCK. Cu 16: Cho cc cht sau: J1K CG 3CCCDa, J1K C1G), J3K CaC1, J+K C+G13, J*K Tl+C3. rwy cc cht iQu chR "#c CG+ bSn! '@t ph.n /n! l(: A. J1K, J3K, J*K. B. J1K, J1K, J*K. C. J1K, J+K, J*K. D. J1K, J+K, J*K. Cu 17: 6r"pn! h#p n(o sau Ny ZhAn! thu "#c ZRt t:a sau Zhi ZRt thOc cc ph.n /n!x A. Cho dun! d&ch qaCl1 tc d n! $%i dun! d&ch DaGSC+ Jd"K. B. Cho dun! d&ch TlCl3 tc d n! $%i dun! d&ch DG3 Jd"K. C. Cho qa tc d n! $%i dun! d&ch G1SC+ Jd"K. D. Cho 5n tc d n! $%i dun! d&ch CrCl3 Jd"K Cu 18: m@t h#p cht cF cAn! th/c phNn tb m0 1, tron! F m chiR' +),)I $Q Zhi l"#n!. 6ron! hPt nhNn m s n,tron nhiQu h,n s proton l( +. 6ron! hPt nhNn 0, s n,tron bSn! s proton. 6_n! s proton tron! phNn tb m01 l( *k. G#p cht m01 l( A. 5nSi1. B. CrCl1. C. ieS1. D. CuCl1. Cu 19: Gjn h#p Zh9 0 !-' hai anZen. cy f l9t Zh9 0 tc d n! $%i '@t l"#n! G 1 $Xa : JDi, toK, thu "#c hjn h#p 4 !-' hai anZan. Et chy ho(n to(n hjn h#p 4 thu "#c G 1C $( 13,1 !a' CC1. ghi t chy ho(n to(n f l9t hjn h#p 0 thu "#c CC1 $( ' !a' G1C. ai tr& c:a ' l( A. ),3. B. 3,). C. *,+. D. 1,I. Cu 20: Cu trOc '@t '?t x9ch c:a '@t loPi poli'e l( -CC-tCG1u+-CC-DG-tCG1u)-DGMoli'e F thu@c loPi n(o sau Nyx A. Cao su buna. B. 6, nilon-I. C. 6, nilon-),). D. 6, capron. Cu 21: Go( tan ho(n to(n ),l+ !a' hjn h#p iexCy $( Tl tron! 133'l dun! d&ch G1SC+ 1,km thu "#c 3,)I1 l9t G1 JZtcK. qiRt l"#n! axit w ly d" 13 so $%i l"#n! c`n thiRt > ph.n /n! J!i. sb ZhAn! cF ph.n /n! Zhb ie3\ th(nh ie1\K. CAn! th/c c:a iexCy l( A. ieC. B. ie1C3. C. ie3C+. D. ieC3 Cu 22: 6hWc hiBn th9 n!hiB' ho( tan hRt c=n! '@t 'u Zn' tron! c=n! '@t dun! d&ch GCl o cc nhiBt @ Zhc nhau cho ZRt Uu.: - ghi thWc hiBn ph.n /n! o 13oC, thpi !ian > ZRt thOc ph.n /n! l( 13,* phOth - ghi thWc hiBn ph.n /n! o +3oC, thpi !ian > ZRt thOc ph.n /n! l( 1,* phOt. DRu thWc hiBn th9 n!hiB' tr;n o **oC thV thpi !ian l( bao nhi;ux A. 1+,** !iNy. B. 1k,+) !iNy. C. 3+,)* !iNy. D. 1I,31 !iNy. Cu 23: Cho ' !a' hjn h#p !-' CuC $( ie 1C3 tc d n! $%i CC, nun! nFn! '@t thpi !ian thu "#c hjn h#p r?n 0 $( hjn h#p Zh9 4. Cho 4 ph.n /n! $%i dun! d&ch qaJCGK1 Jd"K thu "#c 1l,** !a' ZRt t:a. Cht r?n 0 ph.n /n! $%i dun! d&ch GDC3 Jd"K thu "#c f l9t Zh9 DC Js.n ph8' Zhb duy nht, o ZtcK. ai tr& c:a f l( A. 1,11. B. ),I1. C. 3,3). D. 1,1+. Cu 24: ghb 3l,1 !a' hjn h#p 0 !-' ie 1C3 $( ieC bSn! Zh9 CC thu "#c hjn h#p 4 !-' ieC $( ie. E> ho( tan hRt 4 c`n $Xa : 1,* l9t G1SC+ 3,1m. ghi l"#n! c:a ie1C3 $( ieC tron! hjn h#p 0 l(: A. 1) !a' ie1C3h 13,1 !a' ieC. B. 31 !a' ie1C3h I,1 !a' ieC. C. 1k !a' ie1C3h 11,1 !a' ieC. D. 13 !a' ie1C3h 1l,1 !a' ieC. Cu 25: Go( tan ba 'ui n(o sau Ny $(o n"%c "#c dun! d&ch 0 !-': 3,3* 'ol Da \h 3,11* 'ol m!1\h 3,1* 'ol Cl- $( 3,1I* 'ol SC+1-x A. m!Cl1, Da1SC+, DaCl. B. m!SC+, m!Cl1, DaCl. C. m!SC+, Da1SC+, m!Cl1. D. m!SC+, Da1SC+, DaCl. Cu 26: 0 l( axit cacboxylic no, cAn! th/c ,n !i.n nht l( C1G3C1. CAn! th/c phNn tb c:a 0 l(
A. C)GkC). B. C+G)C+. C. CkG11Ck. D. C1G3C1. Cu 27: Cho ' !a' '@t l"#n! Zi' loPi m ph.n /n! ho(n to(n $%i dun! d&ch CuSC +, sau ph.n /n! thu "#c 3,***' !a' Cu. DRu d=n! 3,31 'ol m tc d n! $%i G 1SC+ Jlown!, d"K thV thu "#c 3,)I1 l9t Zh9 JZtcK. gi' loPi m l( A. Cr. B. 5n. C. Tl. D. ie. Cu 28: 6run! ho( ),) !a' hjn h#p !-' axit Yo'ic $( '@t axit cacboxylic ,n ch/c 0 c`n dun! d&ch ch/a 3,1 'ol DaCG. mHt Zhc, Zhi cho ),) !a' hjn h#p tr;n tc d n! $%i '@t l"#n! d" T!DC 3 tron! DG3 thV thu "#c 13,k !a' ZRt t:a. 6;n !<i c:a 0 l( A. axit 'etacrylic. B. axit acrylic. C. axit etanoic. D. axit propanoic. Cu 29: m@t loPi 'ui ^n cF ln tPp cht Da 1SC+, CaSC+, Daqr, $( CaCl1. E> thu "#c 'ui ^n tinh ZhiRt JZ> c. cch un nFn!K c`n d=n! cc cht JhoHc dun! d&chK n(o sau Nyx A. run! d&ch qaCl1, Da1CC3, Zh9 GCl, Zh9 Cl1. B. run! d&ch qaCl1, g1CC3, axit GCl, Zh9 Cl1. C. G1C, qaCl1, g1CC3, G1SC+, Cl1. D. G1C, qaCl1, Da1CC3, Cl1. cao Cu 30: Cho cc ph.n /n!: 0 t 4 \ 5 4 Cl hasZt ~ \ i \ a qiRt 0 l( '@t anZan cF t| Zhi so $%i ZhAn! Zh9 nh h,n 1,)h 4 l( anZan, 5 l( anZen Js n!uy;n tb C tron! 4 nhiQu h,n tron! 5K, ~ $( i l( s.n ph8' thR c:a clo, ~ l( s.n ph8' "u ti;n $( i l( s.n ph8' ZhAn! "u ti;n. Cc cAn! th/c 0, 4, 5, ~, i $( a l`n l"#t l(: A. C*G11, C3Gk, C1G+, CG3-CG1-CG1-Cl, CG3-CGCl-CG3, GCl. B. C)G1+, C+G13, C1G+, CG3-CGCl-CG1-CG3, CG1Cl-CG1-CG1-CG3, GCl. C. C+G13, C1G), C1G+, CG1Cl-CG3, CG3-CG1-CG1-Cl, GCl. D. C*G11, C3Gk, C1G+, CG3-CGCl-CG3, CG3-CG1-CG1-Cl, GCl. Cu 31: Cho 3,1 'ol - a'ino axit 0 dPn! G1DCCCG ph.n /n! hRt $%i GCl thu "#c 11,1* !a' 'ui. 0 l( A. alanin. B. $alin. C. !lyxin. D. phenylalanin. Cu 32: nh h"on! c:a nhF' {CG Rn nhNn benzen $( n!"#c lPi "#c ch/n! 'inh boi ph.n /n! c:a phenol $%i A. n"%c bro' $( dun! d&ch DaCG. B. Da $( n"%c bro'. C. dun! d&ch GDC3 $( n"%c bro'. D. n"%c bro' $( anehit Yo'ic. Cu 33: Eun nFn! h#p cht hdu c, 0 $%i l"#n! d" dun! d&ch T!DC 3 tron! DG3 thu "#c h#p cht 5. Cho 5 tc d n! $%i dun! d&ch G1SC+ lown! hoHc $%i dun! d&ch DaCG un nFn! Qu cF Zh9 $A c, thot ra. S cht tron! dwy: GCGC, GCCCG, CG3CGC, CG3CCCG, GCCCDG+. CG3CCCCG3 tho. 'wn cc t9nh cht n;u tr;n l( A. 3 cht. B. 1 cht. C. + cht. D. 1 cht. Cu 34: rn Zh9 thu "#c Zhi cho gmnC + tinh th> ph.n /n! $%i dun! d&ch GCl Hc $(o n"%c tPo th(nh dun! d&ch 0. Cho '8u !iy Uu[ t9' $(o dun! d&ch 0 thV hiBn t"#n! Uuan st thy l(: A. aiy Uu[ t9' ZhAn! _i '(u. B. aiy Uu[ t9' chuy>n san! '(u xanh. C. aiy Uu[ t9' chuy>n san! '(u r-i b& 't '(u. D. aiy Uu[ t9' chuy>n san! '(u xanh r-i 't '(u. Cu 35: 6;n !<i c:a peptit: G1DCG1CCDGCGJCG3KCCDGCG1CCCG l( A. aly-Tla-aly. B. aly-aly-Tla. C. Tla-Tla-aly. D. aly-aly-aly. Cu 36: DhiBt phNn ho(n to(n 1k !a' '@t 'ui nitrat Zi' loPi thu "#c k !a' oxit Zi' loPi. CAn! th/c 'ui F l( A. 5nJDC3K1. B. ieJDC3K3. C. ieJDC3K1. D. CuJDC3K1. Cu 37: Go(n tan ' !a' hjn h#p r?n !-' Ca, CaC 1 $(o '@t l"#n! d" G1C, thu "#c hjn h#p Zh9 cF t| Zhi so $%i hiro l( *. E> trun! ho( dun! d&ch sau ph.n /n!, c`n d=n! )33 'l dun! d&ch GCl 3,*m. ai tr& c:a ' l( A. k,+. B. I,1. C. 3,1. D. +,3. Cu 38: Mht bi>u n(o sau Ny On!x A. 0enlulo $( tinh b@t l( -n! phNn c:a nhau. B. Saccaroz, cF t9nh cht c:a ancol a ch/c $( anehit ,n ch/c. C. alucoz, $( Yructoz, Zhi tc d n! $%i G1 JDi, toK Qu tPo ra c=n! '@t s.n ph8'. D. alucoz, $( Yructoz, Qu tc d n! "#c $%i n"%c bro'.
