Cu 1 : Oxi ha chm m gam Fe ngoi khng kh sau mt thi gian thu c 12 gam hn

hp X ( Fe , FeO , Fe
2
O
3
,Fe
3
O
4
). ha tan ht X , cn va 300 ml dung dch HCl 1M ,
ng thi gii phng 0,672 lt kh ( ktc ). Tnh m ?
A.10,08 B.8,96 C.9,84 D.10,64
Cu 2: Ha tan hon ton 2,8 gam hn hp FeO , Fe
2
O
3
v Fe
3
O
4
cn va V ml dung
dch HCl 1M , thu c dung dch X. Cho t t dung dch NaOH d vo dung dch X thu
c kt ta Y. Nung Y trong khng kh n khi lng khng i thu c 3 gam cht
rn. Tnh V ?
A.87,5 B.125 C.62,5 D.175
Cu 3 : Trn bt Al vi bt Fe
2
O
3
( t l mol 1 : 1 ) thu c m gam hn hp X. Thc hin
phn ng nhit nhm hn hp X trong iu kin khng c khng kh sau mt thi gian
thu c hn hp rn Y. Ha tan ht Y bng acid nitric long d , thy gii phng 0,448
lt kh NO ( ktc sn phm kh duy nht ). m =?
A.7,48 B.11,22 C.5,61 D.3,74
Cu 4: Ha tan ht 7,68 gam hn hp FeO , Fe
2
O
3
v Fe
3
O
4
cn va 260 ml dung dch
HCl 1M. Dung dch thu c cho tc dng vi dd NaOH d ri lc kt ta nung trong
khng kh n khi lng khng i thu c m gam rn.. tnh m
A.20 B.8 C.16 D.12
Cu 5: X l hn hp gm Fe v 2 oxit ca st. Ha tan ht 15,12 gam X trong dung dch
HCl d , sau phn ng thu c 16,51 gam mui Fe (II) v m gam mui Fe (III ) . Mt khc
, khi cho 15,12 gam X phn ng hon ton vi dung dch acid nitric long d th gii
phng 1,568 lt NO ( sn phm kh duy nht). Thnh phn % khi lng ca Fe trong X
l ?
A.11,11% B.29,63% C.14,81% D.33,33%
Cu 6 :Ha tan ht m gam hn hp X gm Cu v 2 oxit st cn va 500ml dung
dch HCl 1,2M. C cn dung dch sau phn ng thu c 38,74 gam hn hp hai mui
khan . m nhn gi tr ?
A.22,24 B.20,72 C.23,36 D.27,04
Cu 7: Ha tan ht a gam hn hp 2 oxit st bng dung dch HCl d sau phn ng thu
c dung dch cha 9,75 gam FeCl
3
v 8,89 gam FeCl
2
. a nhn gi tr no ?
A.10,08 B.10,16 C.9,68 D.9,84
Cu 8 : Ha tan ht 4 gam hn hp A gm Fe v 1 oxit st trong dung dch acid HCl d
thu c dung dch X. Sc kh Cl
2
cho n d vo X thu c dung dch Y cha 9,75
gam mui tan. Nu cho 4 gam A tc dng vi dung dch HNO3 long d th thu c V lt
NO ( sn phm kh duy nht - ktc)/ V= ?
A.0,896 B.0,747 C.1,120 D.0,672
Cu 9: Ha tan ht a gam hn hp X gm Fe v mt oxit st trong b gam dung dch
H
2
SO
4
9,8% ( lng va ), sau phn ng thu c dung dch cha 51,76 gam hn
hp hai mui khan. Mt khc nu ha tan ht a gam X bng dung dch H
2
SO
4
c nng
th thu c duy nht 58 gam mui Fe (III). Xc nh b ?
A.370 B.220 C.500 D.420
Cu 10 : Ha tan ht m gam hn hp A gm Cu v 1 oxit st bng 320 ml dung dch HCl
1M ( va ). Dung dch thu c sau phn ng ch cha hai mui l FeCl
2
( c khi
lng 15,24 gam ) v CuCl
2
. Xc nh c.thc ca oxit st v m ?
A. Fe
3
O
4
v 14,40 gam B. Fe
2
O
3
v 11,84 gam C. Fe
3
O
4
v 11,84 gam D. Fe
2
O
3
v 14,40 gam
Cu 11: Ha tan ht m gam hn hp Y( gm Cu v 2 oxit ca st ) bng 260 ml dung dch
HCl 1M - lng va , thu c dung dch Z cha 2 mui vi tng khi lng l 16,67
gam. Xc nh m ?
A.11,60 B.9,26 C.11,34 D.9,52
Cu 12 :Y l mt hn hp gm st v 2 oxit ca n. Chia Y lm hai phn bng nhau :
Phn 1 : em ha tan ht trong dung dch HCl d thu c dung dch Z cha a gam
FeCl
2
v 13 gam FeCl
3

