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S GIO DC & O TO TRNG THPT CHUYN QUNG BNH LN 1 Ngy 15/3/2014

THI TH TUYN SINH I HC, CAO NG MN: HO KHI B Thi gian lm bi: 90 pht; khng k thi gian pht (50 cu trc nghim) M thi: 570

(Th sinh khng c s dng ti liu) H, tn th sinh:..................................................................... S bo danh: ............................. Cho bit nguyn t khi (theo vC) ca cc nguyn t: H = 1; He = 4; Li = 7; Be = 9; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Br = 80; Rb = 85; Sr = 88; Ag = 108; Sn = 119; Cs = 133; Ba = 137; Pb = 207. I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1: Cho 0,5 mol Mg v 0,2 mol Mg(NO3)2 vo bnh kn khng c oxi ri nung nhit cao n phn ng hon ton thu c hn hp cht rn X. Hn hp cht rn X tc dng vi nhiu nht 500 ml dung dch Fe(NO 3)3 c nng aM. Gi tr ca a l A. 0,667. B. 0,4. C. 2. D. 1,2. Cu 2: Cho cc cht: NaHSO3; NaHCO3; KHS; NH4Cl; AlCl3; CH3COONH4, Al2O3, Zn, ZnO, NaHSO4. S cht lng tnh l A. 8. B. 7. C. 6. D. 5. Cu 3: Cho cc nguyn t X (Z = 11); Y(Z = 13); T(Z=17). Nhn xt no sau y l ng? A. Oxit v hiroxit ca X, Y, T u l cht lng tnh. B. Nguyn t cc nguyn t X, Y, T trng thi c bn u c 1 electron c thn. C. Cc hp cht to bi X vi T v Y vi T u l hp cht ion. D. Theo chiu X, Y, T bn knh ca cc nguyn t tng ng tng dn. Cu 4: Cho cc th nghim sau (1) Sc SO3 vo dung dch BaCl2 (2) Cho SO2 vo dung dch Ba(OH)2 d (3) Cho dung dch KOH vo dung dch Ba(HCO3)2 (4) Cho dung dch H2S vo dung dch FeCl2 (5) Cho NH3 d vo dung dch AlCl3 S th nghim thu c kt ta l A. 5. B. 3. C. 4. D. 2. Cu 5: Cho s sau:

C2 H5OH X
NaOH

Z F

CH4 Poli(metyl metacrylat)

axit metacrylic

Cng thc cu to ca X l A. CH2=CHOOCC2H5. B. CH2=C(CH3)OOCC2H5. C. CH2=C(CH3) COOC2H5. D. CH2=CHCOOC2H5 Cu 6: Cho cc cht NaCl, FeS2, Fe(NO3)2, NaBr, CaCO3, NaI. C bao nhiu cht m khi tc dng vi dung dch H2SO4 c, un nng th c phn ng oxi ha-kh xy ra? A. 5. B. 3. C. 6. D. 4. Cu 7: x phng ho 10 kg cht bo c ch s axit bng 7, ngi ta un cht bo vi dd cha 1,42 kg NaOH. Sau khi phn ng hon ton, mun trung ho NaOH d cn 500 ml dd HCl 1M. Khi lng x phng nguyn cht to ra l A. 11230,3 gam B. 10365,0 gam C. 10342,5 gam D. 14301,7 gam Cu 8: Nhn xt no sau y sai? A. Cc dung dch glixin, alanin, lysin u khng lm i mu qu B. Polipeptit km bn trong mi trng axit v baz C. lin kt peptit l lin kt ca nhm CO vi nhm NH gia 2 n v -aminoaxit D. Cho Cu(OH)2 trong mi trng kim vo dung dch protein s xut hin mu tm xanh Cu 9: Trong cc phn ng sau: 1, dung dch Na2CO3 + H2SO4 2, dung dch NaHCO3 + FeCl3 3, dung dch Na2CO3 + CaCl2 4, dung dch NaHCO3 + Ba(OH)2 5, dung dch(NH4)2SO4 + Ca(OH)2 6, dung dch Na2S + AlCl3 Cc phn ng c to ng thi c kt ta v kh bay ra l: A. 1, 3, 6 B. 2, 5 C. 2, 3, 5 D. 2, 5, 6 Cu 10: Cho phn ng : 3H2(kh) + Fe2O3 (rn) 2Fe + 3H2O (hi) Nhn nh no sau y l ng? A. Nghin nh Fe2O3 cn bng ha hc chuyn dch theo chiu thun B. Thm Fe2O3 cn bng ha hc chuyn dch theo chiu thun C. Thm H2 vo h cn bng ha hc chuyn dch theo chiu thun D. Tng p sut cn bng ha hc chuyn dch theo chiu thun Cu 11: Nhn nh no sau y khng ng? A. Cc xeton khi cho phn ng vi H2 u sinh ra ancol bc 2. B. Axeton khng lm mt mu dung dch KMnO4 iu kin thng. C. Tr axetilen, cc ankin khi cng nc u cho sn phm chnh l xeton. D. Cc hp cht c cha nhm >C=O u phn ng vi nc Brm. Trang 1/4 - M thi 570- KHI B