o
Cu 39: Cho 1 ph.n /n! sau:
ieSC+ \ GDC3 \ G1SC+ ie1JSC+K3 \ DC \ G1C J1K mnJCGK1 \ Cl1 \ gCG mnC1 \ gCl \ G1C J1K GB s Jn!uy;n ti !i.nK c:a G1C o ph",n! trVnh ho h<c c:a ph.n /n! J1K $( J1K l`n l"#t l(: A. 3 $( 1. B. + $( 1. C. 3 $( 1. D. + $( 1. Cu 40: 6r@n ln dun! d&ch ch/a 3,3) 'ol qaJCGK1 $%i dun! d&ch ch/a 3,31 'ol Tl1JSC+K3. Sau Zhi cc ph.n /n! ZRt thOc Zhi l"#n! ZRt t:a thu "#c l( A. 3,11 !a'. B. 11,) !a'. C. 1I,1 !a'. D. 1*,k !a'. Cu 41: E> iQu chR Ik !a' cro' tX Cr 1C3 bSn! ph",n! php nhiBt nhA' JhiBu sut ph.n /n! l( l3K thV s !a' b@t nhA' 9t nht c`n d=n! l( A. +3,* !a'. B. *+,3 !a'. C. k1,3 !a'. D. +*,3 !a'. Cu 42: Cht 0 cF cAn! th/c phNn tb C+G+C $( cF cc t9nh cht sau: - 6c d n! $%i T!DC3 tron! dun! d&ch DG3 tPo ra hai cht ZRt t:a. - 6c d n! $%i qr1 Jtron! dun! d&chK theo t| lB 'ol ti a 1:3. CAn! th/c c:a 0 l( A. CG1LCLCG-CGC. B. CG C-CC-CG3. C. CG3-C C-CGC. D. CG C-CG1CGC. Cu 43: ghi ho( tan 1,) !a' Zn' bSn! GDC3Jlown!, d"K thu "#c 3,11+ l9t Zh9 0 duy nht JZtcK $( dun! d&ch 4 ch| ch/a '@t 'ui. gh9 0 l( A. DC1. B. D1. C. DC. D. D1C. Cu 44: 6r@n 13 'l dun! d&ch GCl cF pG L 3 $%i f 'l dun! d&ch DaCG cF pG L 13 thu "#c dun! d&ch '%i cF pG L *. ai tr& c:a f l( A. l3. B. +. C. 1*. D. 133 Cu 45: Et chy x !a' '@t axit cacboxylic no, 'Pch cacbon ZhAn! phNn nhnh, thu "#c 3,3) 'ol CC 1 $( 3,3* 'ol G1C. ai tr& c:a x l( A. 3,). B. 1,+). C. 1,l1. D. 3,I3. Cu 46: Cho ),33 !a' hjn h#p !-' etanal $( axetilen tc d n! ho(n to(n $%i l"#n! d" dun! d&ch T!DC 3 tron! DG3, thu "#c +1,+ !a' ZRt t:a. Cho to(n b@ l"#n! ZRt t:a n(y $(o dun! d&ch GCl d", sau Zhi x.y ra ph.n /n! ho(n to(n c}n lPi ' !a' cht r?n ZhAn! tan. ai tr& c:a ' l( A. +1,+33 B. 33,13*. C. 1),133. D. +),33*. Cu 47: 6, $isco thu@c loPi poli'e A. tr=n! h#p. B. bn t_n! h#p. C. t_n! h#p. D. thi;n nhi;n. Cu 48: CF n^' n! n!hiB' b& 't nhwn, 'ji n! Wn! '@t tron! cc dun! d&ch GCl J1K, dun! d&ch DaCG J1K, dun! d&ch phenolphtalein J3K, dun! d&ch DaCl J+K, dun! d&ch DaGSC+ J*K. ghAn! d=n! th;' thuc thb n(o Zhc, Z> c. un nFn!, bSn! ph",n! php ho h<c cF th> nhn biRt "#c cc dun! d&ch: A. J1K, J3K, J+K. B. J1K, J1K, J3K. J+K, J*K. C. J1K, J1K, J3K. D. J1K, J3K, J*K. Cu 49: CAn! th/c cu tPo c:a axit -a'ino!lutaric l( A. DG1CG1CG1JDG1KCGCCCG. B. GCCCCG1CG1CG1JDG1KCGCCCG. C. GCCCCG1CG1JDG1KCGCCCG. D. GCCCCG1CGJDG1KCG1CCCG. Cu 50: 6r"pn! h#p n(o sau Ny ZhAn! x.y ra ph",n! trVnh ph.n /n!x A. Cho dun! d&ch ieCl1 $(o dun! d&ch T!DC3. B. Cho dun! d&ch ieJDC3K3 $(o dun! d&ch T!DC3. C. Cho dun! d&ch ieJDC3K1 $(o dun! d&ch GCl. D. Cho dun! d&ch ieJDC3K1 $(o dun! d&ch T!DC3. B S 27 Cu 1: Cho ),l !a' Da $(o 133,3 'l dun! d&ch GCl thu "#c dun! d&ch 0 ch/a 1+,*l !a' cht tan. Cho dun! d&ch 0 $(o dun! d&ch T!DC3 d", sau Zhi ph.n /n! x.y ra ho(n to(n, e' l"#n! r?n thu "#c > n!o(i ZhAn! Zh9 Rn Zhi l"#n! ZhAn! _i "#c ' !a' r?n. ai tr& c:a ' l( : T. 3k,)* q. 3I,*k C. +3,I) r. 3l,13 Cu 2: mui 0 cF cAn! th/c phNn tb l( CG)C3D1. Eun nFn! 0 $%i DaCG thu "#c 1,1+ l9t Zh9 4 J4 l( h#p cht ch/a C, G, D $( cF Zh. n^n! l(' xanh !iy Uu[ t9' 8'K. 69nh Zhi l"#n! 'ui thu "#cx
T. k,1 !a' q. k,* !a' C. ),k !a' r. k,3 !a' Cu 3: Cho tX tX tXn! !i<t c:a dun! d&ch ch/a b 'ol GCl $(o dun! d&ch ch/a a 'ol Da1CC3 thu "#c f l9t CC1. D!"#c lPi, cho tX tX tXn! !i<t c:a dun! d&ch ch/a a 'ol Da1CC3 $(o dun! d&ch ch/a b 'ol GCl thu "#c 1f l9t CC1. So snh a $( b. T. a L 3,kb q. a L 3,3*b C. a L 3,I*b r. a L 3,*b Cu 4: Cho cc dun! d&ch sau: DaGCC3 J01K CuSC+ J01K JDG+K1CC3 J03K DaDC3 J0+K m!Cl1 J0*K gCl J0)K Dhdn! dun! d&ch khng tPo ZRt t:a Zhi cho Zi' loPi qa $(o l(: T. 01, 03, 0) q. 01, 0+, 0* C. 0+, 0). r. 01, 0+, 0) Cu 5: Gjn h#p 0 !-' CG1LCG-CG1-CG $( CG3-CG1-CG. Cho a !a' hjn h#p 0 tc d n! $%i Da d" thu "#c 1,1+ l9t G1 JZtcK. mHt Zhc, a !a' hjn h#p 0 l(' 't '(u $Xa hRt 133 !a' dun! d&ch qr1 13. fy !i tr& c:a a t",n! /n! l(: T. 11,I !a' q. 11,I !a' C. l,I !a' r. 13,I !a' ieJDC3K3 \ DC1 \ DC \ G1C Cu 6: Cho ph.n /n! sau: ie3C+ \ GDC3 DRu t| lB s 'ol !ida DC $( DC1 l( 1 : 1 thV hB s cNn bSn! c:a GDC3 tron! ph",n! trVnh ho h<c l( T. 33 q. +k C. 3k r. )) Cu 7: E> trun! ho( 1k,k !a' hjn h#p !-' axit axetic, ancol propylic $( p-crezol c`n 1*3 'l dun! d&ch DaCG 1m. mHt Zhc ho( tan ho(n to(n 1k,k !a' hjn h#p tr;n tron! hexan r-i cho Da d" $(o thV thu "#c +,+k l9t G1 Jo ZtcK. c"#n! p-crezol cF tron! hjn h#p l(x T. 3,1 'ol. q. 3,1 'ol. C. 3,3 'ol r. 3,+ 'ol ( 2( 2) ) Cu 8: Cho cc ion sau: Cl h S h Ca h g . 6h/ tW t^n! d`n bn Z9nh c:a cc ion tr;n l( 1\ \ 1- - 11\ \ 1- - \ 1\ 1\ \ T. Ca h g h S h Cl q. Cl h S h Ca h g . C. S h Cl h g h Ca r. .Ca h g h - 1Cl h S . Cu 9: 6r@n ln 133 'l dun! d&ch qaJCGK1 1m $%i 133 'l dun! d&ch Tl1JSC+K3 3,1m, Zhuy Qu cho ph.n /n! x.y ra ho(n to(n thu "#c x !a' ZRt t:a $( dun! d&ch T. S c CC1 d" $(o dun! d&ch T, lPi thu "#c y !a' ZRt t:a. ai tr& c:a x $( y t",n! /n! l( T. 13,lk $( I,3). q. 13,3 $( I,3). C. 13,3 $( 3,11. r. 13,lk $( 3,11. Cu 10: Cho ),I1 !a' ie $(o dun! d&ch cF 3,+ 'ol GDC3 J!i. thiRt DC l( s.n ph8' Zhb duy nhtK. Sau Zhi ph.n /n! ho(n to(n, ph`n dun! d&ch cF s !a' 'ui tan l( T. 1l,3+ q. 1+,1 C. 1*,31 r. 11,) Cu 11: Txit lactic JCG3-CGJCGK-CCCGK cF th> tc d n! "#c $%i tt c. cc cht tron! dwy n(o sau Ny x T. Da, Da1CC3, g1SC+, CG3CCCG. q. Da1C, DaGCC3, C1G*CG, Gqr. C. CG3DG1, GCl, CaSC+. r. CG3CG, G1, DaCG, qr1. Cu 12: Dun! nFn! ' !a' Cu $%i oxi o nhiBt @ cao "#c cht r?n 0. Go( tan 0 tron! G 1SC+ lown! d" thV "#c 3,*' !a' Cu. Cht r?n 0 l( A. Cu1C. B. Cu1C, CuC. C. Cu, Cu1C. D. CuC. Cu 13: Cho cc ph.n /n! sau: aK ieS \ G1SC+ JHc, nFn!K bK m!C \ GDC3 JHc, nFn!K cK ie \ ie1JSC+K3 eK CG3CGC \ T!DC32DG3 !K alixerol \ CuJCGK1 YK CG3CCCCG3 \ DaCG hK GCGC \ CuJCGK1 dK C1G1 \ G1
S ph.n /n! thu@c loPi ph.n /n! oxi ho - Zhb l( T. ) q. + C. I r. * Cu 14: Cho T l( h#p cht th,' cF cAn! th/c phNn tb ch9nh l( cAn! th/c ,n !i.n nht. Et chy ho(n to(n 1,1+ !a' T ch| thu "#c 1,*)k l9t CC1 JZtcK $( 3,I1 !a' G1C. Cho a 'ol T tc d n! $%i Da d" thu "#c a 'ol Zh9 G1. mHt Zhc, a 'ol T tc d n! : $%i a 'ol DaCG. S cAn! th/c cu tPo cF th> ph= h#p $%i T l(
T. + q. ) C. 3 r. * Cu 15: 6huy phNn cc h#p cht sau tron! 'Ai tr"pn! ZiQ' 1. CG3 - CGCl1 1. CG3 - CCC - CG L CG - CG3. 3. CG3 - CCC - CG1 - CG L CG1 +. CG3 - CG1 - CCl3. *. JCG3 - CCCK1CG1 Dhdn! cht sau Zhi th:y phNn cho s.n ph8' cF ph.n /n! trn! bPc l( T. 1, 1, +, * q. 1, 1, + C. 1, 3, * r. 1, 1, * Cu 16: 6yrosin cF cAn! th/c p-GC-C)G+-CG1-CGJDG1K-CCCG. Cho 3,1 'ol 6yrosin tc d n! $Xa : $%i dd DaCG thu "#c h#p cht hdu c, q. c"#n! GCl c`n d=n! > ph.n /n! $%i q l(: T. 3,1 'ol q. 3,+ 'ol C. 3,1 'ol r. 3,3 'ol Cu 17: Cho cc nhn xt sau: J1K G#p cht G1D-CG1-CG1-CC-DG-CG1-CC-DG-CG1-CCCG ch/a 1 li;n ZRt peptit J1K MhNn tb Zhi c:a '@t a'ino axit ch/a 1 nhF' {DG1 $( 1 nhF' {CCCG tron! phNn tb luAn l( s ln J3K Cc peptit Qu tc d n! $%i CuJCGK1 tron! 'Ai tr"pn! ZiQ' tPo ra h#p cht '(u t9' J+K 6ripeptit l( h#p cht '( phNn tb ch/a 3 li;n ZRt peptit J*K run! d&ch c:a anilin ZhAn! l(' xanh Uu[ t9'. S nhn xt ng l(: T. * q. 3 C. + r. 1 Cu 18: EiQu chR este CG3CCCC1G* bSn! cch un C1G*CG $%i CG3CCCG cF 'Ht G1SC+ Hc, Zhi: J1K 6^n! n-n! @ ancol J1K t^n! n-n! @ axit J3K ch"n! ct ly d`n este J+K 6h;' G1SC+ Hc J*K 6^n! n-n! @ c:a c. axit $( ancol CF 'y ph",n! n !Fp ph`n l(' cNn bSn! d&ch chuy>n $Q ph9a tPo th(nh este T. 1 q. * C. + r. 3 Cu 19: Cho 11 !a' m! tc d n! $%i dun! d&ch GDC 3 J$Xa :K thu "#c dun! d&ch T $( f l9t hjn h#p Zh9 JZtcK !-' D1C $( D1 cF t| Zhi so $%i G1 bSn! 1k. CA cPn c8n thn to(n b@ dun! d&ch T thu "#c I* !a' 'ui Zhan. ai tr& c:a f l( A. 1,+k3. B. 1.31). C. 1,1+3. D. 1,)kk. Cu 20: Mht bi>u n(o sau Ny l( saix T. 6ron! tinh th> n!uy;n tb, cc n!uy;n tb li;n ZRt $%i nhau bSn! li;n ZRt c@n! ho tr&. q. 6ron! tinh th> DaCl, xun! Uuanh 'ji ion Qu cF ) ion n!"#c du !