Phn 2 : Cho tc dng ht vi 875 ml dung dch HNO
3
0,8M ( va ) thu c 1,568 lt
kh NO (sn phm kh duy nht). Tnh a. ?
A.10,16 B.16,51 C.11,43 D.15,24
Cu 13 : Ha tan hon ton 13,92 gam hn hp X gm MgO, FeO v Fe
2
O
3
phi dng va
ht 520 ml dung dch HCl 1M. Mt khc , khi ly 0,27 mol hn hp X t nng trong ng
s khng c khng kh ri thi mt lung H
2
d i qua phn ng xy ra hon ton th
thu c m gam cht rn v 4,86 gam nc. Xc nh m?
A.16,56 B.20,88 C.25,06 D.16,02
Cu 14: Hn hp A gm CuSO
4
, FeSO
4
v Fe
2
(SO
4
)
3
, trong % khi lng ca S l 22% . Ly
50 gam hn hp A ho tan vo trong nc. Thm dung dch NaOH d , ly kt ta thu c em
nung ngoi khng kh n khi lng khng i . Lng oxit sinh ra em kh hon ton bng CO
th lng Fe v Cu thu c bng :
A.17 gam B.18 gam C.19 gam D.20 gam
Cu 15 : A l hn hp cc mui Cu(NO
3
)
2
, Fe(NO
3
)
2
v Fe(NO
3
)
3
. Trong N chim 16,03% v
khi lng. Cho dung dch KOH d vo dung dch cha 65,5 gam mui A . Lc kt ta thu c
em nung trong khng kh n khi lng khng i thu c bao nhiu gam oxit ?
A.27 B.34 C.25 D.31
Cu 16: Ha tan ht mt hn hp X gm 0,02 mol Fe : 0,04 mol Fe
3
O
4
v 0,03 mol CuO bng dung
dch HCl d.Cho t t dung dch NH
3
n d vo dung dch sau phn ng, lc kt ta em nung
trong khng kh n khi lng khng i thu c a gam cht rn. a nhn gi tr ?
A.12,8 B.11,2 C.10,4 D.13,6
Cu 17.Ha tan hn hp gm st v 1 oxit ca st cn va 0,1 mol H
2
SO
4
c ; thot ra 0,224 lt
SO
2
( ktc). C cn dung dch sau phn ng thu c bao nhiu gam mui khan ?
A.8 B.12 C.16 D.20
Cu 18: Cho m gam Fe tan va trong dung dch hn hp HCl v FeCl
3
thu c dung dch X
ch cha mt mui duy nht v 5,6 lt H
2
( ktc ). C cn dung dch X thu c 85,09 gam mui
khan. m nhn gi tr no ?
A.14 B.20,16 C.21,84 D.23,52
Cu 19: Cho dung dch acid nitric long vo mt cc thy tinh c ng 5,6 gam Fe v 9,6 gam Cu.
Khuy u phn ng xy ra hon ton ; c 3,136 lt NO thot ra ( ktc ) v cn li m gam cht
rn khng tan. Gi tr ca m bng :
A.2,56 B.1,92 C.4,48 D.5,76
Cu 20: Ha tan hon ton 5,4 gam mt oxit st vo dung dch HNO
3
d thu c 1,456 lt hn hp
NO v NO
2
( ktc - ngoi ra khng cn sn phm kh no khc ). Sau phn ng khi lng dung
dch tng ln 2,49 gam so vi ban u. Cng thc ca oxit st v s mol HNO
3
phn ng l :
A.FeO v 0,74 mol B.Fe
3
O
4
v 0,29 mol C.FeO v 0,29 mol D.Fe
3
O
4
v 0,75 mol
Cu 21: Ha tan 10 gam hn hp gm Fe v Fe
x
O
y
bng HCl thu c 1,12 lt H
2
( ktc ). Cng
lng hn hp ny nu ha tan ht bng dung dch HNO
3
c nng thu c 5,6 lt NO
2
( ktc ).
Xc nh Fe
x
O
y
?
A.FeO B.Fe
2
O
3
C.Fe
3
O
4
D.Khng xc nh c
Cu 22: Cho m gam hn hp X gm Al ,Fe
3
O
4
, FeO, Fe
2
O
3
tc dng vi dung dch HCl d
thu c dung dch Y, trong khi lng ca FeCl
2
l 31,75 gam v 8,064 lt H
2
( ktc
).C cn dung dch Y thu c 151,54 gam cht rn khan. Nu cho m gam hn hp X tc
dng vi dung dch HNO
3
long d thu c dung dch Z v kh NO ( sn phm kh duy nht ).
C cn dung dch Z thu c bao nhiu gam mui khan ?
A.242,3 B.268,4 C.189,6 D.254,9
Cu 23: Nung 23,2 gam hn hp X ( FeCO
3
v Fe
x
O
y
) ti phn ng hon ton thu c kh A
v 22,4gam Fe
2
O
3
duy nht. Cho kh A hp th hon ton vo dung dch Ba(OH)
2
d thu c 7,88
gam kt ta. Mt khc , ha tan ht 23,2 gam X cn va V ml dung dch HCl 2M. CT
Fe
x
O
y
v gi tr ca V l :
A.FeO v 200 B.Fe
3
O
4
v 250 C.FeO v 250 D.Fe
3
O
4
v 360
Cu 24: Ha tan hon ton mt hn hp gm FeO, Fe
2
O
3
v Fe
3
O
4
( trong t l khi lng
caFeO v Fe
2
O
3
bng 9:20 ) bng dung dch HCl , thu c 16,25 gam FeCl
3
. Khi lng mui
FeCl
2
thu c sau phn ng bng :
A.5,08 gam B.6,35 gam C.7,62 gam D.12,7 gam
Cu 25: Cho ln lt 23,2 gam Fe
3
O
4
v 8,4 gam Fe vo dung dch HCl 1M. Th tch dung dch HCl
ti thiu ha tan cc cht rn trn l :
A.0,9 lt B.1,1 lt C.0,8 lt D.1,5 lt
Cu 26: Cho lung kh CO i qua mt lng qung hematit ( cha Fe
2
O
3
) th thu c 300,8 gam
hn hp cc cht rn X v thot ra hn hp kh Y. Cho hp th ton b kh Y bng dung dch
NaOH d thy khi lng bnh NaOH tng thm 52,8 gam. em cht rn X ha tan trong dung
dch HNO
3
d thu c 387,2 gam mui. Thnh phn % khi lng ca Fe
2
O
3
trong qung l :
A.80% B.60% C.50% D.40%
Cu 27: Cho 0,24 mol FeO v 0,03 mol Fe
3
O
4
vo dung dch HNO
3
long , kt thc phn ng thu
c dung dch X v 3,36 gam kim loi d. Khi lng mui c trong dung dch X l :
A.48,6 gam B.58,08 gam C.56,97 gam D.65,34 gam
Cu 28: em nhhit phn hon ton a mol Fe(NO
3
)
2
thu c hn hp kh X c t khi so vi
H
2
bng T
1
. Nhit phn hon ton a mol Fe(NO
3
)
3
thu c hn hp kh Y c t khi so vi H
2
bng
T
2
. Biu thc no di y l ng :
A.T
1
= 0,972T
2
B.T
1
= T
2
C.T
2
= 0,972T
1
D.T
2
= 1,08T
1