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Cu 12: 4,2 gam st trong khng kh mt thi gian thu c 5,32 gam hn hp X gm st v cc oxit ca n. Ha tan ht X bng dung dch HNO3, thy sinh ra 0,448 lt kh NO (ktc, sn phm kh duy nht) v dung dch Y. Vy khi lng mui khan thu c khi c cn dung dch Y l A. 13,5 gam. B. 18,15 gam. C. 16,6 gam. D. 15,98 gam. Cu 13: Nguyn t ca nguyn t X c tng s ht electron trong cc phn lp p l 7. S ht mang in ca mt nguyn t Y nhiu hn s ht mang in ca mt nguyn t X l 8 ht. Cc nguyn t X v Y ln lt l (bit s hiu nguyn t ca nguyn t: A. Al v Cl. B. Al v P. C. Fe v Cl. D. Na v Cl. Cu 14: Nung hn hp bt KClO3, KMnO4, Zn mt thi gian. Ly hn hp sn phm rn cho vo dung dch H2SO4 long th thu c hn hp kh. Hn hp l A. H2, Cl2 v O2. B. Cl2 v O2. C. Cl2 v H2. D. O2 v H2. Cu 15: Cho cc phn ng sau:
t (1) Cu(NO3)2 (2) H2NCH2COOH + HNO2
0