`n nht. C. 6inh th> n"%c , tinh th> iot Qu thu@c loPi tinh th> phNn tb. r. 6t c. cc tinh th> phNn tb Qu ZhF nFn! ch.y $( ZhF bay h,i. Cu 21: Cho cc pht bi>u sau JaK ghi t chy ho(n to(n '@t hirocacbon 0 bt ZV, nRu thu "#c nCC1 L nG1C thV l( anZen JbK 6ron! th(nh ph`n h#p cht hdu c, nht thiRt ph.i cF cacbon. JcK ci;n ZRt ho h<c ch: yRu tron! h#p cht hdu c, l( li;n ZRt c@n! ho tr&. JdK Dhdn! h#p cht hdu c, Zhc nhau cF c=n! phNn tb Zhi l( -n! phNn c:a nhau. JeK Mh.n /n! hdu c, th"pn! x.y ra nhanh $( ZhAn! theo '@t h"%n! nht &nh. J!K G#p cht ClG1+qrCl cF $}n! benzen tron! phNn tb. S pht bi>u ng l( T. *. q. 1. C. 3. r. +. Cu 22: Cho 1,k1 !a' hjn h#p b@t 0 !-' Cu $( T! Jt| lB s 'ol t",n! /n! + : 1K $(o 33 'l dun! d&ch !-' G1SC+ 3,*m $( GDC3 1m, sau Zhi cc ph.n /n! x.y ra ho(n to(n, thu "#c a 'ol Zh9 DC Js.n ph8' Zhb duy nhtK. 6r@n a 'ol DC tr;n $%i 3,1 'ol C1 thu "#c hjn h#p Zh9 4. Cho to(n b@ 4 tc d n! $%i G1C, thu "#c 1*3 'l dun! d&ch cF pG L z. ai tr& c:a z l( T. +. q. 3. C. 1. r. 1. Cu 23: 6hWc hiBn cc th9 n!hiB' sau: JaK Dun! DG+DC3 r?n. JbK Eun nFn! DaCl tinh th> $%i dun! d&ch G1SC+ JHcK. JcK S c Zh9 Cl1 $(o dun! d&ch DaGCC3. JdK S c Zh9 CC1 $(o dun! d&ch CaJCGK1 Jd"K. JeK S c Zh9 SC1 $(o dun! d&ch gmnC+. J!K Cho dun! d&ch gGSC+ $(o dun! d&ch
DaGCC3. JhK Cho Da1SC3 $(o dun! d&ch G1SC+ Jd"K, un nFn!. JiK Cho MbS $(o dun! d&ch GCl Jlown!K. S th9 n!hiB' sinh ra cht Zh9 l( T. +. q. 1. C. ). r. *. Cu 24: Gjn h#p 0 !-' $inyl axetat, 'etyl axetat $( etyl Yo'at. Et chy ho(n to(n 3,3k !a' 0, thu "#c 1,1) !a' G1C. Mh`n tr^' s 'ol c:a $inyl axetat tron! 0 l( T. I1,3k. q. 1I,l1. C. 1*. r. I*. Cu 25: ghi tiRn h(nh ph.n /n! thR !ida anZan q $%i h,i qr1 cF chiRu sn! theo t| lB 'ol 1:1 n!"pi ta thu "#c hjn h#p 0 ch| !-' 1 s.n ph8' ph.n /n! J'@t cht $A c, $( '@t cht hdu c,K o th> h,i. 6| Zhi h,i c:a 0 so $%i ZhAn! Zh9 bSn! +. DRu tiRn h(nh ph.n /n! thR 3 n!uy;n tb hidro tron! phNn tb q bSn! Clo thV cF th> thu "#c 'y -n! phNnx T. 1 q. 3 C.+ r. 1 Cu 26: rwy !-' cc cht n(o sau Ny Qu cF t9nh l"n! t9nh x A. TlCl3, G1C, DaGCC3, 5nJCGK1, 5nC, G1DCG1CCCG, CrC3 B. 5nCl1, TlCl3, DaTlC1, DaGCC3, G1DCG1CCCG, Tl1C3 C. G1C, 5nJCGK1, GCCC-CCCDa, G1DCG1CCCG, DaGCC3 D. Tl, DaGCC3, DaTlC1, 5nC, qeJCGK1 Cu 27: Cho '@t lu-n! Zh9 CC i Uua n! s/ Wn! ' !a' ie1C3 nun! nFn!. Sau '@t thpi !ian thu "#c 13.++ !a' cht r?n 0 !-' ie, ieC, ie1C3 $( ie3C+. G}a tan hRt 0 tron! dun! d&ch GDC3 Hc, nFn! thu "#c +.3)k l9t DC1 Js.n ph8' Zhb duy nht o ZtcK. ai tr& c:a ' l( T. 11 q. 1+ C. 13.k r. 1) Cu 28: EiBn phNn 1 l9t dun! d&ch hjn h#p !-' DaCl $( CuSC+ Rn Zhi G1C b& iBn phNn o hai cWc thV dXn! lPi, tPi catt thu 1.1k !a' Zi' loPi $( ant thu 3.33) l9t Zh9 Jo iQu ZiBn ti;u chu8nK. Coi th> t9ch dun! d&ch ZhAn! _i thV !i tr& pG c:a dun! d&ch thu "#c bSn!: T. 11 q. 13 C. 1 r. 3 Cu 29: Girat ho 3.3) l9t C1G1 JiQu ZiBn ti;u chu8nK thu "#c hjn h#p T JhiBu sut ph.n /n! )3K . Cho hjn h#p s.n ph8' T tc d n! $%i dun! d&ch T!1C2DG3 d" thu "#c ' !a' cht r?n. ai tr& c:a ' l( T. 1l,++ q. 33,k+ C. 1+,+3 r. +k,1+ Cu 30: Go( tan ' !a' hjn h#p !-' Da1CC3 $( gGCC3 $(o n"%c "#c dun! d&ch T. Cho tX tX dun! d&ch GCl $(o dun! d&ch T thy cF +,+k l9t Zh9 bay ra JZtcK $( dun! d&ch q. Cho n"%c $Ai tron! d" $(o dun! d&ch q thu "#c 1* !a' ZRt t:a. mHt Zhc, > tc d n! hRt $%i cc cht cF tron! dun! d&ch T c`n 133 'l dun! d&ch DaCG 1m. 69nh ' x T. 3*,) q.1),* C.+I,1 r. 3),* Cu 31: Cho 1,1 !a' hjn h#p !-' 1 a'in no, ,n ch/c, ZR tiRp nhau tron! dwy -n! n! ph.n /n! hRt $%i dun! d&ch GCl Jd"K thu "#c 3,l1* !a' hjn h#p 'ui. CAn! th/c c:a a'in F l( T. C3GIDG1 $( C+GlDG1 q. CG3DG1 $( C1G*DG1 C. CG3DG1 $( JCG3K3D r. C1G*DG1 $( C3GIDG1 Cu 32: CF bao nhi;u cht hdu c, 'Pch ho d=n! > iQu chR +-'etylpentan-1-ol ch| bSn! ph.n /n! c@n! 3 G1 J xOc tc Di, t K x T. 1 q. * C.+ r. 3 Cu 33: rwy !-' cc Zi' loPi cF cu tPo 'Pn! tinh th> lp ph",n! tN' Zhi l( T. qe, m!, Ca q. ci, Da, g C. Da, g, m! r. ci, Da, Ca Cu 34: Cho 1,*) !a' hjn h#p !-' Tl $( Tl1C3 ph.n /n! hRt $%i dun! d&ch GCl Jd"K, thu "#c f l9t Zh9 G1 JZtcK $( dun! d&ch 0. Dh tX tX dun! d&ch DG3 Rn d" $(o dun! d&ch 0 "#c ZRt t:a, l<c hRt l"#n! ZRt t:a, nun! Rn Zhi l"#n! ZhAn! _i "#c 1,3+ !a' cht r?n. ai tr& c:a f l( T. 3,++k q. 3,11+ C. 1,3++ r. 3,)I1 Cu 35: Cu hVnh c:a n!uy;n tb hay ion n(o d"%i Ny "#c bi>u din khn On!x * 1 1\ 3 1 T. Cr J5 L 1+K tTru 3d +s q. mn J5 L 1*K tTru 3d +s 3\ * 13 1 C. ie J5 L 1)K tTru 3d r. Cu J5 L 1lK tTru 3d +s Cu 36: Cho 1*,3 !a' '@t a'inoaxit 0 cF '@t nhF' a'ino $( '@t nhF' cacboxyl tc d n! : $%i dun!
d&ch DaCG thu "#c dun! d&ch 4. CA cPn 4 "#c 1l,+ !a' 'ui Zhan. 0 l( T. G1DCG1CCCG. q. G1DC1G+CCCG. C. G1DC3G)CCCG. r. G1DC+GkCCCG Cu 37: rwy cc cht n(o sau Ny cF th> tha' !ia ph.n /n! tPo poli'e x T. Txit aipich axit caproich hexa'etilen ia'inh etilen!licol q. popilen, anilin, axit 'etacrilic, cu'en C. Mhenolh xilenh alaninh $alinh axit enantoic r. Caprolacta'h axit terephtalich !lixerolh axit oxalic Cu 38: Cho Zi' loPi m $(o dun! d&ch 'ui c:a Zi' loPi 0 thy cF ZRt t:a $( Zh9 bay l;n. Cho Zi' loPi 0 $(o dun! d&ch 'ui c:a Zi' loPi 4 thy cF ZRt t:a. mHt Zhc, cho Zi' loPi 0 $(o dun! d&ch 'ui c:a Zi' loPi 5, ZhAn! thy cF hiBn t"#n! !V. Cho biRt sW s?p xRp n(o sau Ny On! $%i chiQu t^n! d`n t9nh Zi' loPi c:a 0, 4, 5, m x T. 0 ] 4 ] m ] 5 q. 4 ] 0 ] 5 ] m C. m ] 5 ] 0 ] 4 r. 5 ] 4 ] 0 ] m Cu 39: Gjn h#p 0 ch/a g1C, DG+Cl, gGCC3 $( qaCl1 cF s 'ol 'ji cht Qu bSn! 3,1 'o l. Cho hjn h#p 0 $(o G1C Jd"K, un nFn!, r-i cA cPn ph`n dd thu "#c ' !a' cht r?n Zhan. ai tr& c:a ' l(: T. I,+* q. 11,3* C. 11,1I* r. 1+,l Cu 40: EiBn phNn dun! d&ch ch/a a 'ol CuSC+, b 'ol DaCl J$%i iBn cWc tr,, '(n! n!^n xpK. run! d&ch thu "#c sau ph.n /n! ho( tan "#c Tl1C3. 7uan hB !ida a $( b l( T. a ] 1b hoHc a v 1b. q. a ] b. C. b v 1a hoHc b ] 1a. r. b 1a. Cu 41: S h#p cht l( -n! phNn cu tPo, cF c=n! cAn! th/c phNn tb C+GkC1, tc d n! "#c $%i dun! d&ch DaCG nh"n! ZhAn! tc d n! "#c $%i Da l( T. 1 q. 1 C. 3 r. + Cu 42: Go( tan 1I,1 !a' hjn h#p b@t ie $( ieC tron! dun! d&ch axit sunYuric lown!, sau F l(' bay h,i dun! d&ch thu "#c 111,1 !a' ieSC+.IG1C. 6h(nh ph`n Zhi l"#n! cc cht tron! hjn h#p l( T. 1l,+ ie $( I3,) ieC q. 1+,l ie $( I*,1 ieC C. 13,) ie $( Il,+ ieC r. 1),3 ie $( I+,3 ieC \ \ 1\ 1\ Cu 43: 6ron! dun! d&ch cF ch/a cc cation g , T! , ie , qa $( '@t anion 0. Tnion 0 F l( T. Cl q. DC3 C. SC+1r. CC31Cu 44: 6;n c:a cc loPi UuHn! ch/a ieCC3 , ie1C3, ie3C+, ieS1. l`n l"#t l( T. Ge'atith pirit h 'anhetit h xierit q. 0ierit hmanhetith pirit h Ge'atit C. 0ierit h Ge'atith 'anhetit h pirit r. Mirit h Ge'atith 'anhetit h xierit Cu 45: 6h_i f l9t JZtcK Zh9 CC1 $(o 333 'l dun! d&ch CaJCGK1 3,31m thV thu "#c 3,1 !a' ZRt t:a. ai tr& c:a f l(: T. ++,k 'l hoHc kl,) 'l q. 11+ 'l C. ++,k 'l hoHc 11+ 'l r. ++,k 'l Cu 46: Dun! +,11 !a' hjn h#p 0 !-' Tl, m!, ie tron! oxi sau '@t thpi !ian thu "#c *,k1 !a' hjn h#p 4. G}a tan ho(n to(n 4 tron! dun! d&ch GDC3 d" thu "#c 3,)I1 l9t DC Jo Ztc $( l( s.n ph8' Zhb duy nhtK. S 'ol GDC3 ph.n /n! l(: T. 3,3) 'ol q. 3,1k 'ol C. 3,31 'ol r. 3,1+ 'ol Cu 47: 6ron! tW nhi;n oxi cF ba -n! $& 1)C, 1IC, 1kCh cacbon cF hai -n! $& 11C, 13C. Gi cF th> cF bao nhi;u loPi phNn tb Zh9 cacbonic tPo th(nh tX cc -n! $& tr;nx T. ). q. l. C. 11. r. 1k Cu 48: Cho 1I,kk !a' hjn h#p 0 !-' 1 axit cacboxylic l( -n! n! ZR tiRp nhau ph.n /n! ho(n to(n $%i 133'l dun! d&ch DaCG 1m $( gCG 1m, thu "#c dun! d&ch 4. CA cPn dun! d&ch 4, thu "#c 31,11 !a' hjn h#p cht r?n Zhan. CAn! th/c c:a 1 axit tron! 0 l(: T. C3G+C1 $( C+G)C1 q. C1G+C1 $( C3G)C1 C. C1G+C1 $( C3G+C1 r. C3G)C1 $( C+GkC1 \ o Cu 49: Cho hjn h#p tt c. cc -n! phNn 'Pch ho c:a C+Gk tc d n! $%i G1C JG , t K thu "#c ti a bao nhi;u s.n ph8' c@n! x T. + q. 1 C. ) r. * Cu 50: DRu thuy phNn ZhAn! ho(n to(n pentapeptit: aly{Tla{aly{Tla{aly thV thu "#c ti a bao nhi;u
ipeptit Zhc nhaux T. 1
q. +
C. 1
r. 3