Cu 29: Hn hp A gm st v 2 oxit ca n. Cho m gam A tc dng vi dung dch H
2
SO
4
c nng
d n phn ng hon ton thu c dung dch Y v thot ra 2,24 lt SO
2
( ktc ). Cho dung dch
NaOH d vo Y thu c kt ta Z. Nung Z ti khi lng khng i th thy khi lng gim 7,02
gam. Gi tr ca m gam l :
A.11,2 B.19,2 C.14,4 D.16,0
Cu 30: Ha tan hon ton a gam hn hp X gm Fe , FeS , FeS
2
v S vo dung dch HNO
3
long
d , gii phng 8,064 lt NO (l sn phm kh duy nht tkc ) v dung dch Y. Cho dung
dch Ba(OH)
2
d vo dung dch Y thu c kt ta Z. Ha tan ht lng kt ta Z bng dung dch
HCl d, sau phn ng cn li 30,29 gam cht rn khng tan . Gi tr ca a gam l :
A.7,92 B.9,76 C.8,64 D.9,52
Cu 31:Ha tan ht m gam hn hp gm x mol FeO , x mol Fe
2
O
3
v y mol Fe
3
O
4
bng dung dch
HNO
3
c nng thu c 6,72 lt NO
2
( ktc ). Gi tr ca m gam l :
A.46,4 B.48,0 C.35,7 D.69.6
Cu 32: Ha tan ht 7,52 gam hn hp A gm Cu v 1 oxit ca st bng dung dch HNO
3
long d ,
sau phn ng gii phng 0,1493 lt NO ( ktc - l sn phm kh duy nht ) v cn li 0,96 gam kim
loi khng tan. C cn dung dch sau phn ng thu c 16,44 gam cht rn khan. Cng thc ca
oxit st l :
A.FeO B.Fe
2
O
3
C.Fe
3
O
4
D.FeOv Fe
2
O
3