t (3) NH3 + CuO

0
0

(0 5 ) t (4) NH4NO2 (5) C6H5NH2 + HNO2 HCl (6) (NH4)2CO3 Cc phn ng thu c N2 l A. 4, 5, 6. B. 2, 3, 4. C. 1, 2, 3. D. 3, 4, 5. Cu 16: Nung 18,4 gam hn hp 2 mui cacbonat ca 2 kim loi ha tr 2, thu c 9,6 gam cht rn v kh X. Lng kh X sinh ra cho hp th vo 150 ml dung dch NaOH 2M, khi lng mui khan thu c sau phn ng l A. 12,6 gam. B. 19 gam. C. 15,9 gam. D. 7,95 gam. Cu 17: Trong cc cht sau: HCHO, CH3Cl, CH3COOCH3, CH3ONa, CH3OCH3, CO, CH2Cl2 c bao nhiu cht to ra metanol bng 1 phn ng ? A. 5 B. 6 C. 4 D. 3 Cu 18: Kh m gam Fe3O4 bng kh H2 thu c hn hp X gm Fe v FeO, hn hp X tc dng va ht vi 3 lt dung dch H2SO4 0,2M (long). Gi tr ca m l A. 23,2 gam B. 34,8 gam C. 11,6 gam D. 46,4 gam Cu 19: Dy gm cc cht m khi cho tng cht tc dng vi dung dch HI u sinh ra sn phm c it l A. Fe2O3, Fe3O4, Fe2(SO4)3, Cl2. B. Fe(OH)3, FeO, FeCl3, Fe3O4. C. AgNO3, Na2CO3, Fe2O3, Br2. D. Fe3O4, FeO, AgNO3, FeS. Cu 20: Khng nh khng ng v cht bo l A. Cht bo l trieste ca glixerol vi axit bo. B. un cht bo vi dung dch NaOH th thu c sn phm c kh nng ha tan Cu(OH)2. C. Cht bo v du m bi trn my c cng thnh phn nguyn t. D. Cht bo nh hn nc. Cu 21: Dung dch c kh nng ha tan Ag2S l A. HCl. B. NaCN. C. H2SO4 (long). D. NaOH (c). Cu 22: Cho 100 ml dung dch FeCl2 1M vo 500 ml dung dch AgNO3 1M, sau phn ng hon ton khi lng kt ta thu c l A. 39,5 gam. B. 71,75 gam. C. 28,7 gam. D. 10,8 gam. Cu 23: Cho cc dung dch c cng nng mol/lit: CH3COOH; KHSO4; CH3COONa; NaOH. Th t sp xp cc dung dch theo chiu pH tng dn l A. CH3COOH; CH3COONa; KHSO4; NaOH. B. KHSO4; CH3COOH; NaOH; CH3COONa . C. CH3COOH; KHSO4; CH3COONa; NaOH. D. KHSO4; CH3COOH; CH3COONa; NaOH. Cu 24: Cho cc cht sau: CH3-CH2-CHO (1), CH2=CH-CHO (2), (CH3)2CH-CHO (3), CH2 =CH-CH2-OH (4). Nhng cht phn ng hon ton vi lng d H2 (Ni, t0C) cng to ra mt sn phm l: A. (1),(3) , (4). B. (1),(2) , (4). C. (2),(3), (4). D. (1),(2) , (3). Cu 25: Cho bn hn hp, mi hn hp gm hai cht rn c s mol bng nhau: Na2O v Al2O3; Cu v FeCl3; BaCl2 v CuSO4; Ba v NaHCO3. S hn hp c th tan hon ton trong nc (d) ch to ra dung dch l A. 4. B. 1. C. 3. D. 2. Cu 26: Cho 4,3 gam hn hp BaCl2 v CaCl2 vo 100 ml dung dch hn hp Na2CO3 0,1M v (NH4)2CO3 0,25M thy to thnh 3,97 gam kt ta R. Tnh s mol ca mi cht trong R A. 0,01 mol BaCO3 v 0,02 mol CaCO3 B. 0,015 mol BaCO3 v 0,01 mol CaCO3 C. 0,01 mol BaCO3 v 0,015 mol CaCO3 D. 0,02 mol BaCO3 v 0,01 mol CaCO3 Cu 27: Mt loi nc cng c cha Ca2+ 0,004 M ; Mg2+ 0,003 M v HCO-3. Hy cho bit cn ly bao nhiu ml dung dch Ca(OH)2 0,02 M bin 1 lt nc cng thnh nc mm (cc phn ng xy ra hon ton v kt ta thu c gm CaCO3 v Mg(OH)2). A. 300 ml. B. 200 ml. C. 500 ml. D. 400 ml. Cu 28: Trong cc loi t sau: t visco, t xenluloz axetat, t nitron, T lapsan, nilon-6,6. S t c iu ch bng phng php trng ngng l A. 3 B. 2 C. 4 D. 1 Cu 29: Este n chc X c t khi hi so vi metan bng 6,25. Cho 20 gam tc dng 300ml dung dch KOH 1M (un nng), c cn dung dch thu c 28 gam cht rn khan. Cng thc cu to ca X l A. CH3-CH2-COO-CH=CH2. B. CH3-COO-CH=CH-CH3. C. CH2=CH-CH2-COOH. D. CH2=CH-COO-CH2-CH3 t Cu 30: Cho phn ng ha hc sau: [-CH2-CH(OCOCH3)-]n + nNaOH [-CH2-CH(OH)-]n + nCH3COONa Trang 2/4 - M thi 570- KHI B