B S 28 Cu 1: G#p cht T cF cAn! th/c phNn tb C+G)Cl1C1. Cho 3,1 'ol T tc d n! $Xa : $%i dun! d&ch cF ch/a 3,3 'ol DaCG, thu "#c dun! d&ch hjn h#p tron! F cF hai cht hdu c, !-' ancol etylic $( cht hdu c, 0, cA cPn dun! d&ch sau ph.n /n! thu "#c ' !a' cht r?n Zhan. ghi l"#n! ' l(: A. l,) !a' B. 13,1 !a' C. 11,+ !a' D. 11,3 !a' Cu 2: Dhn &nh n(o sau Ny khn On!x A. Txeton ZhAn! l(' 't '(u dun! d&ch gmnC+ o iQu ZiBn th"pn!. B. Cc xeton Zhi cho ph.n /n! $%i G1 Qu sinh ra ancol bc 1. C. 6rX axetilen, cc anZin Zhi c@n! n"%c Qu cho s.n ph8' ch9nh l( xeton. D. Cc h#p cht cF ch/a nhF' vCLC Qu ph.n /n! $%i dun! d&ch qr1. Cu 3: Cho I3! hjn h#p phenol $( cu'en tc dun! $%i dun! d&ch DaCG 1) $Xa :, sau ph.n /n! thy tch ra hai l%p cht ln! phNn cch, chiRt thy l%p ph9a tr;n cF th> t9ch l( k3 'l $( cF Zhi l"#n! ri;n! 3,k)!2c' 3. theo Zhi l"#n! c:a cu'en tron! hjn h#p l(: A. 1),k) B. lk,1l C. I3,1+ D. *),k Cu 4: Cho 1I,3 !a' hjn h#p T !-' hai este no, ,n ch/c tc d n! $Xa : $%i dun! d&ch gCG, thu "#c 33,k !a' hjn h#p hai 'ui c:a 1 axit ZR tiRp $( 1),1 !a' '@t ancol. ghi l"#n! c:a este cF Zhi l"#n! phNn tb nh cF tron! hjn h#p T l( A. 11 !a'. B. 11 !a'. C. 1I,) !a'. D. 1k,* !a'. Cu 5: Ch| d=n! UuV t9' cF th> nhn biRt "#c ti a bao nhi;u dun! d&ch tron! cc dun! d&ch sau: DaCl, DaGCC3, Da1CC3, DaGSC+, DaDC3, DaCG. A. 3 B. 1 C. + D. ) Cu 6: Cho 13,)1 !a' trinitrotoluen J6D6K $(o '@t bVnh Wn! bSn! thp cF dun! t9ch ZhAn! _i *33'l JZhAn! cF ZhAn! Zh9K r-i !Ny n_. Sau ph.n /n! nhiBt @ bVnh l( 1k33 3C, p sut tron! bVnh l( M at', biRt rSn! s.n ph8' Zh9 tron! bVnh sau n_ l( hjn h#p CC, D1, G1. M cF !i tr& l(: A. 11+,3k B. 133,lk C. 1*1,lk D. k1,) Cu 7: E> trun! ho( dun! d&ch ch/a 3,l3+* !a' 1 axit hdu c, T c`n *+,* 'l dun! d&ch DaCG 3,1 m. 6ron! dun! d&ch ancol q l+ Jtheo Zhi l""#n!K t| s 'ol ancol : n""%c l( k):1+. CAn! th/c c:a T $( q l(: A. C+GkJCCCGK1, C1G*CG B. C)G+JCCCGK1, CG3CG C. C+GkJCCCGK1, CG3CG D. C)G+JCCCGK1, C1G*CG. Cu 8: Cc cht Zh9 sau: SC1, DC1, Cl1, D1C, G1S, CC1. Cc cht Zh9 Zhi tc d n! $%i dun! d&ch DaCG Jo nhiBt @ th"pn!K luAn tPo ra 1 'ui l(: A. DC1, SC1 , CC1 B. CC1, Cl1, D1C C. SC1, CC1, G1S D. Cl1, DC1 Cu 9: G#p cht hdu c, 0 cF cAn! th/c phNn tb C )G13C1, cho l,11 !a' 0 tc d n! $%i dun! d&ch DaCG $Xa : thu "#c dun! d&ch 4, cho dun! d&ch 4 tc d n! $%i dun! d&ch T!DC 3 d" tron! DG3 un nFn! thu "#c 3+,*) !a' T!. S -n! phNn cu tPo c:a 0 l(: A. +. B. * C. 1. D. 3. Cu 10: Cho 11,3) !a' hjn h#p !-' ie, ieC, ie 1C3, ie3C+ ph.n /n! hRt $%i dun! d&ch GDC 3 lown! d" thu "#c 1,3++ l9t Zh9 DC s.n ph8' Zhb duy nht Jo ZtcK $( dun! d&ch 0. run! d&ch 0 cF th> ho( tan "#c ti a 11,1 !a' ie. S 'ol c:a GDC3 cF tron! dun! d&ch ban ù l(: A. 3,l+ 'ol. B. 3,)+ 'ol. C. 3,k) 'ol. D. 3,Ik 'ol. Cu 11: Cho cc cht $( dun! d&ch sau: toluen, stiren, etilen, xiclopropan, isopren, $inyl axetat, etyl acrylat, i$inyl oxalat, Yooc'on, axeton, dun! d&ch !lucoz,, dun! d&ch iructoz,, dun! d&ch 'antoz,, dun! d&ch saccaroz,. S cht $( dun! d&ch cF th> l(' 't '(u dun! d&ch qr1 l(: A. 11. B. 13 C. k D. l Cu 12: G}a tan 1+! hjn h#p Cu, ie3C+ $(o dun! d&ch GCl, sau ph.n /n! c}n d" 1,1)! hjn h#p cht r?n $( dun! d&ch 0. Cho 0 tc d n! $%i T!DC3 d" thu "#c bao nhi;u !a' ZRt t:a: A. +*,l1 B. 11,l) C. *k,kk D. +I,+ Cu 13: Go( tan hRt ' !a' Tl1JSC+K3 $(o n"%c "#c dun! d&ch 0. Cho 3)3 'l dun! d&ch DaCG 1m $(o 0, thu "#c 1a !a' ZRt t:a. mHc Zhc, nRu cho +33 'l dun! d&ch DaCG 1m $(o 0, czn! thu "#c a !a' ZRt t:a. Cc ph.n /n! x.y ra ho(n to(n, !i tr& c:a ' l(: A. 1k,k1 B. 1*,3l C. 13,*1 D. 1l,))*
Cu 14: Cho cc ph.n /n!: to J1K. C3 \ dun! d&ch ge s J)K. i1 \ G1C o t J1K. mnC1 \ GCl Hc JIK. G1S \ dun! d&ch Cl1 s to J3K. gClC3 \ GCl Hc JkK. Gi \ SiC1 s o t to J+K. DG+GCC3 JlK. DG+Cl \ DaDC1 to J*K. DG3JZh9K \ CuC J13K. Cu1S \ Cu1C s S tr"pn! h#p tPo ra ,n cht l(: A. *. B. ). C. I. D. k. Cu 15: G}a tan 1*,k+ !a' hjn h#p !-' '@t oxit Zi' loPi ZiQ' $( '@t oxit Zi' loPi ZiQ' th_ bSn! dun! d&ch GCl d" "#c dun! d&ch 0. CA cPn dun! d&ch 0, ly 'ui Zhan e' iBn phNn nFn! ch.y ho(n to(n thV thu "#c ),3+k l9t Zh9 Jo o ZtcK o anot $( a J!a'K hjn h#p Zi' loPi o catot. ai tr& c:a a l(: A. I,1. B. 11,*1. C. 3,33. D. 13,)k. Cu 16: 0 l( ipeptit Tla-alu, 4 l( tripeptit Tla-Tla-aly. Eun nFn! ' J!a'K hjn h#p ch/a 0 $( 4 cF t| lB s 'ol c:a 0 $( 4 t",n! /n! l( 1:1 $%i dun! d&ch DaCG $Xa :. Mh.n /n! ho(n to(n thu "#c dun! d&ch 6. CA cPn c8n thn dun! d&ch 6 thu "#c *),+ !a' cht r?n Zhan. ai tr& c:a ' l(: A. +*,) B. +3,1I. C. 3l,11. D. 3k,)k. Cu 17: CF cc nhn xt sau: J1K Cht bo thu@c loPi cht este. J1K 6, nilon, t, capron, t, enan! Qu iQu chR bSn! ph.n /n! tr=n! n!"n!. J3K finyl axetat ZhAn! iQu chR "#c trWc tiRp tX axit $( ancol t",n! /n!. J+K Ditro benzen ph.n /n! $%i GDC3 Hc JxOc tc G1SC+ HcK tPo th(nh '-initrobenzen. J*K phenyl a'oni clorua ph.n /n! $%i n"%c bro' d" tPo th(nh J1,+,)-tribro'phenylK a'oni clorua. Dhdn! cNu On! l(: A. 1, 3, +. B. 1, 3, +. C. 6t c.. D. 1, 1, +, *. Cu 18: m@t loPi phNn Supephotphat Zp cF ch/a I1,)k 'ui canxi ihirophotphat c}n lPi !-' cc cht ZhAn! ch/a pht pho. E@ dinh d"n! c:a loPi phNn lNn n(y l(: A. )3,)k B. 3I,l+ C. 33,3+ D. ++,1 Cu 19: Mht bi>u n(o d"%i Ny khn On!x A. Cht bo nh h,n n"%c $( ZhAn! tan tron! n"%c B. m @n! $t ch: yRu cu th(nh tX !c axit bo, no, t-n tPi o trPn! thi r?n C. Giro ho dù thWc $t ln! sn tPo th(nh cc ' @n! $t r?n D. Dh"#c i>' c:a cht !iHt rba t_n! h#p l( !Ny A nhi' cho 'Ai tr"pn! Cu 20: Cho cc cht sau: ieqr3, ieCl1, ie3C+, Tlqr3, m!e1, gqr, DaCl, Cai1, CaC1. Txit G1SC+ Hc nFn! cF th> oxi hFa bao nhi;u chtx A. 3 B. ) C. * D. I Cu 21: Cho anZan 0 tc d n! $%i clo JasK thu "#c 1),* !a' hjn h#p cc dn xut clo J'ono $( icloK. gh9 GCl bay ra "#c hp th ho(n to(n bSn! n"%c sau F trun! h}a bSn! dd DaCG thy tn hRt *33 'l dd DaCG 1m. 0c &nh C6 c:a 0x A. C1G) B. C+G13 C. C3Gk D. CG+ Cu 22: Cho cc cht: xiclobutan, 'etylxiclopropan, 1,1-i'etylxiclopropan, -butilen, but-1-in, trans but-1en, butaien, $inyl axetilen, isobutilen, anlen. CF bao nhi;u cht tron! s cc cht tr;n Zhi tc d n! $%i hiro cF th> tPo ra butan. A. k B. l C. I D. ) Cu 23: ghi iQu chR Da tron! cAn! n!hiBp n!"pi ta d=n! hjn h#p !-' 1 ph`n DaCl $( 3 ph`n CaCl 1 $Q Zhi l"#n! $%i ' c 9ch: A. 6Po ra nhiQu cht iBn ly h,n B. 6^n! n-n! @ ion ClC. ai.' nhiBt @ nFn! ch.y D. 6Po ra hjn h#p cF Zhi l"#n! ri;n! nh n_i l;n tr;n Da nFn! ch.y Cu 24: Cho cc ph.n /n!:
CG 1LCG1 \ G1C C1G*CG \ Gqr JbZK
toc
Cl 1 \ gCG m!JDC 3K1 Da 1C1 \ G1C
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CG3 -CGLCG 1 \ qr 1JddK
ie3C+ \ G1SC+ Jloan!K CG3 -CGC \ G1 6ron! cc ph.n /n! tr;n cF bao nhi;u ph.n /n! l( oxh-Zhb, bao nhi;u ph.n /n! n@i phNn tb: A. I { + B. ) { + C. * { + D. ) { 1 111 113 Cu 25: Sb ch/a 1 -n! $& ch9nh Sb $( Sb, Zhi l"#n! n!uy;n tb trun! bVnh c:a Sb l( 111,I*. Zhi l"#n! c:a -n! $& 111 Sb tron! Sb1C3 JmCL1)K l(: A. *1,1 B. )1,* C. 1),1 D. *1,kl Cu 26: Cho G J5L1K, D J5LIK, C J5LkK. 6ron! phNn tb GDC 3, t_n! s cHp electron l%p n!o(i c=n! khn tha' !ia li;n ZRt c:a * n!uy;n tb l(: A. k. B. l. C. I. D. ). Cu 27: m@t loPi cao su buna-D cF ph`n tr^' Zhi l"#n! c:a nit, l( 1l,I1. 6| lB '?t x9ch butaien $( $inyl xianua l(: A. 1 : 1 B. 1 : 1 C. 1 : 3 D. 3 : 1 Cu 28: Cho cc cNn bSn! sau: J1K 1DG3JZK D1JZK \ 3G1JZK G v 3 J1K 1SC1JZK \ C1JZK 1SC3JZK G ]3 J3K CaCC3JrK CaCJrK \ CC1JZK G v 3 J+K G1JZK \ e1JZK 1GeJZK G ] 3 6ron! cc cNn bSn! tr;n cNn bSn! n(o sn chuy>n d&ch theo chiQu thun Zhi t^n! nhiBt @ $( !i.' p sut: A. 1, 3. B. 1, +. C. 1, 1, 3 ,+. D. 1, +. Cu 29: Cho cc dun! dun! d&ch sau: J1K: natri cacbonath J1K: s?t JeeeK clorruah J3K: axit sunYuaric lown!h J+K: axit axetich J*K: natri phenolath J)K: phenyl a'oni cloruah JIK: i'etyl a'oni clorua. run! d&ch 'etyla'in tc d n! "#c $%i dun! d&ch: A. 3, +, ), I B. 1, 3, +, ) C. 1, 3, +, * D. 1, 1, +, * Cu 30: Cho '@t ipeptit 4 cF cAn! th/c phNn tb C)G11D1C3. S -n! phNn peptit c:a 4 Jch| ch/a !c -a'ino axitK 'Pch ho l(: A. *. B. +. C. I. D. ). Cu 31: Cho dun! d&ch 'ui 0 $(o cc dun! d&ch Da1CC3 h dun! d&ch Da1S Qu thy cF ZRt t:a $( cF Zh9 bay l;n. fy 0 l( : A. TlCl3 B. ieCl3 C. ieCl1 D. CuCl1. Cu 32: CF cc pht bi>u sau Ny: J1K T'iloz, cF cu trOc 'Pch phNn nhnh. J1K mantoz, b& Zhb hFa boi dd T!DC3 tron! DG3. J3K 0enluloz, cF cu trOc 'Pch phNn nhnh. J+K Saccaroz, l(' 't '(u n"%c bro'. J*K iructoz, cF ph.n /n! trn! bPc. J)K alucoz, tc d n! "#c $%i dun! d&ch thuc t9'. JIK 6ron! dun! d&ch, !lucoz, t-n tPi ch: yRu o dPn! 