Cu 33: Thi hn hp kh CO v H
2
i qua a gam hn hp gm CuO v Fe
3
O
4
c t l mol 1:2 , sau
phn ng thu c b gam cht rn A. Ha tan hon ton b gam A bng dung dch HNO
3
long d ,
thu c dung dch X ( khng cha ion Fe
2+
). C cn dung dch X thu c 41 gam mui khan. a
gam nhn gi tr no ?
A.9,8 B.10,6 C.12,8 D.13,6
p n bi tp TN v st :
1A - 2A - 3D - 4B - 5C - 6A - 7D - 8B - 9A - 10C - 11D - 12B - 13A - 14A - 15C - 16B - 17B - 18C
- 19A
20C - 21A - 22A - 23D - 24B - 25A - 26D - 27A - 28C - 29B - 30B - 31D - 32C - 33D
HNG DN GII BI TP V ST :
1/ Cc phng php dng trong gii ton :
- Bo ton khi lng
- Bo ton nguyn t
- Bo ton electron
- Phng php quy i
- Phng php ion - electron ( electron bin i )
- Dng cng thc tnh nhanh
2/Phng php tm CTPT ca oxit st : tm t l s mol ca Fe ( nguyn t ) v O (
nguyn t ) t d kin bi cho
3/Mt vi cch gii nhanh :
- Khi bi cho hn hp 2 oxit ca st , nhng khng nu r l oxit st g , th ta c
th quy i hn hp trn v FeO v Fe
2
O
3
- cch ny khng lm s mol Fe v O trong
hn hp thay i...
- Nu gp bi ton oxi ha 2 ln : Fe ( m gam ) b oxi ha thnh hn hp ( Fe , oxit st
) ( m
1
gam ) ri cho tip vo dung dch acid c tnh oxi ha to sn phm kh th ta
nn dng cng thc : ( n
e
l s mol electron cho hoc nhn )
m
Fe
= 0,7 m
1
+ 5,6 n
e

P N CHI TIT :
Cu 1: n
kh
= n
H2
= 0,672/22,4= 0,03 mol .
Ta c : n
H+(HCl)
= n
H+(ho tan oxit )
+ n
H+(kh )
=> 0,3 = n
H+(ho tan oxit )
+ 2.0,03 => n
H+(ho tan oxit )
= 0,24
mol
n
O(oxit)
= n
H+(ho tan oxit )