t0

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Phn ng ny thuc loi phn ng A. phn ct mch polime. B. gi nguyn mch polime. C. khu mch polime. D. iu ch polime. Cu 31: Nhng mt thanh Magie vo dung dch c cha 0,8 mol Fe(NO3)3 v 0,05 mol Cu(NO3)2, sau mt thi gian ly thanh kim loi ra cn li thy khi lng tng 11,6 gam. Khi lng Magie phn ng l A. 6,96 gam B. 24 gam C. 20,88 gam D. 25,2 gam Cu 32: phn bit hai dung dch Ba(HCO3)2, C6H5ONa v hai cht lng C6H6, C6H5NH2 ta c th dng ha cht no sau y A. Kh CO2 B. Dung dchphenolphtalein. C. Qu tm. D. dung dch H2SO4. Cu 33: Hn hp A gm glucoz v mantoz. Chia A lm 2 phn bng nhau: - Phn 1: Ho tan vo nc, lc ly dung dch ri cho tc dng vi AgNO3/NH3 d c 0,02 mol Ag. - Phn 2: un vi dung dch H2SO4 long. Hn hp sau phn ng c trung ho bi dung dch NaOH, sau cho ton b sn phm tc dng vi lng d dung dch AgNO3/NH3 c 0,03 mol Ag. S mol ca glucoz v mantoz trong A ln lt l A. 0,005 v 0,005. B. 0,0035 v 0,0035. C. 0,01 v 0,01. D. 0,0075 v 0,0025. Cu 34: un nng 5,8 gam hn hp A gm C2H2 v H2 trong bnh kn vi xc tc thch hp sau phn ng c hn hp kh X. Dn hn hp X qua bnh ng dung dch Br2 d thy bnh tng ln 1,4 gam v cn li hn hp kh Y. Tnh khi lng ca hn hp Y. A. 5,4 gam. B. 6.2 gam. C. 3,4 gam. D. 4,4 gam. Cu 35: Hai hp cht hu c mch h c cng thc phn t ln lt l C2H8O3N2 v C3H7O2N u tc dng vi dung dch NaOH un nng, cho hai amin n chc bc 1 thot ra. Nhn xt no sau y ng v hai hp cht hu c trn? A. Chng u l cht lng tnh. B. Chng u tc dng vi dung dch brom. C. Phn t ca chng u c lin kt ion. D. Chng u tc dng vi H2 (xc tc Ni, un nng). Cu 36: tch c CH3COOH t hn hp gm CH3COOH v C2H5OH ta dng ho cht no sau y? A. Ca(OH)2 v dung dch H2SO4 B. CuO (to) v AgNO3/NH3 d C. Na v dung dch HCl D. H2SO4 c Cu 37: Cho cc monome sau: stiren, toluen, metylaxetat, etilenoxit, vinylaxetat, caprolactam, metylmetacrylat, metylacrylat, propilen, benzen, axt etanoic, axt -aminocaproic, acrilonitrin. S monome tham gia phn ng trng hp l A. 8. B. 7. C. 6. D. 9. Cu 38: Trong phng th nghim, ngui ta thng iu ch HNO3 t A. NaNO3 rn v H2SO4 c. B. NaNO3 rn v HCl c. C. NaNO2 rn v H2SO4 c. D. NH3 v O2. Cu 39: Cho Xenluloz phn ng vi anhirit axetic (H2SO4 l xc tc) thu c 11,10 gam hn hp X gm xenluloz triaxetat v xenluloz iaxetat v 6,60 gam axit axetic. Thnh phn phn % theo khi lng ca xenluloz triaxetat v xenluloz iaxetat trong X ln lt l A. 76,84%; 23,16%. B. 70,00%; 30,00%. C. 77,84%; 22,16%. D. 77,00%; 23,00%. Cu 40: Kim loi Al phn ng c tt c cc cht trong nhm no sau y nhit thng? A. dung dch H2SO4 long, dung dch NaOH, dung dch MgCl2 B. dung dch Ba(OH)2, dung dch KHSO4, dung dch FeSO4 C. HNO3 c ngui, dung dch CH3COOH, dung dch CuSO4 D. dung dch FeCl3, dung dch CrCl3, Fe3O4 II. PHN RING [10 cu] Th sinh ch c lm mt trong hai phn (phn A hoc B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41: Ha tan m gam hh X gm CuCl2 v FeCl3 trong nc c dung dch Y. Chia Y thnh 2 phn bng nhau. Phn 1: cho kh H2S d vo c 1,28g kt ta. Phn 2: cho Na2S d vo c 3,04g kt ta. Gi tr ca m l: A. 14,6 g B. 8,4 g C. 10,2 g D. 9,2 g Cu 42: X c cng thc C4H14O3N2. Khi cho X tc dng vi dung dch NaOH th thu c hn hp Y gm 2 kh iu kin thng v u c kh nng lm xanh qu tm m. S CTCT ph hp ca X l: A. 5 B. 3 C. 4 D. 2 Cu 43: Dy cc kim loi c cu trc mng tinh th lp phng tm khi l: A. Na, K, Mg B. Na, K, Ba C. Ca, Sr, Ba D. Mg, Ca, Ba Cu 44: C hai th nghim sau: TN1: Cho 6g ancol no h n chc X tc dng vi m gam Na, sau phn ng thu c 0,075 gam H2. TN 2: Cho 6g ancol no h n chc X tc dng vi 2m gam Na, sau phn ng thu khng ti 0,1gam H2. X c cng thc l: A. C4H9OH. B. C3H7OH. C. C2H5OH. D. CH3OH. Cu 45: Hn hp X gm axit panmitic, axit stearic v axit linoleic. trung ha m gam X cn 50 ml dung dch NaOH 1M. Mt khc, nu t chy hon ton m gam X th thu c 19,04 lt kh CO2 ( ktc) v 14,76 gam H2O. % s mol ca axit linoleic trong m gam hn hp X l: A. 60% B. 31,25% C. 62,5% D. 30% Cu 46: Saccaroz v glucoz u c phn ng A. thu phn trong mi trng axit. B. vi Cu(OH)2 nhit thng. C. vi dung dch NaCl. D. AgNO3 trong dung dch NH3. Trang 3/4 - M thi 570- KHI B