'Pch $}n! $( '@t ph`n nh o dPn! 'Pch ho. S pht bi>u ng l(: A. ). B. +. C. *. D. 3. Cu 33: ai. thiRt tron! tinh th> cc n!uy;n tb s?t l( nhdn! hVnh cù chiR' I+ th> t9ch tinh th>, ph`n c}n lPi l( cc Zhe rjn! !ida cc Uu. cù, cho n!uy;n tb Zhi c:a ie l( **,k* o 13 3C Zhi l"#n! ri;n! c:a ie l( I,kI!2c'3. qn Z9nh n!uy;n tb !`n On! c:a ie l(: A. 1,1k T3. B. 1,+1T3. C. 1,)I T3. D. 1,lI T3. Cu 34: Cho I,k !a' hjn h#p 0 !-' 1 ancol ,n ch/c, bc e Uua CuC d", nun! nFn! Jph.n /n! ho(n to(nK sau ph.n /n! thy Zhi l"#n! cht r?n !i.' 3,1 !a'. Cho hjn h#p s.n ph8' tc d n! $%i T!DC 3 d" tron! DG3, un nFn! thu "#c ' !a' T!. ai tr& c:a ' l(: A. )+,k B. +3,1 C. 11,) D. k),+ Cu 35: Gjn h#p 0 !-' Daqr $( Dae. Cho hjn h#p 0 tan tron! n"%c thu "#c dun! d&ch 4. DRu cho bro' d" $(o dun! d&ch 4, sau ph.n /n! ho(n to(n, cA cPn thy Zhi l"#n! 'ui Zhan thu "#c !i.' I,3* !a'. DRu s c Zh9 clo d" $(o dun! d&ch 4, ph.n /n! ho(n to(n, cA cPn dun! d&ch thy Zhi l"#n! 'ui Zhan !i.' 11,)1* !a'. 6h(nh ph`n Zhi l"#n! c:a '@t cht tron! hjn h#p 0 l(:
A. 3*,l B. +I,k C. 33,ll D. )+,3 Cu 36: Cho h,i n"%c i Uua than nun! nFn! sau Zhi loPi b h,i n"%c d" thu "#c 1I,l1 l9t JZtcK hjn h#p Zh9 0 !-' CC1, CC $( G1. Gp th 0 $(o dun! d&ch qaJCGK1 d" thu "#c 3*,+) !a' ZRt t:a $( cF f l9t Zh9 4 thot ra. Cho 4 tc d n! $%i CuC d" nun! nFn! sau ph.n /n! thy Zhi l"#n! cht r?n !i.' ' !a'. ai tr& c:a ' l(: A. 11,k !a' B. 1,kk !a' C. l,l1 !a' D. 1,3k !a' Cu 37: Et chy ho(n to(n '@t hjn h#p 0 J!lucoz,, Yructoz,, 'etanal $( etanoicK c`n 3,3) l9t C 1 JiQu ZiBn chu8nK. rn s.n ph8' chy Uua bVnh Wn! dun! d&ch CaJCGK 1 d", sau ph.n /n! ho(n to(n thu "#c ' !a' ZRt t:a. ai tr& c:a ' l( A. 13,3 B. 11,3 C. 1*,3 D. 13,* Cu 38: CF cc pht bi>u sau: J1K c"u hu[nh, photpho, C1G*CG Qu bc chy Zhi tiRp xOc $%i CrC3. J1K eon ie3\ cF cu hVnh electron $iRt !<n l( tTru3d*. J3K q@t nhA' tW bc chy Zhi tiRp xOc $%i Zh9 clo. J+K Mhn chua cF cAn! th/c l( Da1SC+.Tl1JSC+K3.1+G1C. Cc pht bi>u !"n l(: A. J1K, J1K, J+K B. J1K, J1K. C. J1K, J1K, J3K. D. J3K, J+K. Cu 39: EiBn phNn cF '(n! n!^n $%i iBn cWc tr, 1*3 'l dun! d&ch hjn h#p CuSC + am $( DaCl 1,*m, $%i c"pn! @ d}n! iBn *T tron! l),* phOt. run! d&ch tPo th(nh b& !i.' so $%i ban ù l( 1I,1*!. ai tr& c:a a l( A. 3,* m. B. 3,+ m. C. 3,+I+m. D. 3,)m. Cu 40: Dun! hjn h#p !-' 11,1 !a' ieh ),+ !a' Cu $( 1l,* !a' 5n $%i '@t l"#n! d" l"u hu[nh Rn Zhi ph.n /n! ho(n to(n. S.n ph8' c:a ph.n /n! tc d n! $%i dun! d&ch GCl d" thu "#c Zh9 q. 6h> t9ch dun! d&ch MbJDC3K1 13 Jd L 1,1 !2'lK ti thi>u c`n d=n! > hp th hRt Zh9 q l( A. I*1,1I 'l B. l31,I3 'l C. 13*3,1k 'l D. l13,1* 'l Cu 41: Cho cc cht sau: axetilen, axit oxalic, axit acrylic, Yo'anehit, phenyl Yo'at, $inyl axetilen, !lucAz,, anehit axetic, 'etyl axetat, saccaroz,, natri Yo'at, axeton. S cht cF th> tha' !ia ph.n /n! trn! !",n! l( A. ) B. k C. I D. * Cu 42: Gjn h#p 0 !-' axit pan'itic, axit stearic $( axit linoleic. E> trun! h}a ' !a' 0 c`n *3 'l dun! d&ch DaCG 1m. mHt Zhc, nRu t chy ho(n to(n ' !a' 0 thV thu "#c 1l,3+ l9t Zh9 CC 1 Jo ZtcK $( 1+,I) !a' G1C. s 'ol c:a axit linoleic tron! ' !a' hjn h#p 0 l(: A. 31,1* B. 33 C. )1,* D. )3 Cu 43: rwy cc Zi' loPi cF cu trOc 'Pn! tinh th> lp ph",n! tN' Zhi l(: A. Da, g, qa B. Ca, Sr, qa C. m!, Ca, qa D. Da, g, m! Cu 44: 0t ph.n /n!: CCJZh9K \ G1C JZh9K CC1JZh9K \ G1JZh9K. 6ron! iQu ZiBn n! nhiBt, Zhi t^n! p sut c:a hB thV tc @ ph.n /n! n!h&ch nh" thR n(ox A. ai.'. B. 6^n!. C. CF th> t^n! hoHc !i.' D. ghAn! _i. Cu 45: GiBn t"#n! l`n l"#t x.y ra Zhi cho tX tX Rn d" dun! d&ch DaCG $(o dun! d&ch CrCl 3, th;' tiRp G1C1 d", r-i cho dun! d&ch qaCl1 $(o l(: A. 6Po ZRt t:a xanh l c r-i tan, th(nh dun! d&ch da ca', sau F cF ZRt t:a '(u $(n!. B. 6Po ZRt t:a xanh l c r-i tan, th(nh dun! d&ch '(u $(n!, sau F cF ZRt t:a da ca'. C. 6Po ZRt t:a xanh l c r-i tan, th(nh dun! d&ch '(u $(n!, sau F cF ZRt t:a '(u $(n!. D. 6Po ZRt t:a tr?n! r-i tan, th(nh dun! d&ch '(u xanh, sau F cF ZRt t:a '(u $(n!. Cu 46: Gjn h#p 0 !-' hai anZen cF t| Zhi so $%i G1 bSn! 1),)1*. cy hjn h#p 4 ch/a 1),) !a' 0 $( 1 !a' G1. Cho 4 $(o bVnh Z9n cF dun! t9ch f l9t Jo ZtcK cF ch/a Di xOc tc. Dun! bVnh '@t thpi !ian sau F "a $Q 3 o C thy p sut tron! bVnh bSn! I2l at. qiRt hiBu sut ph.n /n! hiro ho c:a cc anZen bSn! nhau $( th> t9ch c:a bVnh ZhAn! _i. GiBu sut ph.n /n! hiro ho l( A. +3. B. *3. C. I*. D. II,II. Cu 47: 0 cF cAn! th/c C+G1+C3D1. ghi cho 0 tc d n! $%i dun! d&ch DaCG thV thu "#c hjn h#p 4 !-' 1 Zh9 o iQu ZiBn th"pn! $( Qu cF Zh. n^n! l(' xanh Uu[ t9' 8'. S C6C6 ph= h#p c:a 0 l(: A. * B. 3 C. + D. 1 Cu 48: Co hai thi n!hi;' sau: 6hi n!hi;' 1: Cho )! ancol no ho ,n ch"c 0 tac dun! $,i ' !a' Da, sau phan "n! thu ",c 3,3I* ! G1. 6hi n!hi;' 1: Cho )! ancol no ho ,n ch"c 0 tac dun! $,i 1' !a' Da, sau phan "n! thu ZhAn! t%i 3,1 ! G1. 0 co cAn! th"c la:
A. CG3CG. B. C1G*CG. C. C3GICG. D. C+GlCG. Cu 49: G}a tan ' !a' hh 0 !-' CuCl 1 $( ieCl3 tron! n"%c "#c dun! d&ch 4. Chia 4 th(nh 1 ph`n bSn! nhau. Mh`n 1 : cho Zh9 G 1S d" $(o "#c 1,1k! ZRt t:a. Mh`n 1 : cho Da 1S d" $(o "#c 3,3+! ZRt t:a. ai tr& c:a ' l( : A. 1+,) ! B. k,+ ! C. 13,1 ! D. l,1 ! Cu 50: E> xc &nh h(' l"#n! c:a ieCC3 tron! UuHn! xierit, n!"pi ta l(' nh" sau: CNn 3,)33 !a' 'u UuHn!, chR ho nF theo '@t Uuy trVnh h#p l9, thu "#c dd ieSC + tron! 'Ai tr"pn! G1SC+ lown!. Chu8n @ dun! d&ch thu "#c bSn! dun! d&ch chu8n gmnC + 3,31*m thV d=n! $Xa hRt 1*,1 'l dun! d&ch chu8n. 6h(nh ph`n ph`n tr^' theo Zhi l"#n! c:a ieCC3 tron! UuHn! l(: A. 11,1k B. )3,l C. 1+,1) D. 3),*+ B S 29 Cu 1: CF hai bVnh iBn phNn '?c ni tiRp: qVnh J1K ch/a 133'l dun! d&ch CuSC + 3,1mh qVnh J1K ch/a 133'l dun! d&ch DaCl 3,1m tiRn h(nh iBn phNn cF '(n! n!^n cho t%i Zhi o bVnh hai tPo ra dun! d&ch cF pGL13 thV n!Xn! iBn phNn. ai. sb th> t9ch dun! d&ch o hai bVnh ZhAn! _i. D-n! @ 'ol2l c:a ion Cu 1\ tron! dun! d&ch bVnh J1K sau iBn phNn l(: A. 3,3+m. B. 3,13m. C. 3,3*m. D. 3,3km. Cu 2: ghi t chy ho(n to(n ),++ !a' '@t ancol no 0 thV thu "#c l,1+ !a' Zhi CC 1. mHt Zhc Zhi cho 3,1 'ol 0 tc d n! $%i Zali cho 3,3) l9t Zh9 Jo o ZtcK. CAn! th/c cu tPo thu !<n c:a 0 l( A. C3GICG. B. C1G+JCGK1. C. C3G)CG. D. C3G*JCGK3. Cu 3: Cxi hFa ' !a' 0 !-' CG3CGC, C1G3CGC, C1G*CGC bSn! oxi cF xOc tc s.n ph8' thu "#c sau ph.n /n! !-' 3 axit cF Zhi l"#n! J' \ 3,1K !a'. Cho ' !a' 0 tc d n! $%i l"#n! d" dun! d&ch T!DC 32DG3 thV thu "#c * !a' ZRt t:a. ai tr& c:a * l( A. 13,k. B. +3,1. C. 31,+. D. 11,). Cu 4: Cho cc cht sau: CG3-CG1-CGC J1K, CG1LCG-CGC J1K, JCG3K1CG-CGC J3K, CG1 LCG-CG1-CG J+K. Dhdn! cht ph.n /n! ho(n to(n $%i l"#n! d" G1 JDi, t3CK c=n! tPo ra '@t s.n ph8' l(: A. J1K, J3K, J+K. B. J1K, J3K, J+K. C. J1K, J1K, J+K. D. J1K, J1K, J3K. Cu 5: Cho 1l,k !a' hjn h#p 1 a'in ,n ch/c ZR tiRp tc d n! hRt $%i dun! d&ch GCl, l(' ZhA dun! d&ch thu "#c *1,I !a' 'ui Zhan. CAn! th/c phNn tb 1 a'in l( A. CG*D $( C1GID. B. C3GlD $( C+G11D. C. C1GID $( C3GlD. D. C3GID $( C+GlD. Cu 6: Cho s, - sau: 6inh b@t s !lucoz, s ancol etylic s axit axetic EiQu chR 333 !a' dun! d&ch CG 3CCCG 1* thV ph.i c`n ' !a' !Po Jch/a k3 tinh b@tK. qiRt hiBu sut c:a 'ji ph.n /n! Pt I*. ai tr& c:a ' l( A. 1+3 B. 1*3 C. 333 D. 13* Cu 7: Go( tan ho(n to(n I+ !a' hjn h#p 0 !-' ieC, ie 3C+, ie1C3 bSn! dun! d&ch G1SC+ lown! d" sinh ra 1Ik !a' 'ui sunYat. DRu czn! cho I+ !a' hjn h#p 0 tr;n ph.n /n! $%i l"#n! d" Zh9 CC o nhiBt @ cao. Sau ph.n /n!, dn s.n ph8' Zh9 Uua dun! d&ch n"%c $Ai tron! d" thV Zhi l"#n! ZRt t:a tPo th(nh l( 'J!K. ai tr& c:a ' l( Jcc ph.n /n! x.y ra ho(n to(nK A. 133. B. 1k3. C. 1+3. D. 1*3. Cu 8: 0, 4, 5, 6 l( cc h#p cht c:a clo. Cho Zh9 clo tc d n! n"%c $Ai thu "#c 0. Cho Zh9 clo tc d n! dun! d&ch gCG lown!, n!u@i thu "#c cht 4 $( 5. Cho Zh9 clo tc d n! dun! d&ch gCG Hc, nFn! "#c cht 6 $( 5. Cc cht 0, 4, 5, 6 l`n l"#t l(: A. CaCl1, gClC, gCl, gClC3. B. CaCCl1, gClC, gCl, gClC3. C. CaCCl1, gClC, gClC3, gCl. D. CaCCl1, gCl, gClC, gClC3. Cu 9: Cho s, - sau: Cu \ dun! d&ch 'ui 0 s ZhAn! ph.n /n!h Cu \ dun! d&ch 'ui 4 s ZhAn! ph.n /n!. Cu \ ddun! d&ch 'ui 0 \ dun! d&ch 'ui 4 s ph.n /n! f%i 0, 4 l( 'ui c:a natri. 0, 4 cF th> l( A. DaDC3, DaGSC+. B. DaTlC1, DaDC3. C. DaDC3, DaGCC3. D. DaDC1, DaGSC3. Cu 10: Caroten Jcht '(u $(n! da ca' cF tron! c: c( rtK cF cAn! th/c phNn tb C +3G*) cF ch/a li;n ZRt Ai $( cF $}n!. ghi hiro ho ho(n to(n caroten thu "#c '@t hirocacbon no cF cAn! th/c phNn tb C +3GIk. S $on! $( s li;n ZRt Ai tron! phNn tb caroten l(
