BO CO THC HNH PHN TCH NC

Lp: 02DHDB2
Th 5, tit 1 - 5
GVHD: V Hong Yn
Nhm: 02
Danh sch nhm:
1. Ng Phc Thnh

2022110183

2. Nguyn Vn Tr

2022110331

3. Nguyn Tin Hng

2022110387

4. L Th Ngc nh

2022110281

BI 6: XC NH HM LNG SUNFAT
Nguyn tc:
Trong mi trng acetic acid, sulfate tc dng vi barium chloride to thnh
barium sulfate kt ta mu trng c. Nng sulfate c xc nh bng cch so
snh vi dung dch than chiu bit trc nng trn ng cong chun.
Ba 2 SO4

Dng c v thit b:
Pipet 10 ml
Bnh tam gic 250 ml
Spectrophotometer
Ho cht:
- Dung dch m: ho tan.
30 g MgCl2.6H2O

BaSO4

(kt ta trng c)

5g CH3COONa.3H2O
1,0 g KNO3
20 ml acetic acid CH3COOH trong 500 ml nc ct pha thnh 1000ml
- Barium chloride BaCl2 tinh th
- Dung dch sulfate chun (1ml=100 ug SO42- ): ly chnh xc 10,4 ml H2SO4
0,02N v 147,9 mg Na2SO4 khan, thm nc ct, pha thnh 1000ml.

Cch tin hnh:

Chun b 5 ng nghim v ln lt cho vo tng ng cc dung dch sau:
Bnh nh mc
25ml

Bnh mu

V(ml) SO42(100ppm)

19 ml mu nc + 1ml
SO42- chun

Dung dch m

5 ml

Nc ct(ml)

nh mc

BaCl2
Nng Cx(mg)
C (mg/l)

0.5g
0

0.1 0.2 0.3 0.4

0

12

16

Cx
Cx

o hp thu ca tng ng bc sng 420 nm, dng ng s 0 hiu chnh

my. T lot o hp thu, v gin biu din tng quan gia hp thu vi
hm lng sulfate (thi gian o khng qu 5 pht trnh lng ng).
Chun b mu:
- Ly 19 ml mu, 1ml SO42- v 0,5g BaCl2 tinh th

- Lc u ho tan hon ton BaCl2 thnh dung dch ng nht. o hp

thu ca mu bc sng 420 nm (thi gian o khng qu 5 pht trnh
lng ng kt ta BaSO4).
Tnh kt qu:
- T hp thu ca mu, i chiu trn th xc nh hm lng sulfate
trong mu. Nu mu trong mu vut qu ng cong tham chiu, lm li vi
mt th tch mu pha long n nng thch hp.

m( g ) SO4

m( g ) SO4 ouoc
/l
* 1000
(ml )mau

Ch :
- Nu c ca mu vt qu 20 mg/l, cn pha long mu n khong thch
hp.
- Nu mu c hoc c nhiu cn l lng, cn phi lc trc khi ly mu.

KT QU:
Gi tr Abs o c ti cc gi tr hm lng xc nh ca dung dch sunfat
chun nh sau:
C(mg)

0.1

0.2

0.3

0.4

Mu

Abs

0.055

0,102

0.135

0.177

0.008

Dng ng chun

Chart Title
0.2

y = 0.434x + 0.007
R = 0.9918

0.18
0.16

Axis Title

0.14
0.12
0.1

Series1

0.08

Linear (Series1)

0.06
0.04
0.02
0
0

0.05

0.1

0.15

0.2

0.25

0.3

0.35

0.4

0.45

Axis Title

T phng trnh ng chun y= 0,434x + 0,007 v gi tr Abs ca mu(0.008) ta

tnh c hm lng sunfat c trong mu l:
Cx

0.008 0.007
0,0023(mg )
0.434

Do ta thm vo dung dch mu 1ml dung dch sunfat chun nn hm lng sunfat
thc ca mu nc phn tch l: 0,0023 0.1= -0.0977 (mg)
Vy hm lng sunfat(g/l) c tnh nh sau:

m( g ) SO4

/l

0,0977 *10 3
*1000 0.0051 ( g / l )
19

CC TIU CHUN, CH TIU C S DNG TRONG KHA THC

HNH
1. Nc cp cho n ung v sinh hot thng c mu khng vt qu 15TCU (
theo QCVN 01:2009/BYT v QCVN 02:2009/BYT) vi phng php th l
TCVN 6185:1996 (ISO 7887:1985) hoc SMEWW 2120. Theo QCVN
01:2009/BYT quy nh mu ca mu nc ung khng vt qu15 CTU

2. cng gii hn theo QCVN 02:2009 BYT l 350 (mgCaCO3/l).

3. Hm lng tng cht rn ca mu nc sch quy nh theo tiu chun l khng
vt qu 1200mg/l.
4. Theo QCVN 02:2009/BYT v cht lng nc dng trong sinh hot th gi tr
oxy ho tan khng c quy nh. Theo QCVN 02:2008/BTNMT th hm lng ny
c quy nh l >=6mg/l.
5. Theo QCVN 02:2009/BYT (quy chun nc dung trong sinh hot) th hm
lng st tng s th hm lng ny khng c vt qu 0.5mg/l.
6. Theo QCVN 02:2009/BYT (quy chun quy nh v cht lng nc dng trong
sinh hot) th hm lng sunfat khng c quy nh trong khi QCVN 01:2009/BYT
th hm lng ny cho php c mt l 250 mg/