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Cu 47: Hn hp X gm hai anken c t khi so vi H2 bng 16,625. Ly hn hp Y cha 26,6 gam X v 2 gam H2. Cho Y vo bnh kn c dung tch V lt ( ktc) c cha Ni xc tc. Nung bnh mt thi gian sau a v 0 0C thy p sut trong bnh bng 7/9 at. Bit hiu sut phn ng hiro ho ca cc anken bng nhau v th tch ca bnh khng i. Hiu sut phn ng hiro ho l A. 40%. B. 50%. C. 75%. D. 77,77%. Cu 48: Cho cc cht sau: axetilen, axit oxalic, axit acrylic, fomanehit, phenyl fomat, vinyl axetilen, glucz, anehit axetic, metyl axetat, saccaroz, natri fomat, axeton. S cht c th tham gia phn ng trng gng l A. 8 B. 6 C. 7 D. 5 Cu 49: Hin tng ln lt xy ra khi cho t t n d dung dch NaOH vo dung dch CrCl3, thm tip H2O2 d, ri cho dung dch BaCl2 vo l: A. To kt ta trng ri tan, thnh dung dch mu xanh, sau c kt ta mu vng. B. To kt ta xanh lc ri tan, thnh dung dch mu vng, sau c kt ta da cam. C. To kt ta xanh lc ri tan, thnh dung dch da cam, sau c kt ta mu vng. D. To kt ta xanh lc ri tan, thnh dung dch mu vng, sau c kt ta mu vng. Cu 50: Xt phn ng: CO (kh) + H2O(kh) CO2(kh) + H2(kh). Trong iu kin ng nhit, khi tng p sut ca h th tc phn ng nghch nh th no? A. Tng. B. Gim. C. C th tng hoc gim D. Khng i. ------------------------------------------------------- HT ----------

1D 2C 3B 4C 5C 6D 7C 8A 9D

10C 11D 12C 13A 14C 15B 16B 17A 18D 19A 20C 21B

22A 23D 24B 25B 26A 27C 28B 29A 30B 31D 32D 33A 34D 35C 36A 37A 38A 39C

40B 41D 42B 43B 44A 45D 46B 47B 48D 49D 50A

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