A. 1 $}n! $( 11 ni Ai B. 1 $}n! $( 11 ni Ai. C. 1 $}n! $( 13 ni Ai D. 1 $}n! $( 13 ni Ai to to to Cu 11: Cho s, - C1G1 0 4 CG CCCG. 3 6ron! cc cht: C1G), C1G+, CG3CGC, CG3CCCCGLCG1. S cht ph= h#p $%i cht 0 tron! s, - tr;n l( A. 1. B. 1. C. +. D. 3. Cu 12: G}a tan ho(n to(n hjn h#p 3 Zi' loPi: 5n, ie, Cu bSn! dun! d&ch GDC 3 lown!, sau Zhi ph.n /n! x.y ra ho(n to(n, thu "#c '@t ph`n cht r?n ch"a tan hRt l( Cu. Mh`n dun! d&ch sau ph.n /n! cF cht tan l( A. 5nJDC3K1, ieJDC3K3, CuJDC3K1. B. 5nJDC3K1, ieJDC3K3. C. 5nJDC3K1, ieJDC3K1. D. 5nJDC3K1, ieJDC3K1, CuJDC3K1. Cu 13: DhOn! '@t thanh 'a!ie $(o dun! d&ch cF ch/a 3,k 'ol ieJDC 3K3 $( 3,3* 'ol CuJDC3K1. Sau '@t thpi !ian, ly thanh Zi' loPi ra, rba sPch, cNn lPi thy Zhi l"#n! t^n! 11,) !a' so $%i thanh Zi' loPi ban ù. ghi l"#n! 'a!ie w ph.n /n! l( A. 1*,13 !a'. B. 1+,33 !a'. C. 13,kk !a'. D. ),l) !a'. Cu 14: Et chy ho(n to(n ' !a' hjn h#p !-' hai este 0 1, 01 l( -n! phNn c:a nhau c`n d=n! 1l,) !a' C 1, thu "#c 11,I) lit CC1 JZtcK $( l,+* !a' G1C. mHt Zhc, nRu cho ' !a' hjn h#p tr;n tc d n! hRt $%i 133'l dun! d&ch DaCG 1m r-i cA cPn dun! d&ch sau ph.n /n! thV c}n lPi 13,l* !a' cht r?n Zhan. 6y lB 'ol c:a 0 1, 01 l( A. 1:1. B. +:3. C. 1:3. D. 3:1. Cu 15: Cho tX tX 133 'l dun! d&ch GCl 1,* m $(o 3,+ l9t dun! d&ch 0 !-' Da 1CC3 $( gGCC3 thu "#c 1,33k l9t CC1 JZtcK $( dun! d&ch 4. 6h;' dun! d&ch qaJCGK 1 d" $(o dun! d&ch 4 thu "#c 1l,** !a' ZRt t:a. D-n! @ 'ol2lit c:a Da1CC3 $( gGCC3 tron! dun! d&ch 0 l`n l"#t l( A. 3,111*m $( 3,11*m. B. 3,33I* m $( 3,3*m. C. 3,1)1*m $( 3,11*m. D. 3,1)1*m $( 3,111*m. Cu 16: 6h> t9ch dun! d&ch GCl 3,3m c`n > trun! ho( 133'l dun! d&ch hjn h#p DaCG 3,1m $( qaJCGK 1 3,1m l(: A. 1*3 'l. B. 1*3 'l. C. 133 'l. D. 133 'l. Cu 17: G}a tan ho(n to(n hjn h#p !-' '@t Zi' loPi hFa tr& 1 $( oxit Zi' loPi hFa tr& 1 $(o n"%c d". Sau Zhi ph.n /n! xon! "#c *33 'l dd 0 ch| ch/a '@t cht tan duy nht $( +,+k l9t Zh9 G 1. 69nh n-n! @ 'ol c:a dun! d&ch 0: A. 3,1m B. 3,+ m C. 3,3m D. 3,1* m Cu 18: CF 3 n! n!hiB' Wn! 3 dun! d&ch ri;n! biBt !-': CuJDC 3K1h MbJDC3K1h 5nJDC3K1 "#c nh s theo th/ tW n! l`n l"#t l( 1, 1, 3. DhOn! 3 l Zn' J!in! hBt nhauK 0, 4, 5 $(o 3 n! thV Zhi l"#n! 'ji l Zn' sn thay _i nh" thR n(ox A. 0 !i.', 4 t^n!, 5 ZhAn! _i. B. 0 t^n!, 4 t^n!, 5 ZhAn! _i. C. 0 t^n!, 4 !i.', 5 ZhAn! _i. D. 0 !i.', 4 !i.', 5 ZhAn! _i. Cu 19: rn f l9t hjn h#p Zh9 0 ch/a C1G1, C1G+, G1 Uua DiZen nun! nFn! thu "#c hjn h#p Zh9 4. rn hjn h#p 4 Uua n"%c qr1 d" thy Zhi l"#n! bVnh t^n! 3,1 !a' $( thu "#c hjn h#p Zh9 5. Et chy ho(n to(n hjn h#p Zh9 5 thu "#c +,+k l9t Zh9 CC1 JZtcK $( *,+ !a' G1C. ghi l"#n! hjn h#p 0 l( A. ),1 !a'. B. *,l !a'. C. I,* !a'. D. +,k !a'. Cu 20: Cho tXn! cht : C, ie, qaCl1, ie3C+, ie1C3, ieCC3, Tl1C3, G1S, Ge, GCl, T!DC3, Da1SC3 l`n l"#t ph.n /n! $%i G1SC+ Hc, nFn!. S ph.n /n! thu@c loPi ph.n /n! oxi hFa Zhb l( A. ). B. *. C. I. D. k. Cu 21: Cho cc cht ri;n! biBt: axit Yo'ic, anehit axetic, ancol etylic, axit axetic. 6h/ tW cc ho cht d=n! l(' thuc thb > phNn biBt cc cht tr;n l(: A. Uu[ t9', dun! d&ch DaCG. B. Uu[ t9', dun! d&ch DaGCC3. C. dun! d&ch T!DC32DG3, dun! d&ch DaCG. D. Uu[ t9', dun! d&ch T!DC32DG3. Cu 22: G}a tan ho(n to(n 3 !a' hjn h#p 0 !-' m!, 5n, ie tron! dun! d&ch GDC3 lown! d". Sau ph.n /n! thu "#c dun! d&ch 4 ch/a 1),l*! 'ui JZhAn! cF DG+DC3K $( 1,)k l9t Zh9 5 JZcK. 5 cF th> l(: A. DC1. B. DC. C. D1C. D. D1 Cu 23: Cho cc ph.n /n! sau : to to J1K i1 \ G1C J1K T! \ C3 to to J3K ge \ G1C \ C3 J+K DhiBt phNn CuJDC3K 1
t t J*K EiBn phNn dun! d&ch G1SC+ J)K EiBn phNn dun! d&ch CuCl 1 o 3 t to JIK DhiBt phNn gClC3 JmnC1, t K JkK EiBn phNn dun! d&ch T!DC3 S ph.n /n! '( s.n ph8' tPo ra cF C1 l( A. *. B. I. C. ). D. k. Cu 24: CF hai bVnh Z9n ZhAn! !iwn no Wn! `y cc hjn h#p Zh9 o toC nh" sau: - qVnh J1K ch/a G1 $( Cl1 - qVnh J1K ch/a CC $( C1 Sau Zhi un nFn! cc hjn h#p > ph.n /n! x.y ra, "a nhiBt @ $Q trPn! thi ban ù thV p sut tron! A. bVnh J1K t^n!, bVnh J1K !i.'. B. bVnh J1K !i.', bVnh J1K t^n!. C. bVnh J1K ZhAn! _i, bVnh J1K t^n!. D. bVnh J1K ZhAn! _i, bVnh J1K !i.'. Cu 25: Cho 13,3 !a' hjn h#p 0 !-' m! $( 5n $(o +33 'l dun! d&ch G1SC+ 1,1m thu "#c Zh9 G1. Cho to(n b@ l"#n! Zh9 i Uua CuC d" thy Zhi l"#n! cht r?n !i.' +,+k !a'. Mh`n tr^' $Q Zhi l"#n! c:a m! tron! hjn h#p 0 l( : A. )3. B. 3). C. 1+. D. +k. Cu 26: cy c=n! Zhi l"#n! cc Zi' loPi m!, ie, Tl $( 5n cho $(o dun! d&ch G 1SC+ Hc, nFn!, d". 6h> t9ch Zh9 SC1 thu "#c Jo o c=n! iQu ZiBnK t",n! /n! $%i cc Zi' loPi "#c s?p xRp theo chiQu t^n! d`n l(: A. 5n ] ie ] m! ] Tl. B. ie ] 5n ] Tl ] m!. C. 5n ] ie ] Tl ] m!. D. 5n ] m! ] ie ] Tl. Cu 27: Gjn h#p Zi' loPi Qu ph.n /n! $%i 'ui s?t JeeeK tron! dun! d&ch nh"n! khn 8y "#c s?t ra Zhi 'ui l( A. ie, Di, Cu. B. m!, Tl, 5n. C. g, Ca, Tl. D. Cu, m!, Di. Cu 28: Cho I,1 !a' hjn h#p hai 'ui cacbonat c:a hai Zi' loPi ZR tiRp nhau tron! nhF' eeT. Go( tan hRt hjn h#p hai 'ui F tron! dun! d&ch GCl thu "#c Zh9 q. q "#c hp th ho(n to(n boi +*3'l dun! d&ch qaJCGK1 3,1m thy xut hiBn 1*,I) !a' ZRt t:a. hai Zi' loPi F l(: A. m! - Ca hoHc Ca { Sr. B. qe { m!. C. qe - m! hoHc m! { Ca. D. m! { Ca. Cu 29: DhOn! thanh 5n, thanh Cu $( thanh h#p Zi' 5n-Cu l`n l"#t $(o ba cc 1, 1, 3 Qu ch/a dun! d&ch GCl n-n! @ bSn! nhau. 6c @ thot Zh9 G1 din ra nhanh nht o cc A. 3. B. 1 $( 3. C. 1. D. 1. Cu 30: 6ron! cAn! n!hiBp hiBn nay, > iQu chR axetanehit n!"pi ta A. oxi ho etilen bSn! C1 cF xOc tc MbCl1 $( CuCl1 J t3CK. B. oxi ho ancol etylic bSn! CuC J t3CK. C. cho axetilen h#p n"%c o to L k3oC $( xOc tc G!SC+. D. thuy phNn dn xut halo!en J CG3-CGCl1 K tron! dun! d&ch DaCG. Cu 31: T'ino axit 'Pch ZhAn! phNn nhnh 0 ch/a a nhF' -CCCG $( b nhF' -DG 1. ghi cho 1 'ol 0 tc d n! hRt $%i axit GCl thu "#c 1)l,* !a' 'ui. Cho 1 'ol 0 tc d n! hRt $%i dun! d&ch DaCG thu "#c 1II !a' 'ui.C6M6 c:a 0 l( A. C3GIDC1. B. C+GIDC+. C. C+G)D1C1. D. C*GIDC1. Cu 32: rwy cc Zi' loPi cF th> iQu chR bSn! ph",n! php nhiBt luyBn tron! cAn! n!hiBp l(: A. Da, ie, Sn, Mb. B. Cu, ie, Mb, m!. C. Tl, ie, Cu, Di. D. Di, 5n, ie, Cu. Cu 33: 0\ cF t_n! s hPt l( *I, 4 l( n!uy;n t thu@c chu ZV nh ZR cn li;n tiRp $%i 0, c=n! nhF' $%i 0. fy 4 l(: A. E-n!. B. citi. C. Datri. D. ma!ie. Cu 34: Cho 1),1 ! hjn h#p este c:a ancol 'etylic $( hai axit cacboxylic no, ,n ch/c tc d n! $Xa : $%i dun! d&ch DaCG 1m thu "#c dun! d&ch A. CA cPn dd T thu "#c 1I,k ! hjn h#p hai 'ui Zhan, th> t9ch dun! d&ch DaCG 1 m w d=n! l( A. 3,1 l9t. B. 3,1* l9t. C. 3,3 l9t. D. 3,3* l9t. Cu 35: CF + dun! d&ch ZhAn! '(u Wn! tron! + l< 't nhwn: DaCl, m!Cl 1, TlCl3, ieCl1. CF th> d=n! Zi' loPi n(o d"%i Ny > phNn biBt + dun! d&ch tr;n JZhAn! "#c sb d n! th;' thuc thb ZhcKx A. Tl. B. T!. C. ie. D. Da.
