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  • Synthetic Chart: H Lindlar's Catalyst

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    cutinhawayne
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    This document provides a synthetic chart summarizing common reactions for transforming functional groups between different classes of organic compounds. The chart shows that alkanes can be converted to alkenes or haloalkanes, which can then be converted to alcohols, ketones, aldehydes, carboxylic acids, or esters through reactions with reagents such as Grignard reagents, acids, bases, or oxidizing agents depending on the starting material functional group.

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    Synthesis Chart Complete

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    This document provides a synthetic chart summarizing common reactions for transforming functional groups between different classes of organic compounds. The chart shows that alkanes can be converted to alkenes or haloalkanes, which can then be converted to alcohols, ketones, aldehydes, carboxylic acids, or esters through reactions with reagents such as Grignard reagents, acids, bases, or oxidizing agents depending on the starting material functional group.

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    8 views1 page

    Synthetic Chart: H Lindlar's Catalyst

    Uploaded by

    cutinhawayne
    This document provides a synthetic chart summarizing common reactions for transforming functional groups between different classes of organic compounds. The chart shows that alkanes can be converted to alkenes or haloalkanes, which can then be converted to alcohols, ketones, aldehydes, carboxylic acids, or esters through reactions with reagents such as Grignard reagents, acids, bases, or oxidizing agents depending on the starting material functional group.

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    of 1

    Synthetic chart

    Alkanes Cl2 or Br2 plus light or

    H2, Pd/C Alkynes H2, Pd/C Polymers R-O-O-R


    H2, Lindlars catalyst

    Haloalkanes

    HX or X2 X = Cl, Br, I NaOH (cold, dilute), or H2O H3O+**

    Alkenes

    Mg, Et2O*

    conc. H2SO4,

    R-MgX
    RMgX can go to each degree of alcohol depending on the carbonyl reagent used (H2CO, RHCO, R2CO)

    Alcohols 1o 2o 3o MnO4-, Cr2O72- or PCC,CH2Cl2* 1. NaBH4 2. H3O+** Ketones 1. R-MgX, Et 2O* 2. H3O+ **

    1. NaBH4 PCC, 2. H3O+ ** CH2Cl2* Aldehydes 1. R-MgX , Et 2O* 2. H3O+ **

    MnO4or Cr2O72CO2

    MnO4or Cr2O72-

    1. R-MgX , Et 2O* 2. H3O+** ROH, H+ H3O+**,

    Carboxylic acids

    Ester

    ROH
    H3O
    +

    Anydride

    Notes: formaldehyde only


    * CH2Cl2 and Et2O are solvents, they do not participate in the reaction. ** H3O+ is dilute aqueous acid (e.g., 10% H2SO4). In some reactions, it is used for workup, in others, it is an acid catalyst.

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