NERACA MASSA

Komponen Natural Gas (Pertamina EP, 2008):

CH4
=
94.36
C2H6
=
2.5
C3H8
=
0.71
C4H10
=
0.06
C5H12
=
0.02
C6H14
=
0.01
N2
=
1.6
CO2
=
0.7
O2
=
0.02
H2S
=
0.02
Total
=
100
Produk Ammoniak

Basis gas alam

mol gas alam

1000
3.333333333
0.138888889
138.8888889
790.5241519
46.53696947

%mol
%mol
%mol
%mol
%mol
%mol
%mol
%mol
%mol
%mol

MR JENIS RATA2
15.0976
0.75
0.3124
0.0348
0.0144
0.0086
0.448
0.308
0.0064
0.006814
16.987014

ton/tahun
ton/ hari 1 tahun
300 hari kerja
ton/jam
kg/jam
kg/jam
0.00093096 mmscfd

DESULFURISASI
Gas Alam
H2S

REAKSI
m
r
s

3H2S+
Fe2O3.6H2O
0.009307 0.002885292
0.008656 0.002885292
0.000652
0

Komponen
Gas Alam
H2S
Fe2O3.6H2O
Fe2S3.6H2O
H2O
TOTAL

INPUT
OUTPUT
790.207
790.207049
0.317103 0.022197204
0.801823
0
0.946116135
0.155805774
791.33
791.33

Fe2S3.6H2O+ 3H2O
0.00288529
0.00288529

SEPARATOR 1

0.008655876
0.008655876

Gas Alam
H2S
Fe2S3.6H2O
H2O

Gas Alam
H2S
H2O

konversi separator
Fe2S3.6H2O
Komponen
Gas Alam
H2S
Fe2S3.6H2O
H2O
TOTAL

INPUT
OUTPUT
790.207
790.207049
0.022197 0.022197204
0.946116 0.946116135
0.155806 0.155805774
791.33
791.33

Final Desulfurizer
Gas Alam
H2S
H2O

Gas Alam
ZnS
H2O

ZnO
Reaksi
m
r
s

H2S +
ZnO
0.000652 0.000651518
0.000652 0.000651518
0
0

Komponen
Gas Alam
H2S
H2O
ZnO
ZnS
TOTAL

Input
Output
790.207
790.207049
0.022197
0
0.155806
0.16753309
0.050297
0
0.06350016
790.4
790.4

ZnS+

H2O

0.00065152
0.00065152

SEPARATOR 2
Gas Alam
H2O
ZnS

0.000651518
0.000651518

ZnS
Komponen
Gas Alam
H2O
ZnS
TOTAL

konversi

100%

Input
Output
999.8
999.8
0.105665 0.105664808
0.04005 0.040050191
999.9
999.9

Primary Reforming
Steam
CO2
N2
CO
H2
O2
CH4
H2O

Gas Alam
H2O

Reaksi yang terjadi :

1. CH4 + H2O --> CO + 3H2
2. C2H6 + 2H2O --> 2CO + 5H2
3. C3H8 + 3H2O --> 3CO + 7H2
4. C4H10 + 4H2O --> 4CO + 9H2
5. C5H12 + 5H2O --> 5CO + 11H2
6. C6H14 + 6H2O --> 6CO + 13H2
7. CO + H2O --> CO2 + H2
Konversi
Kellog Company

Reaksi 1
Reaksi 2
Reaksi 3
Reaksi 4
Reaksi 5
Reaksi 6
Reaksi 7

58%
100%
100%
100%
100%
100%
41%

Reaksi 1
m
r
s

CH4 +
H2O
43.91228 25.46912495
25.46912 25.46912495
18.44316
0

CO+

reaksi 2
m
r
s

C2H6+
2H2O
1.163424 2.326848473
1.163424 2.326848473
0
0

2CO +

3H2

25.4691249
25.4691249

2.32684847
2.32684847

76.40737484
76.40737484

5H2
5.817121184
5.817121184

reaksi 3
m
r
s

C3H8 +
3H2O
0.330412
0.99123745
0.330412
0.99123745
0
0

3CO +

reaksi 4
m
r
s

C4H10 + 4H2O
0.027922 0.111688727
0.027922 0.111688727
0
0

4CO +

reaksi 5
m
r
s

C5H12 + 5H2O
0.009307 0.046536969
0.009307 0.046536969
0
0

5CO +

reaksi 6
m
r
s

C6H14 + 6H2O
0.004654 0.027922182
0.004654 0.027922182
0
0

6CO +

reaksi 7
m
r
s

CO +
H2O
28.97336 11.87907709
11.87908 11.87907709
17.09428
0

CO2 +

Komponen
CH4
C2H6
C3H8
C4H10
C5H12
C6H14
CO
CO2
H2
H2O
N2
O2
total

INPUT
OUTPUT
702.5966 295.0905511
34.90273
14.53815
1.619487
0.670132
0.400218
478.6398865
14.33339 537.0127784
193.661279
2471.889 1736.545031
20.84856 20.84856232
0.297837 0.297836605
3262.096 3262.095925