Cu 36: Gjn h#p 0 !-' CG3CCCG $( C1G*CG. Cho ' !a' 0 tc d n! hRt $%i Da thu "#c 3,3) l9t G 1JZtcK. Cho ' !a' 0 tc d n! $%i gGCC3 d" thu "#c 1,1+ l9t CC1 JZtcK. DRu un nFn! ' !a' 0 JxOc tc G1SC+ HcK$%i hiBu sut ph.n /n! )3 thV l"#n! este thu "#c l( A. *,1k !a'. B. ),1) !a'. C. k,k !a'. D. 13,*) !a'. Cu 37: Cho s, - chuy>n ho sau: J1K C3G+C1 \ DaCG JTK \ JqK J1K JTK \ G1SC+ lown! JCK \ JrK J3K JCK \ T!DC3 \ DG3 \ G1C J~K \ T! \ DG+DC3 J+K JqK \ T!DC3 \ DG3 \ G1C JiK \ T! \ DG+DC3 Cc cht JqK $( JCK Jtheo th/ tWK cF th> l( A. CG3CGC $( GCCCG. B. CG3CGC $( GCCCDa. C. GCGC $( GCCCG. D. GCGC $( CG3CGC. Cu 38: Cxi hFa +,) !a' hjn h#p hai ancol no ,n ch/c 'Pch ho th(nh anehit thV d=n! hRt k !a' CuC. Cho to(n b@ andehit tc d n! $%i dun! d&ch T!DC32DG3 d", un nFn! thu "#c 31,+ !a' T! JhiBu sut ph.n /n! l( 133K. CAn! th/c c:a hai ancol l(: A. C3GICG1CG $( C+GlCG1CG. B. CG3CG $( C1G*CG1CG C. C1G*CG $( CG3CG1CG1CG. D. CG3CG $( C1G*CG. Cu 39: Cho cc dun! d&ch: GDC3, DaCl, Da1SC+, CaJCGK1, gGSC+, m!JDC3K1. rwy !-' cc dun! d&ch Qu tc d n! "#c $%i dun! d&ch qaJGCC3K1 l(: A. GDC3, DaCl, Da1SC+, CaJCGK1. B. GDC3, CaJCGK1, gGSC+, m!JDC3K1. C. DaCl, Da1SC+, CaJCGK1, gGSC+. D. GDC3, CaJCGK1, gGSC+, Da1SC+. Cu 40: 6r@n +33 'l dun! d&ch 0 ch/a Da\, g\, x 'ol CG{ Jt_n! s 'ol Da\ $( g\ l( 3,3) 'olK $%i )33 'l dun! d&ch 4 ch/a 3,31 'ol SC+1{, 3,33 'ol Cl{, y 'ol G\. pG c:a dun! d&ch thu "#c sau ph.n /n! l( A. 1,3. B. 11,3. C. 13,3. D. 1,3. Cu 41: m@t h#p cht hdu c, 0 cF C6M6 C 3G13C3D1. Cho 0 ph.n /n! $%i DaCG d", cA cPn dun! d&ch sau ph.n /n! thu "#c cht r?n 4 Jch| cF cc h#p cht $A c,K $( ph`n h,i 5 Jch| cF '@t h#p cht hdu c, no, ,n ch/c 'Pch ZhAn! phNn nhnhK. CAn! th/c cu tPo c:a 0 l( A. G1D-CGJCGKCGJDG1KCCCG. B. GCCCDG3CG1CG1DC1. C. GC-CG1-CG1-CCCDG+. D. CG3-CG1-CG1-DG3DC3. Cu 42: Chia hjn h#p !-' m! $( m!C th(nh 1 ph`n bSn! nhau: - Mh`n 1 cho tc d n! hRt $%i dun! d&ch GCl thu "#c 3,3) l9t G 1JZtcK, dun! d&ch sau ph.n /n! ch/a +1,I* !a' 'ui - Mh`n 1 cho tc d n! hRt $%i dun! d&ch GDC 3 thu d"#c 3,++k l9t Zh9 0 n!uy;n cht JZtcK. CA cPn c8n thn $( l(' ZhA dun! d&ch sau ph.n /n! thu "#c )I,) !a' 'ui. CAn! th/c phNn tb c:a Zh9 0 l(: A. DC1. B. D1. C. DC. D. D1C. Cu 43: qradiZinin cF tc d n! l(' !i.' huyRt p. EF l( nonapeptit cF cAn! th/c $iRt t?t l( Tr! { Mro { Mro { aly { Mhe { Ser { Mro { Mhe { Tr!. ghi th:y phNn ZhAn! ho(n to(n peptit n(y thV s tripeptit cF ch/a phenylalanin JMheK ti a thu "#c l( A. +. B. *. C. ). D. I. Cu 44: Gjn h#p Zh9 0 !-' G1 $( C1G+ cF t| Zhi so $%i Ge l( 3,I*. rn 0 Uua Di nun! nFn!, thu "#c hjn h#p Zh9 4 cF t| Zhi so $%i Ge l( *. GiBu sut c:a ph.n /n! hiro ho l( A. +3. B. 13. C. 1*. D. *3. Cu 45: Cho hjn h#p 0 !-' hai h#p cht hdu c, no, ,n ch/c tc d n! $Xa : $%i 133 'l dun! d&ch DaCG 3,*m, thu "#c '@t 'ui $( ++k 'l h,i '@t ancol Jo ZtcK. DRu t chy ho(n to(n l"#n! hjn h#p 0 tr;n, sau F hp th hRt s.n ph8' chy $(o bVnh Wn! dun! d&ch CaJCGK 1 Jd"K thV Zhi l"#n! bVnh t^n! k,)k !a'. CAn! th/c c:a hai h#p cht hdu c, tron! 0 l( A. GCCCG $( GCCCCG3. B. GCCCG $( GCCCC1G*. C. CG3CCCG $( CG3CCCC1G*. D. C1G*CCCG $( C1G*CCCCG3. Cu 46: 6ron! cc poli'e sau: J1K poliJ'etyl 'etacrylatKh J1K t, capronh J3K nilon-),)h J+K poliJetylenterephtalatKh J*K poliJ$inylcloruaKh J)K poliJ$inyl axetatK. Cc poli'e cF th> t_n! h#p bSn! ph.n /n! tr=n! h#p l(: A. J1K, J3K, J+K, J)K. B. J1K, J1K, J+K, J)K. C. J1K, J1K, J*K, J)K. D. J1K, J1K, J3K, J*K.
Cu 47: 6huy phNn cc cht sau tron! 'Ai tr"pn! ZiQ': CG3CGCl1 J1K, CG3CCCCGLCG-CG3 J1K, CG3CCCCJCG3KLCG1 J3K, CG3CG1CCl3 J+K, CG3CCC-CG1-CCCCG3 J*K, GCCCC1G* J)K. DhF' cc cht sau Zhi thuy phNn cho s.n ph8' cF Zh. n^n! tha' !ia ph.n /n! trn! !",n! l(: A. J1K, J1K, J3K, J)K. B. J1K, J+K, J*K, J)K. C. J1K, J1K, J*K, J3K. D. J1K, J1K, J*K, J)K. Cu 48: G#p cht 0 l( dn xut c:a benzen cF C6M6 C kG13C1. 0 tc d n! $%i DaCG theo t| lB 'ol 1:1. mHt Zhc cho 0 tc d n! $%i Da thV s 'ol G 1 thu "#c On! bSn! s 'ol c:a 0 w ph.n /n!. DRu tch '@t phNn tb G1C tX 0 thV tPo ra s.n ph8' cF Zh. n^n! tr=n! h#p tPo poli'e. S C6C6 ph= h#p c:a 0 l( A. ). B. 1. C. *. D. I. Cu 49: Cho a 'ol ie $(o dun! d&ch b 'ol GDC3 thu "#c Zh9 DC $( dun! d&ch ch/a 1 'ui ie . 6hiRt lp 'i Uuan hB !ida a,b. A. ka23]b]+a. B. 1a] b ]+a. C. Ia23]b]+a. D. 3a] b]+a. Cu 50: CF cc n!uy;n t hFa h<c: l0h 13mh 1*4h 1I. 6h/ tW cc n!uy;n t cF @ N' iBn t^n! d`n l( A. m ] 0 ] 4 ] . B. m ] 4 ] ] 0. C. 4 ] m ] ] 0. D. m ] 4 ] 0 ] . B S 30 Cu 1: ghi iBn phNn '@t dun! d&ch 'ui,!i tr& pG o Zhu $Wc !`n '@t iBn cWc !i.' xun!.run! d&ch 'ui e' iBn phNn l( : A. gCl B. CuSC+ C. g1SC+. D. CuCl1 Cu 2: 6ron! s cc cht sau: GCCCG, CG3CGC, CG3CG1CG, CG3CCCG cht $Xa cF Zh. n^n! tha' !ia ph.n /n! trn! bPc, $Xa cF Zh. n^n! tc d n! $%i Da !i.i phFn! G1 l(: A. CG3CCCG. B. CG3CGC. C. GCCCG. D. CG3CG1CG. Cu 3: Gjn h#p !-' hirocacbon 0 $( oxi cF t| lB s 'ol t",n! /n! l( 1:13. Et chy ho(n to(n hjn h#p tr;n thu "#c hjn h#p Zh9 4. Cho 4 Uua dun! d&ch G1SC+ Hc, thu "#c hjn h#p Zh9 5 cF t| Zhi i $%i hiro bSn! 1l. CAn! th/c phNn tb c:a 0 l( : A. C+Gk. B. C3G). C. C3Gk. D. C3G+. Cu 4: 6h;' tX tX tXn! !i<t G1SC+ $(o dun! d&ch qaJCGK1 Rn d" thV @ dn iBn c:a hB sn biRn _i nh" sau: A. lOc ù t^n!, sau F !i.'. B. !i.' d`n. C. lOc ù !i.', sau F t^n!. D. t^n! d`n. Cu 5: 6X anehit no ,n ch/c T cF th> chuy>n trWc tiRp th(nh ancol q $( axit r t",n! /n! > iQu chR este ~ tX q $( r. Gwy xc &nh t| s d L m~ 2 mT. A. 1 21 B. 123 C. 321 D. 121 Cu 6: 6ron! cc loPi phNn bFn sau: DG+Cl, JDG1K1CC, JDG+K1SC+, DG+DC3h loPi cF h(' l"#n! P' cao nht l( A. DG+DC3. B. DG+Cl. C. JDG1K1CC. D. JDG+K1SC+. Cu 7: m@t loPi thuy tinh ch/a 13,3 Da1Ch 11,I CaC $( I*,3 SiC1 $Q Zhi l"#n!. 6h(nh ph`n c:a loPi thuy tinh n(y bi>u din d"%i dPn! cc oxit l( A. Da1C.)CaC.SiC1. B. Da1C.CaC.)SiC1. C. 1Da1C.CaC.)SiC1. D. 1Da1C.)CaC.SiC1. Cu 8: 6ch n"%c hjn h#p 1 r"#u thu "#c 1 anZen. ~te hFa ho(n to(n hjn h#p 1 r"#u tr;n thV thu "#c 3 ete, tron! F cF 1 ete l( C*G11C. ~te cF Zhi l"#n! phNn tb l%n nht thu "#c l(: A. I+ B. kk C. +) D. 133 Cu 9: Gp th ho(n to(n +,+k l9t Zh9 CC1 Jo ZtcK $(o 133 'l dun! d&ch hjn h#p !-' DaCG 1,* m $( qaJCGK1 1m, sinh ra ' !a' ZRt t:a. ai tr& c:a ' l( A. 1l,I3. B. 3l,+3. C. 11,k1. D. l,k*. Cu 10: Cho 1,3k !a' 0 cF cAn! th/c phNn tb C 1G)C*D1 J l( 'ui c:a -a'ino axit $%i GDC3 K ph.n /n! $%i 1*3 'l dun! d&ch DaCG 3,1 m . Sau ph.n /n! cA cPn thu "#c ' !a' r?n 4. ai tr& c:a ' l(: A. 1,1+ B. 1,11 C. 1,13 D. 1,31 Cu 11: Cho cc cht ln! sau:axit axetic,!lixerol,triolein.E> phNn biBt cc cht ln! tr;n,cF th> ch| c`n d=n!: A. n"%c $( Uu[ t9' B. n"%c $( dd DaCG C. dd DaCG D. n"%c qr1
Cu 12: Chia dun! d&ch 0 !-' CuSC+ $( TlJDC3K3 th(nh 1 ph`n bSn! nhau. Mh`n 1 cho tc d n! $%i dun! d&ch qaCl1 d" thu "#c ),ll !a' ZRt t:a. Mh`n 1 cho tc d n! $%i dun! d&ch DaCG d", r-i ly ZRt t:a nun! Rn Zhi l"#n! ZhAn! _i thu "#c ' !a' cht r?n. ai tr& c:a ' l( A. 11,). B. +,+. C. 3,1. D. 1,+. Cu 13: G#p cht hdu c, 0 ch/a cc n!uy;n tJC,G,ClK cF ClLk+,*3 $Q Zhi l"#n!.0 tc d n! $Xa : $%i dd DaCG thu "#c cht hdu c, 4.ghi l"#n! phNn tb 4 cF !i tr& A. )3 B. lk C. ++ D. k1 Cu 14: E> thu "#c CC1 tinh ZhiRt tX hjn h#p CC1 b& ln Zh9 GCl $( h,i n"%c ta cho hjn h#p Uua l`n l"#t cc bVnh ch/a l"#n! d" A. dd DaGSC+, dd G1SC+ Hc. B. dd G1SC+ Hc, dd Da1CC3. C. dd Da1CC3, dd G1SC+ Hc. D. dd G1SC+ Hc, DaGCC3. Br J1:1K NaOH CuO GCC-CG1-CGC Cu 15: Cho s, - sau: C3G) 0 4 C6C6 c:a 0 l(: A. CG1qr-CGLCG1 B. CG3CG1CG1CG C. qrCG1CG1CG1qr D. CG3CGJqrKCG1qr Cu 16: Ch<n pht bi>u On! $Q C1 $( C3x A. C1 $( C3 cF s proton $( n,tron tron! phNn tb nh" nhau. B. C1 $( C3 l( cc dPn! th= hVnh c:a n!uy;n t oxi. C. C1 $( C3 cF t9nh oxi ho 'anh nh" nhau. D. C. C1 $( C3 Qu ph.n /n! "#c $%i cc cht T!, ge, MbS o nhiBt @ th"pn!. Cu 17: Cho lu-n! Zh9 CC i Uua n! s/ Wn! 