= 0,12 mol => m = m
X

m
O(oxit)
= 12 0,12.16 = 10,08
gam

Cu 2: Quy i hn hp thnh 2,8 gam ( FeO : x mol v Fe
2
O
3
: y mol ) -------> 3
gam Fe
2
O
3

Thit lp h : 72x + 160y = 2,8 v x + 2y = 3.2/160 ( BTNT Fe trong Fe
2
O
3
)
= > x = 0,025 mol v y = 6,25.10
-3
mol
FeO + 2HCl FeCl
2
+ H
2
O Fe
2
O
3
+ 6HCl 2FeCl
3
+ 3 H
2
O
0,025 0,05 6,25.10
-3

0,0375
=> Tng s mol HCl p/ = 0,0875 mol => V = 0,0875 l = 87,5 ml

Cch kh c : ( Cch gii ca bn Hunh Anh T )Quy i thnh 2,8 gam ( Fe : x mol v O
: y mol )
S hp thc : 2Fe Fe
2
O
3
Ta c : n
Fe
= 2n
Fe2O3
= 2.3/160 = 0,0375 mol
=> n
O (oxit)
= ( 2,8 0,0375.56 ) / 16 = 0,04375 mol => n
HCl p/u
= 2 n
O (oxit)
= 0,0875 mol =>V =
87,5 ml

Cu 3: Phn ng nhit nhm khng hon ton nn ta khng th xc nh c r
sn phm Y gm nhng cht no. Ta quy i hn hp Y thnh X ( theo nguyn
BTKL )
Ta c : Al Al
3+
+3e N
+5
+3e NO => m = 0,02( 27 + 160) =
3,74 gam
0,02 0,06 0,06 0,02

Cu 4: Ta c : n
Cl-
= 0,26 mol => n
O2- (oxit )
= n
Cl-
= 0,13 mol ( BT T ) => m
Fe
= 7,68 0,13.16
= 5,6 gam
S hp thc : 2Fe Fe
2
O
3
=> m
Fe2O3
= 160.5,6/112 = 8 gam.

Cu 5: Quy i 15,12 gam X thnh : Fe ; FeO v Fe
2
O
3

( x mol ) ( y mol )
Ho tan vo dd HCl ta c pt : x + y = 16,51/127 = 0,13 mol.
Cho X vo HNO
3
d :
Fe Fe
3+

+ 3e N
+5
+ 3e NO
x 3x 0,21 0,07
FeO Fe
3+
+ 1e
y y
=> Bo ton electron: 3x + y = 0,21
Gii h = > x = 0,04 mol v y = 0,09 mol = > % m
Fe
= 0,04.56/15,12 . 100% =
14,81%

Cu 6: 2 mui khan y l CuCl
2
v FeCl
2
. Ta c : n
O2- (oxit )
= n
Cl-
= .0,6 = 0,3 mol (
BT T )
BTKL : m
Cu & Fe

= m
muoi
m
Cl-
= 38,74 0,6.35,5 = 17,44 gam
m
X
= m
Cu & Fe

+ m
O2- (oxit )
= 17,44 +0,3.16 = 22,24 gam

Cu 7: Quy i thnh a gam FeO v Fe
2
O
3

S hp thc : Fe
2
O
3
2FeCl
3
( 0,06 mol ) v FeO FeCl
2
( 0,07 mol )
=> a = 0,03.160 + 0,07.72 = 9,84 gam

Cu 8: n
Fe
= n
FeCl3
= 0,06 mol => n
O (oxit )
= ( 4 0,06.56)/16 = 0,04 mol
Quy i 4 gam A thnh Fe v O. Cho tc dng vi HNO
3
:
Fe Fe
3+

+ 3e O + 2e O
2-


0,06 0,18 0,08 0,04
N
+5
+ 3e NO => V = 0,1/3.22,4 = 0,747
lit
0,1 0,1/3

Cu 9: 51,76 gam gm 2 mui F eSO
4
: x mol v Fe
2
(SO
4
)
3
: y mol.
Lp h : 152x + 400y = 51,76 v x + 2y = 58.2/400 (BTNT Fe trong Fe
2
(SO
4
)
3
)
=> x = 0,13 mol v y = 0,08 mol => S mol H
2
SO
4
p/ = x +3y = 0,37 mol
=> m
dung dich
= ( 0,37.98.100) / 9,8 gam = 370 gam = b

