UNIVERSIDADE FEDERAL DE GOIS INSTITUTO DE QUMICA Fsico-Qumica Solu !s "a lis#a $! !%!

&ccios

1 Calculate the change in Gibbs energy of 35g of ethanol (mass density 0,789 g cm -3 !hen the "ressure is increased isothermally from 1 to 3000 atm# $ Calculate the change in molar Gibbs energy of a "erfect gas !hen its "ressure is increased isothermally from 9$,0 %&a to $5$ %&a at 50 oC# 3 'hen 3 mol of a gas at $30( and 150 %&a is sub)ected to isothermal com"ression, its entro"y decreases by 15,0 * (-1# Calculate a the final "ressure of the gas and+ b ,G for the com"ression# - ./aluate (01203 4 for a /an der 'aals gas# 5or an isothermal e6"ansion, !ill ,1 be greater for a "erfect gas or a /an der 'aals gas7 .6"lain your conclusion# 5 4he molar /olume of a certain solid is 181,0 cm 3 mol-1 at 1 atm and 350#75 (, its melting tem"erature# 4he molar /olume of the li9uid at this tem"erature and "ressure is 183#3 cm 3 mol-1# :t 1 atm the melting tem"erature changes to 351,$8 (# Calculate the enthal"y and entro"y of fusion of the solid# 8 4he boiling "oint of he6ane is 89#0 oC# .stimate a its enthal"y of /a"ori;ation+ and b its /a"our "ressure at $5 oC and 80 oC# 7 Calculate the Gibbs energy, entro"y, and enthal"y of mi6ing !hen 1#0 mol C 8<1(he6ane is mi6ed !ith 1,0 mol C7<18 (he"tanes at $98 (+ treat the solution as ideal# 8 'hat "ro"ortions of ben;ene and ethylben;ene should be mi6ed a by mole fraction, b by mass in order to achie/e the greatest entro"y of mi6ing7