'J!K ie 1C3 o nhiBt @ cao '@t thpi !ian n!"pi ta thu "#c ),I1J!K hjn h#p + cht r?n Zhc nhau.Ee' h}a tan hjn h#p n(y $(o dun! d&ch GDC 3 d" tPo th(nh 3,)I1JlK DC duy nhtJZtcK.ai tr& c:a ' l(: A. ),k3J!K B. ),I1J!K C. k,k3J!K D. I,++J!K Cu 18: Cho f l9t Cl1 JZtcK tc d n! $%i dd DaCG lown!, n!u@i d" thu "#c ' 1 !a' t_n! Zhi l"#n! 1 'ui. Cho 1f l9t Zh9 Cl1 JZtcK tc d n! $%i dd DaCG Hc, nFn! d" thu "#c '1 !a' t_n! Zhi l"#n! 1 'ui. 6| lB '1: '1 bSn!: A. 1:1. B. 1:3 C. 1:1 D. 1:1 Cu 19: Cho biRt s hiBu n!uy;n tb c:a cc n!uy;n t: 5 G L 1, 5q L *, 5C L ), 5D L I, 5C L k, 5Tl L13, 5M L 1*, 5S L 1). DhF' n(o sau Ny ch/a to(n cc cht ZhAn! tuNn theo Uui t?c bt tbx A. qG3, DC1, MCl*. B. CC1 , C1G), GDC3. C. CG+, CC1, Tl1S3. D. CG+, G1C1, CS1. Cu 20: Cho 3,3* 'ol cht hdu c, 0 tc d n! ho(n to(n $%i dd qr1,thu "#c cht hdu c, 4Jch/a 3 n!uy;n tK.ghi l"#n! dd qr1 t^n! l;n 1,1 !a'.6h:y phNn cht 4 "#c cht 5 ZhAn! cF Zh. n^n! h}a tan CuJCGK1.Cht 0 l(: A. axit Yo'ic B. ancol etylic C. propen D. xiclo propan Cu 21: Cho a J'olK h#p cht hdu c, 0 cF cAn! th/c phNn tb C IGkC1 tc d n! $%i natri d" thu "#c a J'olK Zh9 G1JZtcK. mHt Zhc, a J'olK0 nFi tr;n tc d n! $Xa : $%i a J'olK qaJCGK1. 6ron! phNn tb 0 cF th> ch/a: A. 1 nhF' CCG1CG li;n ZRt $%i nhNn th,'. B. 1 nhF' CG li;n ZRt trWc tiRp $%i nhNn th,'. C. 1 nhF' cacboxyl CCCG li;n ZRt $%i nhNn th,'. D. 1 nhF' CG1CG $( 1 nhF' CG li;n ZRt $%i nhNn th,'. Cu 22: Cho 1+,1 !a' M1C* $(o 133 'l dun! d&ch ch/a DaCG 1m $( gCG 1m thu "#c dun! d&ch 0. 6_n! Zhi l"#n! 'ui tan cF 'Ht tron! 0 l(: A. 1k,) !a' B. 1I,1 !a' C. 1l,+ !a' D. 1l,1 !a' Cu 23: Et chy ho(n to(n a !a' este 0 tPo boi ancol no,,n ch/c,'Pch ho $( axit ZhAn! noJcF '@t li;n ZRt AiK,,n ch/c,'Pch ho thu "#c k,l) l9t CC1 JZcK $( *,+ !a' G1C.ai tr& c:a a l(: A. *,) !a' B. *,+ !a' C. k,) !a' D. k,k !a' Cu 24: DPp 1 Zh9 D1 $( G1 $(o bVnh Z9n > thWc hiBn ph.n /n!: D1 \ 3G1 1DG3. Sau '@t thpi !ian, n-n! @ cc cht tron! bVnh nh" sau:tD1u L 1mh tG1u L 3mh tDG3u L 1m. D-n! @ 'ol2l c:a D1 $( G1 ban ù l`n l"#t l( A. + $( k. B. 1 $( 3. C. 1 $( +. D. 3 $( ). Cu 25: 6ron! cAn! n!hiBp, andehit Yo'ic "#c iQu chR trWc tiRp tX
1
A. r"#u 'etylic B. r"#u etylic C. 'etyl axetat D. axit Yo'ic Cu 26: Cho *,l !a' hirocacbon th,' T J cF $}n! benzen K bc h,i tron! bVnh Z9n dun! t9ch *,) l9t tPi nhiBt @ 13),*3C thV p sut tron! bVnh lOc n(y l( 3,3 at'.S -n! phNn cu tPo tha 'wn T l(: A. ) B. 11 C. k D. 13 Cu 27: 0t cc loPi h#p cht hdu c,, 'Pch ho sau : "#u ,n ch/c no J +K, anehit ,n ch/c no J,K, r"#u ,n ch/c ZhAn! no 1 i Ai J -Kh andehit ,n ch/c, ZhAn! no 1 ni Ai J .K. n! $%i cAn! th/c t_n! Uut CnG1nC ch| cF 1 cht sau : A. 0, 6 B. 5, 6 C. 0, 4 D. 4, 5 Cu 28: 0( ph}n! hFa 1,I) !a' '@t este 0 bSn! dun! d&ch DaCG $Xa :,thu "#c +,++ !a' hjn h#p 1 'ui c:a Da.Dun! nFn! 1 'ui n(y tron! C1 d",sau Zhi ph.n /n! ho(n to(n,thu "#c 3,1k !a' Da 1CC3h1,+)+ l9t Zh9 CC1 JZcK $( 3,l !a' n"%c.CAn! th/c ,n !i.n czn! l( C6M6 c:a 0.fy C6C6 thu !<n c:a 0 l(: A. C)G*CCCCG3 B. GCCCC)G* C. CG3CCCC)G* D. GCCCC)G+CG Cu 29: rn tX tX Rn d" Zh9 G1S Uua dun! d&ch 0 ch/a DaCl, DG+Cl, CuCl1 $( ieCl3 thu "#c ZRt t:a 4 !-' A. CuS $( ieS. B. CuS. C. CuS $( S. D. ie1S3 $( CuS. Cu 30: S n!uy;n t '( n!uy;n tb cF t_n! s + electron tr;n phNn l%p s l(: A. 1. B. I. C. 1. D. ). Cu 31: Et chy ho(n to(n ' !a' '@t a'in 0 bSn! '@t l"#n! ZhAn! Zh9 $Xa : thu "#c 1I,)! CC 1,11,) ! G1C $( )l,++ l9t Zh9 D1 JEg6CK.ai. thiRt ZhAn! Zh9 ch| !-' JfD1 Lk3 $( fC1L13K.ai tr& ' $( s -n! phNn cu tPo c:a a'in 0 l`n l"#t l(: A. l $( ) B. ) $( l C. l $( 1 D. k $( 1 Cu 32: Go( tan ho(n to(n '@t l"#n! Zi' loPi ho tr& ee bSn! dun! d&ch GCl 1+,) $Xa : "#c '@t dun! d&ch 'ui cF n-n! @ 1+,1*.gi' loPi w cho l(: A. ie B. qa C. 5n D. m! Cu 33: ghb ho(n to(n +,3) !a' '@t oxit Zi' loPi bSn! CC o nhiBt @ cao th(nh Zi' loPi. rn to(n b@ Zh9 sinh ra $(o bVnh Wn! dun! d&ch CaJCGK1 d" thy tPo th(nh I !a' ZRt t:a.DRu ly Zi' loPi sinh ra h}a tan hRt $(o dun! d&ch GCl d" thV thu "#c 1,1I) l9t hiro.fy l"#n! 'ui Zi' loPi thu "#c Zhi cho 3+,k !a' oxit tr;n tc d n! ho(n to(n $%i dun! d&ch GCl d" l( A. +3,+1* !a' B. I3,)kI* !a' C. )I,k3 !a' D. )1,3k !a' Cu 34: Gjn h#p 0 !-' axit 4 ,n ch/c $( axit 5 hai ch/cJ4,5 cF c=n! s n!uy;n tb cacbonK.Chia 0 th(nh 1 ph`n bSn! nhau. -Mh`n 1: tc d n! $%i Da d" sinh ra +,+k l9t Zh9 G1JZcK -Mh`n 1: t chy ho(n to(n tPo 1),+ !a' CC1 C6C6 thu !<n $( Zhi l"#n! c:a 5 tron! hjn h#p 0 l(: A. GCCC-CG1-CCCG :I3,kI B. GCCC-CG1-CCCG:*+,kk C. GCCC-CCCG :)3,33 D. GCCC-CCCG : +1,k) Cu 35: D!uy;n tb n!uy;n t cF t_n! s cc loPi hPt l( 11*. S hPt 'an! iBn nhiQu h,n s hPt ZhAn! 'an! iBn l( 1*. S Zhi c:a l(: A. I3. B. l3. C. k3. D. I*. Cu 36: CF th> d=n! G1SC+ Hc > l(' ZhA tt c. cc Zh9 tron! dwy n(o sau Nyx A. CC1, D1, SC1, C1. B. CC1, D1, G1, C1. C. CC1, G1S, D1, C1. D. CC1, DG3, G1 , D1. Cu 37: EiQu Zhn! &nh n(o sau Ny luAn On!: A. CF '@t Zi' loPi duy nht o nhiBt @ th"pn! o trPn! thi ln! . B. qn Z9nh n!uy;n tb Zi' loPi luAn l%n h,n bn Z9nh n!uy;n tb phi Zi'. C. D!uy;n tb Zi' loPi n(o czn! Qu cF 1h1 hoHc 3 electron o l%p n!o(i c=n! . D. Cc Zi' loPi Qu o phNn nhF' ch9nh c:a b.n! hB thn! tu`n ho(n.
JCG1K1CCCG CG3 CG CCCG G1D CG1 C D CG C D C G C G Cu 38: 6h:y phNn peptit :
S.n ph8' n(o d"%i Ny l( khn th> cF A. Tla B. Tla-alu
C. aly-Tla
D. alu-aly
Cu 39: Cho cc 'Bnh Q: 1K cc n!uy;n tb Zi' loPi cF th> tha' !ia ph.n /n! oxi ho - Zhb czn! nh" ph.n /n! trao _i. 1K cc Zi' loPi Zhi tha' !ia ph.n /n! ho h<c luAn Fn! $ai tr} l( cht Zhb. 3K ph.n /n! thRJtron! ho $A c,K luAn l( ph.n /n! oxi ho - Zhb. +K ph.n /n! ho h#p cF th> l( ph.n /n! oxi ho - Zhb hoHc ZhAn!. *K tron! ph.n /n! oxi ho - Zhb ZhAn! th> cF Uu '@t n!uy;n t th> hiBn t9nh oxi ho $( '@t n!uy;n t th> hiBn t9nh Zhb. 6ron! cc 'Bnh Q tr;n thV A. tt c. On!. B. 1 $( * sai. C. ch| cF 1 sai. D. ch| cF * sai. Cu 40: Cho !lucoz, l;n 'en th(nh r"#u JancolK etylic. rn Zh9 CC 1 tPo th(nh Uua dun! d&ch n"%c $Ai tron! d", thu "#c *3 !a' ZRt t:a. qiRt hiBu sut c:a Uu trVnh l;n 'en l( k3. ghi l"#n! !lucoz, c`n d=n! ban ù l( A. *),1* !a'. B. 111,* !a'. C. +*,33 !a'. D. 3),33 !a'. Cu 41: Cho 1+,l+k !a' hjn h#p gmnC+ $( mnC1 Jtron! F mnC1 chiR' ),lk $Q Zhi l"#n!K tc d n! $%i 1*3 'l GCl 3),k Jd L 1,1l !2'lK. c"#n! Zh9 clo thu "#c Jo ZtcK l(: A. 1,31) l9t B. *,1l)k l9t C. 3,311 l9t D. +,l1k l9t Cu 42: Cho cc h#p cht sau: 1K alixerin 1K alucoz, 3K iructoz, +K Saccaroz, *K 6inh b@t )K 0enluloz, Dhdn! h#p cht tc d n! $%i CuJCGK1 cho dun! d&ch '(u xanh la' l(: A. 1, 1, 3, +, B. 1, 1, * C. 1, 1, 3, + D. 1, 1, +, ) Cu 43: Gjn h#p T !-' hai cht ZR tiRp nhau tron! dwy -n! n! c:a axit Yo'ic. Et chy hRt ' !a' hjn h#p T r-i cho s.n ph8' chy hp th hRt $(o l"#n! d" dun! d&ch CaJCGK 1 thV thu "#c 13! ZRt t:a. C}n Zhi cho ' !a' hjn h#p T tc d n! hRt $%i DaGCC3 thV thu "#c 1,31) l9t CC1 JZtcK. ghi l"#n! 'ji axit tron! hjn h#p T l( A. 1,l) !a'h 3 !a' B. 1,k+ !a'h 3 !a' C. 1,3 !a'h 1,l) !a' D. 1,+ !a'h 3,I !a' Cu 44: Eun nFn! '@t hjn h#p 1 ancol no ,n ch/c $%i G1SC+ Hc o 1+33C thu "#c 11,) !a' n"%c $( I1 !a' hjn h#p 3 ete.qiRt 3 ete thu "#c cF s 'ol bSn! nhau $( ph.n /n! x.y ra ho(n to(n.C6M6 c:a 1 r"#u l(: A. C3GICG h CG3CG B. C3GICG h C+GlCG C. CG3CG h C1G*CG D. C1G*CG h C3GICG Cu 45: DRu h(' l"#n! '@t Zi' loPi tron! 'ui cacbonat l( +3 thV h(' l"#n! Zi' loPi n(y tron! 'ui photphat l(: A. +*,33 B. 3k,I1 C. )3,33 D. 1l,*3 Cu 46: CAn! th/c c:a a'in ch/a 1*,3* Zhi l"#n! nit, l(: A. C)GkD1 B. C)GID C. C1GkD1 D. C1GID Cu 47: CAn! th/c chun! c:a axit cacboxylic no, x ch/c, 'Pch ho l(x A. CnG1n\1Cx. B. CnG1nC1x. C. CnG1nC1. D. CnG1n\1-1xC1x. Cu 48: Dhdn! Zi' loPi n(o sau Ny cF th> "#c iQu chR tX oxit, bSn! ph",n! php nhiBt luyBn nhp cht Zhb CC A. qa,Cu,Ca B. ie,Cu,Di C. Mb,m!,ie D. ie,T!,Tl Cu 49: Cho +,1! anehit T 'Pch ho ph.n /n! $%i l"#n! d" dun! d&ch T!DC 3 tron! DG3, to(n b@ l"#n! T! thu "#c h}a tan hRt tron! dun! d&ch GDC 3 Hc nFn! d" nhn "#c 3,Il1 l9t DC 1 o 1I3C $( I+3''G!. CAn! th/c cu tPo c:a T l(: A. CG3CG1CGC B. CG1LCGCG1CGC C. GCC-CGLCG-CGC D. CG1LCGCGC Cu 50: 6ron! dun! d&ch CG3CCCG cF cNn bSn!:CG3CCCG CG 3CCC- \ G\.E@ iBn li c:a CG3CCCG sn nh" thR n(o Zhi nh $(i !i<t dun! d&ch DaCG $(ox A. ZhAn! biRn _i B. t^n! C. !i.' D. ZhAn! xc &nh "#c

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Cu 34: Cho cc cht sau: axetilen, etilen, benzen, buta-1,3-ien, stiren, toluen, anlyl benzen, naphtalen. S cht tc d n!

Cu 39: Cho 1 ph.n /n! sau:

ipeptit Zhc nhaux T. 1

CG 1LCG1 \ G1C C1G*CG \ Gqr JbZK

Cl 1 \ gCG m!JDC 3K1 Da 1C1 \ G1C

CG3 -CGLCG 1 \ qr 1JddK

S.n ph8' n(o d"%i Ny l( khn th> cF A. Tla B. Tla-alu

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