Cu 10: n
Fe
= n
FeCl2
= 0,12 mol v n
O (oxit )
= n
H+
= 0,16 mol => n
Fe
: n
O
= 0,12 : 0,16 = 3:4 =>
Fe
3
O
4

BTNT Cl: n
HCl
= 2n
FeCl2
+ 2n
CuCl2
=> 0,32 = 2.0,12 + 2n
CuCl2
=> n
CuCl2
= 0,04 mol = n
Cu

m = m
Cu
+ m
Fe
+ m
O
= 0,04.64 + 0,12.56 + 0,16.16 = 11,84 gam

Cu 11: n
Cl-
= 0,26 mol => m
Cu&Fe
= m
muoi
- m
Cl-
= 16,67 0,26.35,5 = 7,44 gam
n
O2- (oxit )
= n
Cl-
= 0,13 mol => m
Y
= m
Cu&Fe
+ m
O2- (oxit )
= 7,44 +0,13.16 = 9,52 gam

Cu 12: Phn II : BTNT N : n
NO3- ( muoi )
= n
HNO3 p/u
n
NO
= 0,875.0,8 1,568/22,4 = 0,63 mol
Fe Fe(NO
3
)
3
3NO
3
-
Phn I : BTNT Fe : n
Fe
= n
FeCl2
+ n
FeCl3

0,21 0,63 => n
FeCl2
= 0,21 13/162,5 = 0,13 mol => a =
0,13.127 = 16,51 gam
Cu 13: 13,92 gam X ( MgO x mol ; FeO y mol v Fe
2
O
3
z mol ). Ta c : n
O (oxit )
= n
H+
=
.0,52 = 0,26 mol
=> x + y +3z = 0,26 ( 1 ) v 40x + 72y + 160z = 13,92 ( 2 )
Trong 0,27 mol X s mol MgO , FeO v Fe
2
O
3
ln lt l kx , ky v kz mol => kx +
ky + kz = 0,27 ( 3 )
V : n
H2O
= n
H2
= n
O(FeO)
+ n
O(Fe2O3)
= ky +3kz = 0,27 ( 4 ). Bi n i ( 3 ) & ( 4 ) => x =
2z ( 5 )
Gii ( 1) , (2) v ( 5) => x = 0,08 mol ; y = 0,06 mol v z = 0,04 mol => k = 0,27/0,18 =
1,5
BTKL : m = 1,5.13,92 0,27.16 = 16,56 gam

Cu 14: m
S
= 50.22/100 = 11 gam => n
SO4 (2-)
= n
S
= 11/32 = 0,34375 mol (BTNT S )
m
Cu&Fe
= m
muoi
m
SO4(2-)
= 50 96.0,34375 = 17 gam

Cu 15: m
N
= 65,5.16,03/100 = 10,5 gam => n
NO3-
= n
N
= 10,5/14 = 0,75 mol ( BTNT N )
S : 2NO
3


(

mui ) < = > O
2-
(oxit )
2 mol NO
3


to 1 mol O
2-

khi lng gim 2.62 16 = 108 gam
0,75 mol NO
3


to 0,375 mol O
2-

khi lng gim 108.0,375 = 40,5 gam
=> m
oxit
= m
muoi
- m
giam
= 65,5 40,5 = 25 gam

Cu 16: Cu
2+
to phc trong dd amoniac d => cht rn sau cng l Fe
2
O
3
.
BTNT Fe : n
Fe
= n
Fe
+ 3n
Fe3O4
= 0,02 + 0,04.3 = 0,14 mol
=> n
Fe2O3
= n
Fe
= 0,07 mol => a = 0,07.160 = 11,2 gam

Cu 17: BTNT S : n
H2SO4 p/u
= n
SO4 (2-) muoi
+ n
SO2
=> n
SO4 (2-) muoi
= 0,1 0,01 = 0,09 mol
Fe
2
(SO
4
)
3
3SO
4
2-
=> m
muoi
= 0,03.400 = 12 gam
0,03 0,09