7H2

0.99123745
0.99123745

2.312887383
2.312887383

9H2

0.11168873
0.11168873

0.251299635
0.251299635

11H2

0.04653697
0.04653697

0.102381333
0.102381333

13H2

0.02792218
0.02792218

0.06049806
0.06049806

H2O

11.8790771
11.8790771

11.87907709
11.87907709

perbandingan mol C:H2O

Steam masuk
Steam masuk
Steam Excess
Steam bereaksi

Secondary Reforming

Udara
CO2
N2
CO
H2
O2
CH4
H2O

Konversi

CO2
N2
CO
H2
O2
CH4
H2O

98%

Reaksi 1
m
r
s

2CH4 +
O2
18.44316 9.037148127
18.0743 9.037148127
0.368863
0

2CO +

Reaksi 2

CH4 +
H2O
0.368863
0.3615
0.0074

CO+

Reaksi 3

Reaksi 4

Reaksi 5

Komponen
CH4
CO
CO2
H2
H2O
N2
O2
TOTAL

18.0742963
18.0742963

0.3615
0.3615
0.0000

36.14859251
36.14859251
3H2

0.3615
0.3615

CO+
H2O
35.53006 34.81946256
34.81946 34.81946256
0.710601
0

CO2 +

2CO +
O2
0.710601 0.348194626
0.696389 0.348194626
0.014212
0

2CO2

2H2+
O2
96.83064 47.44701336
94.89403 47.44701336
1.936613
0

2H2O

INPUT
OUTPUT
295.0906
0.11803622
478.6399 0.397936715
537.0128 2099.710258
193.6613 147.9782513
1736.545 2811.380439
6007.19 6007.190073
1818.933 0.297836605
11067.07 11067.07283

4H2

34.8194626
34.8194626

1.084457775
1.084457775
H2
34.81946256
34.81946256

0.69638925
0.69638925

94.8940267
94.8940267

TOTAL O2 dari udara

N2 dari udara
O2 yang bereaksi
H2O yag bereaksi

HTS
CO2
N2
CO
H2
O2
CH4
H2O
Konversi

CO2
N2
CO
H2
O2
CH4
H2O
85.10%

Reaksi
m
r
s

CO +
H2O
CO2 +
H2
0.014212 0.012094434
0.012094 0.012094434 0.012094 0.01209443
0.002118
0 0.012094 0.01209443

Komponen
CH4
CO
CO2
H2
H2O
N2
O2
TOTAL

INPUT
OUTPUT
0.118036
0.11803622
0.397937 0.059292571
2099.71 2100.242413
147.9783 148.0024401
2811.38 2811.162739
6007.19 6007.190073
0.297837 0.297836605
11067.07 11067.07283

H2O yang bereaksi

LTS
CO2
N2
CO
H2
O2
CH4
H2O

konversi
reaksi
M

CO2
N2
CO
H2
O2
CH4
H2O

92.60%
CO +
H2O
0.002118
0.00196089

CO2 +

H2

R
S

Komponen
CH4
CO
CO2
H2
H2O
N2
O2
TOTAL

0.001961
0.000157

0.00196089
0

0.00196089
0.00196089

INPUT
OUTPUT
0.118036
0.11803622
0.059293
0.00438765
2100.242 2100.328693
148.0024 148.0063619
2811.163 2811.127443
6007.19 6007.190073
0.297837 0.297836605
11067.07 11067.07283