Cu 18: C ch 1 : Vit PTHH : n
FeCl2
= 0,67 mol
Fe + 2HCl FeCl
2
+ H
2
(1) Fe + 2FeCl
3
3FeCl
2
( 2 )
0,25 0,25 0,25 0,14 ( 0,67 0,25 = 0,42 )
=> n
Fe
= 0,25 + 0,14 = 0,39 mol => m = 0,39.56 = 21,84 gam
Cch 2: Bo ton electron
Fe Fe
2+
+ 2e 2H
+
+ 2e H
2

x x 2x 0,5 0,25
Fe
3+
+ 1e Fe
2+

0,67 - x 0,67 - x
=> Bo ton electron: 2x = 0,5 + 0,67 x
=> x = 0,39 mol => m = 21,84 gam

Cu 19: Sau phn ng , Cu cn d ( Fe Fe
2+
)
Fe Fe
2+
+ 2e N
+5
+ 3e NO
0,1 0,2 0,42 0,14
Cu Cu
2+
+ 2e
0,11 0,22
=> m = 9,6 0,11.64 = 2,56 gam

Cu 20: m
kh
= 5,4 2,49 = 2,91 gam ( NO x mol v NO
2
y mol ).
Lp h : x + y = 1,456/22,4 = 0,065 mol v 30x + 46y = 2,91 => x = 5.10
-3
mol v y =
0,06 mol
Quy i oxit st thnh Fe ( a mol ) v O ( b mol ) .Ta c : 56a + 16b = 5,4
Fe Fe
3+
+ 3e O + 2e O
2-

N
+5
+ 3e NO N
+5
+
1e NO
2

a 3a b 2b 0,015 5.10
-3
0,06
0,06
Bo ton e: 3a 2b = 0,06 + 0,015. Gii h 2 pt trn : a = b = 0,075 mol = > FeO
BTNT N : n
HNO3 p/u
= n
NO3- muoi
+ n
NO
+ n
NO2
= 3n
FeO
+ n
NO
+ n
NO2
= 0,29 mol

Cu 21: n
Fe
= n
H2
= 0,05 mol ( Fe n cht - khng phi Fe trong oxit ).
Cho vo HNO
3
, quy i 10 gam ( Fe a mol v O b mol ). => 56a + 16b =
10. Bo ton electron :
Fe Fe
3+
+ 3e O + 2e O
2-

N
+5
+ 1e NO
2
=> 3a 2b =
0,25
a 3a b 2b 0,25 0,25
Gii h => a = 0,15 mol = n
Fe
v b = 0,1 mol = n
O(oxit)
=> n
Fe(oxit) =
n
Fe
- n
Fe
= 0,15
0,05 = 0,1 mol => FeO
Cu 22: n
Al
= 2/3 n
H2
= 0,24 mol = n
Al(NO3)3
= > m
AlCl3
= 0,24.133,5 = 32,04 gam
=> m
FeCl3
= m
rn han
m
FeCl2
m
AlCl3
= 151,54 31,75 32,04 = 87,75 gam => n
FeCl3
=
0,54 mol
Cho hn hp vo HNO
3
long d to 2 mui Fe(NO
3
)
3
v Al(NO
3
)
3
. BTNT Al v Fe
ta c :
n
Al(NO3)3
= n
Al
= 0,24 mol v n
Fe(NO3)3
= n
FeCl2
+ n
FeCl3
= 31,75/127 + 0,54 = 0,79 mol
=> m
mui
= 0,24.213 + 0,79.242 = 242,3 gam

Cu 23: n
FeCO3


= n
CO2
= n
BaCO3
= 7,88/197 = 0,04 mol. BTNT Fe : n
Fe
= 2n
Fe2O3
= 0,28
mol
=> n
Fe(oxit)
= 0,28 0,04 = 0,24 mol => m
oxit
= m
X
m
FeCO3
= 23,2 0,04.16 = 18,56
gam
=> n
O (oxit )
= ( 18,56 0,24.56 ) / 16 = 0,32 mol => Fe
3
O
4
.
BTT : n
HCl
= n
H+