0.00196089
0.00196089

H2O yang dibutuhkan

CO2 Absorber
2

CO2
N2
CO
H2
O2
CH4
H2O

K2CO3
H2O

4 CO2
N2
CO
H2
O2
CH4
H2O

3
KHCO3

Reaksi
m
r
s

Komponen
CH4
CO
CO2
H2
H2O
N2
O2
K2CO3
KHCO3
TOTAL

CO2
H2O +
K2CO3
47.73474 47.25739558 47.2574
47.2574 47.25739558 47.2574
0.477347
0
0

INPUT
1
2
0.118036
0.004388
2100.329
148.0064
2811.127 850.6331205
6007.19
0.297837
6521.52059
18439.22654

OUTPUT
3
4
0.11803622
0.00438765
21.0032869
148.006362
2811.12744
6007.19007
0.2978366
9451.479
18439.22654

2KHCO3
94.51479116
94.51479116

CO2 Stripper
K2CO3
H2O
KHCO3

CO2

Reaksi
m
r
s

2KHCO3
94.51479
94.51479
0

CO2

Komponen
KHCO3
K2CO3
H2O
CO2
TOTAL

INPUT
OUTPUT
9451.479
6521.52059
850.6331205
2079.325406
9451.479 9451.479116

H2O

K2CO3

47.2574 47.2573956
47.2574 47.2573956

47.25739558
47.25739558

Methanator
CO2
N2
CO
H2
O2
CH4
H2O
Reaksi 1
m
r
s

CO +
3H2
0.000122 0.000365638
0.000122 0.000365638
0
0

N2
H2
O2
CH4
H2O

CH4 +
0.00036564
0.00036564

H2O
0.000365638
0.000365638

Reaksi 2
m
r
s

CO2 +
4H2
0.477347
1.90938972
0.477347
1.90938972
0
0

Komponen
CO
CO2
H2
CH4
N2
O2
H2O
TOTAL

INPUT
OUTPUT
0.004388
0
21.00329
0
148.0064 144.1868512
0.118036 7.761445303
6007.19 6007.190073
0.297837 0.297836605
2811.127 2828.318532
8987.747 8987.754739

CH4 +

2H2O

0.47734743
0.47734743

0.95469486
0.95469486

Syntesis Loop (Ammonia Converter)

NH3
N2
H2
O2
CH4
H2O

N2
H2
O2
CH4
H2O
Reaksi
m
r
s

3H2 +
N2
72.09343 4.085294118
12.25588 4.085294118
59.83754
0

Komponen
N2
H2
O2
CH4
H2O
NH3
TOTAL

INPUT
OUTPUT
6007.19 5892.801838
144.1869 119.6750865
0.297837 0.297836605
7.761445 7.761445303
2828.319 2828.318532
138.9
8987.755 8987.754739

2NH3

konversi H2

8.17058824
8.17058824
N2 yang dibutuhkan

Chiller
NH3
N2
H2

CH4
N2
2 H2

O2
CH4
H2O

O2
H2O
3
NH3

Komponen
N2
H2
O2
CH4
H2O
NH3
TOTAL

INPUT
1
5892.802
119.6751
0.297837
7.761445
2828.319
138.9
8987.755

OUTPUT
2
5892.801838
119.6750865
0.297836605
7.761445303
2828.318532

138.9 kg/jam

1000.08

8987.754739

SEPARATOR 3
CH4
N2
H2
O2
H2O

CH4
1
2 N2
O2
H2O
3
H2

Komponen

INPUT

OUTPUT

N2
H2
O2
CH4
H2O
TOTAL

1
5892.802
119.6751
0.297837
7.761445
2828.319
8848.855

2
5892.801838

Fresh

YANG AKAN DI RECYCLE

119.6751
0.297836605
7.761445303
2828.318532
8848.854739
119.6751 kg/jam
59.83754 mol

mol
MR
43.91228
1.163424
0.330412
0.027922
0.009307
0.004654
0.744592
0.325759
0.009307
0.009307

massa
702.5966
34.90273
14.53815
1.619487
0.670132
0.400218
20.84856
14.33339
0.297837
0.317103
790.5242

16
30
44
58
72
86
28
44
32
34.07

Gas Alam
Fe2S3.6H20
H2O
H2S
konversi
MR
Fe2O3.6H2O
Fe2S3.6H2O
H2O

93%

277.9
327.91
18

kg/jam
kg/jam
kg/jam
kg/jam
kg/jam
kg/jam
kg/jam
kg/jam
kg/jam
kg/jam
kg/jam

100%

konversi
MR
ZnO
ZnS
H2O

Gas Alam
H2O

100%

77.2
97.465
18

1:03
137.3213 kmol
2471.889 kg/jam
1736.545
735.3438

56.83236
213.7979
56.83236
633.2571

kmol
kmol
kmol
kg/jam

0.2177 kg/jam

0.035296 kg/jam

Mr K2CO3
Mr KHCO3

138
100

KONVERSI

99%

konversi

100%

konversi
Mr CO

100% H2 yang dibuthkan

36

3.819511

nverter)

17%

114.3882

ton/tahun