= 2n
CO3(2-)
+ 2 n
O (oxit )
= 2.0,04 + 2.0,32 = 0,72 mol => V = 0,72/2 = 0,36 lit =
36O ml

Cu 24: m
FeO
/ m
Fe2O3
= 9/20 => n
FeO
= n
Fe2O3
=> n
FeCl2
= n
FeCl3
= 0,05 mol => m
FeCl2
=
0,05.127 = 6,35 gam
Cu 25: PTHH: Fe
3
O
4
+ 8HCl FeCl
2
+ 2FeCl
3
+ 4H
2
O Fe + 2FeCl
3
3FeCl
2
Fe +
2HCl FeCl
2
+ H
2

0,1 0,8 0,2 0,1 0,2 0,05 0,1
=> n
HCl
= 0,8 + 0,1 = 0,9 mol => V = 0,9 lit

Cu 26: m
tng
= m
CO2
= 52,8 gam => n
O ( b kh )
= n
CO2
= 1,2 mol
=> Khi lng ca qung = m
X
+ m
O
= 300,8 +1,2.16 = 320 gam .BTNT Fe : n
Fe2O3
=
n
Fe(NO3)3
= 0,8 mol
=> % m
Fe2O3
= 0,8.160/320.100% = 40%

Cu 27: BTNT Fe : n
FeO
+ 3n
Fe3O4
= n
Fe(NO3)2
+ n
Fe d
=> n
Fe(NO3)2
= 0,27.180 = 48,6 gam
Cu 28: Fe(NO
3
)
2
Fe
2
O
3
+ 4NO
2
+ O
2
2Fe(NO
3
)
3
Fe
2
O
3
+ 6NO
2
+ 3/2
O
2

a 2a 0,25a a 3a 0,75a
T
1
= ( 46.2a + 32.0,25a ) / ( 2a + 0,25a ) = 400/9
T
2
= ( 46.3a + 32.0,75a ) / ( 3a + 0,75a ) = 43,2 => T
2
/ T
1
= 0,972 = > T
2
= 0,972T
1


Cu 29: Fe(OH)
3
Fe
2
O
3
=> n
Fe2O3
= 7,02/ ( 107 80 ) = 0,26 mol = n
Fe

107 80 => m
Fe
= 0,7m
A
+ 5,6n
e
= 0,7m
A
+ 5,6.2n
SO2
=> m
A
=
19,2 gam

Cu 30: m
rn
= m
BaSO4
= 30,29 gam => n
S(X)
= n
BaSO4
= 0,13 mol. Quy i hn hp thnh
Fe v S
Fe Fe
3+
+ 3e S S
+6
+ 6e N
+5
+ 3e NO
0,1 0,3 0,13 0,78 1,08 0,36
=> a = m
Fe
+ m
S
= 9,76 gam

Cu 31: FeO v Fe
2
O
3
c cng s mol => quy i thnh FeO
4
.Nhm : n
Fe3O4
= n
NO2
=
0,3 mol
=> m = 0,3.232 = 69,6 gam
Cu 32: Cn li kim loi Cu khng tan => ion Fe tn ti trong dung dch sau phn ng
l Fe
2+
.
Quy i hn hp A thnh Cu, Fe v O
Cu Cu
2+
+ 2e Fe Fe
2+
+ 2e O + 2e O
2-

N
+5
+
3e NO
x 2x y 2y z 2z
0,02
Bo ton e : 2x + 2y 2z = 0,02 .Ta c : 64x + 56y +16z = 7,52 0,96 v 188x + 180y =
16,44 (cht rn khan )
Gii h ta c : x = 0,03 ; y = 0,06 v z = 0,08 => n
Fe
: n
O
= y : z = => Fe
3
O
4

Cu 33: CuO Cu(NO
3
)
2
Fe
3
O
4
3Fe(NO
3
)
3

x 2x 2x 6x
Ta c : m
muoi
= 188x + 6x.242 = 41 = > x = 0,025 mol => a = 80.0,025 + 23.0,05 = 13,6
gam